CN102883706A - Foaming cosmetic composition containing ellagic acid or one of the salts thereof and an essential oil - Google Patents

Abstract

The invention relates to a cosmetic composition which, in a cosmetically acceptable medium, includes: (i) one or more compounds chosen from ellagic acid, the ethers thereof, the salts of ellagic acid and ethers thereof, and the mixtures of same, and (ii) one or more essential oils, (iii) one or more foaming agents. The invention likewise relates to a cosmetic treatment method implementing such a composition and to the use of said composition for washing and/or anti-dandruff treatment of keratin fibers.

Description

The foaming composition that contains ellagic acid or its a kind of salt and essential oil

The present invention relates to a kind of foaming composition, said composition comprises the salt that is selected from ellagic acid, its ether, these chemical compounds and at least a chemical compound of their mixture, and at least a essential oil; Relate to a kind of cosmetic treatment method that uses described compositions and relate to described compositions in the washing of keratin fiber and scalp, particularly human keratin fibres such as hair and/or the purposes in the anti-dandruff processing.

For satisfy the expectation of new consumer, particularly for the expectation of natural prodcuts and/or Eco-Design product; the preparation of environmental protection cosmetic product is just becoming a significant challenge; namely; run through design and the research and development considering environmental effect in their life cycles (terminal point from raw material to the life-span, during through production, logistics, dispensing and use) and integrate environmental effect.

As any other cosmetic compositions that routinizes, must satisfy performance and service index (stability, the suitability, innocuousness etc.) through Eco-Design and/or natural cosmetic composition.

The anti-dandruff cosmetic composition of the obtainable overwhelming majority contains piroctone olamine, ZPT and/or the selenium sulfide as anti-dandruff activating agent on the market.All these compositions all are effectively for the dandruff, but they are synthetic molecules and are considered to have eco-toxicity (toxic to aquatile) and/or zest when high concentration.

Simultaneously, might find and claim as " anti-dandruff " and contain as the anti-dandruff dose of product for the essential oil of natural component, yet but can't realize the anti-dandruff performance level of synthetic anti-dandruff activating agent, in the dandruff situation that particularly hyper-proliferative of Malassezia (Malassezia genus) yeast causes on facing by scalp.

Therefore, be necessary to have contain satisfy natural sex and/or eco-toxicity index and with the system of the same effective anti-dandruff composition of synthetic anti-dandruff activating agent, and be necessary to a great extent to have a kind of anti-dandruff cosmetic composition that satisfies these requirements.

The applicant unexpectedly finds now by using the combination of at least a chemical compound in the salt have the salt that is selected from ellagic acid, its ether, ellagic acid and its ether in the compositions that comprises at least a essential oil and at least a foaming agent, might obtain to satisfy a kind of cosmetic composition of the above index of carrying, and obtain effective especially as desquamation compositions and have a kind of environmental protection of good operating characteristic, nontoxic cosmetic composition especially.Those that for example mention as preamble with known synthetic anti-dandruff activating agent are compared, this combination with natural agents makes it unexpectedly might be equally effectively to anti-dandruff, the dandruff that is particularly caused by the propagation of Malassezia yeast on the scalp.

Particularly, compositions according to the present invention shows significant especially anti-dandruff effectiveness, especially in the situation that repeated application.

In addition, found that this cosmetic composition is particularly suitable for washing keratin fiber, and particularly human keratin fibres such as hair.In fact, described compositions easily can be distributed on hair and the scalp and produce the foam of the abundant softness that water can easily remove, thereby obtain clean, glittering, smooth, soft hair.

In addition, keep stablizing and can not causing the formation of caking over a long time according to compositions of the present invention.Particularly, said composition all has good stability when ambient temperature (25 ° of C) and the lower storage of higher temperature (for example, 37 ° of C or 45 ° of C).

Therefore, a theme of the present invention is a kind of cosmetic composition, and said composition comprises the following in the acceptable medium on making up:

(i) be selected from the salt of ellagic acid, its ether and ellagic acid and its ether, and one or more chemical compounds of their mixture, and

(ii) one or more essential oil,

(iii) one or more foaming agent.

Another theme of the present invention relates to the described compositions of a kind of use and is used for keratin fiber, especially for washing keratin fiber and/or elimination or reduce the dandruff on the scalp, the anti-dandruff cosmetic treatment method of the dandruff that particularly caused by the Malassezia yeast.

Theme of the present invention or described compositions are used for the dandruff on washing keratin fiber and/or the antagonism scalp, the purposes of the dandruff that is particularly caused by the Malassezia yeast.

Other features of the present invention, aspect, theme and advantage will become more clear after reading the following description and example.

Ellagic acid and derivant

Compositions according to the present invention comprise the salt that is selected from ellagic acid, its ether, ellagic acid with and one or more chemical compounds (i) of the salt of ether.

Ellagic acid is called again also [5,4,3-cde]-1-.alpha.-5:6-benzopyran-5 of 2,3,7,8-tetrahydroxy-1-.alpha.-5:6-benzopyran, and the 10-diketone is a kind of molecule of knowing that exists in the vegetable kingdom.Can be with reference to the Merck index of having delivered (Merck Index), the 20th edition (1996), No. 3588.

Ellagic acid has following chemical formula:

This chemical formula comprises four condensed ring.

Ellagic acid is commercially available, especially can be purchased from SIGMA (Sigma) company of France.

File FR-A-1478523 has disclosed the ellagic acid that is used for a kind of method of purification ellagic acid and has disclosed the purification that obtains via this a kind of method.

One or more ethers of operable ellagic acid preferentially are selected from monoether, diether, three ethers or the polyether that one or more hydroxyls by ellagic acid (in four OH groups of ellagic acid) to the etherification of one or more OR groups obtains according to the present invention, and R is selected from C ₂-C ₂₀Alkyl group, polyalkylene oxide groups and particularly polyoxyethylene and/or polyoxypropylene group and derived from the group of one or more monosaccharide or polysaccharide, for example as the group with following chemical formula:

In diether, three ethers or the polyether situation of ellagic acid, R group as hereinbefore defined can be identical or different.

Patent US 5,073, described this class ether in 545.Preferably, these ethers of ellagic acid are selected from 3,4-, two-O-methyl ellagic acid, 3,3 '-4-, three-O-methyl ellagic acid and 3,3 '-two-O-methyl ellagic acid.

One or more salt of operable ellagic acid and/or its ether preferentially are selected from alkali metal or alkali salt such as sodium salt, potassium salt, calcium salt and magnesium salt, the salt of ammonium salt and amine such as triethanolamine, monoethanolamine, arginine and lysinate according to the present invention.Preferably, one or more salt of operable ellagic acid and/or its ether are selected from alkali metal or alkali salt, particularly sodium salt, potassium salt, calcium salt or magnesium salt according to the present invention.

In all chemical compounds (i) of giving an example, preferably use ellagic acid or its salt.

According to compositions of the present invention preferably comprise for the gross weight of said composition by weight from 0.01% to 10%, particularly by weight from 0.1% to 5% and even be more preferably by weight one or more chemical compounds (i) of from 0.2% to 2%.

One or more essential oil

Compositions according to the present invention comprises at least a essential oil (ii).

The difference of essential oil and vegetable oil is that they can't resolve into glycerol and fatty acid soaps by saponification.In addition, they have volatility.

According to the definition that in international standard ISO 9235, provides and adopted by European Pharmacopoeia Convention (Commission of theEuropean Pharmacopoeia), essential oil be by through the material of vegetable origin of botany definition by entrainment with steam or by dry distilling or the product a kind of odorous that obtains via the suitable mechanical process (colding pressing) that does not heat, it has complicated formation usually.Essential oil is normally via not causing in the compositions physical process of any great change to come from aqueous phase separation.

Be used for obtaining the pattern of essential oil

The selection of technology depends primarily on raw material: its initial condition and its feature, its actual nature." essential oil/material of vegetable origin " productive rate may depend on plant and very big variation: 15ppm occur to as many as 20%.Richness or the poor degree of the feature, particularly viscosity of this selection adjusting essential oil, color, solubility, volatility, some composition.

Entrainment with steam

Entrainment with steam is corresponding to the evaporation of the relatively poor material of a kind of water miscibility in the presence of steam.Raw material placed with boiling water or steam in Charente distillator (alambic) contact.Entrainment with steam goes out the essential oil steam, and this essential oil steam carries out condensation and is recovered in Florence vase (or essence tank) as liquid phase in condenser, therein, by sedimentation make essential oil and moisture from.Separate in case carried out essential oil, remaining watery distillate is called as " Aromatic water " or " hydrosol " or " distillation flower water " after entrainment with steam so.

Dry distilling

Essential oil is by distilling timber, bark or tree root in confined chamber, and does not add water or steam obtains, and this confined chamber is designed such that liquid is recovered in the bottom.Cade oil is the most well-known example in the product that in this way obtains.

Cold pressing

This production method via mechanical process is only applicable to citrus fruit (Citrus (Citrus spp.)) at ambient temperature.The party's ratio juris is as follows: citrus fruit peels is torn to bits and reclaim the inclusions of the secretory sac that has been broken by a kind of physical process.Standard procedure comprises the whole surface that makes corrasion be applied to fruit under current.After removing solid waste, by centrifugal action with essential oil from aqueous phase separation.Most of equipment of industrial product allows simultaneously or in a sequence to reclaim fruit juice and essential oil.

Physicochemical characteristic

Essential oil has volatility and is liquid under ambient temperature (25 ° of C), and this comes they and the difference of " solidifying " oil.They more or less all with color and its density usually less than the density of water.They have high index of refraction and in them great majority polarized light is turned to.They are fat-soluble and dissolve in especially common organic solvent, such as those in the acceptable organic solvent on making up of mentioning subsequently.They also can be by entrainment with steam, and is difficult to water-soluble.

They are by the molecular composition with carbon backbone chain, and the number of carbon atom is usually between 5 and 22.

The main chemical classes that is present in the chemical compound in the essential oil is:

-terpene and sesquiterpene hydrocarbon, for example:

The essential oil of Colophonium: australene, camphene

The essential oil of Juniperus rigida Sieb.et Zucc.: australene, camphene, cadinene

The essential oil of Fructus Citri Limoniae: limonene

-alcohol, for example:

The essential oil of coriander: linalool

The essential oil of rosewood: linalool

The essential oil of Flos Rosae Rugosae: geraniol

The mixture of-ester and alcohol, for example:

The essential oil of lavandula angustifolia: linalool and linalyl acetate

The essential oil of Herba Menthae: menthol and menthyl acetate

-aldehyde, for example:

The essential oil of Cortex Cinnamomi: cinnamic aldehyde

The essential oil of Herba Cymbopogonis Citrari: citral and citronellal

The essential oil of eucalyptus citriodora: citronellol

-ketone, for example:

The essential oil of Fructus cari carvi: carvone

The essential oil of Salvia japonica Thunb.: absinthol

The essential oil of Japanese arborvitae: absinthol

-phenols, for example:

Thymic essential oil: thymol

The essential oil of savoury: carvacrol

The essential oil of Adeps Bovis seu Bubali: thymol and carvacrol

The essential oil of Flos Caryophylli: eugenol

-ether, for example:

The essential oil of Fructus Foeniculi, Fructus Anisi Stellati: methoxybenzene

The essential oil of Fructus Foeniculi: methoxybenzene

The essential oil of Eucalyptus globulus Labill: eucalyptol

The essential oil of Cortex Melaleucae leucadendrae: eucalyptol

The essential oil of Rhizoma Melaleuca Viridiflora: eucalyptol

-peroxide, for example:

The essential oil of Herba chenopodii: ascaridole

The essential oil of Bulbus Allii: allicin

The overwhelming majority of essential oil is that the complex mixture by the chemical compound that belongs to these various chemical families consists of.

Material of vegetable origin

Normally be in plant or the plant part of various drying regimes (dry state, withered form or fresh form) for the production of the material of vegetable origin of essential oil.

