CN102876432A - Corrosion-resistant anti-rust oil - Google Patents
Corrosion-resistant anti-rust oil Download PDFInfo
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- CN102876432A CN102876432A CN2012103528725A CN201210352872A CN102876432A CN 102876432 A CN102876432 A CN 102876432A CN 2012103528725 A CN2012103528725 A CN 2012103528725A CN 201210352872 A CN201210352872 A CN 201210352872A CN 102876432 A CN102876432 A CN 102876432A
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Abstract
The invention provides anti-rust oil capable of resisting corrosion and salt mist and belongs to the technical field of lubricating oil. The anti-rust oil comprises the following components in part by weight: 300 to 450 parts of mineral oil, 5 to 10 parts of polymethylacrylic acid tetradecyl ester, 15 to 20 parts of polyolefin, 2 to 3 parts of barium petroleum sulfonate, 2 to 3 parts of calcium dinonylnaphthalenesulfonate, 20 to 30 parts of oxidation petrolatum, 20 to 30 parts of methyl silicone oil, 1 to 2 parts of zinc alkyl thiophosphate, 1 to 5 parts of p-phenylenediamine, 1 to 5 parts of 2,6-di-tert-butyl-4(dimethylamine methyl)phenol, 2 to 4 parts of wool grease, 3 to 6 parts of dibutyl phthalate, 3 to 6 parts of octanoic acid dicyclohexylamine, 1 to 3 parts of epoxy polyaniline, 1 to 2 parts of calcium dodecyl benzene sulfonate, 2 to 4 parts of dibutyl succinate, 30 to 50 parts of hydrogenated castor oil, 15 to 20 parts of hydrogenated styrene-diene copolymer and 3 to 5 parts of magnesium borate. The anti-rust oil has high lubricating performance, wherein the durability in a salt mist test can reach 108 days and the durability in a warm test can reach 30 days.
Description
Technical field
The invention provides a kind of slushing oil, particularly a kind of slushing oil of corrosion-resistant, salt spray resistance belongs to technical field of lubricating oil.
Background technology
Slushing oil is take lubricating oil as base oil, adds therein rust-preventive agent and some and improves additive and make.Usually slushing oil can be divided into displacing type rust preventive oil, lubricating type rust preventing oil, solvent cutback rust preventing oil etc.
Wherein, lubricating type rust preventing oil is the main slushing oil kind of China, and its use range is very wide, and it is inner antirust to be mainly used in machinery, can be used for after rust-proof seal and the unpacking immediately lubricated the use.In addition, this product also goes for the antirust and lubricated usefulness of the operation friction working face of various machineries, and especially, the friction position on harbour machinery, ship machinery is widely used, such as wireline etc.
But the common deficiency of this class lubricating oil is, and is corrosion-resistant, endurance quality is bad, the phenomenons such as after having used for some time, the lubricating oil on surface hardening occurs easily, comes off, cracking.On harbour, boats and ships, its deteriorated process is accelerated in the easier impact that is subject to salt fog.If when being coated with rust preventive lubricating oil thicker, can affect its lubricant effect again, can't reach desired performance.
Summary of the invention
For above commentary to prior art, technical problem to be solved by this invention is: the problem that the erosion resistance of rust preventive lubricating oil, weather resistance are short, and the technical scheme of employing is:
A kind of corrosion resistant slushing oil, include following component by weight: 300～450 parts in mineral oil, 5～10 parts in polymethyl acrylic acid 14 fat, 15～20 parts of polyolefine, 2～3 parts of barium mahogany sulfonates, 2～3 parts of dinonylnaphthalene sulfonic acid calcium, 20～30 parts of oxidized petrolatums, 20～30 parts of methyl-silicone oils, 1～2 part of alkylthio zinc phosphate, 1～5 part of Ursol D, 1～5 part of 2,6-di-t-butyl-4 (dimethyl aminomethyl) phenol, 2～4 parts in lanolin, 3～6 parts of dibutyl phthalates, 3～6 parts of sad dicyclohexyl amines, 1～3 part of epoxy polyaniline, 1～2 part of calcium dodecylbenzene sulphonate, 2～4 parts of dibutyl succinates, 30～50 parts of hydrogenated castor oils, 15～20 parts of hydrogenated styrene-diene copolymer, 3～5 parts of magnesium borates.
