CN102976771A - High temperature resistant lightweight heat insulation castables - Google Patents
High temperature resistant lightweight heat insulation castables Download PDFInfo
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- CN102976771A CN102976771A CN2012104628468A CN201210462846A CN102976771A CN 102976771 A CN102976771 A CN 102976771A CN 2012104628468 A CN2012104628468 A CN 2012104628468A CN 201210462846 A CN201210462846 A CN 201210462846A CN 102976771 A CN102976771 A CN 102976771A
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Abstract
Disclosed is high temperature resistant lightweight heat insulation castables. Substrate raw materials and the weight percentage are as follows: 53-60% of main substrate particles with the average particle size less than or equal to 7 millimeters, 25-32% of main substrate fine powder which can pass through a target screen mesh not less than 200, 5-10% of ultrafine powder with the average particle size less than or equal to 10 microns, and 6-7% of aluminate cement. The sum of the weight of the substrate raw materials is an entirety, compound water-reducing agents need to be added besides the substrate raw materials, and the weight of the compound water-reducing agents is 0.1-1% of that of the entirety. Besides the substrate raw materials, polystyrene spheres need to be added, the average particle size of the polystyrene spheres is 1-0.5 millimeter, and the weight of the polystyrene spheres is 1-3% of that of the entirety. The high temperature resistant lightweight heat insulation castables can be used as working lining of a thermal furnace which does not contact with molten liquid, the use temperature is from 1250-1650 DEG C according to different main substrates, and the volume density of the high temperature resistant lightweight heat insulation castables can be 1.2-1.7g/cm<3> by adding burning articles with different quantities.
Description
Technical field
The present invention relates to technical field of refractory materials, especially relate to a kind of high temperature resistant adiabatic mould material of burning lost article of adding.
Background technology
General light thermal insulation mould material is to utilize aglite as the gathering materials of mould material, and makees wedding agent with aluminate cement.Aglite has waste light brick sand, haydite, perlite and alumina hollow ball, waste light brick sand wherein, haydite, perlite class light thermal insulation mould material can be according to the regulating working conditions production method, be prepared into the mould material of various volume densities, be lining with at the not too high thermotechnical furnace of temperature and be widely used, oil refining lining material such as petrochemical complex, but on the Thermal Equipment of some temperature higher (>1250 ℃), just can not use as working lining, this is because on the very high Thermal Equipment of temperature, such as metal melting equipment, materials is difficult to satisfy service requirements as thermofin.Alumina hollow ball is as the light thermal insulation mould material of aglite, and volume density can be controlled at 1.5 ~ 1.7g/cm
3, can be applicable to use on the Thermal Equipment of comparatively high temps, but this type of high temperature resistant mould material thermal shock resistance to be poor, thermal conductivity is again to be difficult to meet the demands, workability is poor, and expensive.
Utilize to burn mistake method production definition thermal insulation material and grasped very early, such as volume density at 0.5 ~ 1.5g/cm
3, refractory temperature turns etc. at 1250 ~ 1650 ℃ of poly-hydrogen mullite insulating fire bricks, the lightweight corundum that utilizes the oil incipient scorch to lose, burn the mistake method and produce the adiabatic mould material of heat-resistant light and be not mentioned but utilize.
Summary of the invention
For the problems referred to above that prior art exists, the applicant provides a kind of heat-resistant light adiabatic mould material.This mould material can be used as the thermal kiln furnace working lining that does not contact melt liquid, and from 1250 ~ 1650 ℃, by adding the burning lost articles of different amounts, the adiabatic mould material volume density of this heat-resistant light can be 1.2 ~ 1.7g/cm to use temperature according to the difference of main base material
3
Technical scheme of the present invention is as follows:
The adiabatic mould material of a kind of heat-resistant light, base material raw material and weight percent thereof are:
Main substrate particles: mean particle size≤7mm, 53 ~ 60%;
Main base material fine powder: can cross and be not less than 200 purpose screen clothes, 25 ~ 32%;
Ultrafine powder: mean particle size≤10 μ m, 5 ~ 10%;
Aluminate cement: 6 ~ 7%;
The weight sum of above-mentioned base material raw material is as a whole, will add composite water-reducing agent outside above-mentioned base material raw material, and weight is 0.1 ~ 1% of described overall weight; Will add the polystyrene ball outside above-mentioned base material raw material, mean particle size is 1 ~ 0.5mm, and weight is 1 ~ 3% of described overall weight;
Described main base material can be for flint clay, kyanite, bauxitic clay grog, mullite or corundum at least a;
Described ultrafine powder is Reactive alumina or active SILICA FUME.
The adiabatic mould material of this heat-resistant light is concrete preparation method mix above-mentioned each raw material to stir.Described aluminate cement is selected high-alumina cement or aluminous cement.
