CN102964762A - High thixotropy printing ink adhesive resin composition used for screen printing water transfer printing - Google Patents
High thixotropy printing ink adhesive resin composition used for screen printing water transfer printing Download PDFInfo
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- CN102964762A CN102964762A CN2011102576784A CN201110257678A CN102964762A CN 102964762 A CN102964762 A CN 102964762A CN 2011102576784 A CN2011102576784 A CN 2011102576784A CN 201110257678 A CN201110257678 A CN 201110257678A CN 102964762 A CN102964762 A CN 102964762A
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- adhesive resin
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- ink adhesive
- screen printing
- swabbing
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Abstract
The invention discloses a high thixotropy printing ink adhesive resin composition used for screen printing water transfer printing, which comprises the following components by weight: 100 parts of propylene (co) polymer, 0-40 parts of plasticizer, 0-10 parts of additive, 0-10 parts of thixotropic agent and 50-300 parts of solvent. wherein the propylene (co) polymer takes thermoplastic acrylic alkyl ester as a main body, and the glass transition temperature Tg is -10 DEG C to 100 DEG C. The high thixotropy printing ink adhesive resin composition used for the screen printing water transfer printing has high rheological property and good printability of the printing ink, and has effective effects for reducing the mesh obstruction while printing and residues while burning.
Description
Technical field
The present invention relates to a kind of screen printing swabbing transfer printing high thixotropic ink adhesive resin combination.
Background technology
All the time, the surface of the coloring agent for ceramic products of decorative porcelain device, glass, enamel etc., the drawing practice of employing water transfer-type.The method is to coat equably water-soluble thickener on base stock, uses the ceramic industry printing-ink, then with print patterns such as silk screen print methods, forms in the above afterwards protection film film (support transfer ink).Like this, the transfer paper after the printing is immersed in the water, along with the dissolving of water-soluble thickener, pattern is peeled off together with protection film film, be attached to the specified location that is transferred thing, carry out again drying and burn till.The printing-ink of pattern, decorative pattern etc. is that sole pigment disperses (with three-roller etc.) to form in the ink adhesive resin.Particularly in the mode of printings such as net-point printing, for the angle of collapsing that prevents printing ink, infiltration etc. just need very high thixotropy.Therefore, increasing the thixotropic agent usage quantity just can solve.But, use to contain the many ink adhesive resins of amount of thixotropic agent, occurred that printability is bad, mesh stops up, burns till the problems such as residue during printing.
Summary of the invention
In order to overcome defects, the invention provides a kind of screen printing swabbing transfer printing high thixotropic ink adhesive resin combination, it not only has very high rheological property, and the printability of printing ink is very good, and the residue that the mesh during simultaneously for the minimizing printing stops up, produces when burning till is very effective.
The present invention for the technical scheme that solves its technical problem and adopt is: a kind of screen printing swabbing transfer printing comprises the component of following mass fraction with high thixotropic ink adhesive resin combination:
Propylene (being total to) polymer: 100 parts;
Plasticizer: 0-40 part;
Additive: 0-10 part;
Thixotropic agent: 0-10 part;
Solvent: 50-300 part;
Wherein, described propylene (being total to) polymer is take thermoplastically acrylic acid alkyl fat as main body, and its glass tansition temperature Tg is-10 ℃ to 100 ℃.
As a further improvement on the present invention, the polymeric molecular structural formula of described propylene (being total to) is:
Wherein, R
ABe hydrogen or methyl, R
BFatty group or alicyclic group for hydrogen or carbon number 1-12.
As a further improvement on the present invention, the polymeric glass tansition temperature of described propylene (being total to) Tg (being tried to achieve by the FOX relational expression) satisfies following relationship:
1/Tg＝Wa/Tga+Wb/Tgb+……
Wherein, Wa, Wb represent respectively the quality percentage composition of monomer a, b in the polymeric composition of described propylene (being total to), the glass tansition temperature when Tga, Tgb distinguish described monomer a, b respectively as polymer.
As a further improvement on the present invention, described plasticizer is the plasticizer that phthalic acid fat, adipic acid alkyl fat, citric acid alkyl fat, trimellitic acid 1,2-anhydride fat etc. and propylene (being total to) polymer have consistency.
As a further improvement on the present invention, described additive is at least one of resin fibre, pigment dispersing agent, defoamer, (being total to) polymer and flow agent.
As a further improvement on the present invention, described thixotropic agent can freely be adjusted printability by rheology control.
