CN102976850A - Special fertilizer for rice and preparation method thereof - Google Patents
Special fertilizer for rice and preparation method thereof Download PDFInfo
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- CN102976850A CN102976850A CN2012105270949A CN201210527094A CN102976850A CN 102976850 A CN102976850 A CN 102976850A CN 2012105270949 A CN2012105270949 A CN 2012105270949A CN 201210527094 A CN201210527094 A CN 201210527094A CN 102976850 A CN102976850 A CN 102976850A
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Abstract
The invention relates to a special fertilizer for rice and a preparation method thereof. The special fertilizer is characterized by comprising the components by weight percent: 20-25% of biomass power generation waste, 2-5% of biological black charcoal, 30-38% of urea, 20-25% of ammonium dihydrogen phosphate, 15-20% of potassium chloride and 5-10% of binder in a manner of adding water to pelletize. The preparation method comprises the steps of: mixing the biomass power generation waste with the black charcoal, adding the binder to evenly mix, and then adding the ammonium dihydrogen phosphate and water to evenly mix; and adding the potassium chloride and the urea, and pelletizing by a disc granulator. The pH of the prepared fertilizer is about 6; the defects that the traditional ammonium dihydrogen phosphate is easy to volatilize and the smell is smoky are avoided; the moisture content is 7.19%; and the volume-weight is 5.32g/cm<3>, and the defect that the urea is easy to deliquate is also overcome.
Description
Technical field
The present invention relates to a kind of paddy rice specialty fertilizer that biomass power generation waste and biological black wood charcoal make and preparation method thereof that utilizes.
Background technology
At present, China low yield is ploughed and is accounted for 75% of cultivated area, and oeverall quality is not good enough, and organic content is lower than 1.5% arable land and accounts for 65% of the total area.The annual agricultural crop straw total amount that produces is about 700,000,000 tons, and wherein large agricultural crop straws such as paddy rice, wheat, corn are about 500,000,000 tons.The approach that the active and effective conversion conduct of agricultural wastes increases the remittance reduction of discharging obtains the extensive attention of international scientific circle, agricultural crop straw can be reduced waste discharge through the biological black wood charcoal that the cracking of biomass body heat transforms formation, the development of promotion circular agriculture.
Biomass power generation utilizes the biomass waste combustion power generations such as agricultural crop straw, have that the quality of power supply is good, reliability is high, than the good characteristics of the intermittent generating such as small power station, wind-powered electricity generation and solar electrical energy generation, biomass direct-fired formula generating produces a large amount of ash, along with the development of biomass power generation, this accumulation and stacking take the plant ash as main waste is the limiting factor that affects the sustainable development of biomass power generation industry.This waste contains abundant nitrogen, phosphorus, potassium, to the recycling of these wastes, both can avoid polluting, and can make the waste increment by enlarging the secondary production capacity again.
Summary of the invention
The objective of the invention is to make a kind of paddy rice-dedicated fertilizer material take biomass power generation waste and biological black wood charcoal as main raw material, energy-conserving and environment-protective are that paddy growth improves nutrient, improve the output of paddy rice.
Another object of the present invention is to provide a kind of preparation method of paddy rice-dedicated fertilizer material.
To achieve these goals, the present invention by the following technical solutions
A kind of paddy rice-dedicated fertilizer is characterized in that comprising following component by weight percentage: 20%-25% biomass power generation waste, the biological black wood charcoal of 2%-5%, 30%-38% urea, 20%-25% primary ammonium phosphate, 15%-20% Repone K and 5%-10% tackiness agent add the water granulation and form.
Tackiness agent is red soil, and the addition of tackiness agent and moisture all can affect size and the compactedness of granulation, so tackiness agent is the 5-10% of gross weight; The interpolation weight of moisture is the 1%-5% of gross weight, and it is too many to add water, and then tack of materials is too large, can't granulation; Add water very little, then material is loose, and granulation can not be shaped.
A kind of preparation method of paddy rice-dedicated fertilizer material is characterized in that first biomass power generation waste and black wood charcoal being mixed, and adds tackiness agent, mixes rear adding primary ammonium phosphate, water, mixes; Add again afterwards Repone K and urea, adopt the disc-type granulating machine granulation.
Because power station waste and biological black wood charcoal are alkalescence, and the water-retaining capacity of urea is strengthened under alkaline condition, and can cause the volatilization of ammonium, and then weakens the fertilizer efficiency of fertilizer.Invention mixes power station waste and biological black wood charcoal first with tackiness agent and the primary ammonium phosphate of acidity, pH adds Repone K and urea after transferring to about 6 again, will reduce like this volatilization of ammonium.The process need of simultaneously granulation carries out at normal temperatures, so also can reduce nitrogen loss.