Among the operable essential oil according to the present invention, what can mention is to be subordinated to those that obtain in the plant of following botany family:

Fir section or Pinaceae: coniferous tree

Amaryllidaceae

Anacardiaceae

Fructus Lycopersici esculenti branch section: clothing is blue

Umbelliferae (for example umbelliferae): Fructus anethi, Radix Angelicae Sinensis, coriander, Crithmum maritimum, Radix Dauci Sativae, parsley

Araeceae

Aristolochiaceae

Compositae: yarrow, artemisia, Flos Chrysanthemi, Helichrysum

Betulaceae

Cruciferae

Burseraceae: Olibanum

Caryophyllaceae

Canellaceae

Caesalpiniaceae: face cream Pterostyrax (copaiba balsam)

Chenopodiaceae

Cistaceae: rock Flos Rosae Rugosae

Cyperaceae

Dipterocarpaceae

Ericaceae: Gaultheria (checkerberry)

Euphorbiaceae

Papilionaceae

Mang cattle Seedling section: Flos Pelargonii

Guttiferae

Hamamelidaceae

Hernandiaceae

Hypericaceae: Herba Hyperici perforati

Iridaceae

Juglandaceae

Labiatae: Herba thymi vulgaris, Adeps Bovis seu Bubali, horsemint, savoury, Herba Ocimi (Herba Ocimi Pilosi), Origanum majorana L., Herba Menthae, Herba Pogostemonis, lavandula angustifolia, Salvia japonica Thunb., Catnip, Herba Rosmarini Officinalis, Hyssopus offcinalis L., Balm, Herba Rosmarini Officinalis

Lauraceae: Luo Wenshaye, fragrant and sweet flower, rosewood, Cortex Cinnamomi, Litsea

Liliaceae: Bulbus Allii

Magnoliaceae: Magnolia

Malvaceae

Meliaceae

Cup axle flower section

Moraceae: Fructus Cannabis, Fols lupuli

Myruca ceas

Myristicaceae: Semen Myristicae

Myrtaceae: Eucalyptus genus, Camellia sinensis, Rhizoma Melaleuca Viridiflora, Melaleuca, Ba Hao genus, Flos Caryophylli, Fructus Rhodomyrti

Oleaceae

Piperaceae: Fructus Piperis

Pittosporum tobira section

Grass family: fragrant honeybee leaf, lemonweed, Vetiveria zizanoides

Polygonaceae

Ranunculaceae

Rosaceae: Flos Rosae Rugosae

Rubiaceae

Rutaceae: all Citrus plants

Salicaceae

Santalaceae: sandalwood

Saxifragaceae

Schisandraceae

Styracaceae: Benzoinum

Thymelaeceae: Lignum Aquilariae Resinatum

Tiliaceae (Tilliac é es)

Valerianaceae: valeriana, Radix Et Rhizoma Nardostachyos

Verenaceae: lantana, Verbena

Violaceae

Zingiberaceae: Rhizoma Alpiniae Officinarum, Rhizoma Curcumae Longae, Elettaria cardamomum (L.) Maton, Rhizoma Zingiberis Recens

Zygophyllaceae

And their mixture.

Among the operable essential oil according to the present invention, will more preferably utilize a kind of quintessence oil of the essential oil that is selected from the following:

Torrid zone Herba Ocimi (Herba Ocimi Pilosi)

Cortex Melaleucae leucadendrae

Cortex Cinnamomi

The Fructus Citri Limoniae Catnip

Herba Cymbopogonis Citrari

Flos Caryophylli

Coriander

Australia eucalyptus globolus

Eucalyptus citriodora

Eucalyptus globulus Labill

Flos Pelargonii

Bourbon's Flos Pelargonii

Laser grass (Laser siler)

Bay tree

Lemonweed

Green Citrus

The Spain Origanum majorana L.

Fragrant honeybee leaf

Rhizoma Melaleuca Viridiflora

The Spain Adeps Bovis seu Bubali

The Greece Adeps Bovis seu Bubali

The eucalyptol Herba Rosmarini Officinalis

Flos Rosae Rugosae

Winter savory

Camellia sinensis (alternate leaf Cortex Melaleucae leucadendrae (Melaleuca alternifolia))

The linalool Herba thymi vulgaris

Thymol Herba thymi vulgaris (Herba thymi vulgaris (Thymus vulgaris))

Thymol Herba thymi vulgaris (foreign Herba thymi vulgaris (Thymus zygis))

Herba Verbenae

Vetiveria zizanoides

And their mixture.

Even more preferably, these one or more essential oil are the essential oil that is selected from Fructus Citri Limoniae Catnip, Flos Caryophylli, fragrant honeybee leaf and Greece Adeps Bovis seu Bubali and their mixture.

Preferably comprise for the gross weight of said composition by weight from 0.001% to 10%, particularly from 0.01% to 5% and even be more preferably one or more essential oil of from 0.05% to 1% according to compositions of the present invention.

Therefore, do not comprise imidazoles family such as econazole anti-dandruff dose according to compositions of the present invention.

Foaming agent

Compositions according to the present invention comprises at least a foaming agent (iii).

For purposes of the present invention, term " foaming agent " is intended to represent to have more than or equal to 8 and preferably greater than or equal to 10 HLB(hydrophilic-lipophilic balance) a kind of chemical compound.HLB has characterized the ratio of hydrophilic segment and lipophilic portion in the molecule.This concept of HLB is known to those skilled in the art.In " HLB system, the guide that saves time (The HLB system.Atime-saving guide to Emulsifier Selection) that emulsifying agent is selected " (1984 by ICI Americas publication), specifically described this concept.

Foaming agent is to be characterized by its foaming capacity.

The foaming capacity of foaming agent can be measured by standard method of measurement well known to those skilled in the art.

Preferably, foaming agent be so that with foaming agent with by weight 1.5% when introducing in the water of pH=7, in the following test of using Sita Foam Tester R2000 instrument, produce greater than 100ml, even more preferably greater than 200ml and even be more preferably a foam volume greater than 500ml.The 270ml foaming agent solution is introduced in the double jacket bowl (internal diameter is 20cm, and temperature is 33 ° of C) of a constant temperature.Foam is to produce by a rotor, and this rotor is comprised of a conventional axle and a disk being attached to four perforation set squares, thereby allows air bubble is mechanically introduced among the solution.The rotary speed of rotor is set to per minute 1100 and turns.Generation to foam after three minutes is assessed.The measurement of the foam volume that produces be by installation have an appointment 15 pins, a cylindrical slip-on head with sensor of capacity effect carries out.

Also characterized by its foaming capacity according to compositions of the present invention.

Measure the foaming capacity of compositions according to sieve Xi Miersi (Ross Miles) method (NF T 73-404) of improvement.

The improvement part of the method is as follows:

Measurement is carried out with infiltration water under 22 ° of C temperature.The concentration of solution is 2g/l.Drop is 1m.The amount of composition that drops is 200ml.This 200ml compositions falls into a graduated cylinder that has the 50mm diameter and contain the 50ml test composition.After stopping 5 minutes, measure compositions mobile.

Preferably, the foaming capacity of said composition is greater than 100ml, even more preferably greater than 200ml and even be more preferably greater than 500ml.

One or more foaming agent used according to the invention are surfactant and can be indistinguishably using separately or as mixture preferably.

Preferably, one or more foaming agent that use separately or use as mixture are selected from anion, nonionic, both sexes or amphion and cationic surfactant.

Be suitable for implementing foaming agent of the present invention as follows especially:

One or more anion surfactants:

Term " anion surfactant " means only to comprise anionic group as a kind of surfactant of ionic group or ionogen.These anionic groups preferentially are selected from CO ₂H, CO ₂ ^-, SO ₃H, SO ₃ ^-, OSO ₃H, OSO ₃ ^-, OPO ₃H ₂, OPO ₃H ^-And OPO ₃ ^2-Group.

Example as the anion surfactant of in the context of the present invention can be separately or using as mixture; what can mention is: alkyl sulfate; alkyl ether sulfate; the alkylamide ether sulfate; alkylaryl polyether sulfate; monoglyceride sulfate; alkylsulfonate; alkylamide sulfonate; alkylaryl sulfonates; alpha-alkene sulfonate; paraffin sulfonate; alkyl sulfo succinate; alkyl ether sulfo succinate; the alkylamide sulfosuccinate; alkyl sulfoethanoic acid. salt; acyl sarcosinates; acyl glutamate; the alkyl sulphosuccinamate; acyl isethinate and N acyl taurine salt; the salt of the alkyl monoester of polysaccharide glycosides-polycarboxylic acids; acyl-lactate; the salt of the alkyl D-galactoside alduronic acid (salt of alkyl D-galactoside iduronic acid; les sels d ' acidesalkyl D-galactoside-uroniques); alkyl ether carboxylic acid's salt; the salt of alkyl aryl ether carboxylic acid; the salt of alkylamide ether carboxylic acid and the corresponding salt-independent shape of all these chemical compounds; the alkyl of all these chemical compounds and carboxyl groups comprise from 6 to 24 carbon atoms; preferred from 8 to 20 carbon atoms, and aromatic yl group represents phenyl group.

In these chemical compounds some can be by oxyethylations and are then preferably comprised from 1 to 50 ethylene oxide unit.

C ₆-C ₂₄The salt of alkyl monoester and polysaccharide glycosides-polycarboxylic acids can be selected from C ₆-C ₂₄APG-citrate, C ₆-C ₂₄APG-tartrate and C ₆-C ₂₄APG-sulfosuccinate.

When one or more anion surfactants are salt form, it or they can be selected from alkali metal salt such as sodium salt or potassium salt and particular certain cancers, ammonium salt, amine salt and particularly amino alkoxide, or alkali salt such as magnesium salt.

The example of the amino alkoxide that can especially mention comprises monoethanolamine, diethanolamine and triethanolamine salt, monoisopropanolamine, diisopropanolamine (DIPA) or triisopropanolamine salt, 2-amino-2-methyl-1-propanol salt, AMPD salt and three (methylol) aminomethane salt.

Preferred alkali metal salt or alkali salt and particularly sodium salt or the magnesium salt of using.

One or more anion surfactants used according to the invention also can be selected from C ₁₀-C ₂₂Fatty acid soaps.

C ₁₀-C ₂₂Fatty acid soaps is by one or more C ₁₀-C ₂₂The salt of fatty acid forms.

Can be as among all anion surfactants of foaming agent mentioned, the preferred (C that utilizes ₆-C ₂₄) alkyl sulfate, comprise (the C of 2 to 50 ethylene oxide units ₆-C ₂₄) alkyl ether sulfate, alkali metal particularly preferably, ammonium, amino alcohol and alkaline-earth metal salt form, (C ₆-C ₂₄) acyl sarcosinates, (C ₆-C ₂₄) acyl glutamate, (C ₆-C ₂₄) acyl isethinate, N-(C ₆-C ₂₄) acyl taurine salt, (C ₆-C ₂₄) alkyl ether-carboxylic acid and its salt, (C ₆-C ₂₄) alkyl amido ether-carboxylic acid and its salt, or the mixture of these chemical compounds.

Particularly, the preferred (C that uses ₁₂-C ₂₀) alkyl sulfate, comprise (the C of from 2 to 20 ethylene oxide units ₁₂-C ₂₀) alkyl ether sulfate, and (C ₁₂-C ₂₀) acyl isethinate, particularly alkali metal, ammonium, amino alcohol and alkaline-earth metal salt form, or the mixture of these chemical compounds.Very the person is better, preferred Sodium Lauryl Ether Sulphate or the lauroyl methyl isethionate that comprises the 2.2mol ethylene oxide that use.

According to compositions of the present invention preferably comprise for the gross weight of said composition by weight from 0.1% to 50%, particularly by weight from 4% to 30% and even be more preferably by weight one or more anion surfactants of from 8% to 20%.

One or more non-ionic surface active agents:

Can be used for compositions used according to the invention non-ionic surface active agent example for example in 1991 by Blackie ﹠amp; Son(Glasgow ﹠amp; London) be described among the 116th to 178 page of " surfactant handbook (the Handbook of Surfactants) " of the M.R.Porter that publishes.Non-ionic surface active agent is selected from alcohol, the salmefamol, (C through polyethoxylated, poly-propoxylation and/or bound to polyglycerol especially _{1 – 20}) alkylphenol or fatty acid, they contain and comprise for example aliphatic chain of from 8 to 18 carbon atoms, the number of ethylene oxide and/or propylene oxide group may be especially the number of from 2 to 50 scope and glycerol group can be especially in from 2 to 10 scope.

Can also be mentioned the copolymer of ethylene oxide and propylene oxide; the fatty acid ester of the alternatively oxyethylation of sorbitan; the fatty acid ester of sucrose; the fatty acid ester of polyoxy alkylidene, alternatively derivant, aldose disaccharide amide (Aldobionamide) and the amine oxide of the APG of oxyalkylene, alkyl androstanediol ester, N-alkyl glucamine and N-acyl group methyl glucamine.

Unless otherwise mentioned, term " fat " chemical compound (for example, a kind of fatty acid) is illustrated in and comprises at least one chemical compound saturated or the unsaturated alkyl chain on its main chain, this alkyl chain contains at least 8 carbon atoms, preferred from 8 to 30 carbon atoms, and even be more preferably from 10 to 22 carbon atoms.

