CN102925900A - Alkaline chemical polishing solution and alkaline chemical polishing method - Google Patents

Alkaline chemical polishing solution and alkaline chemical polishing method Download PDF

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Publication number
CN102925900A
CN102925900A CN2012104009824A CN201210400982A CN102925900A CN 102925900 A CN102925900 A CN 102925900A CN 2012104009824 A CN2012104009824 A CN 2012104009824A CN 201210400982 A CN201210400982 A CN 201210400982A CN 102925900 A CN102925900 A CN 102925900A
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chemical polishing
basic chemical
polishing liquid
alkaline chemical
solution
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黄洪文
卢启才
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Guizhou Aerospace Linquan Motor Co Ltd
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Guizhou Aerospace Linquan Motor Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F3/00Brightening metals by chemical means
    • C23F3/02Light metals

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • ing And Chemical Polishing (AREA)

Abstract

The invention discloses an alkaline chemical polishing solution and an alkaline chemical polishing method. Each 1 L of alkaline chemical polishing solution comprises components of 150-280 g of sodium hydroxide, 100-150 g of sodium nitrite, 1-.1.2 g of sodium fluoride, 10-20 g of sodium phosphate, and the balance of a solvent; and meanwhile, the alkaline chemical polishing solution is utilized for alkaline chemical polishing. The alkaline chemical polishing solution and the alkaline chemical polishing method, disclosed by the invention, have the beneficial effects of solving the problems of scratching and impacting of aluminum alloy parts, improving surface roughness of parts, lowering production cost and avoiding environment pollution as a selective self-dissolution function of aluminum and an aluminum alloy is utilized in an alkaline solution to flatten and polish the surface of the aluminum.

