CN110294957A - Chemical coating or ink advertisement remover and preparation method thereof - Google Patents
Chemical coating or ink advertisement remover and preparation method thereof Download PDFInfo
- Publication number
- CN110294957A CN110294957A CN201910660385.7A CN201910660385A CN110294957A CN 110294957 A CN110294957 A CN 110294957A CN 201910660385 A CN201910660385 A CN 201910660385A CN 110294957 A CN110294957 A CN 110294957A
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- China
- Prior art keywords
- ink
- remover
- chemical coating
- advertisement
- parts
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
Abstract
The invention belongs to the remover technical fields of chemical coating or ink with surfactant, and in particular to a kind of chemical coating or ink advertisement remover.The remover includes tributyl phosphate and polyoxyethylene ether.Remover safety and environmental protection of the invention, formula is simple, and it is convenient to make, and the elimination effect of the scribble matrix strong for permeability is good, while removing advertisement, will not damage to the paint of substrate, stability is good.
Description
Technical field
The invention belongs to the remover technical fields of chemical coating or ink with surfactant, and in particular to a kind of
Chemical coating or ink advertisement remover.
Background technique
In recent years, building, structures, the facility in the public place such as the road in China urban area, public square
On facade and residential building institute, residential building inside and outside or even the vehicles, trees common " urban illegal advertising " (" ' urban illegal advertising '
Study on Legal ", Wang Tao, Shandong University's master thesis, 2009, the 2nd section of 1-3 row of page 1, publication date 2010 years
30 days 06 month).However, the appearance of these small advertisements causes to seriously affect to the city appearance environment in entire city, people is significantly reduced
Quality of the life (origin cause of formation and control measures of " simple analysis city ' psoriasis ' small advertisement ", Shou Haibin, " decision forum-place public affairs
Decision Jing Jian scientific seminar altogether " is on collection of thesis, and 2016, page 142,4-5 row of making a summary, publication date December 31 in 2016
Day), therewith and extremely be the factors leading to social instability such as the possible deception of these small advertisements, crime (" improvement city persistent ailment
Path-is ruled by law by taking ' city psoriasis ' as an example ", Li Guanwen, succession, the 3rd phase in 2015,1 section of 5-7 row of the left column of page 96 is public
Open day on 04 28th, 2015).
In recent years, although management of markets in urban districts personnel and the staff of relevant departments never stopped to the clear of illegal small advertisement
Reason, but " psoriasis " was never thoroughly removed, administrative staff and small advertisement beneficiary are controlling patch repeatly and repeatly always repeatly
Patch control repeatly in be turned on protracted war (the ruling by law path-of city persistent ailment " administer by taking ' city psoriasis ' as an example ", Li Guanwen, succession,
3rd phase in 2015,1 section of 7-10 row of the left column of page 96, publication date on 04 28th, 2015).
Requirement with advances in technology with people to print quality is higher and higher, and the quality of ink is also being continuously improved
(" the high-tech tendency of ink development ", Wang Li, Guangdong printing, the 5th phase in 2005, the left column paragraph 1 1-2 row of page 51), extensively
The ink for accusing scribble is also growing with each passing hour.
Currently, scribble advertisement cleaning agent on the market is primarily present following problems: can also be effective to general scribble spot,
However, the region that the and residence time intensive for small advertisement is long, the cleaning effect of the especially strong matrix of permeability are limited.
Summary of the invention
In view of this, the region long the purpose of the present invention is to provide a kind of intensive for the small advertisement and residence time, especially
It is the good chemical coating of the cleaning effect of the strong matrix of permeability or ink advertisement remover.
Secondly, inventor also found, for the matrix for being coated with paint, the detergent of strong detergency exists existing detergent
While removing small advertisement, the paint of substrate can be also destroyed.
Inventors have found that existing scribble advertisement detergent uses some chemical components not environmentally, while cleaning,
Environment is not only polluted, the health of the periphery common people is more jeopardized.
For inventor it has furthermore been found that existing scribble advertisement detergent composition is complicated, some is up to ten several ingredients, places
After a period of time, there is lamination, and elimination effect is obviously deteriorated.Can there is a problem of using and to store process unstable
(such as number of patent application 201510211486.8).
To achieve the above object, the technical solution of the present invention is as follows:
Chemical coating or ink advertisement remover, including tributyl phosphate and polyoxyethylene ether.
