CN102888308A - Prescription and preparation process for environment-friendly and high-efficiency blanket detergent - Google Patents
Prescription and preparation process for environment-friendly and high-efficiency blanket detergent Download PDFInfo
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- CN102888308A CN102888308A CN2011102050054A CN201110205005A CN102888308A CN 102888308 A CN102888308 A CN 102888308A CN 2011102050054 A CN2011102050054 A CN 2011102050054A CN 201110205005 A CN201110205005 A CN 201110205005A CN 102888308 A CN102888308 A CN 102888308A
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- blanket
- main solvent
- efficiency
- environment
- high efficiency
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- 238000002360 preparation method Methods 0.000 title abstract description 6
- 239000003599 detergent Substances 0.000 title abstract 4
- 239000002904 solvent Substances 0.000 claims abstract description 26
- 238000004140 cleaning Methods 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 8
- 230000008569 process Effects 0.000 claims abstract description 8
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 claims abstract description 5
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 claims abstract 2
- 239000012459 cleaning agent Substances 0.000 claims description 25
- 229920001971 elastomer Polymers 0.000 claims description 22
- IVKNZCBNXPYYKL-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 IVKNZCBNXPYYKL-UHFFFAOYSA-N 0.000 claims description 7
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 7
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 7
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 6
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000004806 packaging method and process Methods 0.000 claims description 4
- 230000000149 penetrating effect Effects 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000460 chlorine Substances 0.000 abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract 2
- 238000007639 printing Methods 0.000 description 12
- 239000003350 kerosene Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002357 osmotic agent Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- -1 phosphate ester Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a detergent, and discloses a prescription for an environment-friendly and high-efficiency blanket detergent. The prescription comprises a main solvent, a cleaning auxiliary and a penetrant, wherein the ingredient of the main solvent comprises phosphate series or sodium oleate; and the ingredients of the cleaning auxiliary comprise a surfactant and an emulsifier. The invention further discloses a preparation process for the environment-friendly and high-efficiency blanket detergent. The process comprises the following steps of: (1) mixing; (2) stirring; and (3) forming a finished product. The product produced by the preparation process disclosed by the invention is high in flash point, light in smell, and bubble-free, does not contain a petroleum solvent, can not generate any chemical reaction with a blanket, and the content of chlorine element meets the international environmental-protection standards; and moreover, a product has the advantages of being high in cleaning efficiency, good in effect and little in dosage.
Description
Technical Field
The invention relates to a cleaning agent, in particular to a formula of an environment-friendly high-efficiency rubber blanket cleaning agent and a preparation process thereof.
Background
At present, the main body of the world printing industry is offset printing, ink is transferred to a printing stock through an ink roller, a rubber blanket and the like, and regular cleaning and maintenance are needed to ensure the ink roller and the rubber blanket to work normally. The cleaning agent used at present is mainly pure solvent solvents such as gasoline, kerosene and the like, and the pure solvent cleaning agent such as gasoline, kerosene and the like is used for cleaning ink rollers and rubber blankets, so that the cleaning agent has many defects: firstly, gasoline and kerosene contain volatile substances, have low flash points, are easy to cause dangerous accidents such as fire and the like, have large using amount and high cost, seriously pollute the environment and have great harm to the health of workers; secondly, a large amount of aromatic compounds contained in gasoline and kerosene easily swell the rubber of an ink roller to influence the printing quality, the cleaning effect on water-soluble dirt such as paper wool, paper powder, gum arabic and the like attached to the ink roller is poor, various impurities are easily accumulated on the surface of the ink roller layer by layer, original capillary holes on the surface of a rubber blanket are sealed, the ink transfer performance of the ink roller is reduced, and the printing effect is influenced; thirdly, gasoline and kerosene consume a large amount of petroleum, and cause a certain burden on environmental resources. With the attention on environmental protection all over the world, the printing industry is also advocating low-carbon environment-friendly green printing, and many customers require all related printing materials to meet the environmental protection requirement.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention aims to provide a rubber blanket cleaning agent which has few volatile substances and a high flash point and does not consume petroleum solvent, is used for replacing the traditional rubber blanket cleaning agent which takes gasoline and kerosene as main solvents, not only eliminates the damage of the traditional rubber blanket cleaning agent to the environment and staff, but also can reduce the consumption of petroleum resources, thereby saving resources.
