CN110423129A - A kind of heating furnace partition wall hanger brick castable - Google Patents

A kind of heating furnace partition wall hanger brick castable Download PDF

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Publication number
CN110423129A
CN110423129A CN201910799972.4A CN201910799972A CN110423129A CN 110423129 A CN110423129 A CN 110423129A CN 201910799972 A CN201910799972 A CN 201910799972A CN 110423129 A CN110423129 A CN 110423129A
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CN
China
Prior art keywords
mullite
partition wall
heating furnace
millimeter
hanger brick
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Pending
Application number
CN201910799972.4A
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Chinese (zh)
Inventor
王新杰
张晓波
赵冉
杨少康
丁海瑞
刘丽
颜浩
任林
赵伟
赵现华
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Beijing Lier High Temperature Materials Co Ltd
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Beijing Lier High Temperature Materials Co Ltd
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Publication date
Application filed by Beijing Lier High Temperature Materials Co Ltd filed Critical Beijing Lier High Temperature Materials Co Ltd
Priority to CN201910799972.4A priority Critical patent/CN110423129A/en
Publication of CN110423129A publication Critical patent/CN110423129A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

The invention proposes a kind of heating furnace partition wall hanger brick castables, are made of the raw material of following weight parts: 20~50 parts of light-weight mullite, 30~60 parts of mullite, and 1~20 part of cement, 1~10 part of swelling agent and 0.1~0.2 part of water-reducing agent.Beneficial effects of the present invention are as follows: by using mullite as primary raw material, reasonable expanding material is added simultaneously, hanger brick product obtained are made to have the characteristics that bulk density is moderate, thermal shock resistance is excellent, volume stability is good, long service life, service life was up to 1 year or more.

