CN102925145A - aluminate compound fluorescent powder - Google Patents
aluminate compound fluorescent powder Download PDFInfo
- Publication number
- CN102925145A CN102925145A CN2011102894378A CN201110289437A CN102925145A CN 102925145 A CN102925145 A CN 102925145A CN 2011102894378 A CN2011102894378 A CN 2011102894378A CN 201110289437 A CN201110289437 A CN 201110289437A CN 102925145 A CN102925145 A CN 102925145A
- Authority
- CN
- China
- Prior art keywords
- fluorescent material
- fluorescent powder
- light
- present
- aluminate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000843 powder Substances 0.000 title abstract description 16
- -1 aluminate compound Chemical class 0.000 title abstract 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract description 9
- 150000002602 lanthanoids Chemical class 0.000 claims abstract description 9
- 150000004645 aluminates Chemical class 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 29
- 238000005245 sintering Methods 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000003746 solid phase reaction Methods 0.000 claims description 6
- 238000010671 solid-state reaction Methods 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- 229910052691 Erbium Inorganic materials 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims description 3
- 229910052779 Neodymium Inorganic materials 0.000 claims description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 3
- 229910052772 Samarium Inorganic materials 0.000 claims description 3
- 229910052771 Terbium Inorganic materials 0.000 claims description 3
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 4
- 230000003287 optical effect Effects 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 2
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 239000011575 calcium Substances 0.000 description 11
- 238000009877 rendering Methods 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000005284 excitation Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052692 Dysprosium Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 229910019990 cerium-doped yttrium aluminum garnet Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 241001025261 Neoraja caerulea Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 241001419253 Spathiphyllum cochlearispathum Species 0.000 description 1
- JNDMLEXHDPKVFC-UHFFFAOYSA-N aluminum;oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Y+3] JNDMLEXHDPKVFC-UHFFFAOYSA-N 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 244000144985 peep Species 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 229910019655 synthetic inorganic crystalline material Inorganic materials 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910019901 yttrium aluminum garnet Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/77064—Aluminosilicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7704—Halogenides
- C09K11/7705—Halogenides with alkali or alkaline earth metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
- H01L33/502—Wavelength conversion materials
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Luminescent Compositions (AREA)
- Led Device Packages (AREA)
Abstract
The invention discloses an aluminate compound fluorescent powder and a preparation method thereof, and finds that partial substitution of Al/F element by Si/O element can improve the optical property, and the general formula of the aluminate fluorescent powder is CaaSrbBacAldSieOfFgRhWherein R is one selected from lanthanide series metal elements. In addition, the fluorescent powder disclosed by the invention can be used for carrying out structure fine adjustment by partially replacing Al/F elements with Si/O, and changing the existence proportion of different valences of lanthanide series metal in the fluorescent powder, so as to regulate and control the light emission property of the fluorescent powder.
Description
Technical field
The present invention relates to a kind of phosphor material powder, particularly a kind of improve its optical property partly replace the aluminate class compound fluorescent material of Al/F element with the Si/O element.
Background technology
Along with the evolution of civilization and the enhancing of carbon reduction environmental consciousness, various countries are just step by step with photodiode (Light Emitting Diode at present, LED) replace conventional light source, to have a volume little because of photodiode, current consumption is low (to be 1/10th of white flag bulb, fluorescent lamp 1/2nd), life-span is long, luminous efficiency is good, the advantages such as operant response speed is fast, can solve the problem that conventional light source is difficult to overcome, therefore be applied at present red signal lamp used by rail workers, automotive luminaire, the assemblies such as indicating meter, because it meets the environmental protection concept of emphasizing now, is described as 21st century it " green illumination light source ".
Japan day inferior (Nichia) chemical company proposed to excite by blue-ray LED yttrium aluminum garnet (the Cerium-doped yttrium aluminum garnet of cerium doping in 1996; YAG:Ce) fluorescent material produces yellow fluorescence, its with blue light after can produce cold white light, this is first white light-emitting diodes, however because this white light lacks ruddiness composition, therefore its color rendering is low, and this patent by day an inferior patent limited.Because the full spectral band of white light-emitting diodes palpus tool is given out light and just can be reached high color rendering and desired color temperature, except blue light diode collocation YAG and red fluorescence powder, also have that blue light diode collocation is green, red fluorescence powder and UV-LED arrange in pairs or groups bluish-green red trichromatism fluorescent material etc. blendes together the white light mode, if wherein will produce desirable colour temperature (warm white), UV-LED collocation three-color phosphor has the better efficient of giving out light, and is present primary research topic therefore exploitation is fit to blueness, green, the red fluorescence powder of ultraviolet excitation.