Unless otherwise mentioned, this saturated or unsaturated alkyl chain preferably contains from 8 to 30 carbon atoms, and even is more preferably from 10 to 22 carbon atoms.

In mentioned all non-ionic surface active agents that can be used as foaming agent, preferably use the optionally APG of oxyalkylene.

According to compositions of the present invention preferably comprise for the gross weight of said composition by weight from 0.01% to 20%, particularly by weight from 0.5% to 10% and even be more preferably by weight one or more non-ionic surface active agents of from 1% to 10%.

One or more both sexes or zwitterionic surfactant

Can be used for one or more both sexes among the present invention or the zwitterionic surfactant especially especially alternatively quaternised second month in a season or uncle's aliphatic amine derivative, wherein the aliphatic hydrocarbon group is a kind of straight or branched that contains from 8 to 22 carbon atoms, described amine derivative contains at least one anionic group, for example carboxylate radical, sulfonate radical, sulfate radical, phosphate radical or phosphonate groups.That can mention especially is (C ₈-C ₂₀) alkyl betaine, (C ₈-C ₂₀) alkyl sulfo betaines, (C ₈-C ₂₀Alkyl) acylamino-(C ₂-C ₈Alkyl) betanin or (C ₈-C ₂₀Alkyl) acylamino-(C ₂-C ₈Alkyl) sulfobetaines.Preferably, use (C ₈-C ₂₀Alkyl) acylamino-(C ₂-C ₈Alkyl) betanin such as cocamido propyl betaine.

Among the spendable alternatively quaternised second month in a season or uncle's aliphatic amine derivative, as hereinbefore defined, can also be mentioned to have following counter structure (A1) and chemical compound (A2):

R _a-CONHCH ₂CH ₂-N ⁺(R _b)(R _c)(CH ₂COO ^-) （A1）

Wherein:

R _aRepresentative is derived from a kind of sour R that preferably is present in the cocos nucifera oil that has been hydrolyzed _aThe C of-COOH ₁₀-C ₃₀Alkyl or alkenyl group, heptyl group, nonyl group or undecyl group,

R _bRepresent the beta-hydroxyethyl group, and

R _cRepresent carboxymethyl group;

And R _a'-CONHCH ₂CH ₂-N (B) is (A2) (B')

Wherein:

B representative-CH ₂CH ₂OX ',

B' representative-(CH ₂) _z-Y ', z=1 or 2 wherein,

X' represents group-CH ₂-COOH, CH ₂-COOZ ' ,-CH ₂CH ₂-COOH ,-CH ₂CH ₂-COOZ ' or hydrogen atom,

Y' representative-COOH ,-COOZ ', group-CH ₂-CHOH-SO ₃H or-CH ₂-CHOH-SO ₃Z ',

Z ' representative is derived from a kind of ion of alkali or alkaline-earth metal such as sodium, potassium or magnesium; Ammonium ion; Or derived from organic amine and particularly amino alcohol such as monoethanolamine, diethanolamine and triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA) or triisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, the ion of ammediol and three (methylol) aminomethane

R _a' representative preferably be present in cocos nucifera oil or the Semen Lini oil that has been hydrolyzed in a kind of sour R _a' C of COOH ₁₀-C ₃₀The alkyl or alkenyl group is in particular C ₁₇With and special-shaped formula or undersaturated C ₁₇The alkyl group of group.

These chemical compounds are classified under the following title in the 5th edition the CTFA dictionary in 1993: cocos nucifera oil acyl both sexes base oxalic acid disodium, lauroyl both sexes base oxalic acid disodium, caprinoyl both sexes base oxalic acid disodium, decoyl both sexes base oxalic acid disodium, cocos nucifera oil acyl both sexes base disodium beclomethasone, lauroyl both sexes base disodium beclomethasone, caprinoyl both sexes base disodium beclomethasone, decoyl both sexes base disodium beclomethasone, lauroyl both sexes base dipropionic acid and cocos nucifera oil acyl both sexes base dipropionic acid.

What can mention as an example, is in trade name by Rhodia (Rhodia)

The cocos nucifera oil acyl both sexes base diacetin of selling under the C2M Concentrate.

Among all both sexes referred to above or zwitterionic surfactant, the preferred chemical compound that uses corresponding to chemical formula (A1).More preferably, one or more both sexes or zwitterionic surfactant are selected from cocos nucifera oil acyl both sexes base oxalic acid disodium, lauroyl both sexes base oxalic acid disodium, caprinoyl both sexes base oxalic acid disodium, decoyl both sexes base oxalic acid disodium, cocos nucifera oil acyl both sexes base disodium beclomethasone, lauroyl both sexes base disodium beclomethasone, caprinoyl both sexes base disodium beclomethasone, decoyl both sexes base disodium beclomethasone, lauroyl both sexes base dipropionic acid and cocos nucifera oil acyl both sexes base dipropionic acid.

According to compositions of the present invention preferably comprise for the gross weight of said composition by weight from 0.01% to 30%, particularly by weight from 0.5% to 20% and even be more preferably by weight from 1% to 10% one or more both sexes or zwitterionic surfactant.

One or more cationic surfactants:

A kind of surfactant of positively charged when term " cationic surfactant " means in being comprised in according to compositions of the present invention.This surfactant can carry one or more permanent positive charges or can contain one or more functional groups of cationically in compositions according to the present invention.

According to the present invention can as one or more cationic surfactants of foaming agent preferentially be selected from polyoxy alkylidene optionally primary, the second month in a season or uncle's fatty acid, or its salt, quaternary ammonium salt and their mixture.

Fatty amine comprises at least one usually based on C ₈-C ₃₀The chain of hydrocarbon.Among the operable fatty amine according to the present invention, the example that can mention comprises stearyl acylamino-diemethylamine and Di-Stearyl amine.

The example of the quaternary ammonium salt that can especially mention comprises:

-corresponding to those quaternary ammonium salts of following general formula (A3):

Radicals R wherein ₈To R ₁₁, can be identical or different, representative contains the aliphatic hydrocarbon group of the straight or branched of from 1 to 30 carbon atom, or aromatic hydrocarbon group such as aryl or alkaryl, radicals R ₈To R ₁₁In at least one expression contain from 8 to 30 carbon atoms, the preferably group of from 12 to 24 carbon atoms.The aliphatic hydrocarbon group can comprise hetero atom, looks like especially oxygen, nitrogen, sulfur and halogen.The aliphatic hydrocarbon group for example is selected from C ₁-C ₃₀Alkyl, C ₁-C ₃₀Alkoxyl, (C ₂-C ₆) polyoxy alkylidene, C ₁-C ₃₀Alkylamide, (C ₁₂-C ₂₂) alkyl amido (C ₂-C ₆) alkyl, (C ₁₂-C ₂₂) alkyl acetates and C ₁-C ₃₀Hydroxyalkyl group; X ^-An anion that is selected from following group: halogenide, phosphate, acetate, lactate, (C ₁-C ₄) alkyl sulfate and (C ₁-C ₄) alkylsulfonate or (C ₁-C ₄) alkylaryl sulfonates.

Among the quaternary ammonium salt with chemical formula (A3), preferred those on the one hand, it is tetraalkylammonium salt, for example dialkyl dimethyl ammonium or alkyl trimethyl ammonium salt, wherein alkyl group contains approximate 12 to 22 carbon atoms, particularly mountain Yu base trimethyl ammonium, distearyl Dimethyl Ammonium, cetyltrimethyl ammonium or benzyl dimethyl stearyl ammonium salt, perhaps be on the other hand the amino oxypropyl trimethyl ammonium salt of palmityl amido propyl leptodactyline, stearoyl, the amino propyl-dimethyl cetyl ammonium salt of stearoyl or by Daniel van Dijk company (Van Dyk) in title

Amino propyl-dimethyl (acetic acid myristinate) ammonium salt of the stearoyl of selling for 70 times.Particularly preferably use the chlorate of these chemical compounds;

The quaternary ammonium salt of-imidazoline for example has those of following chemical formula (A4):

R wherein ₁₂Representative contains thiazolinyl or the alkyl group of 8 to 30 carbon atoms, for example, and tallow acid derivant, R ₁₃Represent hydrogen atom, C ₁-C ₄Alkyl group or contain thiazolinyl or the alkyl group of 8 to 30 carbon atoms, R ₁₄Represent C ₁-C ₄Alkyl group, R ₁₅Represent hydrogen atom or C ₁-C ₄Alkyl group, X ^-Be the anion that is selected from following group: halogenide, phosphate, acetate, lactate, alkyl sulfate, alkylsulfonate or alkylaryl sulfonates, alkyl wherein and aromatic yl group preferably comprise respectively from 1 to 20 carbon atom and from 6 to 30 carbon atoms.R ₁₂And R ₁₃Preferred expression comprises the thiazolinyl of from 12 to 21 carbon atoms or a kind of mixture of alkyl group, tallow acid derivant for example, R ₁₄Expression methyl group and R ₁₅The expression hydrogen atom.This product for example by Rewo company in title

W sells for 75 times;

-have di-quaternary ammonium salt or three quaternary ammonium salts of chemical formula (A5):

R wherein ₁₆Expression contains the alkyl group of approximate 16 to 30 carbon atoms, and it optionally interrupts R by hydroxylating and/or by one or more oxygen atoms ₁₇Be selected from hydrogen or contain alkyl group or the following group of from 1 to 4 carbon atom:

R ' ₁₆, R ' ₁₇, R ' ₁₈, R ₁₈, R ₁₉, R ₂₀And R ₂₁, can be identical or different, be selected from hydrogen or contain the alkyl group of 1 to 4 carbon atom, and X ^-And Y ^-The anion that is selected from especially following group: halogenide, acetate, phosphate, nitrate and (C ₁-C ₆) alkyl sulfate, particularly Methylsulfate and sulfovinate.This compounds for example is from Finetex(Quaternium-89) the Finquat CT-P of company, from Finetex(Quaternium 75) the Finquat CT of company and from Innospec Active Chemicals(Quaternium-75) the Condicate CT of company;

-contain the quaternary ammonium salt of at least one ester functional group, as have following chemical formula (A6) those:

Wherein:

R ₂₂To be selected from C ₁-C ₆Alkyl group and C ₁-C ₆Hydroxyalkyl or dihydroxy alkyl group;

R ₂₃Be selected from:

-group

-radicals R ₂₇, they are based on straight or branched, saturated or undersaturated C ₁-C ₂₂The group of hydrocarbon,

-hydrogen atom,

R ₂₅Be selected from:

-group

-radicals R ₂₉, they are based on straight or branched, saturated or undersaturated C ₁-C ₆The group of hydrocarbon,

-hydrogen atom,

R ₂₄, R ₂₆And R ₂₈Can be identical or different, be to be selected from based on C straight chain or side chain, saturated or unsaturated ₇-C ₂₁The group of hydrocarbon;

R, s and t can be identical or different, are the integers of scope from 2 to 6;

Y is the integer of scope from 1 to 10;

X and z can be same or different, are the integers of scope from 0 to 10;

X ^-It is a kind of simple or complicated organic or inorganic anion;

Condition is, the x+y+z sum is from 1 to 15, when x is 0, and R then ₂₃Expression R ₂₇, and when z is 0, R then ₂₅Expression R ₂₉

These alkyl groups R ₂₂Can be straight chain or side chain, and straight chain more especially.

Preferably, R ₂₂The group of expression methyl, ethyl, ethoxy or dihydroxypropyl, and the group of methyl or ethyl more especially.

Advantageously, the x+y+z sum is from 1 to 10.

Work as R ₂₃Be based on the radicals R of hydrocarbon ₂₇The time, it can be long and contain from 12 to 22 carbon atoms, perhaps can be short and contains from 1 to 3 carbon atom.

Work as R ₂₅It is a kind of radicals R based on hydrocarbon ₂₉The time, it preferably contains 1 to 3 carbon atom.

Advantageously, R ₂₄, R ₂₆And R ₂₈, can be identical or different, be to be selected from based on C straight chain or side chain, saturated or unsaturated ₁₁-C ₂₁The group of hydrocarbon, and more especially be selected from straight chain or side chain, saturated or unsaturated C ₁₁-C ₂₁The group of alkyl and thiazolinyl.

Preferably, x can be identical or different with z, equals 0 or 1.

Advantageously, y equals 1.

Preferably, r, s and t can be identical or different, are to equal 2 or 3 and even more especially equal 2.