Description

A kind of heating furnace partition wall hanger brick castable
Technical field
The present invention relates to technical field of fire-resistant material preparation, particularly relate to a kind of heating furnace partition wall hanger brick castable.
Background technique
Heating furnace partition wall hanger brick generallys use high alumina castable and is made at present, due to heating furnace partition wall hanger brick It is chronically in the environment of hot and cold alternation variation in use, it is desirable that it has excellent thermal shock resistance;Simultaneously because Hanger brick itself design feature, it is desirable that it is with lower bulk density and sufficiently high intensity, to prevent in its use process Phenomenon of rupture occurs.
Heating furnace partition wall hanger brick service life traditional at present is mostly or so half a year, frequently replaces hanger brick shadow in this way Rhythm of production is rung, while also will increase the consumption of refractory material, leads to that the production cost increases.
Summary of the invention
The present invention proposes a kind of heating furnace partition wall hanger brick castable, solve the strength of materials in the prior art it is poor, use Service life short problem.
The technical scheme of the present invention is realized as follows:
A kind of heating furnace partition wall hanger brick castable, is made of the raw material of following weight parts: 20~50 parts of light-weight mullite, 30~60 parts of mullite, 1~20 part of cement, 1~10 part of swelling agent and 0.1~0.2 part of water-reducing agent.
Preferably, conventional lightweight mullite or spherical lightweight that the light-weight mullite is 1~5 millimeter of partial size do not come Stone.
Preferably, the mullite is the fused mullite or electricity of 0.088~1 millimeter of partial size, aluminium content greater than 60% Molten mullite.
Preferably, the cement is 71 cement or 70 cement of the partial size less than 0.088 millimeter.
Preferably, the swelling agent is silica flour of the partial size less than 0.088 millimeter or aquamaine mountain flour.
Preferably, the water-reducing agent is sodium tripolyphosphate or calgon of the partial size less than 0.5 millimeter.
The above-mentioned light-weight mullite prepared in raw material and mullite are the materials with porous structure and hollow structure, by In itself have good thermal shock resistance, product obtained not only body is close low and also thermal shock resistance more preferably.
The above-mentioned swelling agent silica flour prepared in raw material has phase transition process, the meeting in phase transition process with the variation of temperature Certain expansion is generated, mullite can be formed with the aluminium oxide in other raw materials at high temperature, also can in this process Certain volume expansion is generated, thus to offset the contraction of material.
The above-mentioned swelling agent aquamaine mountain flour prepared in raw material can be decomposed into mullite at high temperature, generate primary permanent swollen It is swollen, the refractoriness under load and compressive resistance of product can be improved using this characteristic, are improved line after product is burnt and are changed, it is indefinite to eliminate The contraction crack that shape refractory material generates in high temperature and cooling procedure.
The invention has the benefit that
The present invention adds reasonable expanding material by using mullite as primary raw material, makes hanging obtained Brick product have the characteristics that bulk density is moderate, thermal shock resistance is excellent, volume stability is good, long service life, and service life can Up to 1 year or more.
It can be improved the overall stability of material by adding swelling agent, material can be improved using pure calcium aluminate cement Intensity, and then improve the service life of material.
Specific embodiment
Below in conjunction in the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
Embodiment 1
A kind of heating furnace partition wall hanger brick castable, is made of the raw material of following weight parts: partial size is 1~5 millimeter light 20 parts of matter mullite, partial size is 30 parts of mullite of 0.088~1 millimeter, 71 cement 1 part of the partial size less than 0.088 millimeter, partial size 0.1 part of the sodium tripolyphosphate of 1 part of silica flour less than 0.088 millimeter and partial size less than 0.5 millimeter.
Above-mentioned raw materials ratio by weight is weighed, and stirs evenly after being mixed and can be used.
Obtained by testing inspection, the heating furnace partition wall hanger brick castable for using above-mentioned raw materials to prepare can reach with Lower performance: after toasting 24 hours in 110 DEG C of baking ovens, the bulk density of material is 2.02g/cm3;Compressive resistance is up to 32Mpa More than.
Embodiment 2
A kind of heating furnace partition wall hanger brick castable, is made of the raw material of following weight parts: the ball that partial size is 1~5 millimeter 35 parts of shape light-weight mullite, partial size is 45 parts of mullite of 0.088~1 millimeter, 70 cement 10.5 of the partial size less than 0.088 millimeter Part, 0.15 part of sodium tripolyphosphate of 5.5 parts of silica flour of the partial size less than 0.088 millimeter and partial size less than 0.5 millimeter.
Above-mentioned raw materials ratio by weight is weighed, and stirs evenly after being mixed and can be used.
Obtained by testing inspection, the heating furnace partition wall hanger brick castable for using above-mentioned raw materials to prepare can reach with Lower performance: after toasting 24 hours in 110 DEG C of baking ovens, the bulk density of material is 2.04g/cm3;Compressive resistance is up to 30Mpa More than.
Embodiment 3
A kind of heating furnace partition wall hanger brick castable, is made of the raw material of following weight parts: partial size is 1~5 millimeter light 50 parts of matter mullite, partial size is 60 parts of mullite of 0.088~1 millimeter, 71 cement 20 part of the partial size less than 0.088 millimeter, grain 0.2 part of calgon of 10 parts of aquamaine mountain flour of the diameter less than 0.088 millimeter and partial size less than 0.5 millimeter.
Above-mentioned raw materials ratio by weight is weighed, and stirs evenly after being mixed and can be used.
Obtained by testing inspection, the heating furnace partition wall hanger brick castable for using above-mentioned raw materials to prepare can reach with Lower performance: after toasting 24 hours in 110 DEG C of baking ovens, the bulk density of material is 2.0g/cm3;Compressive resistance up to 31Mpa with On.
Embodiment 4
A kind of heating furnace partition wall hanger brick castable, is made of the raw material of following weight parts: partial size is 1~5 millimeter light 50 parts of matter mullite, partial size is 35 parts of mullite of 0.088~1 millimeter, 71 cement 10 part of the partial size less than 0.088 millimeter, grain 0.1 part of calgon of 5 parts of silica flour of the diameter less than 0.088 millimeter and partial size less than 0.5 millimeter.
Above-mentioned raw materials ratio by weight is weighed, and stirs evenly after being mixed and can be used.
Obtained by testing inspection, the heating furnace partition wall hanger brick castable for using above-mentioned raw materials to prepare can reach with Lower performance: after toasting 24 hours in 110 DEG C of baking ovens, the bulk density of material is 2.01g/cm3;Compressive resistance is up to 32Mpa More than.
Embodiment 5
A kind of heating furnace partition wall hanger brick castable, is made of the raw material of following weight parts: partial size is 1~5 millimeter light 20 parts of matter mullite, partial size is 60 parts of mullite of 0.088~1 millimeter, 71 cement 15 part of the partial size less than 0.088 millimeter, grain 0.2 part of sodium tripolyphosphate of 5 parts of aquamaine mountain flour of the diameter less than 0.088 millimeter and partial size less than 0.5 millimeter.
Above-mentioned raw materials ratio by weight is weighed, and stirs evenly after being mixed and can be used.
Obtained by testing inspection, the heating furnace partition wall hanger brick castable for using above-mentioned raw materials to prepare can reach with Lower performance: after toasting 24 hours in 110 DEG C of baking ovens, the bulk density of material is 2.05g/cm3;Compressive resistance is up to 35Mpa More than.
Embodiment 6
A kind of heating furnace partition wall hanger brick castable, is made of the raw material of following weight parts: partial size is 1~5 millimeter light 45 parts of matter mullite, partial size is 30 parts of mullite of 0.088~1 millimeter, 70 cement 15 part of the partial size less than 0.088 millimeter, grain 0.2 part of calgon of 10 parts of aquamaine mountain flour of the diameter less than 0.088 millimeter and partial size less than 0.5 millimeter.
Above-mentioned raw materials ratio by weight is weighed, and stirs evenly after being mixed and can be used.
Obtained by testing inspection, the heating furnace partition wall hanger brick castable for using above-mentioned raw materials to prepare can reach with Lower performance: after toasting 24 hours in 110 DEG C of baking ovens, the bulk density of material is 2.01g/cm3;Compressive resistance is up to 33Mpa More than.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (6)

