CN102860311A - Abamectin anti-photolysis anti-oxidation suspending agent - Google Patents

Abamectin anti-photolysis anti-oxidation suspending agent Download PDF

Info

Publication number
CN102860311A
CN102860311A CN2012103695272A CN201210369527A CN102860311A CN 102860311 A CN102860311 A CN 102860311A CN 2012103695272 A CN2012103695272 A CN 2012103695272A CN 201210369527 A CN201210369527 A CN 201210369527A CN 102860311 A CN102860311 A CN 102860311A
Authority
CN
China
Prior art keywords
percent
abamectin
suspending agent
avermectin
auxiliary agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012103695272A
Other languages
Chinese (zh)
Inventor
谢毅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUNAN DACHENG PHARMACEUTICAL AND CHEMICAL CO Ltd
Original Assignee
HUNAN DACHENG PHARMACEUTICAL AND CHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUNAN DACHENG PHARMACEUTICAL AND CHEMICAL CO Ltd filed Critical HUNAN DACHENG PHARMACEUTICAL AND CHEMICAL CO Ltd
Priority to CN2012103695272A priority Critical patent/CN102860311A/en
Publication of CN102860311A publication Critical patent/CN102860311A/en
Pending legal-status Critical Current

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a pesticide, and in particular relates to abamectin. The abamectin anti-photolysis anti-oxidation suspending agent comprises the following components in percentage by weight: 5 to 30 percent of abamectin, 0.1 to 0.2 percent of BHT (butylated hydroxytoluene), 0.1 to 0.3 percent of bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, 0.1 to 0.2 percent of 2-(2'-hydroxyl-3'-tert-butyl-5'-methyl phenyl)-5-chlorobenzotriazole, 12 to 15 percent of an auxiliary agent, and water which is supplemented to 100 percent, wherein the auxiliary agent is prepared from the following component sin percentage by weight: 0.7 to 2 percent of NNO (naphthyl sulfonate formaldehyde condensate), 4 to 5 percent of Ning emulsion 34#, 1 to 3 percent of Nong emulsion 500#, 1 to 2 percent of aluminium-magnesium silicate, 0.1 percent of sodium benzoate, 5 percent of glycol, and 0.2 percent of defoaming agent. According to the suspending agent, the defect that abamectin is oxidized and photolyzed in the use process can be effectively overcome. The suspending agent has the remarkable advantages of high efficiency, low toxicity, broad spectrum, low cost, safety, environmental friendliness and the like.

Description

Avermectin is prevented the anti-oxidant suspending agent of photodissociation
Technical field
The present invention relates to a kind of agricultural chemicals, particularly Avermectin.
Background technology
Avermectin have tag, stomach toxicity, low toxicity, wide spectrum, penetration be strong; It is a kind of macrolide disaccharide compounds, is the natural products that separates from edaphon, insects and mites is had tag and stomach poison function and faint fumigation action is arranged, and without systemic action, ovicidal not; It has very strong osmosis to blade, can kill subepidermal insect.What its mechanism of action was different from general insecticide is that it disturbs neurophysiology movable, stimulate and discharge the r-aminobutyric acid, and the r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, if the larva that the mite class becomes mite and insect with paralysis symptom namely appears after medicament contacts, inertia does not take food, and is dead after 2-4 days.Because not causing that insect dewaters rapidly, so its lethal effect is slower.Though predatism and parasite there are direct killing effect, because plant surface is residual few, therefore little to the damage of beneficial insect.
Avermectin is exposed in the air oxidized easily, is decomposed easily at strong UV-irradiation.
Summary of the invention
Drug effect and the product safety environmental-protecting performance of the present invention in order to improve Avermectin made suspending agent to Avermectin, and in the Avermectin suspending agent, add antioxidant, light stabilizer, ultraviolet absorber.
Antioxidant is the BHT(Chinese name: antioxidant 264, chemical name: 2,6-di-tert-butyl-4-methy phenol or dibutyl hydroxy toluene), light stabilizer is two (2,2,6,6-tetramethyl-4-piperidyl) sebacate, ultraviolet absorber are 2-(2'-hydroxyl-3'-tertiary butyl-5'-aminomethyl phenyl)-5-chlorobenzotriazole.Auxiliary agent is dispersant NNO(di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate), peaceful breast 34 #(polystyrene-based phenol formaldehyde resin APEO), farming breast 500 #(calcium dodecyl benzene sulfonate), aluminium-magnesium silicate, Sodium Benzoate, ethylene glycol, defoamer.
The anti-oxidant suspending agent of anti-photodissociation of Avermectin of the present invention comprises Avermectin, antioxidant, light stabilizer, ultraviolet absorber, auxiliary agent and water, and its weight portion proportioning is:
Avermectin: 5-30%,
BHT:0.1—0.2%、
Two (2,2,6,6-tetramethyl-4-piperidyl) sebacate: 0.1-0.3%,
2-(2'-hydroxyl-3'-tertiary butyl-5'-aminomethyl phenyl)-5-chlorobenzotriazole: 0.1-0.2%,
Auxiliary agent: 12-15%,
Water is mended to 100%.
Described auxiliary agent is formed by the total weight parts proportioning by following ingredients:
NNO:0.7—2%、
Peaceful breast 34 #: 4-5%,
Farming breast 500 #: 1-3%,
Aluminium-magnesium silicate: 1-2%,
Sodium Benzoate: 0.1%,
Ethylene glycol: 5%,
Defoamer: 0.2%.
Beneficial effect of the present invention: can effectively overcome the drawback of in use oxidized photodissociation of Avermectin, have the advantages such as significant efficient, low toxicity, wide spectrum, cost are low, safety and environmental protection.
Embodiment
The peaceful breast 34 of formulation examples 1:5% Avermectin+0.1%BHT+0.2% light stabilizer+0.1% ultraviolet absorber+1%NNO+4% #+ 1% farming breast 500 #+ 1% aluminium-magnesium silicate+0.1% Sodium Benzoate+5% ethylene glycol+0.2% defoamer, water is mended to 100%.
The peaceful breast 34 of formulation examples 2:10% Avermectin+0.2%BHT+0.2% light stabilizer+0.1% ultraviolet absorber+2%NNO+4% #+ 2% farming breast 500 #+ 2% aluminium-magnesium silicate+0.1% Sodium Benzoate+5% ethylene glycol+0.2% defoamer, water is mended to 100%.
The peaceful breast 34 of formulation examples 3:20% Avermectin+0.2%BHT+0.3% light stabilizer+0.2% ultraviolet absorber+2%NNO+5% #+ 2% farming breast 500 #+ 2% aluminium-magnesium silicate+0.1% Sodium Benzoate+5% ethylene glycol+0.2% defoamer, water is mended to 100%.
The peaceful breast 34 of formulation examples 4:30% Avermectin+0.2%BHT+0.3% light stabilizer+0.2% ultraviolet absorber+2%NNO+5% #+ 3% farming breast 500 #+ 2% aluminium-magnesium silicate+0.1% Sodium Benzoate+5% ethylene glycol+0.2% defoamer, water is mended to 100%.
By field medicine effect test and applying, the present invention reduces the Avermectin usage amount can reach 30%, prevent and treat efficient up to more than 97% for crops such as control paddy rice, wheat, cotton, citrus, and be difficult for developing immunity to drugs, show its outstanding advantage and practical value.