The invention is realized by the following technical measures, the formula of the environment-friendly high-efficiency rubber blanket cleaning agent comprises a main solvent, a cleaning auxiliary agent and a penetrating agent; wherein the main solvent is phosphate ester series or sodium oleate; the cleaning assistant comprises surfactant and emulsifier.
The solid dirt mixed with the printing ink with various colors is adhered to equipment, and the main components of the solid dirt mixed with the printing ink are synthetic resin such as phenolic resin, polyamide resin and the like, organic pigment, colloidal calcium carbonate and other fillers. According to the principle of "similar compatibility" and considering the factors of water solubility and biodegradability, the main solvent in the formula is selected from phosphate series, sodium oleate, etc.
The main solvent is preferably tributyl phosphate.
The surfactant is preferably sodium dodecyl benzene sulfonate, and the emulsifier is preferably one or the combination of any of OP-10, TX-10 and AEO-9. The cleaning assistant can obviously improve the performance of the main solvent. In order to improve the cleaning efficiency, a surfactant and an emulsifier are added into the formula, wherein the surfactant and the emulsifier are mainly selected from sodium dodecyl benzene sulfonate, OP-10, TX-10 and AEO-9, and in the cleaning process, oily dirt is restrained in micelles of the surfactant and cannot be deposited on the surface of an object to be cleaned, so that the object to be cleaned can be prevented from being polluted again.
The osmotic agent is preferably JFC. In order to improve the ink cleaning effect and increase the dissolution rate, a penetrant may be added to improve the permeability of the cleaner to the ink. The formula selects JFC as a penetrating agent.
The invention also discloses a preparation process of the environment-friendly high-efficiency rubber blanket cleaning agent, which comprises the following steps:
(1) and mixing: mixing a main solvent, a surfactant, an emulsifier and a penetrant according to a mass ratio of 85-95: 4-9: 0.5-1.5: 1-3, and then putting into a reaction kettle;
(2) and stirring: starting a stirring motor of the reaction kettle, stirring at the speed of 2000-;
(3) and finished products: and taking out the product obtained in the last step and packaging to obtain a finished product.
The main solvent is preferably tributyl phosphate.
The surfactant is preferably sodium dodecyl benzene sulfonate, and the emulsifier is preferably one or the combination of any of OP-10, TX-10 and AEO-9.
The osmotic agent is preferably JFC.
The mass ratio of the main solvent, the surfactant, the emulsifier and the penetrating agent is preferably 91: 6: 1: 2.
The invention can be mixed with water according to the mass ratio of 1: 1.3 for use.
Due to the adoption of the technical scheme, compared with the traditional rubber blanket cleaning agent and the current environment-friendly rubber blanket cleaning agent on the market, the rubber blanket cleaning agent has the following advantages:
(1) the flash point is high, the traditional rubber blanket cleaning agent and the environment-friendly rubber blanket cleaning agent on the current market mainly contain kerosene or gasoline, the flash point is only about 40 ℃, the flash point of the product can reach 130 ℃, and hidden dangers in the aspects of fire fighting in the transportation, storage and use processes can be eliminated.
(2) The odor is low, toxic and harmful volatile substances such as benzene, dimethylbenzene and trichloroethylene are not contained, the low VOC emission standard required by international standards is ensured, and the environment is not polluted. The currently used environment-friendly blanket cleaning agent has heavy pungent smell, but the product of the invention has no pungent smell, creates a good production environment for staff, and has no harm to the body of the staff.
(3) The cleaning agent does not contain a petroleum solvent, most of the traditional rubber blanket cleaning agents contain the petroleum solvents such as gasoline, kerosene and the like, the environment-friendly rubber blanket cleaning agents sold in the current market mainly use the petroleum solvents and consume a large amount of petroleum resources, and the product of the invention does not contain the petroleum solvents completely and has the effects of low carbon and environment protection.