The research that fluorescent material is relevant at present is except the exploitation of new host lattice, other element that mixes in host lattice replaces host lattice element originally and uses and improve luminous and also be common research direction, such as the people such as Duan in 2011 on Chemistry of material periodical (Chemistry Materials, dx.doi.org/10.1021/cm103495j) deliver Re
2Si
4N
6The research of C (RE=Lu, Y, Gd) series phosphor powder namely uses RE/C to replace originally in MRESi
4N
7In M/N (M=Ba, Sr, Ca), the covalency that utilizes the C element with and use the stability of improving host lattice than the bond characteristic of rigidity, therefore by the replacement of different elements to adjust light-emitting phosphor character and stability also for present main goal in research.
The people such as Yu in 1997 on Cement and Concrete Research periodical (Cement Concrete Res, 1997,27,1439-1449) deliver Ca
12Al
14O
32F
2Preparation method and single crystal structure, its structure is with [AlO
4] tetrahedron consist of, its unit cell belongs to tetragonal spheroidal, spacer is I43d, between the tetrahedron with Sauerstoffatom as bridge joint, calcium atom and six oxygen and a fluorine atom coordination belong to seven coordinations, because the vacancy case that forms in the structure is filled up by fluorine atom, this crystal is compared to Ca
12A
7Structure will have more stability, be fit to be applied to fluorescent material.
Summary of the invention
Purpose of the present invention aims to provide a kind of fluorescent material that has more stability.
An of the present invention purpose aims to provide a kind of fluorescent material of promoting color rendering.
Another object of the present invention aims to provide a kind of making method of simplification and the cost that reduces fluorescent material.
For reaching above-mentioned purpose, the aluminate class compound fluorescent material that the present invention discloses is synthetic with solid state reaction under the condition of sintering temperature T and sintering pressure P, and its prescription is Ca
aSr
bBa
cAl
dSi
eO
fF
gR
h, (0≤a＜12,10≤a+b+c+h≤12 wherein; 0≤b＜12; 0≤c＜12; 0＜h≤1), (12≤d＜14,12＜d+e≤14; 0＜e≤2), 30≤f≤34; , 0＜g≤2, R is the lanthanide series metal dvielement, as the luminescence center of fluorescent material.Wherein, the employed sintering temperature T of this solid state reaction is 1000～1400 ℃, and sintering pressure Y is 0.1～0.9MPa.This fluorescent material can be that the photodiode of 200～400nm excites by wavelength, and its radiation wavelength is 400-700nm.Wherein, lanthanide element R be Ce, Eu, Pr, Nd, Sm, Tb, Er, Yb, Dy one of them, to cause giving out light of different range.
Disclosed fluorescent material, can be the ultraviolet excitation of 200～400nm by the chip wavelength, more can partly replace Al/F by Si/O and carry out the structure fine setting, change by the center coordination environment of giving out light, the modulation lanthanide series metal in lattice different valence mumbers have a ratio, and then control its optical property, and its scope of giving out light can contain blue green light and ruddiness simultaneously, collocation UV-LED synthesize white light can be promoted its color rendering, use the powder of less kind also can simplify making processes and reduce cost, have application potential and learning value.
Description of drawings
Fig. 1 is the diffracting spectrum of its X-ray powder of preferred embodiment of the present invention (A)～(E);
Fig. 2 is the radiating light spectrogram of preferred embodiment of the present invention (A)～(E);
Fig. 3 A is the exciting light spectrogram () of preferred embodiment of the present invention (A)～(E);
Fig. 3 B is the exciting light spectrogram (two) of preferred embodiment of the present invention (A)～(E);
Fig. 4 is the tristimulus coordinates figure of preferred embodiment of the present invention (A)～(E).
Embodiment
Below in conjunction with accompanying drawing, embodiment and testing data, be described in more detail with other technical characterictic and advantage the present invention is above-mentioned.
