CN103045003A - Red ceramic ink for inkjet printing and application method thereof - Google Patents
Red ceramic ink for inkjet printing and application method thereof Download PDFInfo
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- CN103045003A CN103045003A CN2012105493913A CN201210549391A CN103045003A CN 103045003 A CN103045003 A CN 103045003A CN 2012105493913 A CN2012105493913 A CN 2012105493913A CN 201210549391 A CN201210549391 A CN 201210549391A CN 103045003 A CN103045003 A CN 103045003A
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Abstract
The invention discloses red ceramic ink for inkjet printing, which comprises soluble metal complex and organic solvent. The mass percent of the soluble metal complex is 30 to 60 wt percent of the total mass of the ceramic ink; the soluble metal complex adopts carboxylic acid metal salt; and the organic solvent adopts one of n-decane, ethyl silicate, ethyl acetate, isopropyl alcohol, n-hexane and ortho-xylene or more of n-decane, ethyl silicate, ethyl acetate, isopropyl alcohol, n-hexane and ortho-xylene which are mixed at free percentage. The application method of the ceramic ink comprises the steps of coating the ceramic ink on the surface of a ceramic body with transparent glaze, which is heated at 300 DEG C, performing calcining at 900 to 1200 DEG C, and performing thermal insulation for 1 to 3 hours. The ceramic ink adopts uniform phase, does not settle, can not block a printer nozzle or wear the printer nozzle, has good effect, is environmentally friendly, low in production cost and convenient to popularize and apply, and has good decorative effect.
Description
Technical field
The present invention relates to a kind of ink for the ceramic surface decoration, particularly a kind of for the ink jet ink for printing of ceramic decoration and the method for using this ink that the not Low fire ceramic base substrate of executing transparent is decorated.
Background technology
Along with the development of market economy and computer technology, the needs that the decorative means of existing traditional ceramics can not satisfying the market.The introducing of modernization of computer design means is the inexorable trend of design of ceramic products developing direction from now on.At present, the novel process-inkjet technology that is used for mould-free forming is just becoming worldwide study hotspot, and supporting various ceramic inks also expose one after another with it.Ink-jet printing process is a kind of decoration technique that has potentiality, and this method is ceramic surface to be decorated the used tinting material of ink make multi-color ink, by computer-controlled printer it is directly printed to ceramic surface and decorates.
In recent years, domestic existing unit is engaged in the research and development that spray ink Printing is used ceramic ink, delivered some research papers, main research unit has with representational relevant paper: " the Sol-Gel legal system is for the physicochemical property of continuous ink jet printing with the chromatic ceramics ink " of University Of Tianjin, " reverse microemulsion process prepares high density ZrO
2Ceramic ink ", " BaTiO
3The preparation of ceramic ink and performance "; " spraying preparation and the performance of decorating ink with blue and red ceramic surface " of Aviation Engineering Institutes Of Nanchang; " Preparation of Red Ceramic Ink by Inverse Microemulsion Method " of Shaanxi Tech Univ etc.
The research of external ceramic ink is initial early, the ceramic decoration ink-jet printer of the first in the world platform industrial application in 2000 comes out, printer is that ink also is the ceramic ink by FERRO company and Sai Er company joint research and development by the Karejet system of U.S. FERRO company exploitation.The United States Patent (USP) of Airey etc. discloses a kind of printing ink that comprises solid inorganic pigment for No. 5407474, this printing ink can utilize ink-jet printer to be applied on the high temperature article, but because the density difference between the solution of inoganic solids and suspension inoganic solids is large, so this printing ink based on being suspended in the solid in the solution is unsettled.
On January 7th, 2000, FERRO company to United States Patent (USP) trademark office submitted to a by name " be used for glaze for glazed tile (watt) and printing ink and the ink combination of the color jet-ink on the surface uniqueness of printing " patent, this patent has been set forth a kind of making method technology of new ceramic ink, soon tinting material is made organic phase and is dissolved in the organic solvent, and this invention has been established good basis for the ceramic ink jet printing technology.But the related ink production cost of this patent is higher, has mainly used the metal complexes that contains gold such as redness, and these metal complexes price general chargeds are comparatively expensive, and every gram is thousands of units easily, are not suitable for applying.
Now existing numerous documents research that the preparation method of ceramic ink is carried out, what solve emphatically is dispersiveness and the stability problem of ceramic ink.But comprehensive present Research both at home and abroad, the ceramic ink preparation method who has published at present still concentrates on dispersion method, sol-gel method and anti-phase newborn mutually method, and used direct raw material mostly is metal oxide, and in above three kinds of production methods, sol-gel method is restricted owing to method of manufacturing technology is complicated, raw material is expensive, colloidal sol is unstable, anti-phase newborn phase method is because the ink solid load that makes is low, also there are many technical problems to be solved, the problem of dispersion method is that the granules of pigments degree is larger, easily reunites and the printer nozzle that can block or wear and tear.
Summary of the invention
Purpose of the present invention, be for the stability, dispersiveness and the ceramic ink that solve ceramic ink because the large printer nozzle that causes of pigment granules degree blocks and the problem of wearing and tearing, the Red ceramic ink of provide that a kind of effect is good, environmental friendliness, production cost spray ink Printing low, easy to utilize being used.
