CN102838643A - Lauryl glucoside-iodine complex - Google Patents
Lauryl glucoside-iodine complex Download PDFInfo
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- CN102838643A CN102838643A CN2011101668717A CN201110166871A CN102838643A CN 102838643 A CN102838643 A CN 102838643A CN 2011101668717 A CN2011101668717 A CN 2011101668717A CN 201110166871 A CN201110166871 A CN 201110166871A CN 102838643 A CN102838643 A CN 102838643A
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- iodine
- lauryl glucoside
- iodine complex
- complex
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Abstract
The invention provides a chemical intermediate for producing iodine-containing disinfectants, that is, a lauryl glucoside-iodine complex. The lauryl glucoside-iodine complex comprises 92-96 parts of lauryl glucoside (effective matter 50%), 3-5 parts of iodine (I), and 1-3 parts of citric acid. The lauryl glucoside-iodine complex is synthesized by the following steps: adding 92-96kg of lauryl glucoside (effective matter 50%) in an enclosed stainless steel reaction vessel with temperature control, heating up to 48-52 DEG C, then adding 1-3 kg of citric acid, heating up to 93-97 DEG C and then adding 3-5 kg of iodine, reacting for 3h, conducting material cycle homogeneous reaction for 1 h, cooling to 28-32 DEG C and then discharging. The lauryl glucoside-iodine complex is a dark purple sticky liquid, has the pH value of 5-6 and the iodine content of 3-5%. According to the invention, by compounding the lauryl glucoside-iodine complex with other chemicals, a plurality of professional sterilization cleansers can be produced; the lauryl glucoside-iodine complex with an effective concentration is effective against escherichia coli, staphylococcus aureus, pseudomonas aeruginosa, bacillus subtilis, hepatitis A virus, hepatitis B virus and other microbes. A finished product of the lauryl glucoside-iodine complex must be placed in a light-resistant nonmetal container.
Description
[technical field]
The present invention relates to the intermediate feed that a kind of manufacturing contains iodine disinfectant, relate to the method for manufacture of lauryl glucoside iodine complex.
[background technology]
Sterilizing agent, the notion that country sterilization standard provides are the chemokineses that can kill infective or harmful microorganism in the environment.Sterilizing agent is mainly used in medical field at present, and containing the present China of iodine disinfectant is with the more appearance of " Iodophor " commodity.Sterilizing agent not only is applied in medical field, and uses in the middle of daily life.
" Iodophor " be a kind of be the indefinite form chelated iodine of carrier and solubilizing agent with the tensio-active agent.About the chemical structure between iodine and the tensio-active agent, much human is in research.Generally believe that iodine element accumulates among the surfactant micelle, this iodine is surrounded by micella, also is a kind of complexing phenomenon.When micella was diluted by water solvent, micellar concentration reduced, the bonding force between iodine and surfactant micelle or say complexing power and weaken, and dissociated out, this moment, iodine produced the intensive oxygenizement to the mikrobe surface, promptly destroyed proteinic mercapto hydrogen and reached the sterilization purpose." Iodophor " overcome that tincture of iodine working concentration is high, irritating property strong, to the skin effect of burning; Unstable volatile, easy xanthochromia; With after need with deficiencies such as ethanol decolorization, use range are narrow; Kept again simultaneously that fungicidal spectrum is wide, sterilization is rapid, the advantage that under different concns, can both kill to bacterial propagule, bacterial spore, fungi, virus.
[summary of the invention]
The present invention is with the carrier of nonionogenic tenside lauryl glucoside as lauryl glucoside iodine complex.
Structural formula of the present invention:
Carrier lauryl glucoside of the present invention belongs to nonionogenic tenside.The lauryl glucoside has good solvability, wettability, compatibility.The lauryl glucoside is widely used in various fields such as washing Industry, cosmetic industry, food-processing industry, pharmacy industry.The lauryl glucoside is nontoxic, to human body skin and human body mucous membrane nonirritant.
Characteristics of the present invention are to use nonionogenic tenside lauryl glucoside as carrier, make lauryl glucoside iodine complex, are that the Iodophor of 0.3-1% available iodine provides good midbody for making working concentration.
This patent is by lauryl glucoside (working substance 50%) 92-96% and iodine (I) 3-5%, add pH regulator agent Hydrocerol A 1-3% synthesize the preparation and get.
