CN102964902A - Paint remover as well as preparation method and application thereof - Google Patents
Paint remover as well as preparation method and application thereof Download PDFInfo
- Publication number
- CN102964902A CN102964902A CN2012104761801A CN201210476180A CN102964902A CN 102964902 A CN102964902 A CN 102964902A CN 2012104761801 A CN2012104761801 A CN 2012104761801A CN 201210476180 A CN201210476180 A CN 201210476180A CN 102964902 A CN102964902 A CN 102964902A
- Authority
- CN
- China
- Prior art keywords
- parts
- paint remover
- paint
- coating
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a paint remover, in particular relates to a paint remover which can remove multiple organic coatings as well as a preparation method and an application thereof and belongs to the field of fine chemical engineering. The paint remover comprises the following components (in parts by weight): 30-80 parts of dichloromethane, 0.2-5 parts of ethanol amine, 0.5-10 parts of formic acid, 5-20 parts of ethyl alcohol, 2-20 parts of acetone, 2-8 parts of liquid paraffin and 0.01-0.1 part of organic corrosion inhibitor, wherein the corrosion inhibitor is one or more of hexamethylenetetramine, cupferron, benzotriazole and sodium oleate. The preparation method of the paint remover comprises the steps of adding each component into a container in proportion and stirring to be uniform at normal temperature and normal pressure. The paint remover provided by the invention can effectively remove organic coatings on various metal surfaces, such as an epoxy resin coating, a polyurethane resin coating, an organic silicon resin coating and a polyester coating; the paint remover provided by the invention has strong coating dissolving capacity, paint removing speed at normal temperature is high, and metal substrate is not corroded; and raw materials are available, cost is low, and a production process is simple.
Description
Technical field
The present invention relates to a kind of paint remover, particularly a kind of paint remover that multiple organic coating is had the removal effect and preparation method thereof and application belong to field of fine chemical.
Background technology
Organic coating is widely applied in daily life and industrial production.The effect of coating is to provide certain protective effect to base material on the one hand, is the outward appearance of beautifying coated article on the other hand.In the actual life, under environmental activity and physical mechanical effect, along with the prolongation coating of duration of service the part often occurs or big area lost efficacy, such as loss of gloss, efflorescence, come off, crackle, scuffing, ground corrosion etc., or defectives such as tangerine peel, crackle, efflorescence appears in the coating preparation process, cause the appearance of unacceptable product, this just requires thoroughly to remove coating, and again spraying.The mechanical removal coating has the shortcomings such as time-consuming, that efficient is low, often can not realize the removal of coating to complex-shaped component.In addition, also may cause the destructions such as scuffing of ground, the coating that adopts paint remover to remove substrate surface is a kind of effective means.
At present, there is following shortcoming in the paint remover of industrial use: metallic substance is caused corrosion, and high volatility, the paint remover that has need to heat use, contains the toxic substances such as benzene, phenol, hydrofluoric acid etc.
Summary of the invention
In view of above problem, the object of the present invention is to provide a kind of paint remover and preparation method thereof and application, mainly solve exist in the prior art metallic substance is caused corrosion, contain the problems such as toxic substance such as benzene, phenol, hydrofluoric acid.
Technical scheme of the present invention is:
A kind of paint remover, according to the mass fraction, it is composed as follows:
30～80 parts of methylene dichloride;
0.2～5 part of thanomin;
0.5～10 part in formic acid;
5～20 parts of ethanol;
2～20 parts in acetone;
2～8 parts of whiterusss;
0.01～0.1 part of organic inhibitor.
Described paint remover, according to the mass fraction, it is preferably composed as follows:
40～60 parts of methylene dichloride;
0.5～2 part of thanomin;
1～5 part in formic acid;
10～15 parts of ethanol;
10～15 parts in acetone;
3～5 parts of whiterusss;
0.03～0.05 part of organic inhibitor.
In the present invention, used organic inhibitor is one or more combinations of hexamethylenetetramine, N-nitrosophenyl hydroxylamine amine (cupferron), benzotriazole (BTA) and sodium oleate.
In the present invention, the mass fraction of hexamethylenetetramine is 0～0.1 part, and the mass fraction of cupferron is 0～0.1 part, and the mass fraction of benzotriazole is 0～0.1 part, and the mass fraction of sodium oleate is 0～0.1 part.