Description

A kind of basic chemical polishing liquid and basic chemical polishing method
Technical field
The present invention relates to a kind of basic chemical polishing liquid and basic chemical polishing method, belong to industrial polishing technology field.
Background technology
The product of aluminum alloy materials is very many; the part shape complexity is various; and operation, turnover are more in the course of processing, because the material of aluminium alloy is softer, are very easy to scratch, damage; cause part to use; packaging protecting is also kept away the scuffing of unavoidable part, the generation of damaging howsoever, and traditional mode adopts the method for mechanical polishing can't satisfy the needs of product; the method of employing electropolishing has can't satisfy the product size requirement, mainly is the electropolishing lack of homogeneity.
The restriction that is not subjected to part shape, size is processed in chemical rightenning, do not need special frock clamp, once can process more part, now increasing enterprise adopts chemically polishing method to process, chemical rightenning is to utilize the chemical solution of definite composition to the surface of microcosmic injustice, the metal at outstanding position is dissolved fast, thereby just flat microcosmic plane surface not reach the effect of light.Because aluminium is amphoteric metal, so can obtain brightness effect with strong acid polishing fluid and strong basicity polishing fluid, after aluminium alloy is subject to oxidizing reaction, the speed of at a certain temperature aluminium alloy dissolving is corroded product and spreads gradually controlledly from the surface, and just plays polishing action when all electromotive force enough make anode potential reach corresponding oxidizing potential.
And the actual polishing fluid that uses is the strong acid polishing fluid mostly, contain phosphoric acid 60~70%, sulfuric acid 15~25%, nitric acid 10~20%, even higher, although the chemical rightenning for fine aluminium and duralumin adapts to better, produces a large amount of NOx gases when polishing, and is seriously polluted, solution is easy to wear out, cost is higher, and is larger to health and working the mischief property of environment, simultaneously, ununiformity and corrodibility also appear in surface of polished easily, tubercular corrosion occurs easily, dissolution rate is also very fast, is not the needs that adapt to very much alloy product.
Also exist in addition a kind of without the tobacco chemical brightening solution, mainly be in acid polishing slurry, to have added certain chemical substance without the tobacco chemical brightening solution, substitute nitric acid or added the additive that suppresses the oxynitride effusion, thereby reduce the discharging of oxynitride, but of low quality after the polishing mainly is the polishing that is applicable to fine aluminium, after the aluminium alloy polishing, the surface does not reach polishing effect, and burnt hair is brightless, can not meet the needs of production.
And a kind of basic chemical polishing liquid of comparative maturity does not also appear on the market.
Summary of the invention
The object of the present invention is to provide a kind of basic chemical polishing liquid and basic chemical polishing method, can solve the problem that the scuffing of aluminum alloy part is damaged, improve Part Surface Roughness, reduce production costs.
The objective of the invention is to be achieved through the following technical solutions: a kind of basic chemical polishing liquid comprises the component of following content in every 1L basic chemical polishing liquid:
Described solvent is the technical pure water purification.
A kind of basic chemical polishing method is mainly used in the polished finish of aluminium alloy, and it comprises following steps:
(1), the pending place that lip-deep hard defects, the cut of aluminum alloy part is darker is tied with sand paper first, then carries out mechanical sandblasting, removes the vestige of sand papering;
(2), the temperature with above-mentioned basic chemical polishing liquid is heated to 90~100 ℃;
(3), aluminium alloy is put into above-mentioned basic chemical polishing liquid carry out the selective autolyzing solution and be used for surface smooth and the polished aluminum alloy, the time of putting into is 5~15s, namely finishes the polished finish to aluminium alloy.
Utilize aluminium and aluminium alloy selective autolyzing solution in basic solution to be used for smooth and surface polished aluminum, improve the chemical process of its surfaceness, the chemical equation of its polishing process is:
2Al+6NaOH→2Na 3AlO 3+3H 2
Al 2O 3+2NaOH→2NaAlO 2+H 2O
2Al+NaNO 2+NaOH+H 2O→2NaAlO 2+NO 3
Sodium hydroxide has corrosion leveling effect; Sodium Nitrite has the leveling polishing action; the diffusion layer that sodium phosphate meeting formation one deck in reaction contains aluminium salt is adsorbed on the aluminium material surface; solubilizing reaction is proceeded; the aluminum ion that produces must pass diffusion layer and enter solution; therefore the dissolution rate of aluminium is subject to the control of thickness of diffusion layer; the toughness thickness of diffusion layer at calixconcavity place, aluminium surface is obviously greater than the thickness at its protrusion place; causing aluminum ion to be difficult to be diffused in the solution goes; consequently the aluminium at aluminium material surface calixconcavity place is subject to the protection of toughness diffusion layer; dissolution rate becomes slowly, and the aluminium at uneven surface protrusion place can comparatively promptly dissolve, and reaches the leveling effect.
