CN106479256A - A kind of natural green environmental protection Diamond Search car wash water - Google Patents

A kind of natural green environmental protection Diamond Search car wash water Download PDF

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Publication number
CN106479256A
CN106479256A CN201610860579.8A CN201610860579A CN106479256A CN 106479256 A CN106479256 A CN 106479256A CN 201610860579 A CN201610860579 A CN 201610860579A CN 106479256 A CN106479256 A CN 106479256A
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China
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car wash
wash water
environmental protection
natural green
alcohol
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彭坚
韦潇
杜森
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Shanghai Digital Network Technology Co Ltd
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Shanghai Digital Network Technology Co Ltd
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Priority to CN201610860579.8A priority Critical patent/CN106479256A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/04Chemical paint or ink removers with surface-active agents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inking, Control Or Cleaning Of Printing Machines (AREA)

Abstract

The present invention relates to a kind of natural green environmental protection Diamond Search car wash water, this car wash water is aoxidized by vegetable fatty acid esters and nonionic surfactant oxolane and/or third and/or ethoxyquin C1 C10 alcohol is constituted, and the mass ratio of vegetable fatty acid esters and nonionic surfactant is 20 98:80‑2;This car wash water can also include second nonionic surfactant oxolane and/or the third oxidation and/or ethoxyquin C11 C18 alcohol and water.Compared with prior art, the all components of the present invention are all with natural green plant extract as initial feed, it is obtained by solvent-free organic synthesiss process, fool proof to blanket, each formula all can be directly used as washing the severe edema due to hypofunction of the spleen, the severe edema due to hypofunction of the spleen need not be washed for special making of cleaning blanket, in formula, all components all do not contain VOC in addition, and the therefore present invention is real natural green environmental protection Diamond Search.The present invention can start shooting printing after having cleaned printing parts immediately, need not be dried.

Description

A kind of natural green environmental protection Diamond Search car wash water
Technical field
The present invention relates to a kind of car wash water, especially relate to a kind of natural green environmental protection Diamond Search car wash water.
Background technology
Image-text area parent's offset ink of forme used by hectographic printing hates fountain solution, and its non-graphic region parent's fountain solution hates glue Printing ink.In offset printing process, forme is first contacted with damping roller and makes a thin layer fountain solution on its non-graphic region overlay, then with Ink roller contact makes its image-text area cover gluing ink layer.Forme then with blanket contact, picture and text thereon are transferred to On blanket.Blanket is subsequently contacted with paper, by thereon picture and text transfer on paper.By four color double exposures, complete Picture and text have just been printed onto above paper.Whole printing process is exactly above-mentioned each process circulating repetition at high speeds.
It is known that with the increase printing number after last time washing machine, printing quality would generally be deteriorated, such as picture and text and Fei Tu The side of literary composition occurs fuzzy.This is probably by the velveteen building up in printing process on forme and blanket, dust and paper The debris such as hair cause, and now printer must stop to clean blanket, forme, ink roller or ink groove.Most commonly seen is Due to blanket dirty and must stop cleaning blanket.Because blanket is easily subject to some solvents to corrode and expand, and rubber The area of skin cloth is larger to need that solvent cleans to reach dry rate faster faster with rate of volatilization, not every washes Car water is suitable for cleaning blanket, so devise for cleaning blanket special washing the severe edema due to hypofunction of the spleen.Cleaning forme or blanket can With hand rotation to forme or blanket top, dip in car wash water with non-fluff cloth or wash the severe edema due to hypofunction of the spleen and wash finding forme or blanket On offset ink and debris, be then rotated up forme or blanket expose unwashed part continuation non-fluff cloth and dips in and washes Car water or wash the severe edema due to hypofunction of the spleen and wash offset ink and debris on finding forme or blanket.Forme or blanket are cleaned and are dried Afterwards, printing can just be turned back on.As can be seen here, for efficient printing, rapidly and efficiently wash offset ink and miscellaneous Matter and by the quick volatilization of solvent obtain clean forme and blanket quickly turning back on printing it is critical that.
So far, the car wash water that printing industry uses is all some mixed solvents with washing the severe edema due to hypofunction of the spleen, is all VOC, such as oil Ether, trichloroethane, toluene, dimethylbenzene or other similar solvent.Using volatile solvent (VOC) Manual-cleaning forme or rubber Cloth, from the beginning of forme or blanket top, subregion is cleaned, when cleaning to the bottom of forme or blanket, due to solvent Rate of volatilization by car wash water or can be washed the Ju Ti Pei Fang of the severe edema due to hypofunction of the spleen and to be adjusted, can accomplish the top of forme or blanket and its The region that it cleaned has been done, and thus can turn back on continuation printing at once, improve printing efficiency.
