CN102844275B - 用于处理包含氨和硫化氢的精炼厂废水和包含硫化氢的精炼厂排出酸性气体的整合方法 - Google Patents
用于处理包含氨和硫化氢的精炼厂废水和包含硫化氢的精炼厂排出酸性气体的整合方法 Download PDFInfo
- Publication number
- CN102844275B CN102844275B CN201180006861.5A CN201180006861A CN102844275B CN 102844275 B CN102844275 B CN 102844275B CN 201180006861 A CN201180006861 A CN 201180006861A CN 102844275 B CN102844275 B CN 102844275B
- Authority
- CN
- China
- Prior art keywords
- ammonia
- logistics
- stream
- hydrogen sulfide
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 136
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims abstract description 72
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000002351 wastewater Substances 0.000 title claims abstract description 20
- 239000007789 gas Substances 0.000 title abstract description 22
- 239000002253 acid Substances 0.000 title abstract description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 230000003647 oxidation Effects 0.000 claims abstract description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 17
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 11
- 239000007800 oxidant agent Substances 0.000 claims abstract description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 51
- 238000012545 processing Methods 0.000 claims description 6
- 238000007600 charging Methods 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 230000007812 deficiency Effects 0.000 abstract description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 25
- 238000011084 recovery Methods 0.000 description 14
- 229910052717 sulfur Inorganic materials 0.000 description 13
- 239000011593 sulfur Substances 0.000 description 13
- 239000005864 Sulphur Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000010531 catalytic reduction reaction Methods 0.000 description 4
- 230000010354 integration Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 238000005115 demineralization Methods 0.000 description 2
- 230000002328 demineralizing effect Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002352 surface water Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000610375 Sparisoma viride Species 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/101—Sulfur compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
- C02F2103/365—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/06—Pressure conditions
- C02F2301/066—Overpressure, high pressure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Physical Water Treatments (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI2010A000080 | 2010-01-22 | ||
ITMI2010A000080A IT1397745B1 (it) | 2010-01-22 | 2010-01-22 | Processo integrato di purificazione di acque reflue di raffineria, contenenti prevalentemente ammoniaca ed acido solfidrico, e di gas acidi contenenti prevalentemente acido solfidrico. |
PCT/IT2011/000016 WO2011089635A1 (fr) | 2010-01-22 | 2011-01-19 | Procédé intégré de traitement des eaux usées de raffinerie contenant principalement de l'ammoniac et du sulfure d'hydrogène, et un gaz d'acide contenant principalement du sulfure d'hydrogène |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102844275A CN102844275A (zh) | 2012-12-26 |
CN102844275B true CN102844275B (zh) | 2014-11-26 |
Family
ID=42667920
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201180006861.5A Expired - Fee Related CN102844275B (zh) | 2010-01-22 | 2011-01-19 | 用于处理包含氨和硫化氢的精炼厂废水和包含硫化氢的精炼厂排出酸性气体的整合方法 |
Country Status (4)
Country | Link |
---|---|
CN (1) | CN102844275B (fr) |
EA (1) | EA022555B1 (fr) |
IT (1) | IT1397745B1 (fr) |
WO (1) | WO2011089635A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20130268A1 (it) | 2013-02-25 | 2014-08-26 | Saipem Spa | Metodo e sistema per l'abbattimento di ammoniaca da un flusso gassoso di scarico di un impianto urea |
AU2015227041B2 (en) | 2014-03-05 | 2018-02-15 | Bechtel Energy Technologies & Solutions, Inc. | Systems and methods for enhanced separation of hydrogen sulfide and ammonia in a hydrogen sulfide stripper |
RU2620669C2 (ru) * | 2016-05-30 | 2017-05-29 | Константин Владимирович Ладыгин | Способ и установка для сжигания сточных вод |
CN108794359B (zh) * | 2017-04-28 | 2021-04-06 | 中国石油化工股份有限公司 | 一种由硫化氢生产二甲基亚砜的方法 |
CN108794362B (zh) * | 2017-04-28 | 2020-06-16 | 中国石油化工股份有限公司 | 一种由硫化氢生产二甲基亚砜的方法 |
CN111072535A (zh) * | 2018-10-18 | 2020-04-28 | 中国石油化工股份有限公司 | 一种利用炼厂酸性气制备二甲基硫醚的方法 |
CN111252839A (zh) * | 2020-01-18 | 2020-06-09 | 河北荣特化工股份有限公司 | 加氢型废水、废气处理新工艺 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2263293A1 (en) * | 1974-03-05 | 1975-10-03 | Koppers Gmbh Heinrich | Ammonia removal from ammoniacal vapours - by partial combustion followed by total combustion to minimise nitrogen oxides |
EP0492329A1 (fr) * | 1990-12-22 | 1992-07-01 | Hoechst Aktiengesellschaft | Procédé pour le traitement de solutions aqueuses contenant de l'acide sulfhydrique, de l'acide cyanhydrique et de l'ammoniac |
CN1108294A (zh) * | 1993-12-30 | 1995-09-13 | 国际壳牌研究有限公司 | 从合成气中除去污染物 |
JP2006169079A (ja) * | 2004-12-20 | 2006-06-29 | Oita Univ | 脱硫処理廃水からのアンモニアと硫化水素の分離回収方法。 |
EP1916024A1 (fr) * | 2006-10-19 | 2008-04-30 | Total France | Unité et procédé de traitement d'eaux issues de procédés de raffinage |
-
2010
- 2010-01-22 IT ITMI2010A000080A patent/IT1397745B1/it active
-
2011
- 2011-01-19 CN CN201180006861.5A patent/CN102844275B/zh not_active Expired - Fee Related
- 2011-01-19 EA EA201290680A patent/EA022555B1/ru unknown
- 2011-01-19 WO PCT/IT2011/000016 patent/WO2011089635A1/fr active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2263293A1 (en) * | 1974-03-05 | 1975-10-03 | Koppers Gmbh Heinrich | Ammonia removal from ammoniacal vapours - by partial combustion followed by total combustion to minimise nitrogen oxides |
EP0492329A1 (fr) * | 1990-12-22 | 1992-07-01 | Hoechst Aktiengesellschaft | Procédé pour le traitement de solutions aqueuses contenant de l'acide sulfhydrique, de l'acide cyanhydrique et de l'ammoniac |
CN1108294A (zh) * | 1993-12-30 | 1995-09-13 | 国际壳牌研究有限公司 | 从合成气中除去污染物 |
JP2006169079A (ja) * | 2004-12-20 | 2006-06-29 | Oita Univ | 脱硫処理廃水からのアンモニアと硫化水素の分離回収方法。 |
EP1916024A1 (fr) * | 2006-10-19 | 2008-04-30 | Total France | Unité et procédé de traitement d'eaux issues de procédés de raffinage |
Also Published As
Publication number | Publication date |
---|---|
WO2011089635A1 (fr) | 2011-07-28 |
EA201290680A1 (ru) | 2013-01-30 |
EA022555B1 (ru) | 2016-01-29 |
IT1397745B1 (it) | 2013-01-24 |
CN102844275A (zh) | 2012-12-26 |
ITMI20100080A1 (it) | 2011-07-23 |
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Legal Events
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---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141126 |