(4) Do not play any chemical reaction with the blanket, can keep the blanket can not swell, warp when effectively getting rid of printing ink, can effectively improve the life of blanket, use petrol, kerosene as the blanket cleaner, this type of material has the corrosive action to the blanket, and the blanket can warp very fast after wasing with petrol, kerosene, and the swelling rate increase will often shut down among the printing process, influences printing efficiency.
(5) When the environment-friendly blanket cleaning agent used at present is used after being mixed with water, a large amount of water bubbles can be generated on the blanket, the drying speed is low, and the downtime is increased. The product of the invention has no bubble problem when being used after being mixed with water, has high drying speed and can effectively improve the production efficiency.
(6) The content of chlorine element in the currently used environment-friendly rubber blanket cleaning agent is seriously exceeded, and the product produced by the invention does not detect the chlorine element, thereby being more in line with the international environment-friendly requirement.
(7) The cleaning efficiency is high, the effect is good, the dosage is less, and the cleaning can be completely realized by only scrubbing for 1-2 times without leaving stains.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1
An environment-friendly high-efficiency rubber blanket cleaning agent is processed by the following processing steps:
(1) and mixing: mixing sodium oleate, sodium dodecyl benzene sulfonate, OP-10, AEO-9 and JFC according to the mass ratio of 87: 7: 1: 0.5: 3, and then filling the mixture into a reaction kettle;
(2) and stirring: starting a stirring motor of the reaction kettle, stirring at the speed of 2500/min until all components are completely dissolved, and uniformly cleaning and transparent the solution;
(3) and finished products: and taking out and packaging the obtained product in the last step to obtain a finished product.
The prepared finished product is uniform colorless transparent liquid, has specific gravity of 0.96g/cm3, pH value of 6-7, and can be used by mixing with water at a ratio of 1: 1.3 and shaking.
Example 2
An environment-friendly high-efficiency rubber blanket cleaning agent is processed by the following processing steps:
(1) and mixing: mixing tributyl phosphate, sodium dodecyl benzene sulfonate, OP-10 and JFC according to the mass ratio of 91: 6: 1: 2, and filling into a reaction kettle;
(2) and stirring: starting a stirring motor of the reaction kettle, stirring at the speed of 3000r/min until all components are completely dissolved, and uniformly cleaning and transparent the solution;
(3) and finished products: and taking out and packaging the obtained product in the last step to obtain a finished product.
The prepared finished product is uniform colorless transparent liquid, has specific gravity of 0.94g/cm3, pH value of 6-7, and can be used by mixing with water at a ratio of 1: 1.3 and shaking.
The above description is provided for the purpose of illustration and understanding of the present invention, but the present invention is not limited to the above embodiments, and any changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit of the present invention are intended to be equivalent substitutions and shall be included within the scope of the present invention.
Claims (9)
1. The formula of the environment-friendly high-efficiency rubber blanket cleaning agent is characterized in that: comprises a main solvent, a cleaning auxiliary agent and a penetrating agent; wherein,
the main solvent is phosphate or sodium oleate;
the cleaning assistant comprises surfactant and emulsifier.
2. The formulation for an environmentally friendly, high efficiency blanket cleaner according to claim 1, wherein: the main solvent is tributyl phosphate.
3. The formulation for an environmentally friendly, high efficiency blanket cleaner according to claim 1, wherein: the surfactant is sodium dodecyl benzene sulfonate, and the emulsifier is one or the combination of any of OP-10, TX-10 and AEO-9.
4. The formulation for an environmentally friendly, high efficiency blanket cleaner according to claim 1, wherein: the penetrant is JFC.
5. A process for preparing the environmentally friendly, high efficiency blanket cleaner of claim 1, comprising the steps of:
(1) and mixing: mixing a main solvent, a surfactant, an emulsifier and a penetrant according to a mass ratio of 85-95: 4-9: 0.5-1.5: 1-3, and then putting into a reaction kettle;
(2) and stirring: starting a stirring motor of the reaction kettle, stirring at the speed of 2000-;
(3) and finished products: and taking out the product obtained in the last step and packaging to obtain a finished product.