Some offset machines carry Automatic rubber cloth cleaning function, and this function washes severe edema due to hypofunction of the spleen device by spray and skin is washed in removal Water/offset ink mixing liquid device cooperation completes.Volatile solvent (VOC) is washed the severe edema due to hypofunction of the spleen and is washed severe edema due to hypofunction of the spleen device by certain metering by spray Spray on blanket, mix with the offset ink on blanket and impurity and penetrate into dissolving formation wash the severe edema due to hypofunction of the spleen/offset ink mix Close liquid, then the severe edema due to hypofunction of the spleen/offset ink mixing liquid device removal is washed by removal and wash the severe edema due to hypofunction of the spleen/offset ink mixed liquor, residual on blanket Volatile solvent (VOC) thin film staying is vapored away with controllable rate of volatilization, thus obtaining clean blanket it is possible to horse On turn back on continuation printing, there is higher printing efficiency.
However, VOC is to lead to one of key factor of environmental pollution, it is also important hidden danger (the Class A danger of safety in production Product, inflammable and explosive).2006 Nian8Yue15 State Environmental Protection Administration just promulgate《HJ/T293-2006 clean production standard-automobile Manufacturing industry (application)》, on December 1st, 2006 comes into effect.It is that the domestic VOC emission flow control to industrial coating is once made that Concrete regulation.National environmental protection regulation limits more and more strictly to the discharge of VOC, and this allows for invention low VOC content/Diamond Search and contains The severe edema due to hypofunction of the spleen is extremely urgent for amount car wash water/wash, these environment-friendly type car wash waters/wash severe edema due to hypofunction of the spleen not only will cleaning printing press effectively print The parts such as version, ink roller and blanket are it is necessary to higher printing efficiency will be ensured.Core difficulty therein is do not have VOC, the wet film of car wash water/wash severe edema due to hypofunction of the spleen residual would not volatile dry, in order to not allow the wet film of residual affect to turn back on printing Quality, would have to spend substantial amounts of downtime thoroughly to dry the wet film of residual, it is extremely low that this allows for printing efficiency, print Brush factory cannot accept.
Chinese patent CN103642300A discloses printing car wash water, is made up of the raw material of following weight portion:Oleum Terebinthinae 40-50%, diethylene glycol 25-35%, trifluorotrichloroethane 10-15%, fatty alcohol-polyoxyethylene ether 2-3%, anhydrous sorbitol list Oleate 1.5-2.5%, inositol hexaphosphate 2-3%, hexamethylenamine 3-5%, dodecyldimethylammonium hydroxide inner salt 1-2%, oil Sour sodium 2-3%.In above-mentioned formula, Oleum Terebinthinae and trifluorotrichloroethane are VOC that is to say, that printing carwash disclosed in this patent The component that water has half or more is organic volatile part;Although trifluorotrichloroethane reduces the inflammable easy of this printing car wash water Quick-fried property, but Oleum Terebinthinae is still inflammable and explosive, is Class A dangerous materials;And trifluorotrichloroethane is polyhalohydrocarbon, to human body and environment All harmful, European Union's plaintext prohibits the use of;Additionally, Oleum Terebinthinae, diethylene glycol, trifluorotrichloroethane and hexamethylenamine are not greens producing Product, the far from environmental protection of whole formula.
Content of the invention
The purpose of the present invention is exactly to overcome the defect of above-mentioned prior art presence to provide a kind of natural green environmental protection Diamond Search car wash water.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of natural green environmental protection Diamond Search car wash water, by vegetable fatty acid esters and nonionic surfactant four Hydrogen furan and/or the third oxidation and/or ethoxyquin C1-C10 alcohol composition, vegetable fatty acid esters and oxolane and/or third The mass ratio of oxidation and/or ethoxyquin C1-C10 alcohol is 20-98:80-2.
Natural green environmental protection Diamond Search car wash water can also include second nonionic surfactant oxolane And/or third oxidation and/or ethoxyquin C11-C18 alcohol and water, vegetable fatty acid esters, oxolane and/or third oxidation and/or The mass ratio of ethoxyquin C1-C10 alcohol, oxolane and/or the third oxidation and/or ethoxyquin C11-C18 alcohol and water is 20-98: 40-2:40-0:20-0.