The technique effect that the present invention is useful is:
The present invention utilizes to burn the adiabatic mould material of mistake method production heat-resistant light, its ultimate principle is to regulate grain composition in the various refractory castablies of original tested recipe, and add a certain amount of burning lost article (polystyrene spheres), by regulating the add-on of burning lost article, satisfy workability on the mobile basis that guarantees original prescription mould material, form the light thermal insulation mould material of different volumes density and heat-proof quality.Burn lost article behind this mould material casting and burn mistake in the process of baker, thereby cause porous, except volume density descended, other fundamental propertys of material were constant.
When the mould material use temperature was not higher than 1350 ℃, main base material can be flint clay, conventional aluminium bauxite clinker; When the mould material use temperature was higher than 1350 ℃, main base material can be superfine bauxitic clay grog, mullite or corundum.
Embodiment
Embodiment 1
The molten aluminium stove of making a kind of aluminum products company is with bell working lining (ρ=1.3g/cm
3), its bell long term operation temperature is 1000 ~ 1300 ℃ of fluctuations, and employed raw material and each raw material weight are as shown in table 1, and each raw material mixes and gets final product in will showing.
Table 1
Embodiment 2
Make a kind of cupola forehearth bell adiabatic mould material (ρ=1.5g/cm of high-alumina lightening of Foundry Inc.
3), its bell long term operation temperature-stable is at 1450 ℃, and employed raw material and each raw material weight are as shown in table 2, and each raw material mixes and gets final product in will showing.
Table 2
Embodiment 3
Make a kind of ethane cracking furnace corundum light thermal insulation mould material (ρ=1.2g/cm of petro-chemical corporation
3), its long term operation temperature-stable requires material SiO at 1350 ℃
2Content ≯ 0.2%, employed raw material and each raw material weight are as shown in table 3, and each raw material mixes and gets final product in will showing.
Table 3
Claims (3)
1. the adiabatic mould material of a heat-resistant light, it is characterized in that: base material raw material and weight percent thereof are:
Main substrate particles: mean particle size≤7mm, 53 ~ 60%;
Main base material fine powder: can cross and be not less than 200 purpose screen clothes, 25 ~ 32%;
Ultrafine powder: mean particle size≤10 μ m, 5 ~ 10%;
Aluminate cement: 6 ~ 7%;
The weight sum of above-mentioned base material raw material is as a whole, will add composite water-reducing agent outside above-mentioned base material raw material, and weight is 0.1 ~ 1% of described overall weight; Will add the polystyrene ball outside above-mentioned base material raw material, mean particle size is 1 ~ 0.5mm, and weight is 1 ~ 3% of described overall weight;
Described main base material can be for flint clay, kyanite, bauxitic clay grog, mullite or corundum at least a;
Described ultrafine powder is Reactive alumina or active SILICA FUME.
2. the adiabatic mould material of heat-resistant light according to claim 1 is characterized in that concrete preparation method mixes above-mentioned each raw material to stir.
3. the adiabatic mould material of heat-resistant light according to claim 1 is characterized in that described aluminate cement selects high-alumina cement or aluminous cement.
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CN102976771B CN102976771B (en) | 2014-10-22 |
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CN103319186A (en) * | 2013-05-24 | 2013-09-25 | 霍山县新裕炉窑模具有限公司 | Aluminum melting furnace cast refractory material and preparation method thereof |
CN103803993A (en) * | 2014-01-08 | 2014-05-21 | 长兴明晟冶金炉料有限公司 | Self-flow castable of corundum |
CN103936449A (en) * | 2014-04-23 | 2014-07-23 | 武汉钢铁(集团)公司 | High-strength micro-expansive heat preservation material |
CN104193354A (en) * | 2014-08-08 | 2014-12-10 | 上海利尔耐火材料有限公司 | Permanent layer casting material of tundish and preparation method of permanent layer casting material |
CN104311086A (en) * | 2014-10-28 | 2015-01-28 | 宁夏天纵泓光余热发电技术有限公司 | Light magnesium slag refractory castable |
CN104944898A (en) * | 2015-06-24 | 2015-09-30 | 陈威宇 | High-performance light castable |