Above-mentioned mineral oil is preferably from paraffin base mineral oil; More preferably, be No. 39 machine oil.
Above-mentioned polyolefine is preferably from PAO4.
Barium mahogany sulfonate and dinonylnaphthalene sulfonic acid calcium play a part antirust; Alkylthio zinc phosphate, Ursol D, 2,6-di-t-butyl-4 (dimethyl aminomethyl) phenol is antioxidant; The collocation of methyl-silicone oil and lanolin plays a part to improve lubricity; Hydrogenated styrene-diene copolymer plays a part to adjust the lubricating oil viscosity; That the epoxy polyaniline plays a part in lubricating oil is anticorrosion, anti-salt fog; Dibutyl succinate is dispersion agent, makes that component is uniformly dispersed in lubricated preparation and the storage process, does not produce caking and precipitates; Magnesium borate is extreme pressure agent.
The preparation method of above-mentioned slushing oil is:
S1: in reactor, add mineral oil, warming while stirring to 120～130 ℃;
S2: add while stirring polymethyl acrylic acid 14 fat, polyolefine, barium mahogany sulfonate, dinonylnaphthalene sulfonic acid calcium, oxidized petrolatum, methyl-silicone oil, alkylthio zinc phosphate, Ursol D, 2,6-di-t-butyl-4 (dimethyl aminomethyl) phenol, lanolin, dibutyl phthalate, sad dicyclohexyl amine, epoxy polyaniline, calcium dodecylbenzene sulphonate, dibutyl succinate stir 2～3h;
S3: cool to 40～50 ℃, add while stirring hydrogenated castor oil, hydrogenated styrene-diene copolymer, magnesium borate, continue to stir 2～3h, filter, and get final product.
Slushing oil provided by the invention has good lubricity, and antiseptic property also is better than like product.Weather resistance in the salt-fog test can reach 108 days, and the weather resistance in the warm test can reach 30 days.
Embodiment
Prepare each component by the weight ratio shown in the table 1.
The weight proportion of table 1 embodiment 1～embodiment 3
Above-mentioned mineral oil is No. 39 machine oil.
Above-mentioned polyolefine is PAO4.
The preparation method is as follows:
Embodiment 1
S1: in reactor, add mineral oil, warming while stirring to 120 ℃;
S2: add while stirring polymethyl acrylic acid 14 fat, polyolefine, barium mahogany sulfonate, dinonylnaphthalene sulfonic acid calcium, oxidized petrolatum, methyl-silicone oil, alkylthio zinc phosphate, Ursol D, 2,6-di-t-butyl-4 (dimethyl aminomethyl) phenol, lanolin, dibutyl phthalate, sad dicyclohexyl amine, epoxy polyaniline, calcium dodecylbenzene sulphonate, dibutyl succinate stir 2h;
S3: cool to 40 ℃, add while stirring hydrogenated castor oil, hydrogenated styrene-diene copolymer, magnesium borate, continue to stir 2h, filter, and get final product.
Embodiment 2
Be with the difference of embodiment 1: the temperature among the step S1 is 125 ℃; Churning time among the step S2 is 2.5h; Temperature among the step S3 is 45 ℃, and churning time is 2.5h.
Embodiment 3
Be with the difference of embodiment 1: the temperature among the step S1 is 130 ℃; Churning time among the step S2 is 3h; Temperature among the step S3 is 50 ℃, and churning time is 3h.
Performance test
The accurate method of above-described embodiment gained slushing oil sighting target is carried out performance test, and contrast with commercially available common slushing oil, test-results is as shown in table 2.
