CN102965567B - Casting thick large-section pearlite nodular cast iron and casting method thereof - Google Patents
Casting thick large-section pearlite nodular cast iron and casting method thereof Download PDFInfo
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- CN102965567B CN102965567B CN201210477633.2A CN201210477633A CN102965567B CN 102965567 B CN102965567 B CN 102965567B CN 201210477633 A CN201210477633 A CN 201210477633A CN 102965567 B CN102965567 B CN 102965567B
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Abstract
The invention discloses casting thick large-section pearlite nodular cast iron and a casting method thereof. The nodular cast iron comprises the following components in percentage by weight: 3.4%-3.7% of C, 2.1%-2.6% of Si, 0.4%-0.8% of Mn, at most 0.04% of P, at most 0.02% of S, 0.03%-0.05% of Mg, 0.4%-1.0% of Cu, 0.01%-0.02% of Sb, 0.01%-0.03% of rare earth, other microelement the total content of which is at most 0.1%, and the balance of iron. The casting method comprises the following traditional technology steps: blending, smelting, balling treatment, inoculation treatment and pouring. As for the casting thick large-section pearlite nodular cast iron, the tensile strength is more than or equal to 592MPa, the yield strength is more than or equal to 357MPa, the specific elongation is more than or equal to 4%, Brinell hardness is HB224-HB240, the pearlite content is more than or equal to 85%, and the casting thick large-section pearlite nodular cast iron has a favorable mechanic property.
Description
Technical field
The present invention relates to a kind of spheroidal graphite cast iron, is specifically a kind of as cast condition thick and large section pearlite ductile iron and castmethod thereof.
Background technology
Heavy section ductile iron refers to that wall thickness is more than or equal to the spheroidal graphite cast iron of 100mm, and pearlite ductile iron refers to that matrix Medium pearlite accounts for more than 80% spheroidal graphite cast iron, and pearlite ductile iron, with its good performance, is widely used in machine building industry.Producing at present thick and large section pearlite ductile iron need to obtain by later stage thermal treatment mostly, minority adopts the method for producing thick and large section pearlite ductile iron under as cast condition, desired raw material kind is more, processing step relative complex, production cost is high, production efficiency is low, and the spheroidal graphite cast iron mechanical property of simultaneously producing is undesirable.
Summary of the invention
A technical problem to be solved by this invention is to overcome above the deficiencies in the prior art: provide that a kind of desired raw material kind is few, the low as cast condition thick and large section pearlite ductile iron that has again excellent mechanical performances of production cost.
A technical solution of the present invention is as follows:
A kind of as cast condition thick and large section pearlite ductile iron, contain iron, carbon, silicon, manganese, phosphorus, sulphur, magnesium, copper, antimony, rare earth and other trace elements, the weight percent of each component is: carbon 3.4%~3.7%, silicon 2.1%~2.6%, manganese 0.4%~0.8%, phosphorus≤0.04%, sulphur≤0.02%, magnesium 0.03%~0.05%, copper 0.4%~1.0%, antimony 0.01%~0.02%, rare earth 0.01%~0.03% and other micronutrient levels summation≤0.1%, surplus are iron.
Another technical problem that the present invention will solve is to overcome above the deficiencies in the prior art: the castmethod that the as cast condition thick and large section pearlite ductile iron that a kind of technique is simple, production efficiency is high is provided.
Another technical solution of the present invention is as follows:
A castmethod for as cast condition thick and large section pearlite ductile iron, comprises following conventional process: batching, melting, spheroidizing, inoculation, cast; Adopting the pig iron, foundry returns, steel scrap, ferrosilicon, ferromanganese, electrolytic copper, antimony slab is raw material, through batching, adopts cupola furnace-electric furnace duplex to carry out melting, then by melted molten iron process spheroidizing, the cast of tapping a blast furnace after inoculation; Wherein adopt and pour method spheroidizing, the nodulizing agent of employing is yttrium-base heavy rare earth nodulizing agent and light rare earths nodulizing agent mixture, and wherein in mixture, light rare earths nodulizing agent accounts for 60%~80%, and all the other are yttrium-base heavy rare earth nodulizing agent; Inoculation adopts that iron notch breeds, current-following inoculation and mould cavity inoculation combine, and wherein, iron notch breeds and adopts silicon barium calcium nucleating agent; Current-following inoculation adopts silicon barium calcium nucleating agent; Mould cavity inoculation adopts 75 ferrosilicon nucleating agents; The add-on of nodulizing agent and nucleating agent is by determine base iron composition and target hot metal composition COMPREHENSIVE CALCULATING, and before tapping a blast furnace, keeping iron liquid temp is at 1500 ℃ ~ 1520 ℃ standing 10 ~ 30 minutes, and finally teeming temperature is controlled at 1290 ℃ ~ 1320 ℃.
