CN102964911A - Black ceramic ink for ink-jet printing and application method thereof - Google Patents
Black ceramic ink for ink-jet printing and application method thereof Download PDFInfo
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- CN102964911A CN102964911A CN2012105569950A CN201210556995A CN102964911A CN 102964911 A CN102964911 A CN 102964911A CN 2012105569950 A CN2012105569950 A CN 2012105569950A CN 201210556995 A CN201210556995 A CN 201210556995A CN 102964911 A CN102964911 A CN 102964911A
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Abstract
The invention discloses a black ceramic ink for ink-jet printing, which is composed of soluble metal complex and organic solvent, wherein the mass percent of the soluble metal complex in the ceramic ink is 30-60 wt%; and the soluble metal complex is carboxylic acid metal salt, and the organic solvent is one or mixture of any of n-decane, ethyl acetate, isopropanol, n-hexane and o-xylene in any proportion. The application method of the ceramic ink comprises the following steps: coating the ceramic ink on a ceramic blank surface with transparency glaze, which is heated at 300 DEG C; calcining at 900-1200 DEG C; and keeping the temperature for 1-3 hours. The ceramic ink disclosed by the invention is a uniform phase, thus, can not deposit, and can not block or abrade the printer jet; and the ceramic ink has the advantages of good effect, environment friendliness and low production cost, is convenient for popularization, and has favorable decorative effect.
Description
Technical field
The present invention relates to a kind of ink for the ceramic surface decoration, particularly a kind of for the ink jet ink for printing of ceramic decoration and the method for using this ink that the not Low fire ceramic base substrate of executing transparent is decorated.
Background technology
Along with the development of market economy and computer technology, the needs that the decorative means of existing traditional ceramics can not satisfying the market.The introducing of modernization of computer design means is the inexorable trend of design of ceramic products developing direction from now on.At present, the novel process-inkjet technology that is used for mould-free forming is just becoming worldwide study hotspot, and supporting various ceramic inks also expose one after another with it.Ink-jet printing process is a kind of decoration technique that has potentiality, and the method is tinting material to be made multi-color ink be used for the ceramic surface decoration, by computer-controlled printer multi-color ink is directly printed to ceramic surface and decorates.
In recent years, domestic existing unit is engaged in the research and development that spray ink Printing is used ceramic ink, delivered some research papers, main research unit has with representational relevant paper: " the Sol-Gel legal system is for the physicochemical property of continuous ink jet printing with the chromatic ceramics ink " of University Of Tianjin, " reverse microemulsion process prepares high density ZrO
2Ceramic ink ", " BaTiO
3The preparation of ceramic ink and performance "; " spraying preparation and the performance of decorating ink with blue and red ceramic surface " of Aviation Engineering Institutes Of Nanchang; " Preparation of Red Ceramic Ink by Inverse Microemulsion Method " of Shaanxi Tech Univ etc.
The research of external ceramic ink is initial early, the ceramic decoration ink-jet printer of the first in the world platform industrial application in 2000 comes out, printer is that ink also is the ceramic ink by FERRO company and Sai Er company joint research and development by the Karejet system of U.S. FERRO company exploitation.The United States Patent (USP) of Airey etc. discloses a kind of printing ink that comprises solid inorganic pigment for No. 5407474, this printing ink can utilize ink-jet printer to be applied on the high temperature article, but because the density difference between the solution of inoganic solids and suspension inoganic solids is large, so this printing ink based on being suspended in the solid in the solution is unsettled.
On January 7th, 2000, FERRO company to United States Patent (USP) trademark office submitted to a by name " be used for glaze for glazed tile (watt) and printing ink and the ink combination of the color jet-ink on the surface uniqueness of printing " patent, this patent has been set forth the making method of ceramic ink, for the ceramic ink jet printing technology has been established good basis, but the related ink production cost of this patent is higher, mainly used the metal complexes that contains ruthenium such as black, these metal complexes price general chargeds are comparatively expensive, every gram is thousands of units easily, are not suitable for applying.