As a further improvement on the present invention, described thixotropic agent is at least one of fatty acid amide series thixotropic agent, hydrogenated castor oleylamide series thixotropic agent, hydrogenated castor oil series thixotropic agent, the sticking serial thixotropic agent of hydrogenated castor oil, higher fatty acid nitrogen inductor series thixotropic agent and long lock fatty acid ester polymer series thixotropic agent.
As a further improvement on the present invention, the boiling point of described solvent is 100～280 ℃, and it is the mixture of polar solvent or polar solvent and non-polar solvent.
The invention has the beneficial effects as follows: this screen printing swabbing transfer printing has very high rheological property with high thixotropic ink adhesive resin combination, and the printability of printing ink is very good.In addition, the reproducibility during its printing is fine, and the residue that the mesh during for the minimizing printing stops up, produces when burning till etc. are very effective.
Embodiment
A kind of screen printing swabbing transfer printing comprises the component of following mass fraction with high thixotropic ink adhesive resin combination:
Propylene (being total to) polymer: 100 parts;
Plasticizer: 0-40 part;
Additive: 0-10 part;
Thixotropic agent: 0-10 part;
Solvent: 50-300 part;
Wherein, described propylene (being total to) polymer is take thermoplastically acrylic acid alkyl fat as main body, and its glass tansition temperature Tg is-10 ℃ to 100 ℃.
The polymeric molecular structural formula of aforesaid propylene (being total to) is:
Wherein, R
ABe hydrogen or methyl, R
BFatty group or alicyclic group for hydrogen or carbon number 1-12.
The polymeric glass tansition temperature of aforesaid propylene (being total to) Tg (being tried to achieve by the FOX relational expression) satisfies following relationship:
1/Tg＝Wa/Tga+Wb/Tgb+……
Wherein, Wa, Wb represent respectively the quality percentage composition of monomer a, b in the polymeric composition of described propylene (being total to), the glass tansition temperature when Tga, Tgb distinguish described monomer a, b respectively as polymer.
Above-mentioned plasticizer is the plasticizer that phthalic acid fat, adipic acid alkyl fat, citric acid alkyl fat, trimellitic acid 1,2-anhydride fat etc. and propylene (being total to) polymer have consistency.
Above-mentioned additive is at least one of resin fibre, pigment dispersing agent, defoamer, (being total to) polymer and flow agent.
Above-mentioned thixotropic agent can freely be adjusted printability by rheology control.
Above-mentioned thixotropic agent is at least one of fatty acid amide series thixotropic agent, hydrogenated castor oleylamide series thixotropic agent, hydrogenated castor oil series thixotropic agent, the sticking serial thixotropic agent of hydrogenated castor oil, higher fatty acid nitrogen inductor series thixotropic agent and long lock fatty acid ester polymer series thixotropic agent.
The boiling point of above-mentioned solvent is 100～280 ℃, and it is the mixture of polar solvent or polar solvent and non-polar solvent.
Claims (8)
1. a screen printing swabbing transfer printing is characterized in that it comprises the component of following mass fraction with high thixotropic ink adhesive resin combination:
Propylene (being total to) polymer: 100 parts;
Plasticizer: 0-40 part;
Additive: 0-10 part;
Thixotropic agent: 0-10 part;
Solvent: 50-300 part;
Wherein, described propylene (being total to) polymer is take thermoplastically acrylic acid alkyl fat as main body, and its glass tansition temperature Tg is-10 ℃ to 100 ℃.
2. screen printing swabbing transfer printing according to claim 1 is with high thixotropic ink adhesive resin combination, and it is characterized in that: the polymeric molecular structural formula of described propylene (being total to) is:
Wherein, R
ABe hydrogen or methyl, R
BFatty group or alicyclic group for hydrogen or carbon number 1-12.
3. screen printing swabbing transfer printing according to claim 1 is characterized in that the polymeric glass tansition temperature of described propylene (being total to) Tg satisfies following relationship with high thixotropic ink adhesive resin combination:
1/Tg＝Wa/Tga+Wb/Tgb+……
Wherein, Wa, Wb represent respectively the quality percentage composition of monomer a, b in the polymeric composition of described propylene (being total to), the glass tansition temperature when Tga, Tgb distinguish described monomer a, b respectively as polymer.
4. screen printing swabbing transfer printing according to claim 1 is with high thixotropic ink adhesive resin combination, and it is characterized in that: described plasticizer is the plasticizer that phthalic acid fat, adipic acid alkyl fat, citric acid alkyl fat, trimellitic acid 1,2-anhydride fat etc. and propylene (being total to) polymer have consistency.
5. screen printing swabbing transfer printing according to claim 1 is with high thixotropic ink adhesive resin combination, and it is characterized in that: described additive is at least one of resin fibre, pigment dispersing agent, defoamer, (being total to) polymer and flow agent.
6. screen printing swabbing transfer printing according to claim 1 is with high thixotropic ink adhesive resin combination, and it is characterized in that: described thixotropic agent can freely be adjusted printability by rheology control.
7. screen printing swabbing transfer printing according to claim 1 is with high thixotropic ink adhesive resin combination, and it is characterized in that: described thixotropic agent is at least one of fatty acid amide series thixotropic agent, hydrogenated castor oleylamide series thixotropic agent, hydrogenated castor oil series thixotropic agent, the sticking serial thixotropic agent of hydrogenated castor oil, higher fatty acid nitrogen inductor series thixotropic agent and long lock fatty acid ester polymer series thixotropic agent.
8. screen printing swabbing transfer printing according to claim 1 is with high thixotropic ink adhesive resin combination, and it is characterized in that: the boiling point of described solvent is 100～280 ℃, and it is the mixture of polar solvent or polar solvent and non-polar solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102576784A CN102964762A (en) | 2011-09-02 | 2011-09-02 | High thixotropy printing ink adhesive resin composition used for screen printing water transfer printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102576784A CN102964762A (en) | 2011-09-02 | 2011-09-02 | High thixotropy printing ink adhesive resin composition used for screen printing water transfer printing |
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|---|---|
| CN102964762A true CN102964762A (en) | 2013-03-13 |
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| CN2011102576784A Pending CN102964762A (en) | 2011-09-02 | 2011-09-02 | High thixotropy printing ink adhesive resin composition used for screen printing water transfer printing |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945808A (en) * | 2015-07-16 | 2015-09-30 | 田菱精密制版（深圳）有限公司 | Cover oil resin combination used for hydrographics transfer printing |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55104370A (en) * | 1979-02-03 | 1980-08-09 | Sakata Shokai Ltd | Printing ink composition for laminate |
| JPS6198777A (en) * | 1984-10-18 | 1986-05-17 | ヘキスト・アクチエンゲゼルシヤフト | Immediately usable liquid size preparation based on water for transfer method |
| JPH11172168A (en) * | 1997-12-10 | 1999-06-29 | Chuo Rika Kogyo Corp | Composition for water-base ink |
| CN1241600A (en) * | 1998-07-13 | 2000-01-19 | 化学工业部黎明化工研究院 | Thixotropic ink oil for screen printed applique paper |
| CN1487042A (en) * | 2002-09-30 | 2004-04-07 | 罗姆和哈斯公司 | Polymer adhesive for ink jet ink |
| CN101429416A (en) * | 2007-11-07 | 2009-05-13 | 3M新设资产公司 | Adhesion agent composition for environment-friendly water transfer printing volume label |
| CN102093658A (en) * | 2010-12-23 | 2011-06-15 | 陕西科技大学 | Preparation method of water transfer glue |
-
2011
- 2011-09-02 CN CN2011102576784A patent/CN102964762A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55104370A (en) * | 1979-02-03 | 1980-08-09 | Sakata Shokai Ltd | Printing ink composition for laminate |
| JPS6198777A (en) * | 1984-10-18 | 1986-05-17 | ヘキスト・アクチエンゲゼルシヤフト | Immediately usable liquid size preparation based on water for transfer method |
| JPH11172168A (en) * | 1997-12-10 | 1999-06-29 | Chuo Rika Kogyo Corp | Composition for water-base ink |
| CN1241600A (en) * | 1998-07-13 | 2000-01-19 | 化学工业部黎明化工研究院 | Thixotropic ink oil for screen printed applique paper |
| CN1487042A (en) * | 2002-09-30 | 2004-04-07 | 罗姆和哈斯公司 | Polymer adhesive for ink jet ink |
| CN101429416A (en) * | 2007-11-07 | 2009-05-13 | 3M新设资产公司 | Adhesion agent composition for environment-friendly water transfer printing volume label |
| CN102093658A (en) * | 2010-12-23 | 2011-06-15 | 陕西科技大学 | Preparation method of water transfer glue |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945808A (en) * | 2015-07-16 | 2015-09-30 | 田菱精密制版（深圳）有限公司 | Cover oil resin combination used for hydrographics transfer printing |
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Application publication date: 20130313 |