The invention has the beneficial effects as follows: the as cast condition thick and large section pearlite ductile iron of producing by castmethod of the present invention, under as cast condition, according to GB/T 228.1-2010 and GB/T 231.1-2009, record tensile strength >=592MPa, yield strength >=357 MPa, unit elongation >=4%, Brinell hardness HB224 ~ HB240; According to GB/T 9441-2009, recording foundry goods centre metallographic structure matrix is perlite >=85%, 5 ~ 6 grades of graphite sizes, and 2 ~ 3 grades of nodulizing grades, have good mechanical property; Adopt as cast condition to produce pearlite ductile iron simultaneously, can save cost, enhance productivity, to increasing economic efficiency, have very important significance.
Embodiment
Below by embodiment, the present invention is described in further details, but the present invention is not only confined to following specific embodiment.
Embodiment mono-
The as cast condition thick and large section pearlite ductile iron target foundry goods that production casting dimension is 300mm * 300mm * 500mm; Wherein the weight percent of each component of as cast condition thick and large section pearlite ductile iron target foundry goods is: carbon 3.58%, silicon 2.43%, manganese 0.65%, phosphorus 0.03%, sulphur 0.015%, magnesium 0.04%, copper 0.4%, antimony 0.016%, rare earth 0.03% and other micronutrient levels summation≤0.1%, surplus are iron.
Adopting the pig iron, foundry returns, steel scrap, ferrosilicon, ferromanganese, electrolytic copper, antimony slab is raw material, above-mentioned raw materials is prepared burden according to given target foundry goods component, adopt cupola furnace-electric furnace duplex to carry out melting, then by melted molten iron process spheroidizing, the cast of tapping a blast furnace after inoculation; Selecting yttrium-base heavy rare earth nodulizing agent and light rare earths nodulizing agent mixture is nodulizing agent, and in mixture, light rare earths nodulizing agent accounts for 65%, and all the other are yttrium-base heavy rare earth nodulizing agent; Iron notch breeds selects silicon barium calcium nucleating agent; Current-following inoculation is selected silicon barium calcium nucleating agent; Mould cavity inoculation adopts 75 ferrosilicon nucleating agents; The add-on of nodulizing agent and nucleating agent is by determine base iron composition and target hot metal composition COMPREHENSIVE CALCULATING, keeps iron liquid under 1510 ℃ of high temperature standing 10 minutes before tapping a blast furnace, and final teeming temperature is controlled at 1304 ℃, pours into a mould cooling forming.
The iron block of getting gained 300mm * 300mm * 500mm foundry goods centre bit and be a 300mm * 300mm * 20m of 250mm place cutting carries out mechanical property detection.
The as-cast characteristic that records above-mentioned foundry goods according to GB/T 228.1-2010 and GB/T 231.1-2009 is: tensile strength is 592MPa, and yield strength is 357MPa, and unit elongation is 4%, and Brinell hardness is HB224; According to GB/T 9441-2009, recording foundry goods metallographic structure matrix is perlite 85%, 5 grades of graphite sizes, 3 grades of nodulizing grades.
Embodiment bis-
The as cast condition thick and large section pearlite ductile iron target foundry goods that production casting dimension is 250mm * 250mm * 500mm; Wherein the weight percent of each component of as cast condition thick and large section pearlite ductile iron target foundry goods is: carbon 3.6%, silicon 2.1%, manganese 0.8%, phosphorus 0.03%, sulphur 0.02%, magnesium 0.05%, copper 0.8%, antimony 0.02%, rare earth 0.03% and other micronutrient levels summation≤0.1%, surplus are iron.
Adopting the pig iron, foundry returns, steel scrap, ferrosilicon, ferromanganese, electrolytic copper, antimony slab is raw material, above-mentioned raw materials is prepared burden according to given target foundry goods component, adopt cupola furnace-electric furnace duplex to carry out melting, then by melted molten iron process spheroidizing, the cast of tapping a blast furnace after inoculation; Selecting yttrium-base heavy rare earth nodulizing agent and light rare earths nodulizing agent mixture is nodulizing agent, and in mixture, light rare earths nodulizing agent accounts for 70%, and all the other are yttrium-base heavy rare earth nodulizing agent; Iron notch breeds selects silicon barium calcium nucleating agent; Current-following inoculation is selected silicon barium calcium nucleating agent; Mould cavity inoculation adopts 75 ferrosilicon nucleating agents; The add-on of nodulizing agent and nucleating agent is by determine base iron composition and target hot metal composition COMPREHENSIVE CALCULATING, keeps iron liquid under 1520 ℃ of high temperature standing 15 minutes before tapping a blast furnace, and final teeming temperature is controlled at 1300 ℃, pours into a mould cooling forming.