The preparation method of described paint remover joins each component in the container in proportion, stirs at normal temperatures and pressures, inhibiter is dissolved fully after, namely obtain paint remover.
The application of described paint remover, paint remover is used for the removal of metal material surface organic coating, perhaps is applied to the removal of woodenware surface paint film.
In the present invention, the inhibition mechanism of organic inhibitor is: be adsorbed on metal base surface and form organic adsorbent thin film in the depainting process, stop the corrosion of metallic substance in depainting solution.According to the difference of base material, can select different inhibiter or its combination, ferrous materials can be selected hexamethylenetetramine, and aluminium alloy can be selected N-nitrosophenyl hydroxylamine amine (cupferron) and sodium oleate, and copper alloy can be selected benzotriazole.For the various metals subassembly, can select the composite of inhibiter.
Advantage of the present invention and effect:
1, paint remover of the present invention is made of methylene dichloride, thanomin, formic acid, ethanol, acetone, whiteruss and organic inhibitor, take methylene dichloride as solvent, adopt whiteruss as volatilization inhibitor, formic acid, thanomin, ethanol and acetone accelerate the removal of coating, the corrosion of metallic substance in the organic inhibitor establishment depainting process.
2, preparation process of the present invention is to take by weighing in proportion each component, after inhibiter is dissolved fully, namely obtains paint remover, and raw material sources are extensive, and cost is low, and production technique is simple, and paint removing effect is remarkable.
3, paint remover of the present invention need not heat in preparation and use procedure, and the normal temperature paint removing effect is good.Metallic substance without corrosion, is not contained the hazardous and noxious substances such as benzene, phenol and hydrofluoric acid, use safety.
4, the present invention be depainting efficient high, to metal without the low-volatile paint remover of burn into, paint remover can effectively be removed the organic coating of various metallic surfaces, such as epoxy coating, urethane resin coating, silicone resin coating and polyester coatings etc.Paint remover is strong to the dissolving power of coating, and the normal temperature paint stripping rate is fast, and metal base is not corroded.
Embodiment
Embodiment 1
The preparation of paint remover: take by weighing methylene dichloride 30kg, thanomin 2.5kg, formic acid 4kg, ethanol 6kg, acetone 3.5kg, whiteruss 2.5kg, cupferron 0.05kg.Above-mentioned substance is added in the stirred vessel, be stirred at normal temperatures and pressures fully dissolving, can paint remover of the present invention.
Stripping test: will put into above-mentioned paint remover with the LY12 aluminum alloy specimen of the thick epoxy coating of 100 μ m, under the room temperature, the 4min coating begins swelling, and coating comes off fully behind the 11min, and aluminum alloy surface is smooth smooth, without corrosion.
Embodiment 2
The preparation of paint remover: take by weighing methylene dichloride 50kg, thanomin 1kg, formic acid 8kg, ethanol 20kg, acetone 16kg, whiteruss 5kg, benzotriazole 0.03kg.Above-mentioned substance is added in the stirred vessel, be stirred at normal temperatures and pressures fully dissolving, can paint remover of the present invention.
Stripping test: will put into above-mentioned paint remover with the red copper gold sample of the thick silicone resin coating of 100 μ m, under the room temperature, the 5min coating begins swelling, and coating comes off fully behind the 12min, and red copper surface is smooth smooth, without corrosion.
Embodiment 3
The preparation of paint remover: take by weighing methylene dichloride 37.5kg, thanomin 0.25kg, formic acid 0.75kg, ethanol 5kg, acetone 2.5kg, whiteruss 3kg, hexamethylenetetramine 0.08kg.Above-mentioned substance is added in the stirred vessel, be stirred at normal temperatures and pressures fully dissolving, can paint remover of the present invention.
Stripping test: will have the Q235 sample of vibrin coating to put into above-mentioned paint remover with 100 μ m are thick, under the room temperature, the 3min coating begins swelling, and coating comes off fully behind the 13min, and the Q235 surfacing is smooth, without corrosion.
Embodiment 4
The preparation of paint remover: take by weighing methylene dichloride 40kg, thanomin 5kg, formic acid 10kg, ethanol 20kg, acetone 20kg, whiteruss 5kg, hexamethylenetetramine 0.05kg, cupferron 0.015kg, sodium oleate 0.02kg.Above-mentioned substance is added in the stirred vessel, be stirred at normal temperatures and pressures fully dissolving, can paint remover of the present invention.