Now existing numerous documents research that the preparation method of ceramic ink is carried out, what solve emphatically is dispersiveness and the stability problem of ceramic ink.But comprehensive present Research both at home and abroad, the ceramic ink preparation method who has published at present still concentrates on dispersion method, sol-gel method and anti-phase newborn mutually method, and used direct raw material mostly is metal oxide, and in above three kinds of production methods, sol-gel method is restricted owing to method of manufacturing technology is complicated, raw material is expensive, colloidal sol is unstable, anti-phase newborn phase method is because the ink solid load that makes is low, also there are many technical problems to be solved, the problem of dispersion method is that the granules of pigments degree is larger, easily reunites and the printer nozzle that can block or wear and tear.
Summary of the invention
Purpose of the present invention, be for the stability, dispersiveness and the ceramic ink that solve ceramic ink because the large printer nozzle that causes of pigment granules degree blocks and the problem of wearing and tearing, the black ceramic ink of provide that a kind of effect is good, environmental friendliness, production cost spray ink Printing low, easy to utilize being used.
For achieving the above object, technical scheme provided by the invention is:
A kind of spray ink Printing black ceramic ink is comprised of soluble metal title complex and organic solvent, and the mass percentage content of metal complexes is the 30-60wt% of ink total mass in this ceramic ink; Described soluble metal title complex is carboxylic metallic salt, and described organic solvent is the long-chain stable hydrocarbon, unsaturated hydrocarbons, aromatic hydrocarbons, cyclic saturated hydrocarbon, lipid, the wherein mixing of one or any multiple arbitrary proportion of alcohols.
Described metal complexes is ferric carboxylate, carboxylic acid cobalt.
Described metal complexes is isocaprylic acid iron and cobalt iso-octoate.
Described organic solvent is the mixing of n-decane, ethyl acetate, Virahol, normal hexane, o-Xylol one or any multiple any arbitrary proportion wherein.
The viscosity of described black ceramic ink is the 5-50 centipoise, and surface tension is 20-45 milli ox/rice, and density is the 0.5-2.5 grams per milliliter.
A kind of spray ink Printing using method of black ceramic ink has following steps:
(1) marzacotto is coated to the ceramic body surface
(2) ceramic body after step (1) glazing is heated to 300 ℃
The black ceramic ink that (3) will comprise the metal complexes of solubility is coated to the ceramic body surface that is covered with marzacotto after step (2) heating;
(4) ceramic body with step (3) places kiln, is fired to 900-1200 ℃, is incubated 1-3 hour.
The preferred calcining temperature of described step (4) is 1140 ℃.
The invention has the beneficial effects as follows, the black ceramic ink of provide that a kind of effect is good, environmental friendliness, production cost spray ink Printing low, easy to utilize being used, this black ceramic ink is homogeneous phase, not sedimentation, can not block printer nozzle or it is caused wearing and tearing, the ceramic surface of executing transparent is had good decorative effect.
Embodiment
The present invention being coated with on the ceramic body surface of not burning till of transparent, then advances this black ceramic ink printed in stove and is fired to more than 1000 ℃, and be incubated 1 to 3 hours by inkjet-printing device.In this process, the organic bond rupture in the metal complexes that comprises in the ink, and along with temperature raises, wherein institute's carbon containing, protium are burnt, only remaining metal oxide ferric oxide and cobalt oxide.Ferric oxide and cobalt oxide by the series of physical chemical transformation, show preferably black with the oxide compound in the marzacotto that is coated on ceramic surface.
The invention will be further described below by specific embodiment.
Embodiment 1
With reference to the prescription shown in the table 1 (numerical value is mass ratio in the table, and namely embodiment 1 is isocaprylic acid iron: cobalt iso-octoate: the mass ratio of n-decane=3:1:4), the black ceramic ink of preparation embodiment 1, the ink outward appearance is dark-brown solution; By ink-jet printer, print on the not Low fire ceramic surface that is coated with marzacotto, then advance stove and be fired to 1140 ℃, be incubated 3 hours, detect after cooling the color development effect, detected result sees table 2 for details.