The performance test data of table 2 embodiment 1～embodiment 3 and reference examples
| Test method | Embodiment 1 | Embodiment 2 | Embodiment 3 | Reference examples | |
| Kinematic viscosity (40 ℃) mm 2/s | GB/T11137 | 21.3 | 21.2 | 20.9 | 23.1 |
| Salt-fog test (10# steel A level) h | SH/T0081 | 108 | 108 | 108 | 48 |
| Warm test (10# steel A level) sky | GB/T2361 | 30 | 30 | 30 | 20 |
| Low-temperature adhesion | SH/T0211 | Qualified | Qualified | Qualified | Qualified |
| Abradability | SH/T0215 | Without scar | Without scar | Without scar | Without scar |
Claims (4)
1. corrosion resistant slushing oil, include following component by weight: 300～450 parts in mineral oil, 5～10 parts in polymethyl acrylic acid 14 fat, 15～20 parts of polyolefine, 2～3 parts of barium mahogany sulfonates, 2～3 parts of dinonylnaphthalene sulfonic acid calcium, 20～30 parts of oxidized petrolatums, 20～30 parts of methyl-silicone oils, 1～2 part of alkylthio zinc phosphate, 1～5 part of Ursol D, 1～5 part of 2,6-di-t-butyl-4 (dimethyl aminomethyl) phenol, 2～4 parts in lanolin, 3～6 parts of dibutyl phthalates, 3～6 parts of sad dicyclohexyl amines, 1～3 part of epoxy polyaniline, 1～2 part of calcium dodecylbenzene sulphonate, 2～4 parts of dibutyl succinates, 30～50 parts of hydrogenated castor oils, 15～20 parts of hydrogenated styrene-diene copolymer, 3～5 parts of magnesium borates; The preparation method is:
S1: in reactor, add mineral oil, warming while stirring to 120～130 ℃;
S2: add while stirring polymethyl acrylic acid 14 fat, polyolefine, barium mahogany sulfonate, dinonylnaphthalene sulfonic acid calcium, oxidized petrolatum, methyl-silicone oil, alkylthio zinc phosphate, Ursol D, 2,6-di-t-butyl-4 (dimethyl aminomethyl) phenol, lanolin, dibutyl phthalate, sad dicyclohexyl amine, epoxy polyaniline, calcium dodecylbenzene sulphonate, dibutyl succinate stir 2～3h;
S3: cool to 40～50 ℃, add while stirring hydrogenated castor oil, hydrogenated styrene-diene copolymer, magnesium borate, continue to stir 2～3h, filter, and get final product.
2. corrosion resistant slushing oil according to claim 1, it is characterized in that: described mineral oil is paraffin base mineral oil.
3. corrosion resistant slushing oil according to claim 2, it is characterized in that: described paraffin base mineral oil is No. 39 machine oil.
4. corrosion resistant slushing oil according to claim 1, it is characterized in that: described polyolefine is PAO4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201210352872 CN102876432B (en) | 2012-09-20 | 2012-09-20 | Corrosion-resistant anti-rust oil |
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| CN 201210352872 CN102876432B (en) | 2012-09-20 | 2012-09-20 | Corrosion-resistant anti-rust oil |
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| CN102876432A true CN102876432A (en) | 2013-01-16 |
| CN102876432B CN102876432B (en) | 2013-09-25 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254765A (en) * | 2013-04-17 | 2013-08-21 | 马鞍山拓锐金属表面技术有限公司 | Anti-rust oil employing methyl phenyl silicone oil as base oil and preparation method thereof |
| CN103525527A (en) * | 2013-10-28 | 2014-01-22 | 李荣福 | Film-cleaning anti-rust oil for automobile connecting rod, preparation method therefor and applications |
| CN103774151A (en) * | 2014-02-20 | 2014-05-07 | 铜陵祥云消防科技有限责任公司 | Anti-rusting agent containing modified flint clay powder |
| CN103992845A (en) * | 2014-04-17 | 2014-08-20 | 天长市润达金属防锈助剂有限公司 | Corrosion resistant antirust oil |
| CN104531294A (en) * | 2014-12-09 | 2015-04-22 | 安徽荣达阀门有限公司 | Gas-phase slow-release antirust oil |
| CN106047000A (en) * | 2016-08-20 | 2016-10-26 | 哈尔滨锅炉厂有限责任公司 | Hydraulic pressure anti-rust agent for boiler auxiliary machine container products, and preparation method thereof |
| CN106118836A (en) * | 2016-06-29 | 2016-11-16 | 无锡伊佩克科技有限公司 | A kind of preparation method of environmentally-friendly water-based antirust solution |