Sodium Fluoride mainly plays the effect of promotor, can effectively suppress to produce the spot corrosion effect in the polishing process, improves its polishing effect.
Beneficial effect of the present invention is: utilize aluminium and aluminium alloy selective autolyzing solution in basic solution to be used for smooth and surface polished aluminum, solved the problem that the scuffing of aluminum alloy part is damaged, improve Part Surface Roughness, reduced production cost, also can not cause environmental pollution.
Embodiment
Further describe technical scheme of the present invention below in conjunction with embodiment, but that claimed scope is not limited to is described.
Embodiment 1
A kind of basic chemical polishing liquid comprises the component of following content in every 1L basic chemical polishing liquid:
Figure BDA00002281222000041
Described solvent is the technical pure water purification.
A kind of basic chemical polishing method is mainly used in the polished finish of aluminium alloy, and it comprises following steps:
(1), the pending place that lip-deep hard defects, the cut of aluminum alloy part is darker is tied with sand paper first, then carries out mechanical sandblasting, removes the vestige of sand papering;
(2), the temperature with above-mentioned basic chemical polishing liquid is heated to 90 ℃;
(3), aluminium alloy is put into above-mentioned basic chemical polishing liquid carry out the selective autolyzing solution and be used for surface smooth and the polished aluminum alloy, the time of putting into is 15s, namely finishes the polished finish to aluminium alloy.
Embodiment 2
A kind of basic chemical polishing liquid comprises the component of following content in every 1L basic chemical polishing liquid:
Figure BDA00002281222000042
Described solvent is the technical pure water purification.
A kind of basic chemical polishing method is mainly used in the polished finish of aluminium alloy, and it comprises following steps:
(1), the pending place that lip-deep hard defects, the cut of aluminum alloy part is darker is tied with sand paper first, then carries out mechanical sandblasting, removes the vestige of sand papering;
(2), the temperature with above-mentioned basic chemical polishing liquid is heated to 95 ℃;
(3), aluminium alloy is put into above-mentioned basic chemical polishing liquid carry out the selective autolyzing solution and be used for surface smooth and the polished aluminum alloy, the time of putting into is 10s, namely finishes the polished finish to aluminium alloy.
Embodiment 3
A kind of basic chemical polishing liquid comprises the component of following content in every 1L basic chemical polishing liquid:
Described solvent is the technical pure water purification.
A kind of basic chemical polishing method is mainly used in the polished finish of aluminium alloy, and it comprises following steps:
(1), the pending place that lip-deep hard defects, the cut of aluminum alloy part is darker is tied with sand paper first, then carries out mechanical sandblasting, removes the vestige of sand papering;
(2), the temperature with above-mentioned basic chemical polishing liquid is heated to 100 ℃;
(3), aluminium alloy is put into above-mentioned basic chemical polishing liquid carry out the selective autolyzing solution and be used for surface smooth and the polished aluminum alloy, the time of putting into is 5s, namely finishes the polished finish to aluminium alloy.
Embodiment 4
A kind of basic chemical polishing liquid comprises the component of following content in every 1L basic chemical polishing liquid:
Figure BDA00002281222000052
Described solvent is the technical pure water purification.
A kind of basic chemical polishing method is mainly used in the polished finish of aluminium alloy, and it comprises following steps:
(1), the pending place that lip-deep hard defects, the cut of aluminum alloy part is darker is tied with sand paper first, then carries out mechanical sandblasting, removes the vestige of sand papering;
(2), the temperature with above-mentioned basic chemical polishing liquid is heated to 92 ℃;
(3), aluminium alloy is put into above-mentioned basic chemical polishing liquid carry out the selective autolyzing solution and be used for surface smooth and the polished aluminum alloy, the time of putting into is 12s, namely finishes the polished finish to aluminium alloy.
Embodiment 5
A kind of basic chemical polishing liquid comprises the component of following content in every 1L basic chemical polishing liquid:
Figure BDA00002281222000062
Described solvent is the technical pure water purification.
A kind of basic chemical polishing method is mainly used in the polished finish of aluminium alloy, and it comprises following steps:
(1), the pending place that lip-deep hard defects, the cut of aluminum alloy part is darker is tied with sand paper first, then carries out mechanical sandblasting, removes the vestige of sand papering;
(2), the temperature with above-mentioned basic chemical polishing liquid is heated to 98 ℃;
(3), aluminium alloy is put into above-mentioned basic chemical polishing liquid carry out the selective autolyzing solution and be used for surface smooth and the polished aluminum alloy, the time of putting into is 7s, namely finishes the polished finish to aluminium alloy.