Stripping test: will have the Q235 of epoxy coating and 6063 aluminum alloy combination samples to put into above-mentioned paint remover with 100 μ m are thick, under the room temperature, the 5min coating begins swelling, and coating comes off fully behind the 15min, Q235 and 6063 aluminum alloy surface are smooth smooth, without corrosion.
Embodiment 5
The preparation of paint remover: take by weighing methylene dichloride 35kg, thanomin 1.5kg, formic acid 2.5kg, ethanol 5kg, acetone 4kg, whiteruss 2kg, hexamethylenetetramine 0.03kg, cupferron 0.02kg, benzotriazole 0.015kg, sodium oleate 0.012kg.Above-mentioned substance is added in the stirred vessel, be stirred at normal temperatures and pressures fully dissolving, can paint remover of the present invention.
Stripping test: will put into above-mentioned paint remover with the thick Q235 that the urethane resin coating arranged of 100 μ m and 3A21 aluminium alloy and QSn4-3 tinbronze composite sample, under the room temperature, the 6min coating begins swelling, coating comes off fully behind the 13min, Q235 and 3A21 aluminium alloy and QSn4-3 tinbronze gold surface are smooth smooth, without corrosion.
Embodiment result shows that by the paint remover that this technique obtains, paint removing effect is good, and to the metal object corrosion, technique is easy to control, is fit to suitability for industrialized production.
In addition, the above only is the better feasible embodiment of the present invention, the interest field that can not limit to this present invention, and described paint remover can be used for the removal of metal material surface organic coating, also can be applicable to the removal of woodenware surface paint film.Therefore, make other various corresponding changes and distortion according to technical scheme of the present invention and technical thought, still belong within the protection domain that the present invention contains.
Claims (6)
1. a paint remover is characterized in that, according to the mass fraction, it is composed as follows:
30～80 parts of methylene dichloride;
0.2～5 part of thanomin;
0.5～10 part in formic acid;
5～20 parts of ethanol;
2～20 parts in acetone;
2～8 parts of whiterusss;
0.01～0.1 part of organic inhibitor.
2. paint remover according to claim 1, it is characterized in that: according to the mass fraction, it is preferably composed as follows:
40～60 parts of methylene dichloride;
0.5～2 part of thanomin;
1～5 part in formic acid;
10～15 parts of ethanol;
10～15 parts in acetone;
3～5 parts of whiterusss;
0.03～0.05 part of organic inhibitor.
3. paint remover according to claim 1, it is characterized in that: used organic inhibitor is one or more combinations of hexamethylenetetramine, N-nitrosophenyl hydroxylamine amine, benzotriazole and sodium oleate.
4. paint remover according to claim 1, it is characterized in that: the mass fraction of hexamethylenetetramine is 0～0.1 part, the mass fraction of cupferron is 0～0.1 part, and the mass fraction of benzotriazole is 0～0.1 part, and the mass fraction of sodium oleate is 0～0.1 part.
5. the preparation method of paint remover according to claim 1 is characterized in that: in proportion each component is joined in the container, stirs at normal temperatures and pressures, inhibiter is dissolved fully after, namely obtain paint remover.