Claims (1)

1. the anti-oxidant suspending agent of anti-photodissociation of Avermectin comprises Avermectin, antioxidant, light stabilizer, ultraviolet absorber, auxiliary agent and water, and its weight portion proportioning is:
Avermectin: 5-30%,
BHT:0.1—0.2%、
Two (2,2,6,6-tetramethyl-4-piperidyl) sebacate: 0.1-0.3%,
2-(2'-hydroxyl-3'-tertiary butyl-5'-aminomethyl phenyl)-5-chlorobenzotriazole: 0.1-0.2%,
Auxiliary agent: 12-15%,
Water is mended to 100%;
Described auxiliary agent is formed by the total weight parts proportioning by following ingredients:
NNO:0.7—2%、
Peaceful breast 34 #: 4-5%,
Farming breast 500 #: 1-3%,
Aluminium-magnesium silicate: 1-2%,
Sodium Benzoate: 0.1%,
Ethylene glycol: 5%,
Defoamer: 0.2%.
CN2012103695272A 2012-09-29 2012-09-29 Abamectin anti-photolysis anti-oxidation suspending agent Pending CN102860311A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012103695272A CN102860311A (en) 2012-09-29 2012-09-29 Abamectin anti-photolysis anti-oxidation suspending agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012103695272A CN102860311A (en) 2012-09-29 2012-09-29 Abamectin anti-photolysis anti-oxidation suspending agent

Publications (1)

Publication Number Publication Date
CN102860311A true CN102860311A (en) 2013-01-09

Family

ID=47439666

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012103695272A Pending CN102860311A (en) 2012-09-29 2012-09-29 Abamectin anti-photolysis anti-oxidation suspending agent

Country Status (1)