Anion X ^-Preferably halogenide (chloride, bromide or iodide) or alkyl sulfate, more especially Methylsulfate.Yet, can utilize mesylate, phosphate, nitrate, toluene fulfonate, derived from the anion of the anion of organic acid such as acetic acid or lactic acid or any other compatible with the ammonium that contains a kind of ester functional group.

Anion X ^-Even more especially chloride or Methylsulfate.

In compositions according to the present invention, utilize more especially the ammonium salt with chemical formula (A6), wherein:

R ₂₂Expression methyl or ethyl group,

X and y equal 1;

Z equals 0 or 1;

R, s and t equal 2;

R ₂₃Be selected from:

-group

-methyl, ethyl or based on C ₁₄-C ₂₂The group of hydrocarbon;

-hydrogen atom;

R ₂₅Be selected from:

-group

-hydrogen atom;

R ₂₄, R ₂₆And R ₂₈, can be identical or different, be to be selected from based on C straight chain or side chain, saturated or unsaturated ₁₃-C ₁₇The group of hydrocarbon, and preferentially be selected from straight chain or side chain, saturated or unsaturated C ₁₃-C ₁₇The group of alkyl and thiazolinyl.

Based on the group of hydrocarbon straight chain advantageously.

What for example can mention is chemical compound such as diacyl oxygen ethyl Dimethyl Ammonium, diacyl oxygen ethyl-hydroxyethyl ammonium methyl, monoacyl oxygen ethyl dihydroxy ethyl ammonium methyl, three acyl group oxygen ethyl-methyl ammoniums and the monoacyl oxygen ethyl-hydroxyethyl Dimethyl Ammonium (particularly chloride or Methylsulfate) with chemical formula (A6), and their mixture.These carboxyl groups preferably contain 14 to 18 carbon atoms and more especially obtain from vegetable oil such as Petiolus Trachycarpi oil or Oleum helianthi.When this chemical compound contained some carboxyl groups, these groups can be identical or different.

These products for example are by triethanolamine, triisopropanolamine, alkyl diethanolamine or alkyl diisopropanolamine (DIPA) (they are alkoxylated alternatively) and plant or zoogenous C ₁₀-C ₃₀Fatty acid or C ₁₀-C ₃₀The direct esterification of the mixture of fatty acid reaction or obtain by their ester exchange reaction of methyl ester.What follow this esterification closely is use alkylating agent such as alkyl (preferable methyl or ethyl) halogenide, dialkyl group (preferred dimethyl or diethyl) sulfuric ester, methyl mesylate, methyl tosylate, glycol chlorohydrin or glycerin chlorohydrin quaternized.

This compounds for example is to be existed by Henkel Corp. (Henkel)

Sell under the title, existed by Si Taipan company (Stepan)

Sell under the title, existed by Ceca company

That sell under the title or existed by Rewo-Witco company

Sell under WE 18 titles.

Can contain for example a kind of mixture of quaternary ammonium monoesters, diester and three ester salt according to compositions of the present invention, wherein most of weight is diester salt.

The mixture of operable ammonium salt comprises and for example contains by weight 15% to 30% acyl group oxygen ethyl dihydroxy ethyl ammonium methyl Methylsulfate, by weight 45% to 60% diacyl oxygen ethyl-hydroxyethyl ammonium methyl Methylsulfate and the mixture of 15% to 30% three acyl group oxygen ethyl-methyl ammonium methyl sulphates by weight, and carboxyl groups has from 14 to 18 carbon atoms and comes from alternatively by partially hydrogenated Petiolus Trachycarpi oil.

Also might use the ammonium salt that contains at least one ester functional group of in patent US-A-4874554 and US-A-4137180, describing.

According to compositions of the present invention preferably comprise for the gross weight of said composition by weight from 0.01% to 30%, particularly by weight from 0.5% to 20% and even be more preferably by weight one or more cationic surfactants of from 1% to 5%.

Preferably comprise by weight at least 4% foaming agent of total content according to compositions of the present invention.More preferably, said composition comprises for the gross weight of said composition by weight scope from 4% to 50% of total content, and particularly by weight from 4% to 30% and even be more preferably by weight from 4% to 20% foaming agent.

In preferred the first embodiment, one or more foaming agent are selected from anion surfactant, preferably mentioned above those.

In another embodiment, one or more foaming agent are selected from non-ionic surface active agent, preferably (the C of oxyalkylene alternatively ₈-C ₂₀) APG.

In an especially preferred embodiment, foaming agent is a kind of mixture of anion, nonionic and/or both sexes or zwitterionic surfactant, like this so that one or more anion surfactants preferentially are selected from (C ₆-C ₂₄) alkyl sulfate and the (C that comprises from 2 to 50 ethylene oxide units ₆-C ₂₄) alkyl ether sulfate, (C ₈-C ₂₀) acyl sarcosinates, (C ₈-C ₂₀) acylamino-glutamate, Glu, (C ₈-C ₂₀) acyl isethinate, N-(C ₈-C ₂₀) acyl taurine salt, (C ₈-C ₂₀) alkyl ether-carboxylic acid and its salt, (C ₈-C ₂₀) alkylamide ether-carboxylic acid and its salt; Like this so that when having one or more non-ionic surface active agents, it or they preferentially be selected from the alternatively (C of oxyalkylene ₈-C ₂₀) APG; And like this so that when having one or more both sexes or zwitterionic surfactant, it or they preferentially be selected from (C ₈-C ₂₀Alkyl) betanin, (C ₈-C ₂₀Alkyl) acylamino-(C ₂-C ₈Alkyl) betanin and cocos nucifera oil acyl both sexes base diacetate esters, and their salt.

In one even preferred embodiment, foaming agent is a kind of mixture of anion and both sexes or zwitterionic surfactant, like this so that one or more anion surfactants are selected from (C ₁₂-C ₁₄) alkyl sulfate and (C ₁₂-C ₁₄) alkyl ether sulfate and (C ₈-C ₂₀) acyl-hydroxyethyl sulfonate, particularly comprise the sodium-salt form of from 2 to 10 ethylene oxide units; And like this so that one or more both sexes or zwitterionic surfactant are selected from cocos nucifera oil acyl both sexes base diacetate esters, particularly sodium-salt form, and (C ₈-C ₂₀Alkyl) acylamino-(C ₂-C ₈Alkyl) betanin.

In above-described each embodiment, these one or more anion surfactants, one or more non-ionic surface active agents that exist alternatively and one or more both sexes that exist alternatively or the concentration of zwitterionic surfactant can be as described previously.

Advantageously, one or more aniones and both sexes or zwitterionic surfactant and one or more non-ionic surface active agents are present in it or they according in the compositions of the present invention the time, their total content is with respect to be by weight from 4% to 50% for the gross weight of compositions of the present invention, and be more preferably by weight from 4% to 30%, and more particularly be by weight from 10% to 20% scope.

One or more thickening agents

Can also comprise one or more thickening agents according to compositions of the present invention.

For purposes of the present invention, term " thickening agent " means a kind of like this reagent: so that 1% be introduced in a kind of aqueous solution or a kind of water-alcohol solution that contains by weight 30% ethanol and make it during pH=7 might be at 25 ° of C, 1s by weight ^-1Realize at least 100cPs and the preferred at least viscosity of 500cPs under the shear rate.Can use cone/plate viscometer (Haake R600 flow graph or analogous instrument) to measure this viscosity.

These one or more thickening agents can be selected from non-ionic cellulose thickening agent (hydroxyethyl-cellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose), anionic cellulose thickening agent such as carboxymethyl cellulose, guar gum and its non-ionic derivate (hydroxypropyl guar gum), microbe-derived glue (xanthan gum, scleroglucan glue), fatty acid ester PEG(Polyethylene Glycol) and fatty acid ester PEG derivant as by INCI title PEG-150 distearate and PEG-55 propylene glycol oleate and known those, based on acrylic acid, crosslinked or non-crosslinked homopolymer and copolymer, association polymer described below and their mixture of methacrylic acid or acrylamido propane sulfonic acid.

Based on the crosslinked of acrylic or methacrylic acid or non-crosslinked homopolymer and copolymer particularly acrylate homopolymer and/or methacrylic acid homo thing such as the Carbopol980 from promise reputation company (Noveon), and methacrylic acid and C ₁-C ₄The special picture of the copolymer of alkyl acrylate is by (the INCI: the Carbopol Aqua SF1 polymer of acrylate copolymer) selling of Lubrizol Corp. (Lubrizol).Operable one or more associative polymers are can be each other in water-bearing media or the water-soluble polymer that reversibly associates with other molecules according to the present invention.

Their chemical constitution comprises hydrophilic area and the hydrophobic region that is characterized by at least one aliphatic chain that preferably comprises 10 to 30 carbon atoms.

Operable one or more associative polymers can be anion, cation, both sexes or amphion type according to the present invention, as by Goodrich Corporation (Goodrich) (INCI: acrylate/C10-30 alkyl acrylate cross-linked polymer) title Pemulen TR1 or TR2, by vapour Bagong department (CIBA) at title Salcare SC90, by (the Rohm of Rhom and Hass; Haas) at title Aculyn 22,28,33,44 or 46 and the polymer under title Elfacos T210 and T212, sold by Aksu company (Akzo).

Among all mentioned thickening agents, one or more thickening agents are preferably selected from based on the homopolymer of acrylic or methacrylic acid and copolymer, cross linked polymer preferably, and/or from C ₁₀-C ₃₀The fatty acid amide that carboxylic acid obtains.

Cosmetic composition comprises for the gross weight of said composition preferably by weight from 0.1% to 20%, and more preferably one or more thickening agents of from 0.2% to 10% by weight.

One or more regulators

Can also comprise one or more regulators according to compositions of the present invention.

According to the present invention, term " regulator " expression can improve any chemical compound of cosmetic characteristic, particularly flexibility, smoothness (disentangling), sense of touch and the static of hair.

Regulator preferentially is selected from lower group, and this group comprises the following: cationic polymer, be different from cationic surfactant, siloxanes such as the organosiloxane according to foaming agent used in the present invention, C straight chain or side chain ₈-C ₃₀C hydrocarbon, straight chain or side chain ₈-C ₃₀Aliphatic alcohol, C ₈-C ₃₀Fatty acid and C ₁-C ₃₀The ester of alcohol, and C especially ₈-C ₃₀Fatty acid and C ₈-C ₃₀The ester of aliphatic alcohol, C ₁-C ₇Acid or diacid and C ₈-C ₃₀The mixture of the ester of aliphatic alcohol, ceramide or ceramide-analogous, non-volatile vegetable oil and these chemical compounds.

The polymer of positively charged when term " cationic polymer " means in being comprised in according to compositions of the present invention.This polymer can carry one or more permanent positive charges or can contain the functional group of the one or more cationicallies in compositions according to the present invention.

Can preferentially be selected from following polymer as one or more cationic polymers of regulator according to the present invention: comprise the part that forms polymer chain or directly be attached to this polymer chain primary, secondary, uncle and/or quaternary amines and have between 500 and approximately between the 5000000 and preferred molecular weight between 1000 and 3000000.

When regulator is a kind of cationic polymer, it preferentially be selected from contain comprise primary, the unit of secondary, uncle and/or quaternary amines those, these groups can form the host polymer chain part or can be entrained by a side direction substituent group that directly is attached to this host polymer chain.

The polymer of polyamine, polyaminoamide and polyquaternary amine type more particularly among the cationic polymer that can mention.These are known products.They are for example in French Patent (FRP) 2,505, describe in 348 and 2,542,997.

Among these polymer, what can mention is:

(1) derived from propylene acid or methacrylate or amide and comprise homopolymer or the copolymer of at least one unit with following chemical formula:

Wherein:

R ₃And R ₄, be identical or different, represent hydrogen atom or have the alkyl group of from 1 to 6 carbon atom, and preferably methyl or ethyl;

R ₅, be identical or different, expression hydrogen atom or CH ₃Group;

A is identical or different, and representative has from 1 to 6 carbon atom, alkyl group a kind of straight chain of preferred 2 or 3 carbon atoms or side chain, or have the hydroxyalkyl group of from 1 to 4 carbon atom;

R ₆, R ₇, R ₈, be identical or different, representative has alkyl group or the benzyl group of from 1 to 18 carbon atom, and preferably has the alkyl group of from 1 to 6 carbon atom;

X ^-Expression is derived from the anion of a kind of organic acid or mineral acid, such as the methylsulfuric acid salt anionic, or a kind of halogenide such as chloride or bromide.

The copolymer of family (1) can further contain the one or more unit derived from following comonomer, and these comonomers can be selected from following family: acrylamide, Methacrylamide, diacetone acrylamide, on nitrogen by (C ₁-C ₄) the low alkyl group acrylamide and Methacrylamide, acrylic or methacrylic acid or their ester, vinyl lactam such as vinylpyrrolidone or the caprolactam that replace, and vinyl esters.

