Summary of the invention
In order to overcome the low and defect such as easily to make moist of the fire resistance of the wall thermal insulating Flameproof composite material of prior art and poor thermal insulation property, rupture strength, impact strength, the invention provides a kind of fire resistance and heat-insulating property and other performance parameters preferably wall thermal insulating fire-resistant composite panel, it is much better than market common product.
The object of the invention is to be achieved through the following technical solutions:
A kind of wall thermal insulating fire-resistant composite panel, it is made up of the gypsum plank of lower floor and the mask paper on upper strata; Be bonded by binding material between described gypsum plank and described mask paper;
Described gypsum plank is prepared as follows and forms:
Following raw material is taken: line borate 1 part, sodium succinate 1 part, 2 parts, phenolic resins, hydroxyethylcellulose 6 parts, starch ether 6 parts, glass fiber 8 parts, polyvinyl alcohol 8 parts, borax 8-10 part, quartz sand 10-12 part, chitin 10-12 part, dolomite dust 15-20 part, pyrite dust 20-30 part, kieselguhr 30-40 part, water 50-60 part and land plaster 100-120 part according to weight portion;
Above-mentioned each raw material is mixed, then put in mortar mixer, stir and obtain mixed slurry, then mixed slurry is injected die casting and become sheet material, the demoulding after sheet material solidifies, finally sheet material being placed in temperature is 60 DEG C, and humidity is in the hygrothermal environment of 60% 12 hours, obtains gypsum plank;
Described mask paper is prepared as follows and forms:
Prepare burden according to weight portion in pond with slurry: cornstarch 5 parts, sodium phosphate trimer 5 parts, starch ether 20 parts, 30 parts, calcium sulfate, PLA 70 parts, glass fiber 80 parts, 100 parts, water, charcoal powder 150 and precipitated calcium carbonate 300 parts;
First each batching in pond with slurry is stirred and obtain slurry, then enter head box, make slurry be evenly distributed in fourdrinier part, enter vacuum system subsequently and carry out first step dehydration, take off the moisture of more than 50%, form half wet page; Half page wet enters squeezer and carries out second step dehydration, controlled pressure 30MPa, dewaters 30 minutes; Finally, enter dryer and carry out the 3rd step dehydration, control temperature is 120 DEG C, and the time is 15 minutes, obtains mask paper;
Described binding material is prepared as follows and forms:
Ethylene-vinyl acetate resin (EVA) 5 parts, white glue with vinyl 3 parts, French chalk 2 parts, 1 part, agar and casein 1 part is got according to weight portion; Be uniformly mixed and get final product;
The consumption of binding material is that every square metre of bond area uses 100g.
The beneficial effect that the present invention obtains:
1. the wall thermal insulating fire-resistant composite panel fire resistance prepared of the present invention and heat-insulating property is strong, to meet fiery stability time long, environment friendly and pollution-free, can remove pernicious gas effectively;
2. the composite plate that prepared by the present invention improves all greatly in performance parameters such as compressive strength and anti-folding modulus of elasticity, is better than market like product completely, possesses good market prospects;
3. raw material sources of the present invention are extensive, and preparation technology's simple possible, can large-scale industrialization promotion.
Detailed description of the invention
Below employing specific embodiment is further explained the present invention, but should not regards the restriction to initiative spirit of the present invention as.
Embodiment 1
A kind of wall thermal insulating fire-resistant composite panel, it is made up of the gypsum plank of lower floor and the mask paper on upper strata; Be bonded by binding material between described gypsum plank and described mask paper;
Described gypsum plank is prepared as follows and forms:
Following raw material is taken: line borate 1 part, sodium succinate 1 part, 2 parts, phenolic resins, hydroxyethylcellulose 6 parts, starch ether 6 parts, glass fiber 8 parts, polyvinyl alcohol 8 parts, borax 8 parts, quartz sand 10 parts, chitin 10 parts, dolomite dust 15 parts, pyrite dust 20 parts, 30 parts, kieselguhr, 50 parts, water and land plaster 100 parts according to weight portion;
Above-mentioned each raw material is mixed, then put in mortar mixer, stir and obtain mixed slurry, then mixed slurry is injected die casting and become sheet material, the demoulding after sheet material solidifies, finally sheet material being placed in temperature is 60 DEG C, and humidity is in the hygrothermal environment of 60% 12 hours, obtains the gypsum plank that thickness is 10mm;
Described mask paper is prepared as follows and forms:
Prepare burden according to weight portion in pond with slurry: cornstarch 5 parts, sodium phosphate trimer 5 parts, starch ether 20 parts, 30 parts, calcium sulfate, PLA 70 parts, glass fiber 80 parts, 100 parts, water, charcoal powder 150 and precipitated calcium carbonate 300 parts;
First each batching in pond with slurry is stirred and obtain slurry, then enter head box, make slurry be evenly distributed in fourdrinier part, enter vacuum system subsequently and carry out first step dehydration, take off the moisture of more than 50%, form half wet page; Half page wet enters squeezer and carries out second step dehydration, controlled pressure 30MPa, dewaters 30 minutes; Finally, enter dryer and carry out the 3rd step dehydration, control temperature is 120 DEG C, and the time is 15 minutes, namely obtains the mask paper that thickness is 2mm;
Described binding material is prepared as follows and forms:
Ethylene-vinyl acetate resin (EVA) 5 parts, white glue with vinyl 3 parts, French chalk 2 parts, 1 part, agar and casein 1 part is got according to weight portion; Be uniformly mixed and get final product;
The consumption of binding material is that every square metre of bond area uses 100g.
