CN102895841B - A kind of for the isobutylaldehyde tail gas recycle of storage tank and the method for process and device thereof - Google Patents

A kind of for the isobutylaldehyde tail gas recycle of storage tank and the method for process and device thereof Download PDF

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Publication number
CN102895841B
CN102895841B CN201110388097.4A CN201110388097A CN102895841B CN 102895841 B CN102895841 B CN 102895841B CN 201110388097 A CN201110388097 A CN 201110388097A CN 102895841 B CN102895841 B CN 102895841B
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storage tank
nitrogen
appendix
isobutylaldehyde
retort
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CN102895841A (en
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史先召
黄伟金
孙承莉
黄福光
奚吉林
丁亚军
倪震
李岩
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JIANGSU HAIQI CHEMICAL STORAGE Co Ltd
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JIANGSU HAIQI CHEMICAL STORAGE Co Ltd
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Abstract

The invention discloses a kind of for the isobutylaldehyde tail gas recycle of storage tank and the device of process, is nitrogen pot (1) through appendix I? (5) communicate with storage tank (3), storage tank (3) is communicated with retort (8) by appendix II (6), nitrogen air-valve (2) and check valve (4) are respectively on appendix I (5) and on appendix II (6), does retort (8) pass through appendix? III (7) communicates with in water tank (9).The present invention also has and reclaims and the method for process, and one, first give in the storage tank (3) of storage isobutylaldehyde and supplement nitrogen, nitrogen floats on and liquid level is formed nitrogen envelope; Two, the mist entered into containing nitrogen and isobutylaldehyde tail gas in retort (8) is entered in the methanol solution in retort (8) by exhaust shower nozzle (11), is isobutylaldehyde tail gas in mist dissolved by methanol solution absorption, by appendix after remaining nitrogen floats? III? (7) be drained in water tank (9) and collect.