Embodiment 2
With reference to the prescription shown in the table 1 (numerical value is mass ratio in the table), the black ceramic ink of preparation embodiment 2, the ink outward appearance is dark-brown solution, pass through ink-jet printer, print on the not Low fire ceramic surface that is coated with marzacotto, then advance stove and be fired to 1140 ℃, be incubated 3 hours, detect after cooling the color development effect, detected result sees table 2 for details.
Embodiment 3
With reference to the prescription shown in the table 1 (numerical value is mass ratio in the table), the black ceramic ink of preparation embodiment 3, the ink outward appearance is dark-brown solution, pass through ink-jet printer, print on the not Low fire ceramic surface that is coated with marzacotto, then advance stove and be fired to 1140 ℃, be incubated 3 hours, detect after cooling the color development effect, detected result sees table 2 for details.
Embodiment 4
With reference to the prescription shown in the table 1 (numerical value is mass ratio in the table), the black ceramic ink of preparation embodiment 4, the ink outward appearance is dark-brown solution, pass through ink-jet printer, print on the not Low fire ceramic surface that is coated with marzacotto, then advance stove and be fired to 1140 ℃, be incubated 3 hours, detect after cooling the color development effect, detected result sees table 2 for details.
Table 1
| № | Isocaprylic acid iron | Cobalt iso-octoate | N-decane | Ethyl acetate | Virahol | Normal hexane | O-Xylol |
| Embodiment 1 | 3 | 1 | 4 | ? | ? | ? | ? |
| Embodiment 2 | 3 | 1 | ? | 2 | 2 | ? | ? |
| Embodiment 3 | 3 | 1 | ? | ? | ? | 4 | ? |
| Embodiment 4 | 3 | 1 | ? | ? | ? | ? | 4 |
Table 2
| № | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| L* | 6.1 | 7.1 | 9.8 | 8.7 |
| a* | -1.5 | -1.6 | -1.2 | -2.0 |
| b* | -0.7 | -1.4 | -1.9 | -2.3 |
| Print fluency | Smooth | Smooth | Smooth | Smooth |
| Crocking resistance | Without abrasion mark | Without abrasion mark | Without abrasion mark | Without abrasion mark |
| Print performance | Good | Good | Good | Good |
(Lab in the table 2 is the colour model of people's naked eyes energy perception, is a kind of phraseology of color, and wherein L represents brightness, and a represents the scope from the carmetta to the green, and b represents from yellow to blue scope.）
As seen from Table 2, the print performance of black ceramic ink of the present invention, color developing effect are fine.
Above-mentioned description to embodiment is to be convenient to those skilled in the art can understand and apply the invention.The person skilled in the art obviously can easily make various modifications to these embodiment, and needn't pass through performing creative labour being applied in the General Principle of this explanation among other embodiment.Therefore, the invention is not restricted to the embodiment here, those skilled in the art should be within protection scope of the present invention for improvement and modification that the present invention makes according to announcement of the present invention.
Claims (7)
1. a spray ink Printing black ceramic ink is comprised of soluble metal title complex and organic solvent, and the mass percentage content of metal complexes is the 30-60wt% of ink total mass in this ceramic ink; Described soluble metal title complex is carboxylic metallic salt, and described organic solvent is the long-chain stable hydrocarbon, unsaturated hydrocarbons, aromatic hydrocarbons, cyclic saturated hydrocarbon, lipid, alcohols, the mixing of one or any multiple arbitrary proportion wherein.
2. according to claim 1 a kind of spray ink Printing black ceramic ink is characterized in that described metal complexes is ferric carboxylate, carboxylic acid cobalt.
3. according to claim 1 a kind of spray ink Printing black ceramic ink is characterized in that described metal complexes is isocaprylic acid iron and cobalt iso-octoate.