Preferably, the molecular formula of vegetable fatty acid esters is CnO2R;Wherein CnO2 is C8-C22 fat carboxyl, and R is C1- C4 alkyl, comprises all of isomerss.
It is further preferred that CnO2 is n carboxyl, n=8-22, R are methyl Me, ethyl Et, n-pro-pyl Pr, isopropyl iPr, just Butyl Bu, isobutyl group iBu or tertiary butyl tBu.
Preferably, nonionic surfactant oxolane and/or the third oxidation and/or ethoxyquin C1-C10 alcohol Molecular formula is CmOBOxPOyEOz, and wherein CmO represents 1 mole of m carbochain alcohol radical, and m=1-10, BOx represent that fourth aoxidizes x mole, x= 0-20, POy represent y mole of the third oxidation, and y=0-30, EOz represent z mole of ethoxyquin, z=2-40.Specifically, C1-C10 alcohol Successively with oxolane and/or expoxy propane and/or reacting ethylene oxide, prepare oxolane and/or third oxidation and/ Or ethoxyquin C1-C10 alcohol, C1-C10 alcohol is 1 with the mol ratio of oxolane, expoxy propane and oxirane:0-20:0-30: 2-40.
Preferably, nonionic surfactant oxolane and/or the third oxidation and/or ethoxyquin C11-C18 alcohol Molecular formula be CjOBOuPOvEOw, wherein CjO represents 1 mole of j carbochain alcohol radical, and j=11-18, BOu represent that fourth aoxidizes u mole, U=0-30, POv represent v mole of the third oxidation, and v=0-40, EOw represent w mole of ethoxyquin, w=2-50.Specifically, C11- C18 alcohol successively with oxolane and/or expoxy propane and/or reacting ethylene oxide, prepare oxolane and/or the third oxygen Change and/or ethoxyquin C11-C18 alcohol, C11-C18 alcohol is 1 with the mol ratio of oxolane, expoxy propane and oxirane:0- 30:0-40:2-50.
Vegetable fatty acid esters and nonionic surfactant oxolane and/or the third oxidation and/or ethoxyquin The car wash water that C1-C10 alcohol is formed and offset ink match each other compatible, can effectively dissolve and remove the print of printer Offset ink on the parts such as version, ink roller and blanket and impurity.Above-mentioned car wash water equal-volume ratio or greater proportion dilution offset printing Ink can be effectively reduced the adhesive force to printing parts for the offset ink, thus can be easier to clean up the offset printing oil on parts Ink;Above-mentioned car wash water not only with offset ink matched compatible also with fountain solution matched compatible, offset ink and car wash water press volume 2:1 is mixed to form cohesiveness good seriality fluid, and therefore on parts, the car wash water/wash severe edema due to hypofunction of the spleen wet film of residual can print again Brush several within taken away by offset ink or fountain solution, thus after again printing several printed resolution, picture and text definition and Color density just can at all be no less than standard specimen.Above-mentioned car wash water is cleaning the parts such as the forme of printer, ink roller and blanket After a thin layer wet film can be stayed on these parts, the wet film on parts need not be dried, in particular for the rubber of frequent cleaning Cloth need not can print immediately again in drying.Above-mentioned car wash water is fool proof to blanket, and each formula all can be directly used as washing skin Water, so need not specially make and wash the severe edema due to hypofunction of the spleen for cleaning blanket.Above-mentioned car wash water and offset ink match each other compatible, the two It is not significantly affected by the printing performance of offset ink with wider relative scale mixing.When above-mentioned car wash water has cleaned printer When turning back on after the parts such as forme, ink roller and blanket, on parts, the car wash water wet film of residual is mixed into the glue on ink roller The image-text area on image-text area and blanket on printing ink, forme, eventually enters into paper.On the other hand, above-mentioned car wash water Also match each other with fountain solution compatible, on parts, the car wash water wet film of residual is also mixed into non-graphic region and rubber on forme Non-graphic region on skin cloth, eventually enters into paper.Printed resolution, picture and text definition and color density are turning back on printing The requirement being sufficient for commercial printing is risen within several.This just thoroughly solves above-mentioned does not have VOC printing efficiency just extremely low Core difficulty;The present invention establishes after car wash water cleaned each parts of printer simultaneously, each parts, particularly blanket, The method that just can immediately again print need not be dried.Above-mentioned car wash water can also include second nonionic surfactant Oxolane and/or the third oxidation and/or ethoxyquin C11-C18 alcohol and water.Above-mentioned car wash water is that water is flushable, therefore above-mentioned Car wash water may be added in the parts of each carrying offset ink on printer, and such as ink roller roller group, ink fountain etc. is difficult to clean Position, formed offset ink/carwash water mixed liquid, then rinsed well with water.Institute in addition to water in above-mentioned car wash water formula There is component to be all with natural green plant extract as initial feed, be obtained by solvent-free organic synthesiss process, therefore formula In all components all do not contain any VOC, car wash water is real natural green environmental protection Diamond Search.Need not be dried, not contain the upper of VOC State car wash water fool proof to blanket, and cleaned blanket and can turn back on immediately and blanket need not be dried, so The each formula of the present invention all can be directly used as washing the severe edema due to hypofunction of the spleen, need not specially make and wash the severe edema due to hypofunction of the spleen for cleaning blanket.