Warp of the present invention and other chemical be composite makes multiple professional disinfection cleaning agent, under effective concentration, very effective to sterilization and the sterilization of multiple mikrobes such as intestinal bacteria, golden grape coccobacillus, Pseudomonas aeruginosa, Bacillus subtilus, first, hepatitis B virus.
It is stainless steel (or enamel or glass) material that the present invention prepares equipment used, and reaction kettle is stopping property and needs recycle unit and heating installation.Temperature of reaction is controlled between 50-100 ℃, and additive is a pH regulator agent Hydrocerol A, and the material system pH in the building-up process is slightly acidic.
The present invention is that a kind of outward appearance body shape is the grape thick liquid, and the pH value is 5-6, and iodine content is at 3-5%.
The present invention makes that raw material is easy to get, pollution-free in the production process, do not have waste, meet the requirement of environmental protective chemical industry production technique.
Finished product of the present invention need be placed in lucifuge, the nonmetallic container.
This patent is retrieved through document, does not find related data in China.
[embodiment]
The present invention forms and comprises: lauryl glucoside (working substance 50%) 92-96 part and iodine (I) 3-5 part, regulator Hydrocerol A 1-3 part.
The present invention adds lauryl glucoside (working substance 50%) 92-96 kilogram in having temperature controlled airtight stainless steel cauldron, be warming up to 50 ± 2 ℃ and add Hydrocerol A 1-3 kilogram; Heat up 95 ± 2 ℃ and add iodine 3-5 kilogram.
After 2 hours, reaction mass need carry out system circulation 1 hour at the reaction kettle stirring reaction in the present invention, and temperature is reduced to 30 ± 2 ℃ of dischargings after detection is qualified.Material need be placed in lucifuge, the nonmetallic container.
Specific embodiment one:
Throw in raw material by following part by weight: 93 parts of lauryl glucosides (working substance 50%), 5 parts of iodine (I), 2 parts of Hydrocerol As.
Synthesis route: in having temperature controlled airtight stainless steel cauldron, add lauryl glucoside (working substance 50%) 93 kilograms, be warming up to 50 ± 2 ℃ and add 2 kilograms of Hydrocerol As; Heat up 95 ± 2 ℃ and add 5 kilograms of iodine; In 2 hours reaction kettle reaction times, carried out the material circulating reaction then 1 hour.Temperature is reduced to 30 ± 2 ℃ of dischargings after detection is qualified.Material need be placed in lucifuge, the nonmetallic container.
Specific embodiment two:
Throw in raw material by following part by weight: 94 parts of lauryl glucosides (working substance 50%), 4 parts of iodine (I), 2 parts of Hydrocerol As.
Synthesis route: in having temperature controlled airtight stainless steel cauldron, add lauryl glucoside (working substance 50%) 94 kilograms, be warming up to 50 ± 2 ℃ and add 2 kilograms of Hydrocerol As; Heat up 95 ± 2 ℃ and add 4 kilograms of iodine; In 2 hours reaction kettle reaction times, then carried out the material circulating reaction 1 hour.Temperature is reduced to 30 ± 2 ℃ of dischargings after detection is qualified.Material need be placed in lucifuge, the nonmetallic container.
Specific embodiment three:
Throw in raw material by following part by weight: 96 parts of lauryl glucosides (working substance 50%), 3 parts of iodine (I), 1 part of Hydrocerol A.
Synthesis route: in having temperature controlled airtight stainless steel cauldron, add lauryl glucoside (working substance 50%) 96 kilograms, be warming up to 50 ± 2 ℃ and add 1 kilogram of Hydrocerol A; Heat up 95 ± 2 ℃ and add 3 kilograms of iodine; In 2 hours reaction kettle reaction times, then carried out the material circulating reaction 1 hour.Temperature is reduced to 30 ± 2 ℃ of dischargings after detection is qualified.Material need be placed in lucifuge, the nonmetallic container.
Claims (8)
1. the present invention provides the chemical intermediate that a kind of making contains iodine disinfectant: lauryl glucoside iodine complex is characterized in that this chemical main body is by the synthetic gained of lauryl glucoside (working substance 50%), iodine and Hydrocerol A.