Country Link
CN (1) CN102860311A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104126578A (en) * 2014-07-21 2014-11-05 威尔(福建)生物有限公司 Avermectin auxiliary agent and preparation method thereof
CN105557687A (en) * 2016-01-11 2016-05-11 河南省济源白云实业有限公司 Avermectin water suspension and preparation method thereof
CN106135236A (en) * 2016-06-28 2016-11-23 惠州市银农科技股份有限公司 A kind of avilamycin and Envidor compound aqueous suspension agent and preparation method thereof
CN106305710A (en) * 2016-08-23 2017-01-11 安徽久易农业股份有限公司 Herbicide suspension
CN109197863A (en) * 2017-07-04 2019-01-15 东北林业大学 A kind of anti-light solution avermectin composite fibre pulvis production method
CN109792996A (en) * 2019-01-23 2019-05-24 中国农业科学院农业环境与可持续发展研究所 A kind of Avermectins nano powder and its preparation and application method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1072695A (en) * 1991-10-04 1993-06-02 伊斯曼柯达公司 Additive system of dispersible solid form and preparation method thereof in water-bearing media
CN1420907A (en) * 2000-02-01 2003-05-28 西巴特殊化学品控股有限公司 Candle wax stabilized by combination of UV absorber plus selected hindered amine
CN101692808A (en) * 2009-09-30 2010-04-14 深圳诺普信农化股份有限公司 Emamectin benzoate solid lipid nanoparticle and preparation method and application thereof in pesticide formulation
CN101700008A (en) * 2009-11-11 2010-05-05 深圳诺普信农化股份有限公司 Solid lipid nano-avermectin and preparation method and application thereof
CN102355817A (en) * 2009-03-18 2012-02-15 辛根塔有限公司 Formulation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1072695A (en) * 1991-10-04 1993-06-02 伊斯曼柯达公司 Additive system of dispersible solid form and preparation method thereof in water-bearing media
CN1420907A (en) * 2000-02-01 2003-05-28 西巴特殊化学品控股有限公司 Candle wax stabilized by combination of UV absorber plus selected hindered amine
CN102355817A (en) * 2009-03-18 2012-02-15 辛根塔有限公司 Formulation
CN101692808A (en) * 2009-09-30 2010-04-14 深圳诺普信农化股份有限公司 Emamectin benzoate solid lipid nanoparticle and preparation method and application thereof in pesticide formulation
CN101700008A (en) * 2009-11-11 2010-05-05 深圳诺普信农化股份有限公司 Solid lipid nano-avermectin and preparation method and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吴传万等: "《阿维菌素光分解及其光稳定剂的筛选》", 《农药》, vol. 45, no. 12, 31 December 2006 (2006-12-31), pages 828 - 833 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104126578A (en) * 2014-07-21 2014-11-05 威尔(福建)生物有限公司 Avermectin auxiliary agent and preparation method thereof
CN105557687A (en) * 2016-01-11 2016-05-11 河南省济源白云实业有限公司 Avermectin water suspension and preparation method thereof
CN106135236A (en) * 2016-06-28 2016-11-23 惠州市银农科技股份有限公司 A kind of avilamycin and Envidor compound aqueous suspension agent and preparation method thereof
CN106305710A (en) * 2016-08-23 2017-01-11 安徽久易农业股份有限公司 Herbicide suspension
CN109197863A (en) * 2017-07-04 2019-01-15 东北林业大学 A kind of anti-light solution avermectin composite fibre pulvis production method
CN109792996A (en) * 2019-01-23 2019-05-24 中国农业科学院农业环境与可持续发展研究所 A kind of Avermectins nano powder and its preparation and application method
CN109792996B (en) * 2019-01-23 2021-04-09 中国农业科学院农业环境与可持续发展研究所 Avermectin nano-powder and preparation and use method thereof

Similar Documents

Publication Publication Date Title
CN102860311A (en) Abamectin anti-photolysis anti-oxidation suspending agent
CN107996622B (en) Mosquito repellent containing plant essential oil
Farombi Assessment of flavonoid content, free radical scavenging and hepatoprotective activities of Ocimum gratissimum and Spondias mombin in rats treated with dimethylnitrosamine
EP1711192B1 (en) Antiviral preparations obtained from a natural cinnamon extract
CN107494533B (en) Application of bisabolane sesquiterpene compound in preventing and treating wigglers
CN104488918A (en) Phytogenic synergistic compound insecticide containing tea polyphenol and dioscin
CN103300020B (en) A kind of pesticide composition
CN102084868B (en) Azadirachtin and cyfluthrin composite for preventive treatment on potato beetles
CN103355326A (en) High-efficiency pesticide composition
CN110537555A (en) Preparation of mosquito repellent liquid with bactericidal effect based on natural plant extract
CN106879611A (en) A kind of Pesticidal combination containing AVM and second azoles mite nitrile
CN104522000B (en) A kind of miticide composition containing cyflumetofen and ivermectin
CN110250222A (en) Plant insecticide composition
CN102845440A (en) Methylamino abamectin benzoate photolysis-proof antioxidant suspension agent
CN102308827B (en) Pesticide composition containing flufenoxuron and fenproximate
CN108812707A (en) One kind killing thrips plant essential oil composition, preparation and its application
CN101366387B (en) Agricultural chemical composition
CN104206405A (en) Pesticide and method for preventing and controlling evergestis extimalis scopoli
CN100473280C (en) Dipterex acetamiprid EC compound pesticide
CN105994275A (en) Pesticide composition containing chromafenozide and biogenic sources
CN103125501A (en) Abamectin-spinosad emulsion in water and preparing method thereof
CN102037991B (en) Composite pesticide containing abamectin and cidial
CN105052927A (en) Tea geometrid male adult attractant based on tea plant volatile matter
CN104472519A (en) Anti-mite composition
Mya et al. Larvicidal effect of Artemisia vulgaris leaves, flower and leaves essential oil extracts against Aedes aegypti larvae

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20130109