Inventor has found that the chemical remover including tributyl phosphate and polyoxyethylene ether is for small wide in the course of the research
The region for collection and the residence time length of informing against, the cleaning effect of the especially strong matrix of permeability are good.
The tributyl phosphate refers to tricresyl phosphate n-butyl.
Further, the polyoxyethylene ether includes octyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether or combinations thereof object.
Further, the volume ratio of octyl phenol polyoxyethylene ether and fatty alcohol polyoxyethylene ether is 0.1:1-10:1.
Further, the chemical coating or ink advertisement remover, according to volume ratio, including 1-10 parts of tributyl phosphate
With 1-5 parts of polyoxyethylene ether.
Further, the chemical coating or ink advertisement remover, further include butyl glycol ether.
Further, the chemical coating or ink advertisement remover, according to volume ratio, including 5-10 parts of tributyl phosphate,
1-5 parts and butyl glycol ether 4-10 parts of polyoxyethylene ether.
Further, the chemical coating or ink advertisement remover further include mono stearate glyceryl ester and/or sebacic acid two
Ethyl ester and/or trimethyl phosphate.
Further, the chemical coating or ink advertisement remover, according to volume ratio, including 5-10 parts of tributyl phosphate,
1-5 parts of polyoxyethylene ether, 4-10 parts of butyl glycol ether, 5-10 parts of mono stearate glyceryl ester and/or 5-10 parts of sebacic acid diethylester
And/or 5-10 parts of trimethyl phosphate.
The present invention also aims to protect the preparation method of the chemical coating or ink advertisement remover, specifically:
Above-mentioned raw materials are mixed.
The beneficial effects of the present invention are:
Chemical coating or ink advertisement remover safety and environmental protection of the invention.
Chemical coating of the invention or ink advertisement removal agent prescription are simple, and it is convenient to make.
The region that chemical coating or ink advertisement remover of the invention is intensive for small advertisement and the residence time is long, especially
Be the strong matrix of permeability cleaning effect it is good.
Chemical coating or ink advertisement remover of the invention will not cause the paint of substrate while removing advertisement
It destroys.
Chemical coating or ink advertisement remover stability of the invention is good, places 6 months not go out at indoor 20-50 DEG C
Existing lamination, and cleaning effect is stablized.
Remover of the invention has a wide range of application, and can not only remove ink series advertisements, additionally it is possible to remove offset printing, ink paste etc.
Chemical coating series advertisements.
Detailed description of the invention
Fig. 1 is the figure before and after the processing using remover made from embodiment 1, wherein 1A is the picture before processing, Tu1BWei
Treated picture；
Fig. 2 is the figure before and after the processing using remover made from embodiment 3, wherein 2A is the picture before processing, and Fig. 2 B is
Treated picture；
Fig. 3 is the figure before and after the processing using remover made from embodiment 5, wherein 3A is the picture before processing, and Fig. 3 B is
Treated picture；
Fig. 4 is using the figure before and after the processing for placing remover made from 6 months embodiments 1 at room temperature, wherein 4A is
Picture before processing, Fig. 4 B are treated picture；
Fig. 5 is using the figure before and after the processing for placing remover made from 6 months embodiments 3 at room temperature, wherein 5A is
Picture before processing, Fig. 5 B are treated picture；
Fig. 6 is using the figure before and after the processing for placing remover made from 6 months embodiments 5 at room temperature, wherein 6A is
Picture before processing, Fig. 6 B are treated picture.
Specific embodiment
Illustrated embodiment is to preferably be illustrated to the contents of the present invention, but is not that the contents of the present invention only limit
In illustrated embodiment.So those skilled in the art carry out nonessential change to embodiment according to foregoing invention content
Into and adjustment, still fall within protection scope of the present invention.
Embodiment 1
Offset printing, ink paste or ink advertisement remover are specifically prepared according to the following steps using following raw material:
By mono stearate glyceryl ester (1mL), tributyl phosphate (3mL), sebacic acid diethylester (1mL), butyl glycol ether
(0.5mL), Triton X-100 (0.5mL), octyl phenol polyoxyethylene ether OP-10 (1.5 mL) and fatty alcohol polyoxy second
Alkene ether (n=4-8, OE-6) (1.5mL) mixing compounding, is sufficiently stirred, obtains colorless and transparent remover product.