Aluminate class compound fluorescent material of the present invention is to be prepared from solid state reaction, and its sintering temperature T is 1000～1400 ℃, and sintering pressure P is 0.1～0.9MPa.With chemical formula Ca
aSr
bBa
cAl
dSi
eO
fF
gR
hExpression, wherein (0≤a＜12,10≤a+b+c+h≤12; 0≤b＜12; 0≤c＜12; 0＜h≤1), (12≤d＜14,12＜d+e≤14; 0＜e≤2), 30≤f≤34; , 0＜g≤2, wherein R be lanthanide element Ce, Eu, Pr, Nd, Sm, Tb, Er, Yb, Dy one of them.Preferred embodiment of the present invention (A)～(E) is Ca
11.9Al
14-xSi
xO
32+XF
2-x: Eu
0.1(x=0.1,0.2,0.3,0.5,0.6) sample, fill a prescription as shown in the table:
As shown in Figure 1, be the X light powder diffraction collection of illustrative plates of preferred embodiment of the present invention (A)～(E).According to the prepared Ca of the embodiment of the invention (A)～(E)
11.9Al
14-xSi
xO
32+XF
2-x: Eu
0.1(x=0.1,0.2,0.3,0.5,0.6) sample is identified its crystalline phase purity with the X light powder diffraction collection of illustrative plates, can find that the fluorescent material that the present invention synthesizes is pure phase.
Fig. 3 A, 3B are exciting light spectrogram (), (two) of preferred embodiment of the present invention (A)～(E).The prepared Ca of the embodiment of the invention (A)～(E)
11.9Al
14-xSi
xO
32+XF
2-x: Eu
0.1(x=0.1,0.2,0.3,0.5,0.6) sample can be excited by the photodiode of wavelength 200～400nm, and especially along with the increase of Si/O amount, near the excitation of spectra effect wavelength 250nm and the 325nm is more remarkable.
Fig. 2 and Fig. 4 are radiating light spectrogram and the tristimulus coordinates figure of preferred embodiment of the present invention (A)～(E).As shown in FIG., can learn the prepared Ca of the embodiment of the invention (A)～(E)
11.9Al
14-xSi
xO
32+XF
2-x: Eu
0.1(x=0.1,0.2,0.3,0.5,0.6) sample, its radiation wavelength is 400～700nm, and partly replaces the change of Al/F amount with Si/O, the structure fine setting can be controlled Eu
2+/ Eu
3+Ratio, and then adjust the intensity of giving out light of blue green light and red range, along with the Si/O trace increases and the corresponding minimizing of Al/F, bluish-green light intensity presents great growth, red light intensity is corresponding reduction then.In addition, the tristimulus coordinates figure that its emission spectrum data are formulated with International Commission on Illumination carries out the formula conversion, obtains the tristimulus coordinates of each fluorescent material, is shown in respectively on the coordinate diagram, can peep the Ca that knows that this preferred embodiment is synthetic
11.9Al
14-xSi
xO
32+XF
2-x: Eu
0.1Rise with the x value, can be adapted to blue light range by red range with giving out light.
Accordingly, disclosed fluorescent material, can partly replace Al/F by Si/O and carry out the structure fine setting, change by the center coordination environment of giving out light, the modulation lanthanide series metal in lattice different valence mumbers have a ratio, and then control its optical property, and its scope of giving out light can contain blue green light and ruddiness simultaneously, collocation UV-LED synthesize white light can be promoted its color rendering, and the aluminate class compound fluorescent material Ca of this preferred embodiment
11.9Al
14-xSi
xO
32+XF
2-x: Eu
0.1, the raw material of its use is contained CaCO
3, Al
2O
3, SiO
2, CaF
2, Eu
2O
3, takes by weighing suitable raw material behind the even mixed grinding of mortar according to prescription, place under 1250 ℃, sintering 6 hours under hydrogen (5%)-nitrogen (95%) atmosphere, get final product to get product.Making processes is simple, is beneficial to a large amount of productions, uses the powder of less kind also can simplify making processes and reduce cost, has application potential and learning value.
Each cited embodiment of the application's case is preferred embodiment of the present invention only, is not to limit the scope of the invention.Anyone all should be covered by in the claim of the present invention in modification or the change of doing in not unconventional spiritual scope of the present invention.
Claims (6)
1. an aluminate class compound fluorescent material is synthetic with solid state reaction under the condition of sintering temperature T and sintering pressure P, and its prescription is Ca
aSr
bBa
cAl
dSi
eO
fF
gR
h, (0≤a＜12,10≤a+b+c+h≤12 wherein; 0≤b＜12; 0≤c＜12; 0＜h≤1), (12≤d＜14,12＜d+e≤14; 0＜e≤2), 30≤f≤34; , 0＜g≤2, wherein R is lanthanide element.
2. fluorescent material as claimed in claim 1 is characterized in that: described lanthanide element R is a kind of among Ce, Eu, Pr, Nd, Sm, Tb, Er, Yb or the Dy.
3. fluorescent material as claimed in claim 1, it is characterized in that: the sintering temperature T of described solid state reaction is 1000～1400 ℃.