1. a kind of heating furnace partition wall hanger brick castable, which is characterized in that be made of the raw material of following weight parts: light-weight mullite 20~50 parts, 30~60 parts of mullite, 1~20 part of cement, 1~10 part of swelling agent and 0.1~0.2 part of water-reducing agent.
2. a kind of heating furnace partition wall hanger brick castable according to claim 1, which is characterized in that the light-weight mullite For 1~5 millimeter of partial size of conventional lightweight mullite or spherical light-weight mullite.
3. a kind of heating furnace partition wall hanger brick castable according to claim 1, which is characterized in that the mullite is grain 0.088~1 millimeter of diameter, aluminium content are greater than 60% fused mullite or electrofused mullite.
4. a kind of heating furnace partition wall hanger brick castable according to claim 1, which is characterized in that the cement is partial size 71 cement or 70 cement less than 0.088 millimeter.
5. a kind of heating furnace partition wall hanger brick castable according to claim 1, which is characterized in that the swelling agent is grain Silica flour of the diameter less than 0.088 millimeter or aquamaine mountain flour.
6. a kind of heating furnace partition wall hanger brick castable according to claim 1, which is characterized in that the water-reducing agent is grain Sodium tripolyphosphate or calgon of the diameter less than 0.5 millimeter.
CN201910799972.4A 2019-08-27 2019-08-27 A kind of heating furnace partition wall hanger brick castable Pending CN110423129A (en)

Priority Applications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111302818A (en) * 2020-04-22 2020-06-19 河南省宏达炉业有限公司 Anchoring brick and manufacturing method thereof
CN112919890A (en) * 2021-03-24 2021-06-08 浙江吉昌新材料有限公司 Light mullite-alumina hollow sphere-aluminum titanate sagger and preparation method and application thereof