Embodiment 2
Remover made from embodiment 1 is attached in small watering can, being sprayed directly into baking vanish elevator door, (elevator door belongs to infiltration
Strong substrate thoroughly can there are the markings on its surface after general remover is removed) small advertisement is intensive and the residence time is long to clear
Clean region belongs to the strong substrate of permeability (as shown in Figure 1A), after standing 20-30 seconds, according to circumstances uses rag or scouring pad
Wiping, scribble are cleaned, and no trace remains and do not hurt priming paint (as shown in Figure 1B).
As shown in Figure 1, using remover made from embodiment 1, the area to be cleaned of and residence time intensive to small advertisement length
Domain is good especially for the elimination effect of the strong substrate of permeability.
Embodiment 3
Offset printing, ink paste or ink advertisement remover are specifically prepared according to the following steps using following raw material:
By mono stearate glyceryl ester (1mL), tributyl phosphate (3mL), trimethyl phosphate (1mL), butyl glycol ether
(1mL), octyl phenol polyoxyethylene ether OP-10 (2mL) and fatty alcohol polyoxyethylene ether (n=4-8, OE-4) (2mL) mixing are multiple
Match, be sufficiently stirred, obtains colorless and transparent remover product.
Embodiment 4
Remover made from embodiment 3 is attached in small watering can, being sprayed directly into fire hydrant, (it is strong that the fire hydrant belongs to infiltration
Substrate can there are the markings on its surface after general remover is removed) on that small advertisement is intensive and the residence time is long is to be cleaned
Region belongs to the strong substrate of permeability (as shown in Figure 2 A), after standing 20-30 seconds, is according to circumstances wiped with rag or scouring pad
It wipes, scribble is cleaned, no trace residual, and fire hydrant priming paint is intact (as shown in Figure 2 B).
As shown in Figure 2, using remover made from embodiment 3, the area to be cleaned of and residence time intensive to small advertisement length
Domain is good especially for the elimination effect of the strong substrate of permeability.
Embodiment 5
Offset printing, ink paste or ink advertisement remover are specifically prepared according to the following steps using following raw material:
By mono stearate glyceryl ester (1mL), tributyl phosphate (2mL), sebacic acid diethylester (1mL), trimethyl phosphate
(1mL), butyl glycol ether (0.5mL), Triton X-100 (0.5mL), octyl phenol polyoxyethylene ether (1.5mL) and rouge
Fat alcohol polyoxyethylene ether (n=4-8, OE-2) (1.5mL) mixing compounding, is sufficiently stirred, obtains colorless and transparent remover product.
Embodiment 6
Remover made from embodiment 5 is attached in small watering can, ammeter box enclosure (ammeter box enclosure category is sprayed directly into
, can there are the markings on its surface after general remover is removed in permeating strong substrate) on small advertisement it is intensive and the residence time is long
Region to be cleaned belong to the strong substrate of permeability (as shown in Figure 3A), after standing 20-30 seconds, according to circumstances use rag or
Scouring pad wiping, scribble are cleaned, no trace residual, and fire hydrant priming paint is intact (as shown in Figure 3B).
From the figure 3, it may be seen that using remover made from embodiment 3, the area to be cleaned of and residence time intensive to small advertisement length
Domain is good especially for the elimination effect of the strong substrate of permeability.
Stability test
It is to place 6 at 20 DEG C~50 DEG C that remover made from embodiment 1, embodiment 3 and embodiment 5, which is placed in temperature range,
It a month, sees whether to be layered；
And remover made from the embodiment 1, embodiment 3 and embodiment 5 by placement 6 months at room temperature sprays to electricity respectively
Terraced door, fire hydrant, the area to be cleaned that small advertisement is intensive (respectively as shown in 4A, 5A and 6A) in ammeter box enclosure and the residence time is long
Domain belongs to the strong substrate of permeability, after standing 20-30 seconds, is according to circumstances wiped with rag or scouring pad, observation scribble cleaning
Situation (respectively as shown in 4B, 5B and 6B).
The result shows that it is 20 DEG C~50 DEG C that remover made from embodiment 1, embodiment 3 and embodiment 5, which is placed in temperature range,
It is lower to place 6 months, do not occur lamination；And the scribble in region to be cleaned is cleaned, no trace residual, and priming paint
It is intact.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (9)
1. chemical coating or ink advertisement remover, which is characterized in that including tributyl phosphate and polyoxyethylene ether.