4. fluorescent material as claimed in claim 1, it is characterized in that: the sintering pressure P of described solid state reaction is 0.1～0.9MPa.
5. fluorescent material as claimed in claim 1 is characterized in that: described fluorescent material can be that the photodiode of 200～400nm excites by wavelength.
6. fluorescent material as claimed in claim 1, it is characterized in that: the radiation wavelength of described fluorescent material is 400～700nm.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW100128906 | 2011-08-12 | ||
| TW100128906A TWI432555B (en) | 2011-08-12 | 2011-08-12 | Aluminate phosphor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102925145A true CN102925145A (en) | 2013-02-13 |
Family
ID=47640079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102894378A Pending CN102925145A (en) | 2011-08-12 | 2011-09-27 | aluminate compound fluorescent powder |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5563542B2 (en) |
| KR (1) | KR101331302B1 (en) |
| CN (1) | CN102925145A (en) |
| TW (1) | TWI432555B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104119888A (en) * | 2014-08-06 | 2014-10-29 | 广西师范学院 | Europium-doped fluoroaluminate matrix fluorescent powder and preparation method thereof |
| CN107987828A (en) * | 2017-12-29 | 2018-05-04 | 河北工业大学 | A kind of mayenite structure fluorescent powder of LED white light emissions |
| CN112225450A (en) * | 2020-09-23 | 2021-01-15 | 中国计量大学 | Novel lanthanide-doped wide-color-gamut fluorescent glass and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115491196B (en) * | 2022-11-21 | 2023-03-24 | 四川世纪和光科技发展有限公司 | Red light fluorescent composition, red light fluorescent film and red light LED light source |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1537330A (en) * | 1975-04-15 | 1978-12-29 | Philips Electronic Associated | Luminescent materials |
| WO2007056311A2 (en) * | 2005-11-08 | 2007-05-18 | Intematix Corporation | Silicate-based green phosphors |
| CN101208407A (en) * | 2005-04-20 | 2008-06-25 | 易特斯股份公司 | Novel materials used for emitting light |
| US20080149893A1 (en) * | 2006-12-25 | 2008-06-26 | Industrial Technology Research Institute | White light illumination device |
| CN101857361A (en) * | 2010-01-19 | 2010-10-13 | 华东理工大学 | Europium-doped oxyfluoride aluminosilicate luminous glass and preparation method thereof |
| WO2011040709A2 (en) * | 2009-09-29 | 2011-04-07 | 한국화학연구원 | (halo)silicate-based phosphor and method for preparing same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7903102A (en) * | 1979-04-20 | 1980-10-22 | Philips Nv | LUMINESCENT FABRIC WITH NATURAL ALKALINE SILICATE ALUMINATE GRID. |
| US7351281B2 (en) * | 2001-09-26 | 2008-04-01 | Doxa Aktiebolag | Powdered material and ceramic material manufactured therefrom |
| WO2006111568A2 (en) * | 2005-04-20 | 2006-10-26 | Etech Ag | Novel materials used for emitting light |
| JP4931176B2 (en) * | 2005-09-14 | 2012-05-16 | 株式会社アルバック | Phosphor, method for manufacturing the same, and light emitting device |
| CN101605867B (en) * | 2006-10-03 | 2013-05-08 | 渲染材料公司 | Metal silicate halide phosphors and led lighting devices using the same |
| TW201005075A (en) * | 2008-07-24 | 2010-02-01 | Univ Nat Chiao Tung | White-emitting phosphors and lighting apparatus thereof |
| KR20100070731A (en) | 2008-12-18 | 2010-06-28 | 삼성전자주식회사 | Halosilicate phosphors and white light emitting devices including same |
-
2011
- 2011-08-12 TW TW100128906A patent/TWI432555B/en not_active IP Right Cessation
- 2011-09-27 CN CN2011102894378A patent/CN102925145A/en active Pending
- 2011-11-10 JP JP2011246358A patent/JP5563542B2/en not_active Expired - Fee Related
- 2011-12-08 KR KR1020110130741A patent/KR101331302B1/en active IP Right Grant
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1537330A (en) * | 1975-04-15 | 1978-12-29 | Philips Electronic Associated | Luminescent materials |
| CN101208407A (en) * | 2005-04-20 | 2008-06-25 | 易特斯股份公司 | Novel materials used for emitting light |
| WO2007056311A2 (en) * | 2005-11-08 | 2007-05-18 | Intematix Corporation | Silicate-based green phosphors |
| US20080149893A1 (en) * | 2006-12-25 | 2008-06-26 | Industrial Technology Research Institute | White light illumination device |
| WO2011040709A2 (en) * | 2009-09-29 | 2011-04-07 | 한국화학연구원 | (halo)silicate-based phosphor and method for preparing same |