6. the application of paint remover according to claim 1 is characterized in that: paint remover is used for the removal of metal material surface organic coating, perhaps is applied to the removal of woodenware surface paint film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210476180.1A CN102964902B (en) | 2012-11-21 | 2012-11-21 | Paint remover as well as preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210476180.1A CN102964902B (en) | 2012-11-21 | 2012-11-21 | Paint remover as well as preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102964902A true CN102964902A (en) | 2013-03-13 |
| CN102964902B CN102964902B (en) | 2014-07-30 |
Family
ID=47795347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210476180.1A Active CN102964902B (en) | 2012-11-21 | 2012-11-21 | Paint remover as well as preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102964902B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103172183A (en) * | 2013-03-28 | 2013-06-26 | 哈尔滨工程大学 | Water treatment corrosion inhibitor and water treatment agent containing same |
| CN103602991A (en) * | 2013-11-18 | 2014-02-26 | 广东电网公司电力科学研究院 | Compound corrosion inhibitor, preparation method and application thereof |
| CN104231714A (en) * | 2014-09-25 | 2014-12-24 | 无锡康柏斯机械科技有限公司 | Mechanical part paint remover and preparation method and application thereof |
| JP5940204B1 (en) * | 2015-09-16 | 2016-06-29 | 株式会社オフィス・エー・ティー | Film remover |
| CN106833102A (en) * | 2017-03-14 | 2017-06-13 | 苏州市金纳润特科技有限公司 | A kind of natural gas line paint stripper and its construction method |
| CN106893395A (en) * | 2017-03-24 | 2017-06-27 | 苏州市金纳润特科技有限公司 | A kind of ship of high-efficiency environment friendly depainting cream |
| CN107686676A (en) * | 2017-09-25 | 2018-02-13 | 安徽香杨新能源科技发展有限公司 | A kind of environmental friendly material |
| CN108519300A (en) * | 2018-03-08 | 2018-09-11 | 中国科学院金属研究所 | A kind of galvanic corrosion weightless test method under the conditions of realization high hydrostatic pressure |
| CN108726654A (en) * | 2018-07-01 | 2018-11-02 | 李冬生 | A kind of lacquer mist coagulant |
| CN113861746A (en) * | 2021-08-26 | 2021-12-31 | 中国人民解放军第五七二一工厂 | Method for removing radar wave-absorbing paint coating of airplane |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1743389A (en) * | 2005-10-08 | 2006-03-08 | 北京化工大学 | General efficient paint remover |
| US20060234889A1 (en) * | 2005-04-15 | 2006-10-19 | Ecolab Inc. | Method for stripping floor finishes using composition that thickens upon dilution with water |
| CN101130647A (en) * | 2007-04-10 | 2008-02-27 | 大连工业大学 | Paint stripper |
| CN101684213A (en) * | 2009-07-31 | 2010-03-31 | 南京师范大学 | Multifunctional chorine-free and benzene-free compound paint stripper and production method thereof |
-
2012
- 2012-11-21 CN CN201210476180.1A patent/CN102964902B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060234889A1 (en) * | 2005-04-15 | 2006-10-19 | Ecolab Inc. | Method for stripping floor finishes using composition that thickens upon dilution with water |
| CN1743389A (en) * | 2005-10-08 | 2006-03-08 | 北京化工大学 | General efficient paint remover |
| CN101130647A (en) * | 2007-04-10 | 2008-02-27 | 大连工业大学 | Paint stripper |
| CN101684213A (en) * | 2009-07-31 | 2010-03-31 | 南京师范大学 | Multifunctional chorine-free and benzene-free compound paint stripper and production method thereof |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103172183A (en) * | 2013-03-28 | 2013-06-26 | 哈尔滨工程大学 | Water treatment corrosion inhibitor and water treatment agent containing same |
| CN103172183B (en) * | 2013-03-28 | 2014-03-26 | 哈尔滨工程大学 | Water treatment corrosion inhibitor and water treatment agent containing same |
| CN103602991A (en) * | 2013-11-18 | 2014-02-26 | 广东电网公司电力科学研究院 | Compound corrosion inhibitor, preparation method and application thereof |
| CN103602991B (en) * | 2013-11-18 | 2015-05-13 | 广东电网公司电力科学研究院 | Compound corrosion inhibitor, preparation method and application thereof |
| CN104231714A (en) * | 2014-09-25 | 2014-12-24 | 无锡康柏斯机械科技有限公司 | Mechanical part paint remover and preparation method and application thereof |
| JP6047255B1 (en) * | 2015-09-16 | 2016-12-21 | 株式会社オフィス・エー・ティー | Film remover |
| JP5940204B1 (en) * | 2015-09-16 | 2016-06-29 | 株式会社オフィス・エー・ティー | Film remover |
| CN106833102A (en) * | 2017-03-14 | 2017-06-13 | 苏州市金纳润特科技有限公司 | A kind of natural gas line paint stripper and its construction method |