2. according to claim 1, the structural formula of lauryl glucoside iodine complex is:
3. according to claim 1; Warp of the present invention and other chemical be composite makes multiple professional disinfection cleaning agent; Under effective concentration, very effective to sterilization and the sterilization of multiple mikrobes such as intestinal bacteria, golden grape coccobacillus, Pseudomonas aeruginosa, Bacillus subtilus, first, hepatitis B virus.
4. according to claim 1, the synthetic of lauryl glucoside iodine complex is in particular device, temperature, additive and reasonable synthetic route, to accomplish.Equipment used is that stainless steel (or enamel or glass) material, reaction kettle are air-tight state; Reaction kettle needs material recycle unit and heating installation.
5. according to claim 1, lauryl glucoside (working substance 50%) 92-96% and iodine (I) 3-5% add pH regulator agent Hydrocerol A 1-3% and synthesize preparation.Temperature of reaction is controlled between 50-100 ℃, and the material synthetic system pH value in the building-up process is slightly acidic.
6. according to claim 1, in having temperature controlled chuck stainless steel cauldron, add lauryl glucoside (working substance 50%), be warming up to 50 ± 2 ℃ and add Hydrocerol A; Be warming up to 95 ± 2 ℃ and add iodine, the reaction kettle building-up reactions is after 2 hours, and reaction mass carries out system circulation 1 hour, and temperature is reduced to 30 ± 2 ℃ of dischargings after detection is qualified.Finished product need be placed in lucifuge, the nonmetallic container.
7. according to claim 1, lauryl glucoside iodine complex outward appearance body shape is the grape thick liquid, and the pH value is 5-6, iodine content 3-5%.
The present invention make that raw material is easy to get, pollution-free in the production process, do not have waste, meet the requirement of environmental protective chemical industry production technique.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101668717A CN102838643A (en) | 2011-06-21 | 2011-06-21 | Lauryl glucoside-iodine complex |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101668717A CN102838643A (en) | 2011-06-21 | 2011-06-21 | Lauryl glucoside-iodine complex |
Publications (1)
| Publication Number | Publication Date |
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| CN102838643A true CN102838643A (en) | 2012-12-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN2011101668717A Pending CN102838643A (en) | 2011-06-21 | 2011-06-21 | Lauryl glucoside-iodine complex |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103833799A (en) * | 2012-11-20 | 2014-06-04 | 苏州天人合生物技术有限公司 | Glucose iodine derivative, preparation method thereof and application thereof in pharmacy |
| CN103891773A (en) * | 2014-04-21 | 2014-07-02 | 成都科宏达科技有限公司 | Sterilizing agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3291692A (en) * | 1965-05-26 | 1966-12-13 | Grace W R & Co | Germicidal compositions containing complexes of iodine |
| US6777003B1 (en) * | 1995-06-07 | 2004-08-17 | Cognis Corporation | Iodine complex of alkyl polyglycosides |
| CN102002132A (en) * | 2009-09-02 | 2011-04-06 | 陈煜� | Improvement on method for preparing complex of polyvinylpyrrolidone grafted with natural polymer or water-soluble derivate thereof and iodine derivate |
-
2011
- 2011-06-21 CN CN2011101668717A patent/CN102838643A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3291692A (en) * | 1965-05-26 | 1966-12-13 | Grace W R & Co | Germicidal compositions containing complexes of iodine |
| US6777003B1 (en) * | 1995-06-07 | 2004-08-17 | Cognis Corporation | Iodine complex of alkyl polyglycosides |
| CN102002132A (en) * | 2009-09-02 | 2011-04-06 | 陈煜� | Improvement on method for preparing complex of polyvinylpyrrolidone grafted with natural polymer or water-soluble derivate thereof and iodine derivate |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103833799A (en) * | 2012-11-20 | 2014-06-04 | 苏州天人合生物技术有限公司 | Glucose iodine derivative, preparation method thereof and application thereof in pharmacy |
| CN103833799B (en) * | 2012-11-20 | 2017-02-08 | 苏州天人合生物技术有限公司 | Glucose iodine derivative, preparation method thereof and application thereof in pharmacy |
| CN103891773A (en) * | 2014-04-21 | 2014-07-02 | 成都科宏达科技有限公司 | Sterilizing agent and preparation method thereof |
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Application publication date: 20121226 |