Description

A kind of for the isobutylaldehyde tail gas recycle of storage tank and the method for process and device thereof
Technical field
The present invention relates to a kind of for the isobutylaldehyde tail gas recycle of storage tank and the method for process and device thereof.
Background technology
Tail gas at present in the air accumulator of storage isobutylaldehyde is often directly be discharged in air by breather valve, owing to containing isobutylaldehyde gas and nitrogen, so not only contaminated environment in tail gas, harmful, and material loss in storage tank is high.
Summary of the invention
The invention provides a kind of recovery for isobutylaldehyde tail gas and processing method and device thereof, the tail gas of isobutylaldehyde not only can reclaim and process, preventing pollution environment by effectively, avoids tail gas to damage human body.
Present invention employs following technical scheme: a kind of for the isobutylaldehyde tail gas recycle of storage tank and the device of process, it comprises nitrogen pot, nitrogen air-valve, check valve, appendix I, appendix II, appendix III, retort and water tank, appendix I is between nitrogen pot and the storage tank top of storage isobutylaldehyde, nitrogen pot communicates with storage tank through appendix I, nitrogen air-valve is arranged on appendix I, appendix II is between storage tank and the retort that methanol solution is housed, storage tank is communicated with retort by appendix II, exhaust shower nozzle is provided with in one end that appendix II extend in retort, check valve is arranged on appendix II, appendix III is between the top and water tank of retort, retort is communicated with in water tank by appendix III, also filler is provided with at the top of retort, outlet is provided with in the bottom of retort.
Described check valve is set to one-way breather valve.
The invention also discloses a kind of for the isobutylaldehyde tail gas recycle of storage tank and the method for process, it comprises the following steps:
Step one, first the nitrogen in nitrogen pot is supplemented nitrogen in the storage tank that storage isobutylaldehyde given by nitrogen air-valve, the liquid level that nitrogen floats on isobutylaldehyde is formed nitrogen envelope, when the air pressure in storage tank is greater than the pressure of storage tank, the mist containing nitrogen and isobutylaldehyde tail gas in storage tank will overflow and enter into retort by one-way breather valve and adsorb, when the air pressure in storage tank is less than the pressure of storage tank, in storage tank, carry out benefit nitrogen, make the air pressure in storage tank reach pressure;
Step 2, the mist entered into containing nitrogen and isobutylaldehyde tail gas in retort is entered in the methanol solution in retort by exhaust shower nozzle, exhaust shower nozzle immerses in methanol solution completely, isobutylaldehyde tail gas in mist is dissolved by methanol solution absorption, is drained in water tank collects after remaining nitrogen floats by appendix III.
In step 2 of the present invention, the concentration of methanol solution is the methanol solution of 60%.When having the taste of isobutylaldehyde tail gas in step 2 of the present invention in water tank, the isobutylaldehyde tail gas adsorbed in methanol solution is saturated, and at this moment methanol solution needs to change.
The present invention has following beneficial effect: after adopting above technical scheme, the present invention can utilize methanol solution that the tail gas in storage tank is effectively absorbed, dissolved, isobutylaldehyde exhaust emissions so just can be prevented in air, so not only preventing pollution environment, avoids tail gas to damage human body.The raw material that the present invention adopts is methyl alcohol, and the raw material adopted is all daily nontoxic raw material, and cost is low, little to the injury of human body.Check valve of the present invention adopts one-way breather valve, and it can regulate conveying gas effectively.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Detailed description of the invention
In FIG, the invention provides a kind of for the isobutylaldehyde tail gas recycle of storage tank and the device of process, it comprises nitrogen pot 1, nitrogen air-valve 2, check valve 4, appendix I 5, appendix II 6, appendix III 7, retort 8 and water tank 9, appendix I 5 is between nitrogen pot 1 and storage tank 3 top of storage isobutylaldehyde, nitrogen pot 1 communicates with storage tank 3 through appendix I 5, nitrogen air-valve 2 is arranged on appendix I 5, appendix II 6 is between storage tank 3 and the retort 8 that methanol solution is housed, storage tank 3 is communicated with retort 8 by appendix II 6, exhaust shower nozzle 11 is provided with in appendix II 6 one end extend in retort 8, check valve 4 is arranged on appendix II 6, check valve 4 is set to one-way breather valve, appendix III 7 is between the top of retort 8 and water tank 9, retort 8 is communicated with in water tank 9 by appendix III 7, filler 12 is also provided with at the top of retort 8, outlet 10 is provided with in the bottom of retort 8.
The invention also discloses a kind of for the isobutylaldehyde tail gas recycle of storage tank and the method for process, it comprises the following steps:
Step one, first the nitrogen in nitrogen pot 1 is supplemented nitrogen in the storage tank 3 that storage isobutylaldehyde given by nitrogen air-valve 2, the liquid level that nitrogen floats on isobutylaldehyde is formed nitrogen envelope, when the air pressure in storage tank 3 is greater than the pressure of storage tank 3, the mist containing nitrogen and isobutylaldehyde tail gas in storage tank 3 will overflow and enter into retort 8 by one-way breather valve and adsorb, when the air pressure in storage tank 3 is less than the pressure of storage tank 3, carry out benefit nitrogen in storage tank 3, make the air pressure in storage tank 3 reach pressure; Step 2, the mist entered into containing nitrogen and isobutylaldehyde tail gas in retort 8 is entered in the methanol solution in retort 8 by exhaust shower nozzle 11, the concentration of methanol solution is the methanol solution of 60%, exhaust shower nozzle 11 immerses in methanol solution completely, isobutylaldehyde tail gas in mist is dissolved by methanol solution absorption, be drained in water tank 9 by appendix III 7 after remaining nitrogen floats and collect, when there being the taste of isobutylaldehyde tail gas in water tank 9, the isobutylaldehyde tail gas adsorbed in methanol solution is saturated, and at this moment methanol solution needs to change.