| CN106350163A (en) * | 2016-08-17 | 2017-01-25 | 吴江华威特种油有限公司 | Metal anti-rust oil and preparation method thereof |
| CN110373258A (en) * | 2019-08-14 | 2019-10-25 | 中国人民解放军32181部队 | A kind of high salt fog area of high temperature and humidity equips with arms protection composition and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US3897350A (en) * | 1974-05-30 | 1975-07-29 | Mobil Oil Corp | Anti-rust compositions |
| CN102443483A (en) * | 2010-09-30 | 2012-05-09 | 刘世超 | Anti-rust oil |
| CN102459705A (en) * | 2009-06-29 | 2012-05-16 | 吉坤日矿日石能源株式会社 | Rust-preventive oil composition |
| CN102618357A (en) * | 2012-02-13 | 2012-08-01 | 中国人民解放军空军油料研究所 | Sealing and antirust oil composition |
-
2012
- 2012-09-20 CN CN 201210352872 patent/CN102876432B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3897350A (en) * | 1974-05-30 | 1975-07-29 | Mobil Oil Corp | Anti-rust compositions |
| CN102459705A (en) * | 2009-06-29 | 2012-05-16 | 吉坤日矿日石能源株式会社 | Rust-preventive oil composition |
| CN102443483A (en) * | 2010-09-30 | 2012-05-09 | 刘世超 | Anti-rust oil |
| CN102618357A (en) * | 2012-02-13 | 2012-08-01 | 中国人民解放军空军油料研究所 | Sealing and antirust oil composition |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254765A (en) * | 2013-04-17 | 2013-08-21 | 马鞍山拓锐金属表面技术有限公司 | Anti-rust oil employing methyl phenyl silicone oil as base oil and preparation method thereof |
| CN103525527A (en) * | 2013-10-28 | 2014-01-22 | 李荣福 | Film-cleaning anti-rust oil for automobile connecting rod, preparation method therefor and applications |
| CN103525527B (en) * | 2013-10-28 | 2014-11-12 | 广州粤晖金属机械防护技术有限公司 | Film-cleaning anti-rust oil for automobile connecting rod, preparation method therefor and applications |
| CN103774151A (en) * | 2014-02-20 | 2014-05-07 | 铜陵祥云消防科技有限责任公司 | Anti-rusting agent containing modified flint clay powder |
| CN103992845A (en) * | 2014-04-17 | 2014-08-20 | 天长市润达金属防锈助剂有限公司 | Corrosion resistant antirust oil |
| CN104531294A (en) * | 2014-12-09 | 2015-04-22 | 安徽荣达阀门有限公司 | Gas-phase slow-release antirust oil |
| CN106118836A (en) * | 2016-06-29 | 2016-11-16 | 无锡伊佩克科技有限公司 | A kind of preparation method of environmentally-friendly water-based antirust solution |
| CN106350163A (en) * | 2016-08-17 | 2017-01-25 | 吴江华威特种油有限公司 | Metal anti-rust oil and preparation method thereof |
| CN106047000A (en) * | 2016-08-20 | 2016-10-26 | 哈尔滨锅炉厂有限责任公司 | Hydraulic pressure anti-rust agent for boiler auxiliary machine container products, and preparation method thereof |
| CN110373258A (en) * | 2019-08-14 | 2019-10-25 | 中国人民解放军32181部队 | A kind of high salt fog area of high temperature and humidity equips with arms protection composition and preparation method thereof |
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| CN102876432B (en) | 2013-09-25 |
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Effective date of registration: 20151030 Address after: Song Ling Zhen Wujiang District of Suzhou City, Jiangsu province 215200 Suzhou River Road No. 18 Patentee after: Suzhou Xielv Network Technology Co., Ltd. Address before: Wujiang City, Suzhou City, Jiangsu province 215212 Lili Town Industrial Park of arch bridge Patentee before: Wujiang Tianyuan Plastic Co., Ltd. |
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Address after: 215200 Shengze, Jiangsu, China Town, Shengze, West No. two ring road, No. 1188, China Textile Science and Technology Park, Wujiang, building 10 Patentee after: Suzhou Xielv Network Technology Co., Ltd. Address before: Song Ling Zhen Wujiang District of Suzhou City, Jiangsu province 215200 Suzhou River Road No. 18 Patentee before: Suzhou Xielv Network Technology Co., Ltd. |
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Granted publication date: 20130925 Termination date: 20170920 |