6. The process of preparing an environmentally friendly high efficiency blanket cleaner of claim 5, wherein: the main solvent is tributyl phosphate.
7. The process of preparing an environmentally friendly high efficiency blanket cleaner of claim 5, wherein: the surfactant is sodium dodecyl benzene sulfonate, and the emulsifier is one or the combination of any of OP-10, TX-10 and AEO-9.
8. The process of preparing an environmentally friendly high efficiency blanket cleaner of claim 5, wherein: the penetrant is JFC.
9. The process of preparing an environmentally friendly high efficiency blanket cleaner of claim 5, wherein: the mass ratio of the main solvent to the surfactant to the emulsifier to the penetrant is 85-95: 4-9: 0.5-1.5: 1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102050054A CN102888308A (en) | 2011-07-21 | 2011-07-21 | Prescription and preparation process for environment-friendly and high-efficiency blanket detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102050054A CN102888308A (en) | 2011-07-21 | 2011-07-21 | Prescription and preparation process for environment-friendly and high-efficiency blanket detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102888308A true CN102888308A (en) | 2013-01-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102050054A Pending CN102888308A (en) | 2011-07-21 | 2011-07-21 | Prescription and preparation process for environment-friendly and high-efficiency blanket detergent |
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| Country | Link |
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| CN (1) | CN102888308A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109055045A (en) * | 2018-07-13 | 2018-12-21 | 广州市宝绅科技应用有限公司 | Digital printing rubber cloth cleaning fluid and cleaning process |
| CN110294957A (en) * | 2019-07-22 | 2019-10-01 | 重庆睦邻信息技术有限公司 | Chemical coating or ink advertisement remover and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86102195A (en) * | 1986-04-01 | 1987-10-14 | 中国人民解放军后勤工程学院 | Detergent for cleaning printing ink on hand and purposes |
| CN1332234A (en) * | 2001-08-06 | 2002-01-23 | 万裕全 | Scavenger for rubber and clothe |
| CN1670090A (en) * | 2005-03-04 | 2005-09-21 | 广西大学 | Method for preparing water-soluble quick cleaning agent for outdoor adlet |
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
-
2011
- 2011-07-21 CN CN2011102050054A patent/CN102888308A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86102195A (en) * | 1986-04-01 | 1987-10-14 | 中国人民解放军后勤工程学院 | Detergent for cleaning printing ink on hand and purposes |
| CN1332234A (en) * | 2001-08-06 | 2002-01-23 | 万裕全 | Scavenger for rubber and clothe |
| CN1670090A (en) * | 2005-03-04 | 2005-09-21 | 广西大学 | Method for preparing water-soluble quick cleaning agent for outdoor adlet |
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
Non-Patent Citations (1)
| Title |
|---|
| 王益民等: "水基油墨清洗剂的研制", 《包装工程》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109055045A (en) * | 2018-07-13 | 2018-12-21 | 广州市宝绅科技应用有限公司 | Digital printing rubber cloth cleaning fluid and cleaning process |
| CN110294957A (en) * | 2019-07-22 | 2019-10-01 | 重庆睦邻信息技术有限公司 | Chemical coating or ink advertisement remover and preparation method thereof |
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Address after: 518000 Guangdong city of Shenzhen province Baoan District Shiyan Street Community in Paddy Field Stone Ring Road 1 building A, building B, building C, building E, building H, building J, building G Applicant after: SHENZHEN YUTONG PACKAGING SCIENCE & TECHNOLOGY CO., LTD. Address before: 518000 Guangdong city of Shenzhen province Baoan District Shiyan Street Community in Paddy Field Stone Ring Road 1 building A, building B, building C, building E, building H, building J, building G Applicant before: Shenzhen Yuto Printing Co., Ltd. |
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Application publication date: 20130123 |