Claims (3)

1. basic chemical polishing liquid is characterized in that: the component that comprises following content in every 1L basic chemical polishing liquid:
Figure FDA00002281221900011
2. basic chemical polishing liquid according to claim 1, it is characterized in that: described solvent is the technical pure water purification.
3. basic chemical polishing method, it is characterized in that: be mainly used in the polished finish of aluminium alloy, it comprises following steps:
(1), the pending place that lip-deep hard defects, the cut of aluminum alloy part is darker is tied with sand paper first, then carries out mechanical sandblasting, removes the vestige of sand papering;
(2), the temperature with above-mentioned basic chemical polishing liquid is heated to 90~100 ℃;
(3), aluminium alloy is put into above-mentioned basic chemical polishing liquid carry out the selective autolyzing solution and be used for surface smooth and the polished aluminum alloy, the time of putting into is 5~15s, namely finishes the polished finish to aluminium alloy.
CN2012104009824A 2012-10-19 2012-10-19 Alkaline chemical polishing solution and alkaline chemical polishing method Pending CN102925900A (en)

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103334107A (en) * 2013-05-21 2013-10-02 内蒙古包钢钢联股份有限公司 Magnesium-aluminum alloy polishing solution and its preparation method and polishing method
CN103668228A (en) * 2013-11-20 2014-03-26 茹林宝 Surface treatment technology of aluminum alloy sectional material
CN104131294A (en) * 2014-07-01 2014-11-05 蚌埠市高华电子有限公司 Antibacterial mixed polishing solution for aluminium and aluminium alloy and preparation method thereof
CN104647195A (en) * 2013-11-22 2015-05-27 重庆市南川区南双科技有限公司 Polishing process for aluminum alloy hub surface
CN105039992A (en) * 2015-07-21 2015-11-11 安徽江威精密制造有限公司 Alkaline polishing solution and preparation method thereof
CN105177586A (en) * 2015-07-21 2015-12-23 安徽江威精密制造有限公司 Aluminum alloy polishing solution and preparing method thereof
CN105331979A (en) * 2015-10-21 2016-02-17 上海瑞特良化工有限公司 Aluminum chemical polishing solution and polishing method with same
CN105463483A (en) * 2015-11-27 2016-04-06 广东长盈精密技术有限公司 Aluminum product surface treatment method
CN106319522A (en) * 2015-07-08 2017-01-11 中国计量学院 Alkaline polishing process for aluminium alloy surface
CN106676529A (en) * 2015-03-30 2017-05-17 江苏理工学院 1060 aluminum alloy alkaline chemical polishing method and alkaline chemical polishing solution adopted by same
CN106757034A (en) * 2016-11-28 2017-05-31 江南大学 A kind of preparation method of alkalinous metal polishing fluid
CN108265295A (en) * 2016-12-30 2018-07-10 鸿富锦精密工业(深圳)有限公司 Decoating liquid
CN109576709A (en) * 2019-01-29 2019-04-05 中国科学院金属研究所 The chemical minimizing technology of Ta coating is sputtered on a kind of alloy steel matrix
CN110629225A (en) * 2018-06-25 2019-12-31 比亚迪股份有限公司 Aluminum alloy alkaline chemical polishing solution, preparation method and polishing method
CN111074280A (en) * 2019-12-20 2020-04-28 中建材浚鑫科技有限公司 Novel alkali polishing process
CN113201738A (en) * 2021-05-10 2021-08-03 哈尔滨工业大学 Electrochemical surface treatment method for selectively laser melting AlSi10Mg formed workpiece
CN114438497A (en) * 2022-02-25 2022-05-06 东莞市伟元科技有限公司 Non-phosphatizing polishing additive and production process thereof
CN114606498A (en) * 2022-05-12 2022-06-10 中唯精密工业有限公司 Plasma nano polishing solution and polishing method of cast aluminum alloy workpiece