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Publication number Priority date Publication date Assignee Title
CN101792294A (en) * 2010-03-30 2010-08-04 武汉钢铁(集团)公司 Light thermal-shield refractory castable
CN102701756A (en) * 2012-05-10 2012-10-03 莱芜钢铁集团有限公司 Bake-free casting material for ladle online roaster cladding lining and preparation method thereof
CN102976771A (en) * 2012-11-16 2013-03-20 宜兴天霸非金属材料有限公司 High temperature resistant lightweight heat insulation castables
CN103204692A (en) * 2013-05-10 2013-07-17 郑州瑞泰耐火科技有限公司 Novel lightweight mullite brick and fabrication method thereof
CN103214258A (en) * 2013-05-20 2013-07-24 昆山思创耐火材料有限公司 Semi-lightweight mullite-combined castable for burner of annular heating furnace
CN107266097A (en) * 2017-07-28 2017-10-20 武汉科技大学 A kind of light weight mullite refractory and preparation method thereof
CN109232004A (en) * 2018-10-30 2019-01-18 浙江锦诚新材料股份有限公司 A kind of resistive connection skin wear-resistant castable
WO2019049815A1 (en) * 2017-09-11 2019-03-14 黒崎播磨株式会社 Monolithic refractory

Patent Citations (8)

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Publication number Priority date Publication date Assignee Title
CN101792294A (en) * 2010-03-30 2010-08-04 武汉钢铁(集团)公司 Light thermal-shield refractory castable
CN102701756A (en) * 2012-05-10 2012-10-03 莱芜钢铁集团有限公司 Bake-free casting material for ladle online roaster cladding lining and preparation method thereof
CN102976771A (en) * 2012-11-16 2013-03-20 宜兴天霸非金属材料有限公司 High temperature resistant lightweight heat insulation castables
CN103204692A (en) * 2013-05-10 2013-07-17 郑州瑞泰耐火科技有限公司 Novel lightweight mullite brick and fabrication method thereof
CN103214258A (en) * 2013-05-20 2013-07-24 昆山思创耐火材料有限公司 Semi-lightweight mullite-combined castable for burner of annular heating furnace
CN107266097A (en) * 2017-07-28 2017-10-20 武汉科技大学 A kind of light weight mullite refractory and preparation method thereof
WO2019049815A1 (en) * 2017-09-11 2019-03-14 黒崎播磨株式会社 Monolithic refractory
CN109232004A (en) * 2018-10-30 2019-01-18 浙江锦诚新材料股份有限公司 A kind of resistive connection skin wear-resistant castable

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王月月等: "蓝晶石含量对球形45 莫来石轻骨料浇注料显微结构及性能的影响", 《硅酸盐通报》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111302818A (en) * 2020-04-22 2020-06-19 河南省宏达炉业有限公司 Anchoring brick and manufacturing method thereof
CN112919890A (en) * 2021-03-24 2021-06-08 浙江吉昌新材料有限公司 Light mullite-alumina hollow sphere-aluminum titanate sagger and preparation method and application thereof
CN112919890B (en) * 2021-03-24 2023-01-03 浙江吉昌新材料有限公司 Light mullite-alumina hollow sphere-aluminum titanate sagger and preparation method and application thereof

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Inventor after: Liu Li

Inventor after: Wang Xinjie

Inventor after: Zhang Xiaobo

Inventor after: Zhao Ran

Inventor after: Yang Shaokang

Inventor after: Ding Hairui

Inventor after: Yan Hao

Inventor after: Ren Lin

Inventor after: Zhao Wei

Inventor after: Zhao Xianhua

Inventor before: Wang Xinjie

Inventor before: Zhao Xianhua

Inventor before: Zhang Xiaobo

Inventor before: Zhao Ran

Inventor before: Yang Shaokang

Inventor before: Ding Hairui

Inventor before: Liu Li

Inventor before: Yan Hao

Inventor before: Ren Lin

Inventor before: Zhao Wei

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20191108