Therefore, among these copolymers of family (1), what can mention is:

-with dimethyl sulfate or with the copolymer of the quaternised acrylamide of dimethyl halogenide and dimethylaminoethyl methacrylate, such as the product of under title Hercofloc, being sold by Hercules company (Hercules),

The copolymer of-acrylamide and MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride is for example described in patent application EP-A-080976 and is sold for 100 times at title BinaQuat P by Ciba-Geigy AG (Ciba Geigy),

-acrylamide and methylacryoyloxyethyl trimethylammonium Methylsulfate are sold under the Reten title by Hercules company,

The vinylpyrrolidone of-quaternised or on-quaternised/acrylic or methacrylic acid dialkyl aminoalkyl ester copolymer, such as the product of under title Gafquat, being sold by the international special product companies of the U.S. (ISP), for example as Gafquat 734 or Gafquat 755, or as an alternative scheme be called as Copolymer 845,958 and 937 product.These polymer are in French Patent (FRP) 2,077, described in detail in 143 and 2,393,573,

-dimethylaminoethyl methacrylate/caprolactam/vinylpyrrolidone trimer, such as the product of under Gaffix VC 713 titles, being sold by the international special product companies of the U.S. (ISP),

-vinylpyrrolidone/methacrylamido diemethylamine copolymer is sold for 10 times at title Styleze CC by the international special product companies of the U.S. (ISP) especially,

-quaternised vinylpyrrolidone/dimethylaminopropyl methacrylamide copolymer, such as the product of being sold for 100 times at title Gafquat HS by the international special product companies of the U.S. (ISP), and

-methacryloxy (C ₁-C ₄) alkyl three (C ₁-C ₄) cross linked polymer of alkylammonium salt, such as the polymer that obtains in the following manner: with the homopolymerization of the quaternised dimethylaminoethyl methacrylate of chloromethanes, or acrylamide and with the copolyreaction of the quaternised dimethylaminoethyl methacrylate of chloromethanes, and a kind of alefinically unsaturated compounds that more especially methylene-bisacrylamide is crosslinked after homopolymerization or the copolyreaction.More particularly utilize a kind of crosslinked acrylamide/methacryl oxy-ethyl-trimethyl salmiac copolymer (by weight 20/80), its form is for containing the by weight dispersion of 50% described copolymer in mineral oil.This dispersion is in title by vapour Bagong department

SC sells for 92 times.Can also use a kind of crosslinked methacryl oxy-ethyl-trimethyl salmiac homopolymer, for example as a kind of dispersion in the mineral oil or in the liquid ester.These dispersions are in title by vapour Bagong department

SC 95 Hes

SC sells for 96 times;

(2) polymer that is consisted of by piperazinyl units and divalent alkyl or hydroxyl alkylidene group, these groups contain straight or branched, optionally interrupt by oxygen, sulfur or nitrogen-atoms or by aromatic rings or heterocycle, and the oxidation of these polymer and/or quaternized product.This base polymer is especially in French Patent (FRP) 2,162, is described in 025 and 2,280,361;

(3) the water-soluble poly amino amides for preparing of the polycondensation by a kind of acid compound and a kind of polyamine particularly; These polyaminoamides can be crosslinked with the following: epihalohydrin, diepoxide, dianhydride, unsaturated dianhydride, two unsaturated derivant, two halohydrin, dinitrogen heterocycle butadiene, two halogen acyl group diamidogen, two alkyl halide, perhaps alternately carry out crosslinkedly with a kind of oligomer from a kind of reaction gained of difunctional's compound, this difunctional's compound has reactivity for two halohydrins, dinitrogen heterocycle butadiene, two halogen acyl group diamidogen, two alkyl halide, epihalohydrin, diepoxide or two unsaturated derivant; Cross-linking agent is to use from the ratio of 0.025 to 0.35mol scope with each amine groups of polyaminoamide; If these polyaminoamides can be comprised one or more tertiary amine functional group by alkanisation or they, they can be quaternized so.This base polymer is especially in French Patent (FRP) 2,252, is described in 840 and 2,368,508;

(4) condensation by polyalkylene polyamine and polycarboxylic acids, the polyaminoamide derivant that the alkanisation of two function reagent afterwards obtains.What can mention is, adipic acid/dialkyl amido hydroxyalkyl two alkylene triamine polymer for example, wherein alkyl group contains from 1 to 4 carbon atom and preferably represents methyl, ethyl or propyl group, and alkylidene group contains from 1 to 4 carbon atom and preferably represents the ethylidene group.This base polymer is especially in French Patent (FRP) 1,583, is described in 363.

Among these derivants, what can mention more especially is the adipic acid sold under title Cartaretine F, F4 or F8 by Shandeshi company (Sandoz)/dimethylamino hydroxypropyl/diethylenetriamines polymer;

(5) polymer that obtains of the reaction of a kind of polyalkylene polyamine by containing two primary amine groups and at least one secondary amine group and a kind of dicarboxylic acids, this dicarboxylic acids is selected from the acid of diethylene glycol and has the saturated aliphatic dicarboxylic acids of from 3 to 8 carbon atoms.Mol ratio between polyalkylene polyamine and the dicarboxylic acids is between 0.8:1 and 1.4:1; Thus the polyaminoamide of gained by following mole recently and chloropropylene oxide react: chloropropylene oxide with respect to the secondary amine group of polyaminoamide between 0.5:1 and 1.8:1.This base polymer is especially at United States Patent (USP) 3,227, is described in 615 and 2,961,347.

In the situation that adipic acid/glycidyl/diethylenetriamines copolymer, the polymer of this type particularly by Hercules company (Hercules Inc.) at title Hercosett 57 or alternately sold for 101 times at title PD 170 or Delsette by Hercules company;

(6) cyclopolymer of cyclopolymers of alkyldiallylamine or dialkyl diallyl ammonium, as contain corresponding to following chemical formula V or unit (VI) homopolymer or the copolymer as the main constituent of chain:

In this chemical formula: k and t be equal 0 or 1, k+t sum equal 1; R ₁₂Expression hydrogen atom or methyl group; R ₁₀And R ₁₁, independent of one another, expression has the alkyl group of from 1 to 6 carbon atom, wherein alkyl group preferably has the hydroxyalkyl group of from 1 to 5 carbon atom, rudimentary (C ₁-C ₄) amidoalkyl group, perhaps R ₁₀And R ₁₁Can also represent heterocyclic group such as piperidyl or morpholinyl together with their accompanying nitrogen-atoms extremely; Y ^-Anion such as bromide, chloride, acetate, borate, citrate, tartrate, disulfate, bisulfites, sulfate or phosphate.These polymer are especially in French Patent (FRP) 2,080, and 759 and in its certificate of addition 2,190,406, be described.

R ₁₀And R ₁₁, independent of one another, preferred expression has the alkyl group of from 1 to 4 carbon atom.

Among defined polymer above, what can mention more especially is: the dimethyl diallyl ammonium chloride homopolymer (with the homologue of its lower molecular wt) of being sold for 100 times at title Merquat by Ondeo Nalco Co. (Nalco) and the diallyldimethylammonium chloride of particularly selling for 550 times at title Merquat and the copolymer of acrylamide;

(7) contain two (quaternary ammonium) polymer corresponding to the repetitive of chemical formula (VII):

In chemical formula (VII):

R ₁₃, R ₁₄, R ₁₅And R ₁₆, can be identical or different, representative contains the aliphatic of from 1 to 20 carbon atom, alicyclic or aromatic yl aliphat group or rudimentary hydroxyalkyl aliphatic group, perhaps scheme R as an alternative ₁₃, R ₁₄, R ₁₅And R ₁₆Together or dividually consist of the second heteroatomic heterocycle that contains alternatively a non-nitrogen with their accompanying nitrogen-atoms on it, perhaps scheme R as an alternative ₁₃, R ₁₄, R ₁₅And R ₁₆Representative is by nitrile, ester, acyl group or amide group or group-CO-O-R ₁₇-D or-CO-NH-R ₁₇A C straight chain or side chain that-D replaces ₁-C ₆Alkyl group, wherein, R ₁₇That alkylidene and the D with from 1 to 10 carbon atom is quaternary ammonium group;

A ₁And B ₁Representative contains the polymethylene group of from 2 to 20 carbon atoms, these groups can be straight chain or side chain and saturated or unsaturated and can contain the one or more aromatic rings that are connected to or insert main chain, perhaps one or more oxygen or sulphur atom or sulfoxide, sulfone, disulphide, amino, alkylamino, hydroxyl, quaternary ammonium, urea groups, amide or ester group, and

X ^-Expression is derived from a kind of mineral acid or organic acid anion;

A ₁, R ₁₃And R ₁₅Can form piperazine ring with they accompanying two nitrogen-atoms on it; In addition, if A ₁A straight chain of expression or side chain, saturated or unsaturated alkylidene or hydroxyalkyl group, B ₁Also can represent following group

-(CH ₂) _n-CO-D-OC-(CH ₂) _p-

Wherein:

N and p are the integers of scope approximate from 2 to 20,

D represents:

A) have the glycol residue of chemical formula-O-Z-O-, wherein Z represents one based on the group of hydrocarbon straight chain or side chain or corresponding to the group of one of following chemical formula:

-(CH ₂-CH ₂-O) _x-CH ₂-CH ₂-

-[CH ₂-CH(CH ₃)-O] _y-CH ₂-CH(CH ₃)-

Wherein x and y represent to represent from 1 to 4 integer of a definition and unique degree of polymerization, perhaps represent any numeral of from 1 to 4 of average degree of polymerization;

B) two secondary diamine residues such as bridged piperazine derivatives;

C) have two primary diamines residues of chemical formula-NH-Y-NH-, wherein Y represents one based on the group of hydrocarbon straight chain or side chain, perhaps also has divalent group-CH ₂-CH ₂-S-S-CH ₂-CH ₂-;

D) has the urylene group of following chemical formula-NH-CO-NH-.

Preferably, X ^-Anion such as chloride or bromide.

These polymer have the number-average molecular weight between 1000 and 100000 generally.

The polymer of this type is particularly in French Patent (FRP) 2,320, and 330,2,270,846,2,316,271,2,336,434 and 2,413,907 and United States Patent (USP) 2,273,780,2,375,853,2,388,614,2,454,547,3,206,462,2,261,002,2,271,378,3,874,870,4,001,432,3,929,990,3,966,904,4,005,193,4,025,617,4,025,627, be described in 4,025,653,4,026,945 and 4,027,020.

Can utilize more especially the polymer that is formed by the repetitive corresponding to following chemical formula (VIII):

Wherein: R ₁₈, R ₁₉, R ₂₀And R ₂₁, be identical or different, approximate alkyl or the hydroxyalkyl group with from 1 to 4 carbon atom of expression, r and s are the integers of scope approximate from 2 to 20, and X ^-Derived from a kind of mineral acid or organic acid anion.

A kind of particularly preferred chemical compound with chemical formula (VIII) is for it, R ₁₈, R ₁₉, R ₂₀And R ₂₁Represent methylidene group and r=3, s=6 and X=Cl are referred to as extra large U.S. oronain according to INCI nomenclature (CTFA);

(8) by the polyquaternary amine polymer of the cell formation with chemical formula (IX):

In chemical formula:

R ₂₂, R ₂₃, R ₂₄And R ₂₅, be identical or different, represent hydrogen atom or methyl, ethyl, propyl group, β ethoxy, β hydroxypropyl or-CH ₂CH ₂(OCH ₂CH ₂) _pThe OH group, wherein p equals 0 or equal integer between 1 and 6, and condition is R ₂₂, R ₂₃, R ₂₄And R ₂₅Different times table hydrogen atom,

T and u can be identical or different, are the integers between 1 and 6,

V equals 0 or equal integer between 1 and 34,

X ^-Expression anion such as halogenide,

A represents dihalide group or preferred representative-CH ₂-CH ₂-O-CH ₂-CH ₂-.

This compounds is described in patent application EP-A-122 324 especially.

Among these, what for example can mention is the product of being sold by Miranol company

A 15,

AD1,

AZ1 and

175;

(9) the season polymer of vinylpyrrolidone and vinyl imidazole, for example by BASF AG in title

The product that FC 905, FC 550 and FC sell for 370 times;

(10) cationic polysaccharides, particularly cationic cellulose and cationic cellulose derivative and cationic galactomannan glue.