CN105130459A (en) * | 2015-07-11 | 2015-12-09 | 郑州汇特耐火材料有限公司 | Aluminum-use anode carbon roasting furnace fire path wall burning-free prefabricated big brick |
CN105503216A (en) * | 2015-12-24 | 2016-04-20 | 中钢集团洛阳耐火材料研究院有限公司 | Preparation method of light and high-strength alumina bubble product |
CN106045353A (en) * | 2016-05-31 | 2016-10-26 | 无锡锡能锅炉有限公司 | Cement for high-temperature-resistant gas boiler |
CN106830958A (en) * | 2017-03-21 | 2017-06-13 | 北京兰海金诚耐火材料有限责任公司 | A kind of low aluminum heat conduction Alkali resistant castable refractory |
CN107573098A (en) * | 2017-09-01 | 2018-01-12 | 武汉钢铁有限公司 | A kind of lightweight castable for sintering ignition furnace |
CN107759233A (en) * | 2016-08-19 | 2018-03-06 | 张丽媛 | A kind of insulated pouring material |
CN108675809A (en) * | 2018-07-02 | 2018-10-19 | 中钢集团洛阳耐火材料研究院有限公司 | A kind of Ultralight corundum castable and preparation method thereof |
CN109020582A (en) * | 2018-09-29 | 2018-12-18 | 武汉钢铁有限公司 | A kind of ladle heat insulation castable and its application |
CN110423129A (en) * | 2019-08-27 | 2019-11-08 | 北京利尔高温材料股份有限公司 | A kind of heating furnace partition wall hanger brick castable |
CN110436858A (en) * | 2019-08-15 | 2019-11-12 | 成都三强轧辊股份有限公司 | A kind of large H-shaped steel collars end cap concrete and its application method |
CN111004044A (en) * | 2019-12-26 | 2020-04-14 | 上海宝九和耐火材料有限公司 | Lightweight refractory castable for petrochemical industry |
CN111116218A (en) * | 2020-02-18 | 2020-05-08 | 巩义市瑞东耐火材料有限公司 | Acid-corrosion-resistant high-strength combined block for circulating fluidized bed boiler lining |
CN113800926A (en) * | 2021-09-26 | 2021-12-17 | 中钢洛耐科技股份有限公司 | Thermal insulation material and preparation method thereof |
CN116178031A (en) * | 2022-12-27 | 2023-05-30 | 上海利尔耐火材料有限公司 | Insulating layer castable for aluminum ash rotary kiln and preparation method thereof |
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CN1830903A (en) * | 2005-03-10 | 2006-09-13 | 宜兴市张泽耐火材料厂 | Refractory fibre pouring material and its prodn, method |
CN102381880A (en) * | 2011-07-25 | 2012-03-21 | 郑州京华耐火材料实业有限公司 | Corundum-mullite light brick and preparation method thereof |
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CN1762906A (en) * | 2004-10-21 | 2006-04-26 | 宜兴市炉顶密封工程公司耐火保温厂 | Corundum-mullite heat-insulating brick |
CN1830903A (en) * | 2005-03-10 | 2006-09-13 | 宜兴市张泽耐火材料厂 | Refractory fibre pouring material and its prodn, method |
CN102381880A (en) * | 2011-07-25 | 2012-03-21 | 郑州京华耐火材料实业有限公司 | Corundum-mullite light brick and preparation method thereof |
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CN103319186B (en) * | 2013-05-24 | 2014-12-17 | 霍山县新裕炉窑模具有限公司 | Aluminum melting furnace cast refractory material and preparation method thereof |
CN103319186A (en) * | 2013-05-24 | 2013-09-25 | 霍山县新裕炉窑模具有限公司 | Aluminum melting furnace cast refractory material and preparation method thereof |
CN103803993A (en) * | 2014-01-08 | 2014-05-21 | 长兴明晟冶金炉料有限公司 | Self-flow castable of corundum |
CN103803993B (en) * | 2014-01-08 | 2015-09-09 | 长兴明晟冶金炉料有限公司 | Corundum gravity flow pouring material |
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CN103936449A (en) * | 2014-04-23 | 2014-07-23 | 武汉钢铁(集团)公司 | High-strength micro-expansive heat preservation material |
CN104193354A (en) * | 2014-08-08 | 2014-12-10 | 上海利尔耐火材料有限公司 | Permanent layer casting material of tundish and preparation method of permanent layer casting material |
CN104311086A (en) * | 2014-10-28 | 2015-01-28 | 宁夏天纵泓光余热发电技术有限公司 | Light magnesium slag refractory castable |
CN104944898A (en) * | 2015-06-24 | 2015-09-30 | 陈威宇 | High-performance light castable |
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CN105503216B (en) * | 2015-12-24 | 2019-04-12 | 中钢集团洛阳耐火材料研究院有限公司 | A kind of preparation method of high-strength light alumina hollow ball product |
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CN109020582A (en) * | 2018-09-29 | 2018-12-18 | 武汉钢铁有限公司 | A kind of ladle heat insulation castable and its application |
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CN111004044A (en) * | 2019-12-26 | 2020-04-14 | 上海宝九和耐火材料有限公司 | Lightweight refractory castable for petrochemical industry |
CN111116218A (en) * | 2020-02-18 | 2020-05-08 | 巩义市瑞东耐火材料有限公司 | Acid-corrosion-resistant high-strength combined block for circulating fluidized bed boiler lining |
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