The iron block of getting gained 250mm * 250mm * 500mm foundry goods centre bit and be a 250mm * 250mm * 20m of 250mm place cutting carries out mechanical property detection.
The as-cast characteristic that records above-mentioned foundry goods according to GB/T 228.1-2010 and GB/T 231.1-2009 is: tensile strength is 600MPa, and yield strength is 360MPa, and unit elongation is 4%, and Brinell hardness is HB230; According to GB/T 9441-2009, recording foundry goods metallographic structure matrix is perlite 90%, 5 grades of graphite sizes, 2 grades of nodulizing grades.
Embodiment tri-
The as cast condition thick and large section pearlite ductile iron target foundry goods that production casting dimension is 200mm * 200mm * 500mm; Wherein the weight percent of each component of as cast condition thick and large section pearlite ductile iron target foundry goods is: carbon 3.7%, silicon 2.6%, manganese 0.7%, phosphorus 0.03%, sulphur 0.01%, magnesium 0.03%, copper 0.7%, antimony 0.02%, rare earth 0.03% and other micronutrient levels summation≤0.1%, surplus are iron.
Adopting the pig iron, foundry returns, steel scrap, ferrosilicon, ferromanganese, electrolytic copper, antimony slab is raw material, above-mentioned raw materials is prepared burden according to given target foundry goods component, adopt cupola furnace-electric furnace duplex to carry out melting, then by melted molten iron process spheroidizing, the cast of tapping a blast furnace after inoculation; Selecting yttrium-base heavy rare earth nodulizing agent and light rare earths nodulizing agent mixture is nodulizing agent, and in mixture, light rare earths nodulizing agent accounts for 70%, and all the other are yttrium-base heavy rare earth nodulizing agent; Iron notch breeds selects silicon barium calcium nucleating agent; Current-following inoculation is selected silicon barium calcium nucleating agent; Mould cavity inoculation adopts 75 ferrosilicon nucleating agents; The add-on of nodulizing agent and nucleating agent is by determine base iron composition and target hot metal composition COMPREHENSIVE CALCULATING, keeps iron liquid under 1520 ℃ of high temperature standing 15 minutes before tapping a blast furnace, and final teeming temperature is controlled at 1300 ℃, pours into a mould cooling forming.
The iron block of getting gained 200mm * 200mm * 500mm foundry goods centre bit and be a 200mm * 200mm * 20m of 250mm place cutting carries out mechanical property detection.
The as-cast characteristic that records above-mentioned foundry goods according to GB/T 228.1-2010 and GB/T 231.1-2009 is: tensile strength is 620MPa, and yield strength is 380MPa, and unit elongation is 3%, and Brinell hardness is HB226; According to GB/T 9441-2009, recording foundry goods metallographic structure matrix is perlite 95%, 6 grades of graphite sizes, 3 grades of nodulizing grades.
Claims (1)
1. an as cast condition thick and large section pearlite ductile iron, is characterized in that: it is comprised of the component of following weight percent:
Carbon 3.6%, silicon 2.1%, manganese 0.8%, phosphorus 0.03%, sulphur 0.02%, magnesium 0.05%, copper 0.8%, antimony 0.02%, rare earth 0.03% and other micronutrient levels summation≤0.1%, surplus are iron;
The castmethod of described as cast condition thick and large section pearlite ductile iron is: adopting the pig iron, foundry returns, steel scrap, ferrosilicon, ferromanganese, electrolytic copper, antimony slab is raw material, through batching, adopt cupola furnace-electric furnace duplex to carry out melting, again by melted molten iron process spheroidizing, the cast of tapping a blast furnace after inoculation; Wherein adopt and pour method spheroidizing, the nodulizing agent of employing is yttrium-base heavy rare earth nodulizing agent and light rare earths nodulizing agent mixture, and wherein in mixture, light rare earths nodulizing agent accounts for 60%~80%, and all the other are yttrium-base heavy rare earth nodulizing agent; Inoculation adopts that iron notch breeds, current-following inoculation and mould cavity inoculation combine, and wherein, iron notch breeds and adopts silicon barium calcium nucleating agent; Current-following inoculation adopts silicon barium calcium nucleating agent; Mould cavity inoculation adopts 75 ferrosilicon nucleating agents; The add-on of nodulizing agent and nucleating agent is by determine base iron composition and target hot metal composition COMPREHENSIVE CALCULATING, and before tapping a blast furnace, keeping iron liquid temp is at 1500 ℃~1520 ℃ standing 10~30 minutes, and finally teeming temperature is controlled at 1290 ℃~1320 ℃.
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