Among cationic polysaccharides, what can mention more especially is: comprise cellulose ether derivative, the cationic cellulose copolymer of quaternary ammonium group or be grafted with a kind of cellulose derivative and cationic galactomannan glue of water solublity quaternary ammonium monomer.

The cellulose ether derivative that comprises quaternary ammonium group is described in French Patent (FRP) Isosorbide-5-Nitrae 92,597.Also in the CTFA dictionary, these polymer are defined as the quaternary ammonium of the hydroxyethyl-cellulose that reacts with a kind of epoxide that is replaced by the trimethyl ammonium group.

Cationic cellulose copolymer or the cellulose derivative that is grafted with a kind of water solublity quaternary ammonium monomer especially are described in patent US 4 131 576, such as hydroxy alkyl cellulose, for example be grafted with especially methylol, ethoxy or the hydroxypropyl cellulose of a kind of methacryl ethyl trimethyl ammonium, methacrylamido oxypropyl trimethyl ammonium or dimethyldiallylammonium salt.

Cationic galactomannan glue is more in particular in United States Patent (USP) 3,589, is described in 578 and 4,031,307, particularly contains the guar gum of cation trialkyl ammonium group.For example utilize the guar gum through 2,3-glycidyl leptodactyline (for example, chloride) modification.

Operable other cationic polymers are cationic protein or cationic protein hydrolyzate, polyolefin imines, particularly polymine, the condensation substance that contains polymer, polyamine and the chloropropylene oxide of vinylpyridine or vinylpyridine unit, season gather urylene (quaternarypolyureylene) and chitin derivative in the context of the invention.

Cationic protein or protein hydrolysate particularly carry or are grafted with the chemical modification polypeptide of quaternary ammonium group thereon in the end of chain.Their molecular weight for example can from 1500 to 10 000 and approximate from 2000 to 5000 is changed especially.Among these chemical compounds, what especially can mention is:

-carry the collagen hydrolysate of three second ammonium groups, as under title Quat-Pro E, sell and in the CTFA dictionary, be called the product of triethyl ammonium hydrolytic collagen sulfovinate (Triethonium Hydrolyzed Collagen Ethosulfate) by Maybrook company;

-carry the collagen hydrolysate of trimethyl ammonium chloride and trimethyl stearyl chlorination ammonium group, they are to be sold under title Quat-Pro S and be called as stearyl trimethyl ammonium hydrolytic collagen (Steartrimonium HydrolyzedCollagen) in the CTFA dictionary by Maybrook company;

-carry the animal proteinum hydrolyzate of trimethyl benzyl ammonium group, as under title Crotein BTA, sold and in the CTFA dictionary, be called the product of the animal proteinum of benzyltrimethylammon.um (Benzyltrimonium) hydrolysis by standing grain major company (Croda);

-carrying the protein hydrolysate of quaternary ammonium group at polypeptide chain, described ammonium group contains at least one alkyl group with from 1 to 18 carbon atom.

Among these protein hydrolysates, what can mention except other things is:

-Croquat L, wherein quaternary ammonium group contains a C ₁₂Alkyl group;

-Croquat M, wherein quaternary ammonium group contains C ₁₀-C ₁₈Alkyl group;

-Croquat S, wherein quaternary ammonium group contains a C ₁₈Alkyl group;

-Crotein Q, wherein quaternary ammonium group contains at least one alkyl group with from 1 to 18 carbon atom.

These different products are to be sold by standing grain major company of company.

Other quaternised protein or hydrolyzate are for example corresponding to those of chemical formula (X):

X wherein ^-Be the anion of a kind of organic acid or mineral acid, A represents the protein residues derived from collagen hydrolysate, R ₂₉Expression contains the at the most lipophilic group of 30 carbon atoms, and R ₃₀Representative has the alkylidene group of 1 to 6 carbon atom.What for example can mention is to be sold for 3000 times at title Lexein QX by Inolex company, is called the product of cocoyl trimethyl ammonium collagen protein (Cocotrimonium Collagen) hydrolyzate in the CTFA dictionary.

Can also be mentioned quaternised vegetable protein such as Semen Tritici aestivi, Semen Maydis or soybean protein: the quaternised wheat protein that can mention comprise by standing grain major company sell under the following title those: the Hydrotriticum WQ or the QM that in the CTFA dictionary, are called cocoyl Dimethyl Ammonium (Cocodimonium) hydrolyzed wheat protein, or in the CTFA dictionary, be called the Hydrotriticum QL of lauryl dimethyl ammonium (Laurdimonium) hydrolyzed wheat protein, or in the CTFA dictionary, be called the Hydrotriticum QS of stearyl Dimethyl Ammonium (Steardimonium) hydrolyzed wheat protein.

In the context of the present invention among operable all cationic polymers, the preferred cationic cyclopolymerization thing that uses as hereinbefore defined, particularly dimethyl diallyl ammonium chloride homopolymer or copolymer (under title Merquat 100, Merquat 550 and Merquat S, being sold by Ondeo Nalco Co.), and season vinylpyrrolidone and vinyl imidazole polymer, cationic polysaccharides and their mixture.

According to the present invention can as among the siloxanes of regulator, with what non-limiting way can be mentioned be:

I. volatile siloxane:

These siloxanes have the boiling point between 60 ° of C and 260 ° of C.Among the siloxanes of this type, what mention is:

(a) comprise from 3 to 7, and the annular siloxane of preferred from 4 to 5 silicon atoms.

These for example are at title Volatile Silicone by carbon connection company (Union Carbide)

Lower or by Rhone-Poulenc

At title Silbione 70045

The octamethylcy-clotetrasiloxane of lower sale joins company at title Volatile Silicone by carbon

Lower or by Rhone-Poulenc at title Silbione 70045

The decamethylcyclopentasiloxane of lower sale, and their mixture.What also mention is: the cyclopolymer of dimethyl siloxane/methyl alkyl siloxane type, and such as the Volatile Silicone FZ that is sold by carbon connection company

It is a kind of dimethyl siloxane/Methyl Octyl siloxanes cyclisation copolymer;

(b) contain 2 to 9 silicon atoms and have under 25 ° of C and be less than or equal to 5 * 10 ^-6m ²The volatile siloxane of the straight chain of the viscosity of/s.

These for example are at title Silbione 70041 by Rhone-Poulenc

The hexamethyl disiloxane of lower sale.The product of this type is in January, 76 Todd; " the volatile siloxane liquid (Volatile silicone fluids for cosmetics) that is used for cosmetics " literary composition that the cosmetics of Byers and toilet articles (Cosmetics and Toiletries) the 91st volume is the 27th to 32 page is described.

II. non-volatile siloxane

These siloxanes are mainly by poly-alkylsiloxane, poly-aryl siloxanes, polyoxyethylene alkyl aryl radical siloxane and organically-modified polysiloxanes, and their mixture consists of.They can be oil, glue and resin form.

Among these poly-alkylsiloxanes, what can mainly mention is: have greater than 5 * 10 ^-6m ²/ s, and preferably less than 2.6m ²The polydimethylsiloxane of the straight chain of the viscosity of/s, that is:

-contain trimethylsilyl end groups, as, such as but not limited to 70047 series of being sold by Rhone-Poulenc Oil, from the oily Wacker BelsilDM 60000 of Wa Ke company (Wacker) or from some of General Electric Co. Limited (General Electric)

Product;

-to contain trihydroxy silyl-terminated, from 48 of Rhone-Poulenc

Series.

In this type of other poly-alkylsiloxane, can also be mentioned: by Gao Shi Mitt USA Corporation (Goldschmidt) at title Abil Wax

With Abil Wax

Lower sale be poly-(C _1-20) the poly-alkylsiloxane of alkylsiloxane.

Among these polyoxyethylene alkyl aryl radical siloxanes, what can mention is: have from 10 ^-5To 5 * 10 ^-2m ²The poly dimethyl phenyl siloxane straight chain of the viscosity of/s and/or side chain and polydimethyldiphenylsiloxane, for example:

-from the oil of Rhone-Poulenc

763,

-from 70641 series of Rhone-Poulenc Oil is such as oily Silbione70641

And Silbione 70641

-from the DC of Dow Corning Corporation (Dow Corning)

Cosmetics-stage liquid (Cosmetic Grade Fluid) product,

-from the siloxanes of the PK series of Bayer AG (Bayer), as

-from the PN of Bayer AG and the siloxanes of PH series, as

And Product;

-from some oil of the SF series of General Electric Co. Limited, such as SF

SF SF

And SF

Glue according to siloxanes of the present invention is the polydiorganosiloxanepolyurea with the high number-average molecular weight between 200 000 and 1 000 000, these polydiorganosiloxanepolyureas use separately or as the mixture in a kind of solvent, and this solvent is selected from: volatile siloxane, polydimethylsiloxane (PDMS) oil, polyphenyl methyl siloxane (PPMS) oil, isoparaffin, dichloromethane, pentane, dodecane, tridecane and the tetradecane or their mixture.

What for example mention is the chemical compound with following structure:

-poly-[(dimethyl siloxane)/(ethylene methacrylic radical siloxane)] glue,

-poly-[(dimethyl siloxane)/(diphenyl siloxane)] glue,

-poly-[(dihydro dimethyl siloxane)/(divinylsiloxanes)] glue,

-poly-[(dimethyl siloxane)/(phenyl methyl siloxanes)] glue,

-poly-[(dimethyl siloxane)/(diphenyl siloxane)/(ethylene methacrylic radical siloxane)] glue.

What can mention is Mirasil DM 300 000 glue from Rhodia.

What for example can also mention with non-limiting way is following mixture:

1) mixture that is formed by hydroxylated a kind of polydimethylsiloxane (according to the dimethiconol of CTFA nomenclature) and a kind of annular dimethyl polysiloxane (according to the Cyclomethicone of CTFA nomenclature) in the end of chain is such as the Q2 that is sold by Dow Corning Corporation

Or DowCorning 1501 Fluid products;

2) mixture that is formed by a kind of polydimethylsiloxane glue and a kind of annular siloxane is such as SF 1214 Silicone from General Electric Co. Limited

Product, this product are to be dissolved in SF 1202Silicone MW 500000(-M in (decamethylcyclopentasiloxane) _n) a kind of SE Glue;

3) have the mixture of two kinds of PDMS of different viscosities, the mixture of especially a kind of PDMS glue and a kind of PDMS oil is such as the product SF from General Electric Co. Limited And CF Product SF

The defined 20m of having above ²A kind of SE of the viscosity of/s

Glue with have 5 * 10 ⁶m ²A kind of SF of the viscosity of/s

Mixture (the 15%SE of oil

Glue and 85%SF

Oil).

CF

Product is a kind of SE

Glue (33%) and a kind of PDMS(67%) have 10 ^-3m ²The mixture of the viscosity of/s.

Operable organopolysiloxane resins is to contain following unit R according to the present invention ₂SiO _2/2, RSiO _3/2And SiO _4/2Crosslinked siloxanes system, wherein, R representative contains group or the phenyl group based on hydrocarbon of 1 to 6 carbon atom.At these products, particularly preferred those are that wherein R represents a rudimentary (C ₁-C ₄) those of alkyl group or phenyl group.

Among these resins, what can mention is at title Dow Corning

The product of lower sale or under title Silicone Fluid SS 4230 and Silicone Fluid SS4267, sold by General Electric Co. Limited those, they are dimethyl/trimethyl polysiloxanes.

Organically-modified silica alkane according to the present invention is siloxanes as hereinbefore defined, and these siloxanes comprise in its universal architecture and directly are attached to siloxane chain or via one or more organo-functional groups that adhere to based on the group of hydrocarbon.