For achieving the above object, technical scheme provided by the invention is:
A kind of spray ink Printing Red ceramic ink is comprised of soluble metal title complex and organic solvent, and the mass percentage content of metal complexes is the 30-60wt% of ink total mass in this ceramic ink; Described soluble metal title complex is carboxylic metallic salt, and described organic solvent is the long-chain stable hydrocarbon, unsaturated hydrocarbons, aromatic hydrocarbons, cyclic saturated hydrocarbon, lipid, the wherein mixing of one or any multiple arbitrary proportion of alcohols.
Described metal complexes is carboxylic acid tin, carboxylic acid chromium.
Described metal complexes is dibutyl tin laurate, isocaprylic acid chromium.
Described organic solvent is the mixing of n-decane, tetraethyl silicate, ethyl acetate, Virahol, normal hexane, o-Xylol one or any multiple any arbitrary proportion wherein.
Described Red ceramic ink viscosity is the 5-50 centipoise, and surface tension is 20-45 milli ox/rice, and density is the 0.5-2.5 grams per milliliter.
A kind of spray ink Printing using method of Red ceramic ink has following steps:
(1) in existing marzacotto, adds the 5.0wt% calcium oxide, stir, then be coated to the ceramic body surface
(2) ceramic body after step (1) glazing is heated to 300 ℃
The Red ceramic ink that (3) will comprise the metal complexes of solubility is coated to the ceramic body surface that is covered with marzacotto after step (2) heating;
(4) ceramic body with step (3) places kiln, is fired to 900-1200 ℃, is incubated 1-3 hour.
The preferred calcining temperature of described step (4) is 1140 ℃.
The invention has the beneficial effects as follows, the Red ceramic ink of provide that a kind of effect is good, environmental friendliness, production cost spray ink Printing low, easy to utilize being used, this Red ceramic ink is homogeneous phase, not sedimentation, can not block printer nozzle or it is caused wearing and tearing, the ceramic surface of executing transparent is had good decorative effect.
Embodiment
The present invention is printed on this Red ceramic ink on the ceramic body surface of not burning till that is coated with transparent by inkjet-printing device, then advances stove and is fired to more than 1000 ℃, and be incubated 1 to 3 hours.In this process, the organic bond rupture in the metal complexes that comprises in the ink, and along with temperature raises, wherein institute's carbon containing, protium are burnt, only remaining metal oxide stannic oxide and chromic oxide.Stannic oxide and cobalt oxide by the series of physical chemical transformation, show preferably black with the oxide compound (silicon-dioxide, calcium oxide etc.) in the marzacotto that is coated on ceramic surface.
The invention will be further described below by specific embodiment.
Embodiment 1
(numerical value is mass ratio in the table with reference to the prescription shown in the table 1, be that embodiment 1 is dibutyl tin laurate: isocaprylic acid chromium: tetraethyl silicate: the mass ratio of n-decane=16: 1: 10: 7), the Red ceramic ink of preparation embodiment 1, the ink outward appearance is green transparent solution; In existing marzacotto, add the 5.0wt% calcium oxide, stir, then be coated to the ceramic body surface; By ink-jet printer, print on the not Low fire ceramic surface that is coated with marzacotto, then advance stove and be fired to 1140 ℃, be incubated 3 hours, detect after cooling the color development effect, detected result sees table 2 for details.
Embodiment 2
With reference to the prescription shown in the table 1 (numerical value is mass ratio in the table), the Red ceramic ink of preparation embodiment 2, the ink outward appearance is green transparent solution; In existing marzacotto, add the 5.0wt% calcium oxide, stir, then be coated to the ceramic body surface; By ink-jet printer, print on the not Low fire ceramic surface that is coated with marzacotto, then advance stove and be fired to 1140 ℃, be incubated 3 hours, detect after cooling the color development effect, detected result sees table 2 for details.
Embodiment 3
With reference to the prescription shown in the table 1 (numerical value is mass ratio in the table), the Red ceramic ink of preparation embodiment 3, the ink outward appearance is green transparent solution; In existing marzacotto, add the 5.0wt% calcium oxide, stir, then be coated to the ceramic body surface; By ink-jet printer, print on the not Low fire ceramic surface that is coated with marzacotto, then advance stove and be fired to 1140 ℃, be incubated 3 hours, detect after cooling the color development effect, detected result sees table 2 for details.
Embodiment 4
With reference to the prescription shown in the table 1 (numerical value is mass ratio in the table), the Red ceramic ink of preparation embodiment 4, the ink outward appearance is green transparent solution; In existing marzacotto, add the 5.0wt% calcium oxide, stir, then be coated to the ceramic body surface; By ink-jet printer, print on the not Low fire ceramic surface that is coated with marzacotto, then advance stove and be fired to 1140 ℃, be incubated 3 hours, detect after cooling the color development effect, detected result sees table 2 for details.