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Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103334107B (en) * 2013-05-21 2016-06-01 内蒙古包钢钢联股份有限公司 The finishing method on magnesium-aluminium alloy material surface
CN103334107A (en) * 2013-05-21 2013-10-02 内蒙古包钢钢联股份有限公司 Magnesium-aluminum alloy polishing solution and its preparation method and polishing method
CN103668228A (en) * 2013-11-20 2014-03-26 茹林宝 Surface treatment technology of aluminum alloy sectional material
CN103668228B (en) * 2013-11-20 2016-08-31 上海闽坚铝业有限公司 The process of surface treatment of aluminium alloy extrusions
CN104647195A (en) * 2013-11-22 2015-05-27 重庆市南川区南双科技有限公司 Polishing process for aluminum alloy hub surface
CN104131294A (en) * 2014-07-01 2014-11-05 蚌埠市高华电子有限公司 Antibacterial mixed polishing solution for aluminium and aluminium alloy and preparation method thereof
CN104131294B (en) * 2014-07-01 2015-10-28 蚌埠市高华电子有限公司 A kind of Al and Alalloy mixed polishing solution with antibacterial effect and preparation method thereof
CN106702389B (en) * 2015-03-30 2019-01-25 江苏理工学院 7075 aluminum alloy alkaline chemical polishing method and alkaline chemical polishing solution adopted by same
CN106676529B (en) * 2015-03-30 2019-01-25 江苏理工学院 1060 aluminum alloy alkaline chemical polishing method and alkaline chemical polishing solution adopted by same
CN106676529A (en) * 2015-03-30 2017-05-17 江苏理工学院 1060 aluminum alloy alkaline chemical polishing method and alkaline chemical polishing solution adopted by same
CN106702389A (en) * 2015-03-30 2017-05-24 江苏理工学院 7075 aluminum alloy alkaline chemical polishing method and alkaline chemical polishing solution adopted by same
CN106319522A (en) * 2015-07-08 2017-01-11 中国计量学院 Alkaline polishing process for aluminium alloy surface
CN105039992A (en) * 2015-07-21 2015-11-11 安徽江威精密制造有限公司 Alkaline polishing solution and preparation method thereof
CN105177586A (en) * 2015-07-21 2015-12-23 安徽江威精密制造有限公司 Aluminum alloy polishing solution and preparing method thereof
CN105331979B (en) * 2015-10-21 2017-12-26 上海瑞特良化工有限公司 A kind of aluminium chemical polishing liquid and the polishing method using the polishing fluid
CN105331979A (en) * 2015-10-21 2016-02-17 上海瑞特良化工有限公司 Aluminum chemical polishing solution and polishing method with same
CN105463483B (en) * 2015-11-27 2017-11-21 广东长盈精密技术有限公司 Surface treating method for aluminum product
CN105463483A (en) * 2015-11-27 2016-04-06 广东长盈精密技术有限公司 Aluminum product surface treatment method
CN106757034A (en) * 2016-11-28 2017-05-31 江南大学 A kind of preparation method of alkalinous metal polishing fluid
CN108265295A (en) * 2016-12-30 2018-07-10 鸿富锦精密工业(深圳)有限公司 Decoating liquid
CN110629225A (en) * 2018-06-25 2019-12-31 比亚迪股份有限公司 Aluminum alloy alkaline chemical polishing solution, preparation method and polishing method
CN110629225B (en) * 2018-06-25 2021-11-12 比亚迪股份有限公司 Aluminum alloy alkaline chemical polishing solution, preparation method and polishing method
CN109576709A (en) * 2019-01-29 2019-04-05 中国科学院金属研究所 The chemical minimizing technology of Ta coating is sputtered on a kind of alloy steel matrix
CN111074280A (en) * 2019-12-20 2020-04-28 中建材浚鑫科技有限公司 Novel alkali polishing process
CN113201738A (en) * 2021-05-10 2021-08-03 哈尔滨工业大学 Electrochemical surface treatment method for selectively laser melting AlSi10Mg formed workpiece
CN114438497A (en) * 2022-02-25 2022-05-06 东莞市伟元科技有限公司 Non-phosphatizing polishing additive and production process thereof
CN114606498A (en) * 2022-05-12 2022-06-10 中唯精密工业有限公司 Plasma nano polishing solution and polishing method of cast aluminum alloy workpiece

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Application publication date: 20130213