Biological black wood charcoal surface porosity, porous that the present invention adopts, have larger specific surface area and adsorptivity, fine granularity biomass power plant waste has stronger water-absorbent, the fertilizer of preparation is particulate state, diameter is 3-4mm, pH is about 6, the shortcoming of avoided traditional primary ammonium phosphate to be easy to volatilize, smell being choked the people; Water content is 7.19%, and unit weight is 5.32g/cm
3, overcome the shortcoming that urea itself is easy to deliquescence.
Table 1 is the contained component of biomass power generation waste and physical and chemical index table, and wherein silicone content is higher, and silicon is the beneficial element of paddy growth.Practice shows that silicon has important effect to Rice Photosynthesis, enhancing plant intensity, the plant type of improving, raising to the aspects such as resistance, alleviation heavy metallic poison and raising output of lodging and disease and pest.
The contained component of table 1 biomass power generation waste and physical and chemical index
The particle diameter of biological black wood charcoal has certain adsorptivity less than 0.25 mm, can increase the compactedness of gained particle in the granulation process.And because biological black wood charcoal density is little, if consumption is too large, then greatly finally cause the granulation failure because of the shared volume of biological black wood charcoal; And the ash element that biological black wood charcoal contains such as K, Ca, Mg are soluble state, thereby increase the content of soil ash element.Magnesium is the essential element of crop growth, is the composition of chlorophyll and hormone, is the activator of plurality of enzymes in the plant materials, can promote the synthetic of protein, to the photosynthesis important, can promote the growth of paddy rice, improves rice yield.
Biological black wood charcoal not only contains a large amount of element silicons, contains simultaneously the organic matter of high level, abundant phosphorus, potassium element (seeing Table 2).Organic matter helps to improve the quality problems of soil.And potassium element can improve the leaf photosynthesis characteristic, delays to bloom to ripening period functional leaf and Senescence of Root System.The researchs such as Yin Wen think, execute potassium and make rice tillering early, and the middle and later periods blade is blue or green elegant, and life has enlarged photosynthetic area, has improved photosynthetic productivity, is conducive to form more photosynthate, have promoted the grouting, solid of seed.
Table 2 is the contained component of biological black wood charcoal and physical and chemical index tables that wheat stalk is made
In a word, the paddy rice-dedicated fertilizer material that the present invention obtains both can improve soil quality, increased soil organic matter content, can take full advantage of biomass power generation waste and straw refuse again, turned waste into wealth, and product has wide market outlook.
Embodiment
The black wood charcoal that following examples adopt is available from the sharp new forms of energy in Henan three company limited, and particle diameter is less than 0.25mm; The biomass power generation waste is from Anhui Province state auspicious biomass power generation company, and pH is greater than 10; Urea comes to Xilong Chemical Co., Ltd to Jinhuada Chemical Agent Co., Ltd., Guangzhou City, primary ammonium phosphate and Repone K; Tackiness agent red soil is taken from the Chizhou City, Anhui.
Embodiment 1
A kind of paddy rice-dedicated fertilizer comprises following component by weight percentage: biomass power generation waste 21%, biological black wood charcoal 3%, urea 34%, primary ammonium phosphate 20%, Repone K 16%; Red soil 6%; Account for the water of gross weight 10%, carry out granulation, obtain character such as the table 3 of paddy rice-dedicated fertilizer material.
Table 3
As seen from Table 3, compound fertilizer dedicated to paddy total nutrient, water-soluble phosphorus and the granularity for preparing all belongs to the high density of national standard, and chloride ion content is on the low side, this shows that this is a kind of composite fertilizer of high-quality.
After embodiment 2 uses different fertilizer, the comparative experiments of organic matter in the paddy soil
Take the paddy rice-dedicated fertilizer material of making of embodiment 1 as sample (sample sets), according to 250 kilograms of per hectare purity nitrogens for during base manure is manured into soil, with live form rice cultivation, rice varieties is No. 11, Zhenjiang, the blank group (CK group) of not adding any fertilizer is set simultaneously, also has conventional fertilizer contrast (conventional fertilizer is according to urea: the weight ratio of primary ammonium phosphate: Repone K=17:10:8 mixes, with the fertiliser mixtures of the present invention except biological black wood charcoal and tackiness agent).Before paddy rice enters tillering phase, sample, the soil after the plantation carried out organic mensuration, the result of mensuration such as following table 4:
The content of table 4 rice soil organic matter
Organic (g/kg) | |
The blank group | 51.42 |
Sample sets | 53.17 |
Conventional fertilizer group | 50.09 |
The soil organic matter content of sample sets and blank group content do not have significant difference in the table 4, and with conventional fertilizer group significant difference, and the content difference of conventional fertilizer group and blank group is not remarkable.As seen, add the paddy rice-dedicated fertilizer material, increased the content of soil with organic matter, thereby improved the quality of soil.