Table 1
Table 2
| №? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| L* | 64.5 | 59.6 | 65.6 | 61.9 |
| a* | 38.6 | 37.7 | 39.3 | 38.0 |
| b* | 7.8 | 12.7 | 7.2 | 7.7 |
| Print fluency | Smooth | Smooth | Smooth | Smooth |
| Crocking resistance | Without abrasion mark | Without abrasion mark | Without abrasion mark | Without abrasion mark |
| Print performance | Good | Good | Good | Good |
As seen from Table 2, product print performance of the present invention is better, and color developing effect is good.
Do not departing under the Main principle of the present invention; those skilled in the art is easy to the present invention made other change or variation; such as the carboxylic acid tin or the carboxylic acid chromium that use other; or the weight ratio of carboxylic acid tin or carboxylic acid chromium in the change ink; or the change employed concrete solvent of ink or auxiliary agent etc.; therefore; the present invention is not limited to above-described embodiment; those skilled in the art needn't pass through performing creative labour according to announcement of the present invention, all should be within protection scope of the present invention for improvement and modification that the present invention makes.
Claims (7)
1. a spray ink Printing Red ceramic ink is comprised of soluble metal title complex and organic solvent, and the mass percentage content of metal complexes is the 30-60wt% of ink total mass in this ceramic ink; Described soluble metal title complex is carboxylic metallic salt, and described organic solvent is the long-chain stable hydrocarbon, unsaturated hydrocarbons, aromatic hydrocarbons, cyclic saturated hydrocarbon, lipid, alcohols, the mixing of one or any multiple arbitrary proportion wherein.
2. according to claim 1 a kind of spray ink Printing Red ceramic ink is characterized in that described metal complexes is carboxylic acid tin, carboxylic acid chromium.
3. according to claim 1 a kind of spray ink Printing Red ceramic ink is characterized in that described metal complexes is dibutyl tin laurate, isocaprylic acid chromium.
4. according to claim 1 a kind of spray ink Printing Red ceramic ink, it is characterized in that described organic solvent is the mixing of n-decane, tetraethyl silicate, ethyl acetate, Virahol, normal hexane, o-Xylol one or any multiple any arbitrary proportion wherein.
5. according to claim 1 a kind of spray ink Printing Red ceramic ink is characterized in that described Red ceramic ink viscosity is the 5-50 centipoise, and surface tension is 20-45 milli ox/rice, and density is the 0.5-2.5 grams per milliliter.
6. according to claim 1 a kind of spray ink Printing has following steps with the using method of Red ceramic ink:
(1) in existing marzacotto, adds the 5.0wt% calcium oxide, stir, then be coated to the ceramic body surface
(2) ceramic body after step (1) glazing is heated to 300 ℃
The Red ceramic ink that (3) will comprise the metal complexes of solubility is coated to the ceramic body surface that is covered with marzacotto after step (2) heating;
(4) ceramic body with step (3) places kiln, is fired to 900-1200 ℃, is incubated 1-3 hour.
7. use the using method of Red ceramic ink according to a kind of spray ink Printing of claim 5, it is characterized in that, the preferred calcining temperature of described step (4) is 1140 ℃.
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| CN2012105493913A CN103045003A (en) | 2012-12-18 | 2012-12-18 | Red ceramic ink for inkjet printing and application method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104309223A (en) * | 2014-10-11 | 2015-01-28 | 杭州诺贝尔陶瓷有限公司 | Ceramic brick having braided texture and production method thereof |
| US20150132476A1 (en) * | 2013-11-13 | 2015-05-14 | Xerox Corporation | Conductive compositions comprising metal carboxylates |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069041A (en) * | 1991-05-24 | 1993-02-17 | 伊马治公司 | Be used for mark or article and decorate, the ink that especially ceramic thing is decorated |
| CN1420916A (en) * | 2000-01-07 | 2003-05-28 | 费罗公司 | Individual inks and ink set for use in color ink jet printing of glazed ceramic tiles and surfaces |
-
2012
- 2012-12-18 CN CN2012105493913A patent/CN103045003A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069041A (en) * | 1991-05-24 | 1993-02-17 | 伊马治公司 | Be used for mark or article and decorate, the ink that especially ceramic thing is decorated |
| CN1420916A (en) * | 2000-01-07 | 2003-05-28 | 费罗公司 | Individual inks and ink set for use in color ink jet printing of glazed ceramic tiles and surfaces |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150132476A1 (en) * | 2013-11-13 | 2015-05-14 | Xerox Corporation | Conductive compositions comprising metal carboxylates |
| US9540734B2 (en) * | 2013-11-13 | 2017-01-10 | Xerox Corporation | Conductive compositions comprising metal carboxylates |
| US10160869B2 (en) | 2013-11-13 | 2018-12-25 | Xerox Corporation | Conductive compositions comprising metal carboxylates |
| CN104309223A (en) * | 2014-10-11 | 2015-01-28 | 杭州诺贝尔陶瓷有限公司 | Ceramic brick having braided texture and production method thereof |
| CN104309223B (en) * | 2014-10-11 | 2018-11-27 | 杭州诺贝尔陶瓷有限公司 | A kind of Ceramic Tiles and its production method with braiding skin texture |
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Application publication date: 20130417 |