Claims (1)

1., for the isobutylaldehyde tail gas recycle of storage tank and a method for process, it comprises the following steps:
Step one, first the nitrogen in nitrogen pot (1) is supplemented nitrogen in the storage tank (3) that storage isobutylaldehyde given by nitrogen air-valve (2), the liquid level that nitrogen floats on isobutylaldehyde is formed nitrogen envelope, when the air pressure in storage tank (3) is greater than the pressure of storage tank (3), the mist containing nitrogen and isobutylaldehyde tail gas in storage tank (3) will overflow and enter into retort (8) by one-way breather valve and adsorb, when the air pressure in storage tank (3) is less than the pressure of storage tank (3), storage tank carries out benefit nitrogen in (3), the air pressure in storage tank (3) is made to reach pressure,
Step 2, the mist entered into containing nitrogen and isobutylaldehyde tail gas in retort (8) is entered in the methanol solution in retort (8) by exhaust shower nozzle (11), exhaust shower nozzle (11) is immersed in methanol solution completely, the concentration of methanol solution is the methanol solution of 60%, isobutylaldehyde tail gas in mist is dissolved by methanol solution absorption, be drained in water tank (9) by appendix III (7) after remaining nitrogen floats and collect, when having the taste of isobutylaldehyde tail gas in water tank (9), the isobutylaldehyde tail gas adsorbed in methanol solution is saturated, at this moment methanol solution needs to change, nitrogen pot (1) is comprised for the isobutylaldehyde tail gas recycle of storage tank and the device of process, nitrogen air-valve (2), check valve (4), appendix I (5), appendix II (6), appendix III (7), retort (8) and water tank (9), appendix I (5) is positioned between storage tank (3) top of nitrogen pot (1) and storage isobutylaldehyde, check valve (4) is set to one-way breather valve, nitrogen pot (1) communicates with storage tank (3) through appendix I (5), nitrogen air-valve (2) is arranged on appendix I (5), appendix II (6) is positioned between storage tank (3) and the retort (8) that methanol solution is housed, storage tank (3) is communicated with retort (8) by appendix II (6), exhaust shower nozzle (11) is provided with in appendix II (6) one end extend in retort (8), check valve (4) is arranged on appendix II (6), appendix III (7) is positioned between the top of retort (8) and water tank (9), retort (8) is communicated with in water tank (9) by appendix III (7), filler (12) is also provided with at the top of retort (8), outlet (10) is provided with in the bottom of retort (8).
CN201110388097.4A 2011-11-30 2011-11-30 A kind of for the isobutylaldehyde tail gas recycle of storage tank and the method for process and device thereof Active CN102895841B (en)

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CN104014240A (en) * 2014-05-20 2014-09-03 中国石油化工股份有限公司 Processing method for malodorous gas of storage tank
CN108275386A (en) * 2017-12-27 2018-07-13 山东高成石油科技有限公司 A kind of device for recovering oil and gas
CN113209783A (en) * 2021-03-08 2021-08-06 江苏海企化工仓储股份有限公司 A tail gas recovery system for isobutyraldehyde is stored

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CN2159252Y (en) * 1993-03-27 1994-03-23 田原宇 Simple gas generating and washing plant
CN1320473A (en) * 2001-03-13 2001-11-07 魏德兴 Method and equipment for absorbing volatilized gas of gasoline
JP2010254512A (en) * 2009-04-23 2010-11-11 Nihon Innovation:Kk Method for producing ultrahigh purity hydrogen gas
CN202048361U (en) * 2011-04-02 2011-11-23 南通新邦化工科技有限公司 Nitrogen protection device of atmospheric storage tank
CN202355996U (en) * 2011-11-30 2012-08-01 江苏海企化工仓储有限公司 Recycling and treatment device for exhaust of isobutylaldehyde storage tank

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2159252Y (en) * 1993-03-27 1994-03-23 田原宇 Simple gas generating and washing plant
CN1320473A (en) * 2001-03-13 2001-11-07 魏德兴 Method and equipment for absorbing volatilized gas of gasoline
JP2010254512A (en) * 2009-04-23 2010-11-11 Nihon Innovation:Kk Method for producing ultrahigh purity hydrogen gas
CN202048361U (en) * 2011-04-02 2011-11-23 南通新邦化工科技有限公司 Nitrogen protection device of atmospheric storage tank
CN202355996U (en) * 2011-11-30 2012-08-01 江苏海企化工仓储有限公司 Recycling and treatment device for exhaust of isobutylaldehyde storage tank

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