Embodiment 2
A kind of wall thermal insulating fire-resistant composite panel, it is made up of the gypsum plank of lower floor and the mask paper on upper strata; Be bonded by binding material between described gypsum plank and described mask paper;
Described gypsum plank is prepared as follows and forms:
Following raw material is taken: line borate 1 part, sodium succinate 1 part, 2 parts, phenolic resins, hydroxyethylcellulose 6 parts, starch ether 6 parts, glass fiber 8 parts, polyvinyl alcohol 8 parts, borax 10 parts, quartz sand 12 parts, chitin 12 parts, dolomite dust 20 parts, pyrite dust 30 parts, 40 parts, kieselguhr, 60 parts, water and land plaster 120 parts according to weight portion;
Above-mentioned each raw material is mixed, then put in mortar mixer, stir and obtain mixed slurry, then mixed slurry is injected die casting and become sheet material, the demoulding after sheet material solidifies, finally sheet material being placed in temperature is 60 DEG C, and humidity is in the hygrothermal environment of 60% 12 hours, obtains the gypsum plank that thickness is 10mm;
Described mask paper is prepared as follows and forms:
Prepare burden according to weight portion in pond with slurry: sodium phosphate trimer 5 parts, starch ether 20 parts, 30 parts, calcium sulfate, PLA 70 parts, glass fiber 80 parts, 100 parts, water, charcoal powder 150 and precipitated calcium carbonate 300 parts;
First each batching in pond with slurry is stirred and obtain slurry, then enter head box, make slurry be evenly distributed in fourdrinier part, enter vacuum system subsequently and carry out first step dehydration, take off the moisture of more than 50%, form half wet page; Half page wet enters squeezer and carries out second step dehydration, controlled pressure 30MPa, dewaters 30 minutes; Finally, enter dryer and carry out the 3rd step dehydration, control temperature is 120 DEG C, and the time is 15 minutes, namely obtains the mask paper that thickness is 2mm;
Described binding material is prepared as follows and forms:
Ethylene-vinyl acetate resin (EVA) 5 parts, white glue with vinyl 3 parts, French chalk 2 parts, 1 part, agar and casein 1 part is got according to weight portion; Be uniformly mixed and get final product;
The consumption of binding material is that every square metre of bond area uses 100g.
Embodiment 3
Wall thermal insulating fire-resistant composite panel various aspects of performance parameter experiment prepared by the present invention detects:
Contrast test 1: the composite plate prepared according to patented method (CN200710139236.3); Composite plate prepared by embodiment 1, composite plate (without cornstarch compared with embodiment 1) prepared by embodiment 2, the results are shown in Table 1.
Table 1
Group | Maximum operation (service) temperature DEG C | Compressive strength kpa | Coefficient of thermal conductivity W/ (m.K) | Anti-folding modulus of elasticity mpa |
Contrast test 1 | 600 | 178 | 0.068 | 3547 |
The embodiment of the present invention 1 | 980 | 323 | 0.016 | 7219 |
The embodiment of the present invention 2 | 990 | 315 | 0.023 | 7135 |
The composite plate fire resistance that after tested prepared by the embodiment of the present invention 1 is A1 level, and meeting fiery stability time is more than 80 minutes (with reference to GB/T9775-2008 standards).Composite plate prepared by the embodiment of the present invention 1 possesses good fire resistance and lower coefficient of thermal conductivity, and its heat-insulating property is better, and possesses preferably compressive strength and anti-folding modulus of elasticity, is better than market like product completely, possesses good market prospects.
Finally, it is also to be noted that what enumerate above is only several specific embodiments of the present invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be had.All distortion that those of ordinary skill in the art can directly derive from content disclosed by the invention or associate, all should think protection scope of the present invention.