Certain embodiments of the present invention can be used as printing the car wash water of machine using UV offset ink, and the therefore present invention also provides For cleaning the natural green environmental protection Diamond Search car wash water of UV offset ink.
Compared with prior art, the present invention has advantages below:
1st, the alcohol chain in nonionic surfactant is reacted with oxolane and achieves fourth oxidation, with the oxidation of oxolane fourth Cooperation expoxy propane third aoxidizes and/or oxirane ethoxyquin adjusts alcohol chain, and above-mentioned car wash water can not only be made to carry out institute of the present invention The whole car wash water functions of requiring are mutually matched compatible with offset ink and are mutually matched phase with fountain solution moreover it is possible to be better achieved Balance between appearance.Additionally, with oxolane fourth aoxidize adjust alcohol chain make above-mentioned car wash water be more suitable for clean vegetable oil type, Zero or low dry moves back environmental protection offset ink.
2nd, the car wash water component of the present invention is all with natural green plant extract as initial feed, by solvent-free organic Building-up process is obtained, and raw material and production process are all without any VOC;After above-mentioned car wash water goes back to nature, can naturally drop Solution enters the Nature endless-chain;So the car wash water of the present invention is " natural green environmental protection Diamond Search " worthy of the name.
3rd, the present invention has conceptually overturned car wash water, particularly washes the severe edema due to hypofunction of the spleen it is necessary to thoroughly drying could be printed again.Logical Cross vegetable fatty acid esters and nonionic surfactant oxolane and/or the third oxidation and/or ethoxyquin C1-C10 Alcohol reasonably combined so that car wash water not only with offset ink matched compatible also with fountain solution matched compatible, larger amount of carwash Water can clean up the offset ink on parts easily, and on parts, the car wash water wet film of residual can print several again Within taken away by offset ink or fountain solution, this just thoroughly solves aforementioned core difficulty, thus setting up a kind of high efficiency The method of picture and text transitional surface on cleaning printing press.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.
Production code member lexical or textual analysis:CnO2 indicates n carboxyl, and Me indicates methyl, and Bu indicates normal-butyl, and CmO indicates m carbochain alcohol radical, BOx indicates fourth and aoxidizes x mole, and POy indicates y mole of the third oxidation, and EOz indicates z mole of ethoxyquin;% indicates mass percent.
Natural green environmental protection Diamond Search raw material is provided by Guangxi Sen Ke resin company limited, and production code member and composition are as follows:
C18O2Me is to extract C18 acid by refine Oleum Camelliae soap stock to react, with methanol, the ester generating
C18O2Bu is to extract C18 acid by refine Oleum Camelliae soap stock to react, with n-butyl alcohol, the ester generating
C16O2Me is to extract C16 acid by refined palm oil soap stock to react, with methanol, the ester generating
C12O2Me is to extract C12 acid by refined coconut oil soap foot to react, with methanol, the ester generating
C2OBO3EO7 is first to be reacted with 3 moles of oxolanes by 1 mole of cassava alcohol to react with 7 moles of ethylene oxide again Product
C4OBO2EO7 be by 1 mole of amylofermentation butanol first react with 2 moles of oxolanes again with 7 moles of ethylene oxide The product of reaction
C6OBO1EO7 be by 1 mole of Citrus berry extract C6 alcohol first react with 1 mole of oxolane again with 7 moles of epoxies The product of ethane reaction
C6OBO1PO2EO9 be by 1 mole of Citrus berry extract C6 alcohol first react with 1 mole of oxolane again with 2 moles of rings The product that Ethylene Oxide reaction is finally reacted with 9 moles of ethylene oxide
C8OBO1EO8 is first to be reacted with 1 mole of oxolane again with 8 by 1 mole of Oleum Cocois lauric acid by-product C8 alcohol The product of moles of ethylene oxide reaction
C12OBO1EO9 be by 1 mole of Oleum Cocois hydrogenation products C12 alcohol first react with 1 mole of oxolane again with 9 moles The product of reacting ethylene oxide
Embodiment 1
Car wash water formula 1:85%C18O2Me and 15%C4OBO2EO7.Picture and text transfer table on this car wash water cleaning printing press Again print 8 behind face and reach satisfied commercial printing quality, with 10 times of volume ratios dilute offset inks still formed homogeneous solution, No pigment separates out or resin coagulation, reduces offset ink adhesive force and show excellent, equal-volume ratio after equal-volume ratio dilution offset ink Non-fluff cloth performance is penetrated into excellent after dilution offset ink.