4. according to claim 1 a kind of spray ink Printing black ceramic ink is characterized in that described organic solvent is the mixing of n-decane, ethyl acetate, Virahol, normal hexane, o-Xylol one or any multiple any arbitrary proportion wherein.
5. according to claim 1 a kind of spray ink Printing black ceramic ink is characterized in that the viscosity of described black ceramic ink is the 5-50 centipoise, and surface tension is 20-45 milli ox/rice, and density is the 0.5-2.5 grams per milliliter.
6. a kind of spray ink Printing of claim 1 has following steps with the using method of black ceramic ink:
(1) marzacotto is coated to the ceramic body surface
(2) ceramic body after step (1) glazing is heated to 300 ℃
The black ceramic ink that (3) will comprise the metal complexes of solubility is coated to the ceramic body surface that is covered with marzacotto after step (2) heating;
(4) ceramic body with step (3) places kiln, is fired to 900-1200 ℃, is incubated 1-3 hour.
7. according to claim 5 a kind of spray ink Printing is characterized in that with the using method of black ceramic ink the preferred calcining temperature of described step (4) is 1140 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012105569950A CN102964911A (en) | 2012-12-18 | 2012-12-18 | Black ceramic ink for ink-jet printing and application method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012105569950A CN102964911A (en) | 2012-12-18 | 2012-12-18 | Black ceramic ink for ink-jet printing and application method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104309223A (en) * | 2014-10-11 | 2015-01-28 | 杭州诺贝尔陶瓷有限公司 | Ceramic brick having braided texture and production method thereof |
| CN107735463A (en) * | 2015-06-23 | 2018-02-23 | 图像电子公司 | Jetted ink for Ceramic Tiles decoration |
| CN108976911A (en) * | 2018-07-09 | 2018-12-11 | 山东汇龙色釉新材料科技有限公司 | It is a kind of to burn ceramic marking ink and its preparation process three times |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069041A (en) * | 1991-05-24 | 1993-02-17 | 伊马治公司 | Be used for mark or article and decorate, the ink that especially ceramic thing is decorated |
| US5273757A (en) * | 1987-09-01 | 1993-12-28 | Lts Lohmann Therapie-Systeme Gmbh & Co. Kg | Apparatus for the delivery of substances, processes for the production thereof and use thereof |
| CN1420916A (en) * | 2000-01-07 | 2003-05-28 | 费罗公司 | Individual inks and ink set for use in color ink jet printing of glazed ceramic tiles and surfaces |
-
2012
- 2012-12-18 CN CN2012105569950A patent/CN102964911A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5273757A (en) * | 1987-09-01 | 1993-12-28 | Lts Lohmann Therapie-Systeme Gmbh & Co. Kg | Apparatus for the delivery of substances, processes for the production thereof and use thereof |
| CN1069041A (en) * | 1991-05-24 | 1993-02-17 | 伊马治公司 | Be used for mark or article and decorate, the ink that especially ceramic thing is decorated |
| CN1420916A (en) * | 2000-01-07 | 2003-05-28 | 费罗公司 | Individual inks and ink set for use in color ink jet printing of glazed ceramic tiles and surfaces |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104309223A (en) * | 2014-10-11 | 2015-01-28 | 杭州诺贝尔陶瓷有限公司 | Ceramic brick having braided texture and production method thereof |
| CN104309223B (en) * | 2014-10-11 | 2018-11-27 | 杭州诺贝尔陶瓷有限公司 | A kind of Ceramic Tiles and its production method with braiding skin texture |
| CN107735463A (en) * | 2015-06-23 | 2018-02-23 | 图像电子公司 | Jetted ink for Ceramic Tiles decoration |
| CN108976911A (en) * | 2018-07-09 | 2018-12-11 | 山东汇龙色釉新材料科技有限公司 | It is a kind of to burn ceramic marking ink and its preparation process three times |
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Application publication date: 20130313 |