2. chemical coating according to claim 1 or ink advertisement remover, which is characterized in that the polyoxyethylene ether packet
Include octyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether or combinations thereof object.
3. chemical coating according to claim 2 or ink advertisement remover, which is characterized in that octyl phenol polyoxyethylene ether
With the volume ratio of fatty alcohol polyoxyethylene ether are as follows: 0.1:1~10:1.
4. chemical coating according to claim 1,2 or 3 or ink advertisement remover, which is characterized in that according to volume ratio,
Including 1-10 parts and polyoxyethylene ether 1-5 parts of tributyl phosphate.
5. chemical coating according to claim 1,2 or 3 or ink advertisement remover, which is characterized in that further include second two
Alcohol butyl ether.
6. chemical coating according to claim 5 or ink advertisement remover, which is characterized in that according to volume ratio, including
1-10 parts of tributyl phosphate, 1-5 parts and butyl glycol ether 4-10 parts of polyoxyethylene ether.
7. chemical coating according to claim 5 or 6 or ink advertisement remover, which is characterized in that further include single-stearic
Acid glyceride and/or sebacic acid diethylester and/or trimethyl phosphate.
8. chemical coating according to claim 7 or ink advertisement remover, which is characterized in that according to volume ratio, including
5-10 parts of tributyl phosphate, 1-5 parts of polyoxyethylene ether, 4-10 parts of butyl glycol ether, 1-10 parts of mono stearate glyceryl ester and/or certain herbaceous plants with big flowers
1-10 parts of diethyl adipate and/or 1-10 parts of trimethyl phosphate.
9. the preparation method of any one of the claim 1-8 chemical coating or ink advertisement remover, which is characterized in that will be upper
Raw material is stated to mix.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910660385.7A CN110294957A (en) | 2019-07-22 | 2019-07-22 | Chemical coating or ink advertisement remover and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910660385.7A CN110294957A (en) | 2019-07-22 | 2019-07-22 | Chemical coating or ink advertisement remover and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110294957A true CN110294957A (en) | 2019-10-01 |
Family
ID=68031560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910660385.7A Pending CN110294957A (en) | 2019-07-22 | 2019-07-22 | Chemical coating or ink advertisement remover and preparation method thereof |
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| Country | Link |
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| CN (1) | CN110294957A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1670090A (en) * | 2005-03-04 | 2005-09-21 | 广西大学 | Method for preparing water-soluble quick cleaning agent for outdoor adlet |
| CN102391712A (en) * | 2011-10-13 | 2012-03-28 | 上海嘉华广告有限公司 | Scavenger for outdoor adlet |
| CN102888140A (en) * | 2011-07-20 | 2013-01-23 | 深圳市裕同印刷股份有限公司 | Formula and preparation process of environment-friendly printing ink cleaning agent |
| CN102888308A (en) * | 2011-07-21 | 2013-01-23 | 深圳市裕同印刷股份有限公司 | Prescription and preparation process for environment-friendly and high-efficiency blanket detergent |
| CN104559431A (en) * | 2013-10-25 | 2015-04-29 | 天津汉林通商科技有限公司 | Metal printing cloth-washing water |
-
2019
- 2019-07-22 CN CN201910660385.7A patent/CN110294957A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1670090A (en) * | 2005-03-04 | 2005-09-21 | 广西大学 | Method for preparing water-soluble quick cleaning agent for outdoor adlet |
| CN102888140A (en) * | 2011-07-20 | 2013-01-23 | 深圳市裕同印刷股份有限公司 | Formula and preparation process of environment-friendly printing ink cleaning agent |
| CN102888308A (en) * | 2011-07-21 | 2013-01-23 | 深圳市裕同印刷股份有限公司 | Prescription and preparation process for environment-friendly and high-efficiency blanket detergent |
| CN102391712A (en) * | 2011-10-13 | 2012-03-28 | 上海嘉华广告有限公司 | Scavenger for outdoor adlet |
| CN104559431A (en) * | 2013-10-25 | 2015-04-29 | 天津汉林通商科技有限公司 | Metal printing cloth-washing water |
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Application publication date: 20191001 |
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