Embodiment 2
Car wash water formula 2:80%C18O2Bu and 20%C2OBO3EO7.Picture and text transfer table on this car wash water cleaning printing press Again print 8 behind face and reach satisfied commercial printing quality, with 10 times of volume ratios dilute offset inks still formed homogeneous solution, No pigment separates out or resin coagulation, reduces offset ink adhesive force and show excellent, equal-volume ratio after equal-volume ratio dilution offset ink Non-fluff cloth performance is penetrated into excellent after dilution offset ink.
Embodiment 3
Car wash water formula 3:85%C18O2Me and 15%C6OBO1EO7.Picture and text transfer table on this car wash water cleaning printing press Again print 9 behind face and reach satisfied commercial printing quality, with 10 times of volume ratios dilute offset inks still formed homogeneous solution, No pigment separates out or resin coagulation, reduces offset ink adhesive force and show excellent, equal-volume ratio after equal-volume ratio dilution offset ink Non-fluff cloth performance is penetrated into excellent after dilution offset ink.
Embodiment 4
Car wash water formula 4:85%C18O2Me and 15%C6OBO1PO2EO9.On this car wash water cleaning printing press, picture and text turn Again print 9 after moving surface and reach satisfied commercial printing quality, dilute offset ink with 10 times of volume ratios and still formed uniformly Solution, no pigment separate out or resin coagulation, and after equal-volume ratio dilution offset ink, reduction offset ink adhesive force performance is excellent, waits body Non-fluff cloth performance is penetrated into excellent after the long-pending offset ink than dilution.
Embodiment 5
Car wash water formula 5:85%C18O2Me and 15%C8OBO1EO8.Picture and text transfer table on this car wash water cleaning printing press Again print 9 behind face and reach satisfied commercial printing quality, with 10 times of volume ratios dilute offset inks still formed homogeneous solution, No pigment separates out or resin coagulation, reduces offset ink adhesive force and show excellent, equal-volume ratio after equal-volume ratio dilution offset ink Non-fluff cloth performance is penetrated into excellent after dilution offset ink.
Embodiment 6
Car wash water formula 6:50%C18O2Me, 20%C4OBO2EO7,20%C12OBO1EO9 and 10% water.This car wash water Again print 6 after picture and text transitional surface on cleaning printing press and reach satisfied commercial printing quality, diluted with 10 times of volume ratios Offset ink still forms homogeneous solution, no pigment separates out or resin coagulation, reduces offset printing oil after equal-volume ratio dilution offset ink Black adhesive force performance is good, penetrates into non-fluff cloth performance good after equal-volume ratio dilution offset ink.
Embodiment 7
Car wash water formula 7:50%C18O2Me, 20%C6OBO1EO7,20%C12OBO1EO9 and 10% water.This car wash water Again print 6 after picture and text transitional surface on cleaning printing press and reach satisfied commercial printing quality, diluted with 10 times of volume ratios Offset ink still forms homogeneous solution, no pigment separates out or resin coagulation, reduces offset printing oil after equal-volume ratio dilution offset ink Black adhesive force performance is good, penetrates into non-fluff cloth performance good after equal-volume ratio dilution offset ink.
Embodiment 8
Car wash water formula 8:50%C18O2Me, 20%C8OBO1EO8,20%C12OBO1EO9 and 10% water.This car wash water Again print 7 after picture and text transitional surface on cleaning printing press and reach satisfied commercial printing quality, diluted with 10 times of volume ratios Offset ink still forms homogeneous solution, no pigment separates out or resin coagulation, reduces offset printing oil after equal-volume ratio dilution offset ink Black adhesive force performance is good, penetrates into non-fluff cloth performance good after equal-volume ratio dilution offset ink.