| CN106893395A (en) * | 2017-03-24 | 2017-06-27 | 苏州市金纳润特科技有限公司 | A kind of ship of high-efficiency environment friendly depainting cream |
| CN107686676A (en) * | 2017-09-25 | 2018-02-13 | 安徽香杨新能源科技发展有限公司 | A kind of environmental friendly material |
| CN108519300A (en) * | 2018-03-08 | 2018-09-11 | 中国科学院金属研究所 | A kind of galvanic corrosion weightless test method under the conditions of realization high hydrostatic pressure |
| CN108726654A (en) * | 2018-07-01 | 2018-11-02 | 李冬生 | A kind of lacquer mist coagulant |
| CN113861746A (en) * | 2021-08-26 | 2021-12-31 | 中国人民解放军第五七二一工厂 | Method for removing radar wave-absorbing paint coating of airplane |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102964902B (en) | 2014-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102964902B (en) | Paint remover as well as preparation method and application thereof | |
| CN101240141B (en) | Water-based antirust agent | |
| CN102766388A (en) | Heavy-duty coating for prolonging life of sheet metals and preparation method thereof | |
| US11613813B2 (en) | Low temperature-cured corrosion inhibition coating | |
| Almeida | Surface treatments and coatings for metals. A general overview. 1. Surface treatments, surface preparation, and the nature of coatings | |
| CN103834940A (en) | Environment-friendly fluorine-free metal surface treatment agent and metal surface treatment method | |
| CN102260451B (en) | Solvent-free epoxy glass flake coating and preparation method | |
| Drak et al. | Corrosion of Nd-Fe-B permanent magnets | |
| CN103088335A (en) | Surface modification and silanization treating agent for metal and preparation method thereof | |
| CN102533052B (en) | Solvent-free type epoxy zinc rich primer and preparation method thereof | |
| CN101381578B (en) | Super-light Mg-Li alloy high-efficiency anticorrosive paint | |
| Avdeev et al. | Chromate-free passivation of aluminum alloys for paint repair technologies | |
| CN102181200B (en) | Reactive-water-based paint remover and preparation method thereof | |
| CN102560319A (en) | Metal transfer method of resin-based carbon fiber composite material | |
| CN101392384B (en) | Surface treatment agent of waste and old easy open can surface | |
| CN103087569A (en) | Surface silanization protection treatment agent for stainless steel plates and preparation method thereof | |
| CN109401521B (en) | Phenolic resin modified metal protection antirust non-drying oil and preparation method thereof | |
| CN103882445A (en) | Rust-removal and rust-proof liquor capable of being coated and preparation method thereof | |
| US8361948B2 (en) | Paint stripper | |
| CN101792622A (en) | Dispensing viscosity adjustable neutral potent water-soluble paint stripper | |
| CN102181199A (en) | Aluminium alloy paint stripper and preparation method thereof | |
| CN104356837B (en) | A kind of metallic paint compositions and preparation method thereof | |
| CN107474626A (en) | A kind of potent paint stripper and preparation method thereof | |
| Kuśmierczak et al. | Macroscopic quality evaluation of lacquered steel sheets | |
| CN103087567A (en) | Surface silanization protection treatment agent for corrosion inhibiting and resisting metal and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: ELECTRICAL POWER RESEARCH INSTITUTE OF GUANGDONG P Effective date: 20140110 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Cheng Inventor after: Fu Qiang Inventor after: Wang Wen Inventor after: Wu Hang Inventor after: Wang Qunchang Inventor after: Zhu Shenglong Inventor after: Wang Fuhui Inventor after: Liu Shinian Inventor after: Su Wei Inventor after: Lv Wangyan Inventor before: Wang Cheng Inventor before: Wang Wen Inventor before: Wu Hang Inventor before: Wang Qunchang Inventor before: Zhu Shenglong Inventor before: Wang Fuhui |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: WANG CHENG WANG WEN WU HANG WANG QUNCHANG ZHU SHENGLONG WANG FUHUI TO: WANG CHENG WANG WEN WU HANG WANG QUNCHANG ZHU SHENGLONG WANG FUHUI LIU SHINIAN SU WEI LV WANGYAN FU QIANG |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20140110 Address after: 110016 Shenyang, Liaoning Province Cultural Road, No. 72, Shenhe Applicant after: Institute of metal research, Chinese Academy of Sciences Applicant after: Electrical Power Research Institute of Guangdong Power Grid Corporation Address before: 110016 Shenyang, Liaoning Province Cultural Road, No. 72, Shenhe Applicant before: Institute of metal research, Chinese Academy of Sciences |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |