CN102964107A - Inorganic insulation composite material for building energy-saving wall and preparation method thereof - Google Patents

Inorganic insulation composite material for building energy-saving wall and preparation method thereof Download PDF

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Publication number
CN102964107A
CN102964107A CN2012104165362A CN201210416536A CN102964107A CN 102964107 A CN102964107 A CN 102964107A CN 2012104165362 A CN2012104165362 A CN 2012104165362A CN 201210416536 A CN201210416536 A CN 201210416536A CN 102964107 A CN102964107 A CN 102964107A
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Prior art keywords
composite material
insulation composite
building energy
preparation
grams
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CN2012104165362A
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Chinese (zh)
Inventor
张原僖
周日升
赵建卿
郭秀娟
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TIANYI TECHNOLOGY Co Ltd SHANXI NANOMATERIALS
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TIANYI TECHNOLOGY Co Ltd SHANXI NANOMATERIALS
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Publication of CN102964107A publication Critical patent/CN102964107A/en
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Abstract

The invention discloses an inorganic insulation composite material for building energy-saving wall and a preparation method thereof. The inorganic insulation composite material for building energy-saving wall provided by the invention is composed of the following raw materials, by weight: 40-50 parts of silica aerogel, 10-20 parts of expanded perlite, 5-10 parts of clay and 5-10 parts of glass fiber. The above materials and liquid water glass 2-5 wt% of the composite material are mixed by stirring, and pressed to obtain the insulation composite material for wall. The inorganic insulation composite material for building energy-saving wall provided by the invention has advantages of excellent thermal insulation properties and mechanical properties, good waterproof and flame retardant performance, good weather resistance, green and environment-friendliness.

Description

A kind of inorganic building energy conservation wall thermal insulating heat-insulation composite material and preparation method thereof
Technical field
The present invention relates to heat-insulating composite material, relate to particularly the external-wall heat-insulation material of aerosil and inorganic building material preparation.
Background technology
At present although thermal and insulating performance is good, also there is critical defect take the styrofoam of organic, urethane etc. as main in the wall thermal insulating lagging material of domestic construction thing.Organic heat-insulating lagging material weathering resistance is poor, and especially fire resistance does not reach national fire protection requirement, consequence that especially can bringing on a disaster property after Highrise buildings uses.Beijing " CCTV's fire ", Shanghai " 11.15 " fire in 2009 all are to have used the organic heat preserving and insulating material.Under the serious situation that current organic heat-insulating lagging material frequently catches fire, how to solve performance of heat protective material and the lagging material contradiction between catching fire, in the urgent need to a kind of novel heat preserving and insulating material, the demand of satisfying the market.Aerosil, it is a kind of novel nano hole inorganic materials, this material has high porosity (80%-99.8%), low density (0.03-0.3g/cm 3), the high-performance such as low-thermal conductivity (0.013-0.018 w/mk), low-k (1.0-2.0), aerosil is a kind of heat insulating material, its unit weight is ultralight, thermal conductivity is little, excellent thermal insulation performance, and fire resistance is good.But owing to be subject to the restriction of material choice, preparation technology, formulation parameter, product cost, make aerogel also have the problems such as the too high and Architectural Construction of cost is unreasonable in the application of building energy saving field, its application is restricted.Therefore, exploitation excellent thermal insulation performance and the good external-wall heat-insulation material of fire resistance are problems in the urgent need to address.
Summary of the invention
The present invention overcomes the defective that prior art exists, and a kind of inorganic building energy conservation wall thermal insulating heat-insulation composite material and preparation method thereof is provided, and this material has superior thermal and insulating performance and mechanical property, water proof fire retardant, and weather resistance is good, environmental protection.
For achieving the above object, the present invention adopts aerosil and pearlstone, glass fibre, clay compound, and preparation has the wall thermal insulating heat-insulation composite material of splendid heat-insulating property and mechanical property concurrently.
Inorganic building energy conservation wall thermal insulating heat-insulation composite material of the present invention is comprised of the raw material of following mass parts: aerosil 40-50, pearlstone 10-20, clay 5-10, glass fibre 5-10.
After above-mentioned materials and mineral binder bond mixed, repressed wall thermal insulating heat-insulation composite material.
Aerosil of the present invention adopts the method preparation of colloidal sol-gel take water glass as raw material, and the operation by optimizations such as soda acid two step method catalysis increases the porosity of material and specific surface area, and aperture size and thermal conductivity descend.
Described pearlstone is traditional inorganic heat preserving and heat insulation material that a kind of unit weight is light, thermal conductivity is lower, and price is lower, can reduce the cost of wall thermal insulating heat-insulation composite material.
Described clay, glass fibre can strengthen the intensity of wall thermal insulating heat-insulation composite material.
Described mineral binder bond is liquid soluble glass, and consumption is the 2%-5% of matrix material quality, the 2%-3.5% of preferred composite materials quality.
The present invention is than the beneficial effect of prior art
The present invention adopts sol-gel method to prepare the large aperture capacity silicon oxide aerogel take water glass as the silicon source, and pore volume reaches 2.5-3.0ml/g, and the thermal conductivity of matrix material reaches 0.030-0.040w/mk, and fire-protection rating reaches the A1 grade standard.Product of the present invention has superior thermal and insulating performance and mechanical property, water proof fire retardant, and weather resistance is good, environmental protection.
The present invention is further elaborated below in conjunction with embodiment.
Embodiment 1
Take by weighing aerosil 500 grams, pearlstone 200 grams, clay 100 grams, glass fibre 100 grams, add 18 gram liquid soluble glass, after stirring, put into special mould compression moulding, be the finished product that thermal conductivity 0.037 w/mk, fire-protection rating reach the A1 level after the oven dry.
Embodiment 2
Take by weighing aerosil 400 grams, pearlstone 100 grams, clay 50 grams, glass fibre 50 grams, add 30 gram liquid soluble glass, after stirring, put into special mould compression moulding, be the finished product that thermal conductivity 0.033 w/mk, fire-protection rating reach the A1 level after the oven dry.
Embodiment 3
Take by weighing aerosil 450 grams, pearlstone 150 grams, clay 75 grams.Glass fibre 75 gram adds 26.3 gram liquid soluble glass, after stirring, puts into special mould compression moulding, is the finished product that thermal conductivity 0.032w/mk, fire-protection rating reach the A1 level after the oven dry.
Embodiment 4
Take by weighing aerosil 400 grams, pearlstone 200 grams, clay 50 grams, glass fibre 100 grams, add 23 gram liquid soluble glass, after stirring, put into special mould compression moulding, be the finished product that thermal conductivity 0.034 w/mk, fire-protection rating reach the A1 level after the oven dry.
Embodiment 5
Take by weighing aerosil 500 grams, pearlstone 100 grams, clay 100 grams, glass fibre 50 grams, add 18.8 gram liquid soluble glass, after stirring, put into special mould compression moulding, be the finished product that thermal conductivity 0.037 w/mk, fire-protection rating reach the A1 level after the oven dry.
Embodiment 6
Take by weighing aerosil 480 grams, pearlstone 130 grams, clay 60 grams, glass fibre 80 grams, add 30 gram liquid soluble glass, after stirring, put into special mould compression moulding, be the finished product that thermal conductivity 0.033 w/mk, fire-protection rating reach the A1 level after the oven dry.
Embodiment 7
Take by weighing aerosil 420 grams, pearlstone 180 grams, clay 90 grams, glass fibre 60 grams, add 33.8 gram liquid soluble glass, after stirring, put into special mould compression moulding, be the finished product that thermal conductivity 0.035 w/mk, fire-protection rating reach the A1 level after the oven dry.
Embodiment 8
Take by weighing aerosil 460 grams, pearlstone 140 grams, clay 65 grams, glass fibre 90 grams, add 25 gram liquid soluble glass, after stirring, put into special mould compression moulding, be the finished product that thermal conductivity 0.032 w/mk, fire-protection rating reach the A1 level after the oven dry.

Claims (4)

1. an inorganic building energy conservation wall thermal insulating heat-insulation composite material is characterized in that being comprised of the raw material of following mass parts: aerosil 40-50, pearlstone 10-20, clay 5-10, glass fibre 5-10.
2. the preparation method of an inorganic building energy conservation wall thermal insulating heat-insulation composite material, after it is characterized in that aerosil, pearlstone, clay and glass fiber material and mineral binder bond mixed, repressed.
3. the preparation method of a kind of inorganic building energy conservation wall thermal insulating heat-insulation composite material according to claim 2 is characterised in that described mineral binder bond is liquid soluble glass, and consumption is the 2%-5% of matrix material quality.
4. according to claim 2 or/and the preparation method of 3 described a kind of inorganic building energy conservation wall thermal insulating heat-insulation composite materials, the consumption that is characterised in that described mineral binder bond is the 2%-3.5% of matrix material quality.
CN2012104165362A 2012-10-27 2012-10-27 Inorganic insulation composite material for building energy-saving wall and preparation method thereof Pending CN102964107A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103386281A (en) * 2013-07-15 2013-11-13 陕西盟创纳米新型材料股份有限公司 Silica aerogel particles with expanded perlite as a carrier, a preparation method and applications thereof
CN104496399A (en) * 2014-12-15 2015-04-08 苏州同玄新材料有限公司 Aerogel building heat preservation and thermal insulation composite material and preparation method thereof
CN104671737A (en) * 2015-02-11 2015-06-03 杭州钱江称重技术有限公司 High temperature thermal insulation material for tank number of torpedo cars
CN105481339A (en) * 2015-12-25 2016-04-13 山东鲁阳节能材料股份有限公司 Vacuum insulation board core veneer for buildings and preparation method thereof
CN106673585A (en) * 2016-12-01 2017-05-17 湖北硅金凝节能减排科技有限公司 Environment-friendly SiO2 aerogel heat insulation coating and preparation method thereof
CN107663103A (en) * 2016-07-27 2018-02-06 天津奇才科技发展有限公司 A kind of ultralow heat conduction high-fire-resistance warming plate of aeroge
CN107698227A (en) * 2015-06-17 2018-02-16 天津城建大学 A kind of preparation method of inorganic foamed insulating board for building
CN111647289A (en) * 2020-05-25 2020-09-11 贵州省昊越新型材料科技有限公司 Inorganic heat-preservation and heat-insulation coating
WO2021023321A1 (en) 2019-08-06 2021-02-11 First Point a.s. Fire-proof insulation material and a method for its production
CN114560677A (en) * 2022-03-31 2022-05-31 周道禹 Building energy-saving heat-insulating material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0106246B1 (en) * 1982-10-01 1986-12-17 General Refractories Company Expanded perlite/alkali metal silicate insulation material and a process for the production thereof
CN101143776A (en) * 2006-09-13 2008-03-19 上海暄洋化工材料科技有限公司 Nano thermal insulation energy-saving material and producing technique
CN102503349A (en) * 2011-11-05 2012-06-20 童甘霖 Inorganic composite heat insulating material
CN102603348A (en) * 2012-03-14 2012-07-25 刘相红 Nano-pore heat-insulation material and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0106246B1 (en) * 1982-10-01 1986-12-17 General Refractories Company Expanded perlite/alkali metal silicate insulation material and a process for the production thereof
CN101143776A (en) * 2006-09-13 2008-03-19 上海暄洋化工材料科技有限公司 Nano thermal insulation energy-saving material and producing technique
CN102503349A (en) * 2011-11-05 2012-06-20 童甘霖 Inorganic composite heat insulating material
CN102603348A (en) * 2012-03-14 2012-07-25 刘相红 Nano-pore heat-insulation material and manufacturing method thereof

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103386281A (en) * 2013-07-15 2013-11-13 陕西盟创纳米新型材料股份有限公司 Silica aerogel particles with expanded perlite as a carrier, a preparation method and applications thereof
CN103386281B (en) * 2013-07-15 2015-08-05 陕西盟创纳米新型材料股份有限公司 Take expanded perlite as silica aerogel particles, the Preparation method and use of carrier
CN104496399A (en) * 2014-12-15 2015-04-08 苏州同玄新材料有限公司 Aerogel building heat preservation and thermal insulation composite material and preparation method thereof
CN104671737A (en) * 2015-02-11 2015-06-03 杭州钱江称重技术有限公司 High temperature thermal insulation material for tank number of torpedo cars
CN104671737B (en) * 2015-02-11 2016-03-30 杭州钱江称重技术有限公司 A kind of high temperature insulating material for torpedo tank car tank number
CN107698227B (en) * 2015-06-17 2020-08-21 天津城建大学 Preparation method of inorganic foaming building insulation board
CN107698227A (en) * 2015-06-17 2018-02-16 天津城建大学 A kind of preparation method of inorganic foamed insulating board for building
CN105481339A (en) * 2015-12-25 2016-04-13 山东鲁阳节能材料股份有限公司 Vacuum insulation board core veneer for buildings and preparation method thereof
CN107663103A (en) * 2016-07-27 2018-02-06 天津奇才科技发展有限公司 A kind of ultralow heat conduction high-fire-resistance warming plate of aeroge
CN106673585A (en) * 2016-12-01 2017-05-17 湖北硅金凝节能减排科技有限公司 Environment-friendly SiO2 aerogel heat insulation coating and preparation method thereof
WO2021023321A1 (en) 2019-08-06 2021-02-11 First Point a.s. Fire-proof insulation material and a method for its production
CZ309105B6 (en) * 2019-08-06 2022-02-02 First Point a.s. Fire insulation material and producing it
CN111647289A (en) * 2020-05-25 2020-09-11 贵州省昊越新型材料科技有限公司 Inorganic heat-preservation and heat-insulation coating
CN114560677A (en) * 2022-03-31 2022-05-31 周道禹 Building energy-saving heat-insulating material and preparation method thereof

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Inventor after: Zhang Yuanxi

Inventor after: Zhou Risheng

Inventor after: Zhao Jianqing

Inventor after: Liang Jianqiang

Inventor after: Guo Xiujuan

Inventor before: Zhang Yuanxi

Inventor before: Zhou Risheng

Inventor before: Zhao Jianqing

Inventor before: Guo Xiujuan

COR Change of bibliographic data

Free format text: CORRECT: INVENTOR; FROM: ZHANG YUANXI ZHOU RISHENG ZHAO JIANQING GUO XIUJUAN TO: ZHANG YUANXI ZHOU RISHENG ZHAO JIANQING LIANG JIANQIANG GUO XIUJUAN

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Application publication date: 20130313