Embodiment 9
Car wash water formula 9:85%C16O2Me and 15%C2OBO3EO7.Picture and text on this car wash water cleaning UV offset machine Again print 8 after transitional surface and reach satisfied commercial printing quality, dilute UV offset ink with 10 times of volume ratios and still formed Homogeneous solution, no pigment separate out or resin coagulation, reduce UV offset ink adhesive force table after equal-volume ratio dilution UV offset ink Existing excellent, penetrate into non-fluff cloth performance after equal-volume ratio dilution UV offset ink excellent.
Embodiment 10
Car wash water formula 10:85%C12O2Me and 15%C4OBO2EO7.This car wash water cleans the upper figure of UV offset machine Again print 9 after civilian transitional surface and reach satisfied commercial printing quality, dilute UV offset ink still shape with 10 times of volume ratios Uniformly solution, no pigment separate out or resin coagulation, reduce UV offset ink adhesive force after equal-volume ratio dilution UV offset ink Performance is excellent, penetrates into non-fluff cloth performance excellent after equal-volume ratio dilution UV offset ink.
Embodiment 11
Car wash water formula 11:50%C16O2Me, 20%C2OBO3EO7,20%C12OBO1EO9 and 10% water.This carwash Again print 6 after picture and text transitional surface on water cleaning UV offset machine and reach satisfied commercial printing quality, with 10 times of bodies Long-pending ratio dilution UV offset ink still forms homogeneous solution, no pigment separates out or resin coagulation, and equal-volume ratio dilutes UV offset ink Reduce the performance of glue UV printing ink adhesive force afterwards good, penetrate into non-fluff cloth performance after equal-volume ratio dilution UV offset ink good.
Embodiment 12
Car wash water formula 12:50%C12O2Me, 20%C4OBO2EO7,20%C12OBO1EO9 and 10% water.This carwash Again print 7 after picture and text transitional surface on water cleaning UV offset machine and reach satisfied commercial printing quality, with 10 times of bodies Long-pending ratio dilution UV offset ink still forms homogeneous solution, no pigment separates out or resin coagulation, and equal-volume ratio dilutes UV offset ink Reduce the performance of UV offset ink adhesive force afterwards good, penetrate into non-fluff cloth performance after equal-volume ratio dilution UV offset ink good.
In said components, all components in addition to water are all with natural green plant extract as initial feed, by no Solvent organic synthesiss process is obtained, and therefore in formula, all components all do not contain any VOC, and car wash water is real natural green colour circle Protect Diamond Search.
The manufacture method compared of above-mentioned car wash water is simple, is initially charged vegetable fatty acid esters and nonionic in producing vessel Surfactant, stirs;If there is no water in formula, canned after just directly filtering;If having water in formula, just to plant Add water in oil and fat acid esters and nonionic surfactant mixed liquor, stir, after waiting bubble to be wholly absent, you can mistake Canned after filter.Corresponding stir speed (S.S.) is divided into third gear, and the rotating speed of low or first gear is 1-70RPM, and the rotating speed of mid ranger is 71- 120RPM, the rotating speed of top gear is 121-6000RPM;Produce above-mentioned car wash water bottom gear stir speed (S.S.).Corresponding filter Net can be plastic filter screen, non-woven fabrics filter screen and stainless steel filtering net etc., and the mesh number of filter screen is divided three classes, and low mesh number filter screen is 10-90 Mesh, middle mesh number filter screen is 100-270 mesh, and high mesh number filter screen is 300-625 mesh;Produce above-mentioned car wash water high mesh number filter screen mistake Filter.