| CN101857361A (en) * | 2010-01-19 | 2010-10-13 | 华东理工大学 | Europium-doped oxyfluoride aluminosilicate luminous glass and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104119888A (en) * | 2014-08-06 | 2014-10-29 | 广西师范学院 | Europium-doped fluoroaluminate matrix fluorescent powder and preparation method thereof |
| CN104119888B (en) * | 2014-08-06 | 2016-08-24 | 广西师范学院 | A kind of europium doped with fluorine aluminate substrate fluorescent powder and preparation method thereof |
| CN107987828A (en) * | 2017-12-29 | 2018-05-04 | 河北工业大学 | A kind of mayenite structure fluorescent powder of LED white light emissions |
| CN112225450A (en) * | 2020-09-23 | 2021-01-15 | 中国计量大学 | Novel lanthanide-doped wide-color-gamut fluorescent glass and preparation method thereof |
| CN112225450B (en) * | 2020-09-23 | 2022-10-28 | 中国计量大学 | Lanthanide-doped wide-color-gamut fluorescent glass and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201307530A (en) | 2013-02-16 |
| KR20130018094A (en) | 2013-02-20 |
| TWI432555B (en) | 2014-04-01 |
| JP5563542B2 (en) | 2014-07-30 |
| JP2013040318A (en) | 2013-02-28 |
| KR101331302B1 (en) | 2013-11-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101726246B1 (en) | Oxynitride orange-red fluorescent substance and light-emitting film or light-emitting sheet and light-emitting device comprising same | |
| CN103881706B (en) | A kind of nitric oxide fluorescent powder, its preparation method and the light-emitting device containing this fluorescent material | |
| CN107384399A (en) | YAG types fluorescent material and preparation method, its YAG type crystalline ceramics fluorophor prepared and application | |
| CN106479498A (en) | A kind of Nitrogen oxide blue fluorescent powder and preparation method and application | |
| CN102421869A (en) | Luminous substances based on eu2+-(co-)doped mixed garnet crystals and production and use thereof | |
| CN106544021B (en) | The borate fluorescent powder and preparation method thereof that a kind of cerium, terbium are co-doped with | |
| CN107474842A (en) | A kind of fluorescent tube fluorescent material formula | |
| CN102925145A (en) | aluminate compound fluorescent powder | |
| CN102391859A (en) | Green fluorescent powder for white LED (light-emitting diode) use, its preparation method and application | |
| CN103881705B (en) | Cerium, terbium or europium silico-aluminate blue-green fluorescent powder mixing activation altogether and preparation method thereof | |
| CN105349147A (en) | Ultraviolet-to-blue light excited phosphate-based red fluorescent powder and preparation method thereof | |
| CN103254895B (en) | Aluminosilicate green fluorescent powder and preparation method thereof | |
| KR101602313B1 (en) | NASICON-structure phosphor and light emitting diodes including the NASICON-structure phosphor for solid-state lighting applications | |
| CN101838533B (en) | Fluorescent material for LED and preparation method thereof | |
| CN102229802A (en) | Rare earth double primary colour luminescent material for converting white light by utilizing violet light LED (light-emitting diode) and preparation method thereof | |
| CN102876325B (en) | Light color adjustable valence alternation manganese ion doped aluminate luminescent material and preparation method thereof | |
| CN104893720A (en) | Blue-green phosphor for white LED, preparation method of blue-green phosphor and white LED light-emitting device | |
| CN111138191B (en) | Eu (Eu)3+Ion activated tantalate fluorescent ceramic and synthesis method and application thereof | |
| CN104327852B (en) | Silicon/germinate phosphor, preparation method and application thereof | |
| CN101921591B (en) | Green light luminescent material and preparation method thereof | |
| CN109943324A (en) | A kind of ultra-wide white light phosphor and its preparation method and application and luminaire | |
| CN109628093A (en) | A kind of Eu2+Ion doping alumino-silicate blue colour fluorescent powder and preparation method thereof | |
| CN104804742B (en) | Red fluorescent powder for white light LED and preparation method thereof | |
| CN103265953B (en) | A kind of europium ion Eu 3+the red fluorescence powder activated, preparation method and application | |
| CN103087709A (en) | Cerium-ion-doped silicate blue fluorescent powder and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130213 |