What for example can mention is the siloxanes that comprises the following, that is:

A) the perfluoro group is such as three fluoro-alkyls, for example by General Electric Co. Limited at title FF.150Fluorosilicone

Lower or by company of SHIN-ETSU HANTOTAI (Shin-Etsu) in title

And Those of lower sale;

B) hydroxy amide base group, those that for example in patent application EP 0 342 834, describe and particularly by Dow Corning Corporation in title

The siloxanes of lower sale;

C) thiol group is as at the siloxanes X from Dow Corning Corporation

In or at the GP from Genesee company

And GP

In;

D) amine groups of on-quaternised is such as GP 4 Silicone from Genesee company

GP from Genesee company

Q2 from Dow Corning Corporation

AFL from carbon connection company

Or in the CTFA dictionary, be called the siloxanes of amino dimethyl polysiloxane (Amodimethicone);

E) carboxylate groups, the product of for example in from the patent EP 186 507 of Chisso Corp (Chisso Corporation), describing;

F) hydroxylated group, the polysiloxane that contains a hydroxyalkyl functional group of for example in french patent application FR 85/16334, describing;

What can mention the most especially is the product of being sold for 190 times at title DC by Dow Corning Corporation;

G) alkoxylate group is for example at the silicone copolymers F from SWS siloxanes company (SWS Silicones)

And from the Abil Wax of Gao Shi Mitt USA Corporation

Abil Wax And Abil Wax In the product;

H) acyloxy alkyl group, the poly-organopolysiloxane of for example in patent application FR 88/17433, describing;

I) quaternary ammonium group is as at the X2 from Gao Shi Mitt USA Corporation

And X2 Product and Abil In the product;

J) both sexes or betanin group, as by Gao Shi Mitt USA Corporation at title Abil B In the product of lower sale;

K) bisulfite salt groups, as by Gao Shi Mitt USA Corporation at title Abil S

And Abil S

In the product of lower sale;

L) comprise alternatively C ₆-C ₂₄The polyethyleneoxy of alkyl group and/or polypropylene oxygen base group, such as the product that is called dimethicone copolyol (dimethicone copolyol) of being sold for 1248 times at title DC by Dow Corning Corporation, or from oily Silwet L 722, L7500, L 77 and the L 711 of carbon connection company, and the alkyl (C that is sold for 5200 times at title Q2 by Dow Corning Corporation ₁₂) polymethyl siloxane polyol (methicone copolyol).

According to the present invention, also might use the siloxanes of a part that comprises polysiloxanes part and consisted of by a non-silicone organic chain, wherein in two parts consists of the main chain of polymer and another is grafted on the described main chain.These polymer for example are described in patent application EP-A-412 704, EP-A-412 707, EP-A-640 105 and WO 95/00578, EP-A-582 152 and WO 93/23009 and patent US 4 693 935, US 4 728 571 and US 4 972 037.These polymer are anion or nonionic preferably.

This base polymer for example is the copolymer that can obtain from the monomer mixture that is formed by the following by the radical polymerization effect, that is:

A) 50% to 90% tert-butyl acrylate by weight;

B) 0 to 40% acrylic acid by weight;

C) 5% to 40% the siloxane macromer with following chemical formula (XI) by weight:

Wherein v is the number of scope from 5 to 700; These percentage ratios by weight calculate with respect to the gross weight of monomer.

Other examples of the siloxane polymer of grafting are particularly: by connector of sulfo-propylene type grafting thereon the polydimethylsiloxane (PDMS) of mixed polymer unit of poly-((methyl) acrylic acid) type and poly-((methyl) alkyl acrylate) type; And by connector of sulfo-propylene type grafting thereon the polydimethylsiloxane (PDMS) of polymer unit of poly-((methyl) Isobutyl 2-propenoate) type.

According to the present invention, all siloxanes can also use with the form of emulsion, nanoemulsions or microemulsion.

Particularly preferred polysiloxane is as follows according to the present invention:

-non-volatile siloxane is selected from the poly-alkylsiloxane family with trimethylsilyl end groups, as has under 25 ° of C 0.2 and 2.5m ²The oil of the viscosity the between/s, for example, the oil from the DC200 series of Dow Corning Corporation particularly has 60 000cSt viscosity persons, the perhaps oil of Silbione70047 and 47 series, and 700,47V,500 000 oil of more especially being sold by Rhodia Chemical company; And the poly-alkylsiloxane with dimethyl-silicon alkanol end group, such as dimethiconol, or the polyoxyethylene alkyl aryl radical siloxane, Silbione70641V 200 oil of for example being sold by Rhodia Chemical company;

-contain the polysiloxanes of amino group, such as amino dimethyl polysiloxane or the amino polydimethylsiloxane (trimethylsilylamodimethicone) of trimethyl silyl.

The viscosity of siloxanes can especially be measured by ASTM D445-97 standard (viscosimetry).

When the regulator according to compositions of the present invention was a kind of hydrocarbon, this hydrocarbon was C a kind of straight chain or side chain ₈-C ₃₀Hydrocarbon.

Be among liquid and the hydrocarbon corresponding to this definition at ambient temperature, what can mention especially is: Fancol ID, 2-Methylpentadecane and its isomers are (such as 2,2,4,4,6,6-heptamethylnonane), the mixture of the isomers of Isoeicosane, isotetracosane, described chemical compound, AI3-36122, n-dodecane, n-undecane, n-tridecane, Pentadecane and these hydrocarbon.

Preferably utilize Fancol ID or its a kind of isomers according to the present invention.

When regulator is a kind of aliphatic alcohol, this alcohol be a kind of straight chain or side chain, saturated or unsaturated C ₈-C ₃₀Alcohol.Among the latter, what for example can mention is: 2-butyl capryl alcohol, lauryl alcohol, 2-octyldodecanol, oleyl alcohol, different spermol, isooctadecanol, behenyl alcohol and their mixture.

When regulator was a kind of fatty ester, this ester can be a kind of C ₈-C ₃₀Fatty acid and a kind of C ₁-C ₃₀The ester of alcohol, and a kind of C particularly ₈-C ₃₀Fatty acid and a kind of C ₈-C ₃₀The ester of aliphatic alcohol, or a kind of C ₁-C ₇Acid or diacid and a kind of C ₈-C ₃₀The ester of aliphatic alcohol.

Among these esters, what for example can mention is: ethyl palmitate, isopropyl ester, 2-Octyl Nitrite and 2-octyl group ester in the last of the ten Heavenly stems, isopropyl myristate, butyl ester, cetyl and 2-octyl group ester in the last of the ten Heavenly stems, butyl stearate and own ester, lauric acid hexyl ester and 2-hexyl ester in the last of the ten Heavenly stems, isononyl isononanoate, malic acid dioctyl ester, myristyl myristate, cetin and their mixture.

In compositions according to the present invention, can be that itself is known and be can be corresponding to the natural or synthetic molecule of following general formula (XII) as the ceramide of regulator or ceramide-analogous such as glycerol ceramide (glycoceramide):

Wherein:

-R ₁Represent a kind of derived from C ₁₄-C ₃₀The straight chain of fatty acid or side chain, saturated or unsaturated alkyl group, this group may be replaced by oh group at alpha position place or an oh group of Ω position, this oh group is with a kind of saturated or unsaturated C ₁₆-C ₃₀Fatty acid carries out esterification;

-R ₂Expression hydrogen atom or (glycosyl) _n, (galactosyl) _mOr sulfo group galactosyl group, wherein n is an integer of scope from 1 to 4, and m is an integer of scope from 1 to 8;

-R ₃Be illustrated in the alpha position place saturated or unsaturated based on C ₁₅-C ₂₆The group of hydrocarbon, this group may be by one or more C ₁-C ₁₄Alkyl group replaces;

It should be understood that in the situation that natural ceramide or glycerol ceramide R ₃Can also represent C ₁₅-C ₂₆Alpha-hydroxyalkyl group, this oh group are by a kind of C alternatively ₁₆-C ₃₀'alpha '-hydroxy acids comes esterification.

In the context of the present invention preferred ceramide be by Downing at dermatological document (Arch.Dermatol), the 123rd volume, the 1381st to 1384 page, those that describe in 1987 or in French Patent (FRP) FR 2 673 179, describe those.

More particularly preferred one or more ceramides are R wherein according to the present invention ₁Expression is derived from C ₁₆-C ₂₂A saturated or unsaturated alkyl of fatty acid, R ₂Expression hydrogen atom, and R ₃The C that represents saturated straight chain ₁₅The chemical compound of group.

This compounds for example is:

The inferior oil base dihydrosphingosine of-N-,

-N-oleyl dihydrosphingosine,

-N-palmityl dihydrosphingosine,

-N-stearoyl dihydrosphingosine,

-N-mountain Yu base dihydrosphingosine,

Or the mixture of these chemical compounds.

Even more preferably, use following ceramide: R wherein ₁Expression is derived from a saturated or unsaturated alkyl group of fatty acid, R ₂Expression galactosyl or sulfo group galactosyl group, and R ₃Expression-CH=CH-(CH ₂) ₁₂-CH ₃Group.

The example that can mention comprises by a kind of compositions of mixtures of these chemical compounds and the product sold under trade name Glycocer by Waitaki international bio scientific company (Waitaki International Biosciences).

Among all these regulators, preferred one or more regulators that are selected from siloxanes such as organosiloxane and cationic polymer that use.

Preferably contain for the gross weight of said composition by weight from 0.01% to 20% according to cosmetic composition of the present invention, and more preferably one or more regulators of from 0.05% to 10% by weight.

The surfactant that one or more are other

Can also comprise at least a other surfactant different from the defined foaming agent of preamble according to compositions of the present invention.These other surfactants can be anion, nonionic, both sexes or amphion or cationic.

One or more other surfactants for example can be selected from emulsifying surfactant and foam booster or foaming booster.In the CTFA(2004 version of title for " surfactant---emulsifying agent (surfactants – emulsifying agents) " and " surfactant---foam booster (surfactants – foam booster) ") in mentioned especially emulsifying surfactant and the foam booster that can be used for compositions of the present invention.

Among these emulsifying surfactants, what can mention especially is known chemical compound under following INCI title, that is: Surfhope SE Cosme C 1216, caprylin and polyglycereol-4 decanoins.

Among these foam boosters, what can mention is: fatty acid alkanol amides preferably has the aliphatic chain, particularly Coconut Fatty Acid Monoethanolamide or the coconut oil list isopropanol amide that contain from 8 to 20 carbon atoms.

Compositions according to the present invention is generally used in the topical application.

Particularly, can be any galenical form that is generally used for local application according to compositions of the present invention.Can be a kind of flushing or flushing free compositions according to compositions of the present invention.Preferably after using, said composition is rinsed out.Particularly, can be a kind of frost, gel or foam according to compositions of the present invention.

Can be used as a kind of shampoo according to compositions of the present invention, or bath gel, and even be more preferably as a kind of shampoo.

Can pack with a kind of pressurized compositions form such as aerosol or pump formula liquid taking bottle according to compositions of the present invention.

Compositions according to the present invention comprises acceptable medium in a kind of cosmetic.Acceptable organic solvents form this medium by water with on optionally one or more are made up.

These one or more organic solvents can be selected from C ₁-C ₄Lower alcohol is such as ethanol, isopropyl alcohol, the tert-butyl alcohol or n-butyl alcohol; Polyhydric alcohol is such as glycerol, propylene glycol, 1,3-PD, hexanediol (or 2-methyl-2,4-pentanediol) and Polyethylene Glycol; Polyol ethers is such as dipropylene glycol monomethyl ether; And their mixture.

When medium comprises at least a cosmetic acceptable organic solvent, the latter for the gross weight of said composition can with by weight from 0.1% to 30% and preferred by weight from 0.2% to 15% ratio exist.

Cosmetic composition according to the present invention has between 3 and 10 and a preferred pH between 5 and 7.This pH can regulate by acidulant and the basifier of conventional usefulness in cosmetic field.

Cosmetic composition used according to the invention can also contain one or more common in cosmetic field adjuvant, such as alopecia antagonist, oxidant, the vitamin and the vitamin source that comprise pantothenylol, plant, animal, mineral or artificial oil except essential oil, wax, sunscreen, mineral or organic, coloured or colourless pigment, dyestuff, pearling agent and opacifier, chelating agen, plasticizer, solubilizing agent, antioxidant, hydroxy acid, spice, antiseptic, set polymer, and their mixture.

The amount of the adjuvant that these are different is conventional those amounts of considering of using in this field.

Certainly, those of ordinary skill in the art can select carefully to be added to one or more the optional chemical compounds in the compositions according to the present invention, like this so that intrinsic be attached to according to the favourable characteristic of compositions of the present invention not can, perhaps can not be subject in fact the adverse effect of one or more contemplated additives.

Another theme of the present invention is a kind of cosmetic treatment method for scalp and keratin fiber, particularly human keratin fibres such as hair, and the method comprises a kind of composition, foam according to the present invention is administered on scalp and the described keratin fiber.After time, preferred water rinses out said composition subsequently at from 1 to 15 minute flushing free of one section optional preferable range.Preferably, described method is intended to be used to washing described keratin fiber and/or be used for being intended to eliminating and/or reducing the dandruff, and the anti-dandruff processing of the dandruff that is particularly caused by the Malassezia yeast.

Another theme of the present invention be a kind of compositions according to the present invention for washing keratin fiber, the purposes of human keratin fibres such as hair particularly.

To be a kind of compositions according to the present invention eliminate and/or reduce the dandruff for being intended to another theme of the present invention, and the purposes of the anti-dandruff processing of the dandruff that is particularly caused by the Malassezia yeast.