Vegetable fatty acid esters and nonionic surfactant oxolane and/or the third oxidation and/or ethoxyquin The car wash water that C1-C10 alcohol is formed and offset ink match each other compatible, can effectively dissolve and remove the print of printer Offset ink on the parts such as version, ink roller and blanket and impurity.Above-mentioned car wash water equal-volume ratio or greater proportion dilution offset printing Ink can be effectively reduced the adhesive force to printing parts for the offset ink, thus can be easier to clean up the offset printing oil on parts Ink;Above-mentioned car wash water not only with offset ink matched compatible also with fountain solution matched compatible, offset ink and car wash water press volume 2:1 is mixed to form cohesiveness good seriality fluid, and therefore on parts, the car wash water/wash severe edema due to hypofunction of the spleen wet film of residual can print again Brush several within taken away by offset ink or fountain solution, thus after again printing several printed resolution, picture and text definition and Color density just can at all be no less than standard specimen.Above-mentioned car wash water is cleaning the parts such as the forme of printer, ink roller and blanket After a thin layer wet film can be stayed on these parts, the wet film on parts need not be dried, in particular for the rubber of frequent cleaning Cloth need not can print immediately again in drying.Above-mentioned car wash water is fool proof to blanket, and each formula all can be directly used as washing skin Water, so need not specially make and wash the severe edema due to hypofunction of the spleen for cleaning blanket.Above-mentioned car wash water and offset ink match each other compatible, the two It is not significantly affected by the printing performance of offset ink with wider relative scale mixing.When above-mentioned car wash water has cleaned printer When turning back on after the parts such as forme, ink roller and blanket, on parts, the car wash water wet film of residual is mixed into the glue on ink roller The image-text area on image-text area and blanket on printing ink, forme, eventually enters into paper.On the other hand, above-mentioned car wash water Also match each other with fountain solution compatible, on parts, the car wash water wet film of residual is also mixed into non-graphic region and rubber on forme Non-graphic region on skin cloth, eventually enters into paper.Printed resolution, picture and text definition and color density are turning back on printing The requirement being sufficient for commercial printing is risen within several.This just thoroughly solves above-mentioned does not have VOC printing efficiency just extremely low Core difficulty;The present invention establishes after car wash water cleaned each parts of printer simultaneously, each parts, particularly blanket, The method that just can immediately again print need not be dried.Above-mentioned car wash water can also include second nonionic surfactant tetrahydrochysene Furan/the third oxidation/ethoxyquin C11-C18 alcohol and water.Above-mentioned car wash water is that water is flushable, and therefore above-mentioned car wash water can add To on printer, each carries in the parts of offset ink, and such as ink roller roller group, ink fountain etc. are difficult to the position cleaned, and forms glue Printing ink/carwash water mixed liquid, is then rinsed well with water.In above-mentioned car wash water formula, all components in addition to water are all with sky So green plantss extract is initial feed, is obtained by solvent-free organic synthesiss process, and therefore in formula, all components are not Containing any VOC, car wash water is real natural green environmental protection Diamond Search.Need not be dried, not contain the above-mentioned car wash water of VOC to rubber Cloth is fool proof, and has cleaned blanket and can turn back on immediately and blanket need not be dried, so each formula of the present invention is equal Can be directly used as washing the severe edema due to hypofunction of the spleen, need not specially make and wash the severe edema due to hypofunction of the spleen for cleaning blanket.
Embodiment 13
Can be with picture and text transitional surface on cleaning printing press using the car wash water preparing, the picture and text transfer table on printer Kept man of a noblewoman's forme before this, the image-text area rubber cover ink layer of forme, non-graphic region overlay a thin layer fountain solution, forme is with rubber Picture and text and part fountain solution are transferred on blanket by the contact of skin cloth, and blanket contacts picture and text and part fountain solution with paper again Transfer on paper.The present invention is to find that above-mentioned Diamond Search car wash water/the wash severe edema due to hypofunction of the spleen and offset ink match each other phase based on author Hold, with the miscible offset ink of the car wash water of the q.s sufficiently long time it is possible to effectively dissolving and removing printer Forme, the offset ink on the parts such as ink roller and blanket.When offset ink and car wash water/wash the severe edema due to hypofunction of the spleen by volume 2:1 mixing Afterwards, form uniform seriality fluid, this fluid cohesion very well, does not have the tables such as pigment precipitation, resin coagulation or ink layering Show that the phenomenon that ink structure is destroyed occurs.When more substantial car wash water/the wash severe edema due to hypofunction of the spleen is miscible enter offset ink after, formed Mixed liquor significantly reduces the adhesive force to printing parts for the ink, removes offset ink on parts such that it is able to be easier to reach Purpose.When above-mentioned car wash water/wash turns back on after the severe edema due to hypofunction of the spleen has cleaned the parts such as forme, ink roller and the blanket of printer immediately, On parts, the car wash water wet film of residual is mixed into the offset ink on ink roller, the figure on the image-text area and blanket on forme Civilian region, eventually enters into paper and is pulled away, and therefore on parts, the wet film of residual need not be dried, in particular for frequent cleaning Blanket need not be dried, and the wet film of residual just can be taken away by ink within printing several turning back on, thus in printing several Within reach satisfied commercial printing quality, printed resolution, picture and text definition and color density at all be no less than standard specimen.This Outward, above-mentioned car wash water/the wash severe edema due to hypofunction of the spleen also matches each other compatible with fountain solution, and the car wash water of residual on parts/wash severe edema due to hypofunction of the spleen wet film also may be used To be mixed into the non-graphic region on non-graphic region and the blanket on forme, eventually enter into paper and be pulled away.