After embodiment 3 uses different fertilizer, the comparative experiments of nitrogen content in the paddy soil
Sample sets is used the paddy rice-dedicated fertilizer material that the ratio of embodiment 1 is made, according to 250 kilograms of per hectare purity nitrogens for during base manure is manured into soil, with live form rice cultivation, rice varieties is No. 11, Zhenjiang, the blank group of not adding any fertilizer is set simultaneously, also has conventional fertilizer control group (conventional fertilizer is according to urea: the ratio of primary ammonium phosphate: Repone K=17:10:8 mixes).Before paddy rice enters tillering phase, sample, the soil after the plantation carried out the mensuration of full nitrogen and ammonium nitrogen, the result of mensuration such as following table 4:
The content of the full nitrogen of table 4 rice soil and ammonium nitrogen
Ammonium nitrogen (mg/kg) | Full nitrogen (g/kg) | |
The blank group | 832.15 | 5.15 |
Sample sets | 4759.35 | 5.29 |
Conventional fertilizer group | 5151.82 | 5.31 |
As known from Table 4, the total nitrogen content of sample sets and conventional fertilizer control group is suitable, and all is higher than the blank group; The plant absorbing nitrogen is that the form with ammonium nitrogen absorbs, and the content of conventional fertilizer group ammonium nitrogen is higher than sample sets, and the nitrogen in the soil of illustrative experiment group is adsorbed fixing.Be because biological black wood charcoal porous surface has adsorptivity, the nitrogen in the energy adsorption fertilizer makes fertilizer have slow-releasing, can be released along with the growth of paddy rice, reduces the loss of Nitrogen.
After embodiment 4 uses different fertilizer, the comparative experiments of nitrogen content in the paddy rice
Experiment condition separates paddy rice over-ground part and underground part with embodiment 5, after the oven dry two-part full nitrogen is measured, and the result is as shown in table 5:
Table 5
The full nitrogen of overground part (%) | The full nitrogen of underground part (%) | Total Total nitrogen (%) | |
The blank group | 1.26 | 3.62 | 4.88 |
Sample sets | 1.76 | 4.74 | 6.50 |
Conventional fertilizer group | 1.76 | 3.62 | 5.38 |
We can find out from upper table, the total nitrogen content of the paddy rice over-ground part of sample sets and conventional fertilizer group all is higher than the blank group, and in the total nitrogen content of paddy rice underground part, conventional fertilizer group is identical with blank group content, and the total nitrogen content of sample sets is than they height.The conventional fertilizer of this explanation paddy rice helps rice absorbing nitrogen, has improved the utilising efficiency of nitrogenous fertilizer.
Embodiment component that 5-7 adopts sees Table 6:
Table 6
Claims (4)
1. a paddy rice-dedicated fertilizer is characterized in that comprising that biomass power generation waste, biological black wood charcoal, urea, primary ammonium phosphate, Repone K and tackiness agent add the water granulation and form.
2. paddy rice-dedicated fertilizer according to claim 1 is characterized in that comprising following component by weight percentage: 20%-25% biomass power generation waste, the biological black wood charcoal of 2%-5%, 30%-38% urea, 20%-25% primary ammonium phosphate, 15%-20% Repone K and 5%-10% tackiness agent add the water granulation and form.
3. paddy rice-dedicated fertilizer according to claim 1 is characterized in that tackiness agent is red soil.
4. the preparation method of claim 1 or 2 each described paddy rice-dedicated fertilizer material is characterized in that first biomass power generation waste and black wood charcoal being mixed, and adds tackiness agent, mixes rear adding primary ammonium phosphate, water, mixes; Add again afterwards Repone K and urea, adopt the disc-type granulating machine granulation.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103304318A (en) * | 2013-06-19 | 2013-09-18 | 王石麟 | Rice seedling toughening matrix and production method thereof |
CN104496630A (en) * | 2014-11-06 | 2015-04-08 | 国家林业局竹子研究开发中心 | Fertilizer special for paddy rice and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1106366A (en) * | 1994-02-02 | 1995-08-09 | 广州农药厂 | Organic and inorganic mixed fertilizer containing azotobacteria and its prodn. method |
CN102765998A (en) * | 2012-06-27 | 2012-11-07 | 南京农业大学 | Acid soil conditioner prepared by biomass power generation waste and preparation method of acid soil conditioner |
-
2012
- 2012-12-10 CN CN2012105270949A patent/CN102976850A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1106366A (en) * | 1994-02-02 | 1995-08-09 | 广州农药厂 | Organic and inorganic mixed fertilizer containing azotobacteria and its prodn. method |
CN102765998A (en) * | 2012-06-27 | 2012-11-07 | 南京农业大学 | Acid soil conditioner prepared by biomass power generation waste and preparation method of acid soil conditioner |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103304318A (en) * | 2013-06-19 | 2013-09-18 | 王石麟 | Rice seedling toughening matrix and production method thereof |
CN104496630A (en) * | 2014-11-06 | 2015-04-08 | 国家林业局竹子研究开发中心 | Fertilizer special for paddy rice and preparation method thereof |
CN104496630B (en) * | 2014-11-06 | 2017-04-12 | 国家林业局竹子研究开发中心 | Fertilizer special for paddy rice and preparation method thereof |
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Application publication date: 20130320 |