Following instance is intended to illustrate the present invention, however the conditional character of tool not.

Example 1:

Prepare following composition, foam: quantity is the percentage ratio that is indicated as active material (M.A.) by weight with respect to the gross weight of compositions.

This compositions has good anti-dandruff effect.

Example 2:

Prepare following composition, foam: quantity is the percentage ratio that is indicated as active material (M.A.) by weight with respect to the gross weight of compositions.

This compositions has good anti-dandruff effect.

Example 3:

Prepare following composition, foam: quantity is the percentage ratio that is indicated as active material (M.A.) by weight with respect to the gross weight of compositions.

Claims (21)

1. cosmetic composition comprises in the acceptable medium in a kind of cosmetic:

(i) be selected from ellagic acid, its ether and ellagic acid with and the salt of ether, and one or more chemical compounds of their mixture, and

(ii) one or more essential oil,

(iii) one or more foaming agent.

2. compositions as claimed in claim 1 is characterized in that one or more salt of this chemical compound (i) are selected from alkali metal or alkali salt, particularly sodium salt, potassium salt, calcium salt or magnesium salt.

3. compositions as claimed in claim 1 or 2 is characterized in that this chemical compound (i) is ellagic acid or its salt.

4. according to any one of the preceding claims compositions, it is characterized in that it comprise for the gross weight of said composition by weight from 0.01% to 10%, particularly by weight from 0.1% to 5% and even be more preferably by weight one or more chemical compounds (i) of from 0.2% to 2%.

5. according to any one of the preceding claims compositions is characterized in that described one or more essential oil are selected from the essential oil that obtains from the plant of following botany family:

Fir section or Pinaceae: coniferous tree

Amaryllidaceae

Anacardiaceae

Fructus Lycopersici esculenti branch section: clothing is blue

Umbelliferae: Fructus anethi, Radix Angelicae Sinensis, coriander, Crithmum maritimum, Radix Dauci Sativae, parsley

Araeceae

Aristolochiaceae

Compositae: yarrow, artemisia, Flos Chrysanthemi, Helichrysum

Betulaceae

Cruciferae

Burseraceae: Olibanum

Caryophyllaceae

Canellaceae

Caesalpiniaceae: face cream Pterostyrax (copaiba balsam)

Chenopodiaceae

Cistaceae: rock Flos Rosae Rugosae

Cyperaceae

Dipterocarpaceae

Ericaceae: Gaultheria (checkerberry)

Euphorbiaceae

Papilionaceae

Mang cattle Seedling section: Flos Pelargonii

Guttiferae

Hamamelidaceae

Hernandiaceae

Hypericaceae: Herba Hyperici perforati

Iridaceae

Juglandaceae

Labiatae: Herba thymi vulgaris, Adeps Bovis seu Bubali, horsemint, savoury, Herba Ocimi (Herba Ocimi Pilosi), Origanum majorana L., Herba Menthae, Herba Pogostemonis, lavandula angustifolia, Salvia japonica Thunb., Catnip, Herba Rosmarini Officinalis, Hyssopus offcinalis L., Balm, Herba Rosmarini Officinalis

Lauraceae: Luo Wenshaye, fragrant and sweet flower, rosewood, Cortex Cinnamomi, Litsea

Liliaceae: Bulbus Allii

Magnoliaceae: Magnolia

Malvaceae

Meliaceae

Cup axle flower section

Moraceae: Fructus Cannabis, Fols lupuli

Myruca ceas

Myristicaceae: Semen Myristicae

Myrtaceae: Eucalyptus genus, Camellia sinensis, Rhizoma Melaleuca Viridiflora, Melaleuca, Ba Hao genus, Flos Caryophylli, Fructus Rhodomyrti

Oleaceae

Piperaceae: Fructus Piperis

Pittosporum tobira section

Grass family: fragrant honeybee leaf, lemonweed, Vetiveria zizanoides

Polygonaceae

Ranunculaceae

Rosaceae: Flos Rosae Rugosae

Rubiaceae

Rutaceae: all Citrus plants

Salicaceae

Santalaceae: sandalwood

Saxifragaceae

Schisandraceae

Styracaceae: Benzoinum

Thymelaeceae: Lignum Aquilariae Resinatum

Tiliaceae

Valerianaceae: valeriana, Radix Et Rhizoma Nardostachyos

Verenaceae: lantana, Verbena

Violaceae

Zingiberaceae: Rhizoma Alpiniae Officinarum, Rhizoma Curcumae Longae, Elettaria cardamomum (L.) Maton, Rhizoma Zingiberis Recens

Zygophyllaceae

And their mixture.

6. such as the described compositions of preceding paragraph claim, it is characterized in that these one or more essential oil are selected from the essential oil of the following:

Torrid zone Herba Ocimi (Herba Ocimi Pilosi)

Cortex Melaleucae leucadendrae

Cortex Cinnamomi

The Fructus Citri Limoniae Catnip

Herba Cymbopogonis Citrari

Flos Caryophylli

Coriander

Australia eucalyptus globolus

Eucalyptus citriodora

Eucalyptus globulus Labill

Flos Pelargonii

Bourbon's Flos Pelargonii

The laser grass

Bay tree

Lemonweed

Green Citrus

The Spain Origanum majorana L.

Fragrant honeybee leaf

Rhizoma Melaleuca Viridiflora

The Spain Adeps Bovis seu Bubali

The Greece Adeps Bovis seu Bubali

The eucalyptol Herba Rosmarini Officinalis

Flos Rosae Rugosae

Winter savory

Camellia sinensis (alternate leaf Cortex Melaleucae leucadendrae)

The linalool Herba thymi vulgaris

Thymol Herba thymi vulgaris (Herba thymi vulgaris)

Thymol Herba thymi vulgaris (foreign Herba thymi vulgaris)

Herba Verbenae

Vetiveria zizanoides

And their mixture.

7. such as the described compositions of preceding paragraph claim, it is characterized in that described one or more essential oil are the essential oil that is selected from Fructus Citri Limoniae Catnip, Flos Caryophylli, fragrant honeybee leaf and Greece Adeps Bovis seu Bubali and their mixture.

8. according to any one of the preceding claims compositions, it is characterized in that described compositions comprise for the gross weight of said composition by weight from 0.001% to 10%, particularly by weight from 0.01% to 5% and even be more preferably by weight one or more essential oil of from 0.05% to 1%.

9. such as each described compositions of claim 1 to 8, it is characterized in that described one or more foaming agent (iii) are selected from anion, nonionic, both sexes or amphion and cationic surfactant, and their mixture.

10. such as the described compositions of preceding paragraph claim, it is characterized in that described one or more anion surfactants are selected from: alkyl sulfate, alkyl ether sulfate, the alkylamide ether sulfate, alkylaryl polyether sulfate, monoglyceride sulfate, alkylsulfonate, alkylamide sulfonate, alkylaryl sulfonates, alpha-alkene sulfonate, paraffin sulfonate, alkyl sulfo succinate, alkyl ether sulfo succinate, the alkylamide sulfosuccinate, alkyl sulfoethanoic acid. salt, acyl sarcosinates, acyl glutamate, the alkyl sulphosuccinamate, acyl isethinate and N-acyl taurine salt; The salt of the salt of the alkyl monoester of polysaccharide glycosides-polycarboxylic acids, acyl-lactate, alkyl D-galactoside alduronic acid, alkyl ether carboxylic acid's salt, the salt of alkyl aryl ether carboxylic acid, the salt of alkylamide ether carboxylic acid; And the corresponding salt-independent shape of all these chemical compounds; The alkyl of all these chemical compounds and carboxyl groups contain from 6 to 24 carbon atoms, and this aromatic yl group represents a phenyl group, and these anion surfactants are all optional by oxyethylation.

11. such as the described compositions of preceding paragraph claim, it is characterized in that one or more salt of described one or more anion surfactants are selected from these alkali metal salts, ammonium salt, amine salt, amino alkoxide and alkali salt.

12. each described compositions such as claim 9 to 11, it is characterized in that it comprises by weight from 0.1% to 50%, particularly by weight from 4% to 30%, and even be more preferably by weight one or more anion surfactants of from 8% to 20%.

13. compositions as claimed in claim 9 is characterized in that described one or more non-ionic surface active agents are selected from: by alcohol, the salmefamol, (C of polyethoxylated, poly-propoxylation and/or bound to polyglycerol _1-20) alkylphenol or fatty acid, they contain the aliphatic chain that comprises from 8 to 18 carbon atoms, and optionally from 2 to 50 ethylene oxides and/or propylene oxide group and/or from 2 to 10 glycerol groups; The copolymer of ethylene oxide and propylene oxide; the fatty acid ester of the alternatively oxyethylation of sorbitan; the fatty acid ester of sucrose; the fatty acid ester of polyoxy alkylidene, alternatively derivant, aldose disaccharide amide and the amine oxide of the APG of oxyalkylene, alkyl androstanediol ester, N-alkyl glucamine and N-acyl group methyl glucamine.

14. such as claim 9 or 13 described compositionss, it is characterized in that it comprise for the gross weight of said composition by weight from 0.01% to 20%, particularly by weight from 0.5% to 10% and even be more preferably by weight one or more non-ionic surface active agents of from 1% to 10%.

15. compositions as claimed in claim 9 is characterized in that described one or more both sexes or zwitterionic surfactant are selected from: (C ₈-C ₂₀) alkyl betaine, (C ₈-C ₂₀) alkyl sulfo betaines, (C ₈-C ₂₀Alkyl) acylamino-(C ₂-C ₈Alkyl) betanin, and (C ₈-C ₂₀Alkyl) acylamino-(C ₂-C ₈Alkyl) sulfobetaines.

16. compositions as claimed in claim 9 is characterized in that described one or more both sexes or amphion foaming surfactant are to be selected to have following counter structure (A1) and chemical compound (A2):

R _a-CONHCH ₂CH ₂-N ⁺(R _b)(R _c)(CH ₂COO ^-) （A1）

Wherein:

R _aRepresentative is derived from a kind of sour R that preferably is present in the cocos nucifera oil that has been hydrolyzed _aThe C of-COOH ₁₀-C ₃₀Alkyl or alkenyl group, heptyl group, nonyl group or undecyl group,

R _bRepresent the beta-hydroxyethyl group, and

R _cRepresent carboxymethyl group;

And R _a'-CONHCH ₂CH ₂-N (B) is (A2) (B')

Wherein:

B represents-CH ₂CH ₂OX ',

B' represents-(CH ₂) _z-Y ', z=1 or 2 wherein,

X' represents group-CH ₂-COOH, CH ₂-COOZ ' ,-CH ₂CH ₂-COOH,

-CH ₂CH ₂-COOZ ' or hydrogen atom,

Y' representative-COOH ,-COOZ ', group-CH ₂-CHOH-SO ₃H or

-CH ₂-CHOH-SO ₃Z’，

Z ' representative is derived from the ion of a kind of alkali or alkaline-earth metal such as sodium, potassium or magnesium; Ammonium ion; Or derived from a kind of organic amine and particularly derived from a kind of amino alcohol such as monoethanolamine, diethanolamine and triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA) or triisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, the ion of ammediol and three (methylol) aminomethane

R _{A '}Represent a kind of sour R in the Semen Lini oil that preferably is present in cocos nucifera oil or has been hydrolyzed _{A '}The C of COOH ₁₀-C ₃₀The alkyl or alkenyl group is in particular C ₁₇With and special-shaped formula or a undersaturated C ₁₇The alkyl group of group.

17. such as claim 9,15 or 16 described compositionss, it is characterized in that it comprise for the gross weight of said composition by weight from 0.01% to 30%, particularly by weight from 0.5% to 20% and even be more preferably by weight from 1% to 10% one or more both sexes or zwitterionic surfactant.

18. compositions according to any one of the preceding claims, the total content that it is characterized in that foaming agent is for the gross weight of said composition by weight at least 4%, preferably by weight from 4% to 50%, particularly by weight from 4% to 30% and even be more preferably by weight from 4% to 20%.

19. compositions according to any one of the preceding claims is characterized in that it comprises one or more thickening agents and/or one or more regulators, and/or except these foaming agent one or more other surfactants (iii).

20. a cosmetic treatment method is characterized in that it comprises each the described cosmetic composition in claim 1 to 19 is administered on scalp and the keratin fiber that particularly on human keratin fibres such as the hair, water washes alternatively afterwards.

21. such as each described cosmetic composition of claim 1 to 19 for washing keratin fiber, particularly human keratin fibres such as hair, and/or for eliminating or reduce the dandruff on scalp, and the purposes of the dandruff that is particularly caused by the Malassezia yeast.