Car wash water/wash the severe edema due to hypofunction of the spleen is that water is flushable, and therefore above-mentioned car wash water/wash the severe edema due to hypofunction of the spleen may be added to each on printer Carry in the parts of offset ink, such as ink roller roller group, ink fountain etc. are difficult to the position cleaned at ordinary times, form offset ink/carwash Water mixed liquid, is then rinsed well with water.The Automatic rubber cloth cleaning device being equipped with also be can be directly used on printer, also can be straight Connect for Automatic rubber cloth cleaning machine.

Claims (10)

1. a kind of natural green environmental protection Diamond Search car wash water is it is characterised in that this car wash water is by vegetable fatty acid esters and nonionic Surfactant is 20-98 in mass ratio:80-2 compounds and obtains, and described nonionic surfactant is through oxolane And/or third oxidation and/or ethoxyquin C1-C10 alcohol.
2. a kind of natural green environmental protection Diamond Search car wash water according to claim 1 is it is characterised in that also to include second non- Ionic surface active agent and water, the second described nonionic surfactant is through oxolane and/or the third oxidation and/or second The C11-C18 alcohol of oxidation, vegetable fatty acid esters, the matter of nonionic surfactant, the second nonionic surfactant and water Amount ratio is 20-98:40-2:40-0:20-0.
3. a kind of natural green environmental protection Diamond Search car wash water according to claim 1 is it is characterised in that described vegetable oil The molecular formula of fatty acid ester is CnO2R;Wherein CnO2 is C8-C22 fat carboxyl, and R is C1-C4 alkyl, comprises all of same point Isomer.
4. the molecular formula of vegetable fatty acid esters according to claim 3 is CnO2R it is characterised in that CnO2 is n carboxylic Base, n=8-22, R are methyl Me, ethyl Et, n-pro-pyl Pr, isopropyl iPr, normal-butyl Bu, isobutyl group iBu or tertiary butyl tBu.
5. a kind of natural green environmental protection Diamond Search car wash water according to claim 1 is it is characterised in that described nonionic The molecular formula of surfactant is CmOBOxPOyEOz, and wherein CmO represents 1 mole of m carbochain alcohol radical, and m=1-10, BOx represent fourth X mole of oxidation, x=0-20, POy represent y mole of the third oxidation, and y=0-30, EOz represent z mole of ethoxyquin, z=2-40.
6. a kind of natural green environmental protection Diamond Search car wash water according to claim 5 is it is characterised in that described nonionic Surfactant be C1-C10 alcohol successively with oxolane and/or expoxy propane and/or reacting ethylene oxide, prepare non-from Sub- surfactant, C1-C10 alcohol is 1 with the mol ratio of oxolane, expoxy propane and oxirane:0-20:0-30:2-40.
7. a kind of natural green environmental protection Diamond Search car wash water according to claim 2 is it is characterised in that described second is non- The molecular formula of ionic surface active agent is CjOBOuPOvEOw, and wherein CjO represents 1 mole of j carbochain alcohol radical, j=11-18, BOu table Show that fourth aoxidizes u mole, u=0-30, POv represent v mole of the third oxidation, and v=0-40, EOw represent w mole of ethoxyquin, w=2-50.
8. a kind of natural green environmental protection Diamond Search car wash water according to claim 7 is it is characterised in that described second is non- Ionic surface active agent be C11-C18 alcohol successively with oxolane and/or expoxy propane and/or reacting ethylene oxide, be prepared into To the second nonionic surfactant, C11-C18 alcohol is 1 with the mol ratio of oxolane, expoxy propane and oxirane:0- 30:0-40:2-50.
9. a kind of natural green environmental protection Diamond Search car wash water according to any one of claim 1-8 is it is characterised in that join In side, all components in addition to water are all with natural green plant extract as initial feed, by solvent-free organic synthesiss process It is obtained, all components all do not contain any VOC.
10. a kind of natural green environmental protection Diamond Search car wash water according to claim 1 and 2 is it is characterised in that prepare Car wash water can be additionally used in clean using UV offset ink UV offset machine.
CN201610860579.8A 2016-09-28 2016-09-28 A kind of natural green environmental protection Diamond Search car wash water Pending CN106479256A (en)

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