CN102827461A - Nanometer quantum energy masterbatch and preparation method thereof - Google Patents
Nanometer quantum energy masterbatch and preparation method thereof Download PDFInfo
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- CN102827461A CN102827461A CN2012103260054A CN201210326005A CN102827461A CN 102827461 A CN102827461 A CN 102827461A CN 2012103260054 A CN2012103260054 A CN 2012103260054A CN 201210326005 A CN201210326005 A CN 201210326005A CN 102827461 A CN102827461 A CN 102827461A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92514—Pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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- Engineering & Computer Science (AREA)
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- Artificial Filaments (AREA)
Abstract
The invention provides a nanometer quantum energy masterbatch which comprises the following components in percentage by weight: 10-16wt% of nanometer quantum energy ore powder, 80-85.5wt% of polyester (PET) and 1-4.5wt% of accessory ingredient, wherein the accessory ingredient comprises 7.5-17.5wt% of coupling reagent, 2.5-12.5wt% of dispersing agent and 0.01-0.1wt% of antioxygen. The nanometer quantum energy masterbatch is a good carrier for functions such as temperature regulation, far infrared release, antibiosis deodorization and moisture absorption and quick-drying, and the nanometer quantum energy masterbatch enables functional active ingredients of ore to be evenly dispersed in a spinning solution.
Description
Technical field
The present invention relates to a kind of synthon master batch and preparation method thereof, concrete, the present invention relates to a kind of preparation method of nanometer quantum energy master batch.
Background technology
Terylene is that world wide production is maximum, most widely used synthon kind, and terylene accounts for more than 60% of world's synthon output at present.Be used for textiles and other industrial fibre goods such as dress material, bedclothes, various trimming cloth, defence and military particular fabric in a large number, like filtering material, insulating material, tire cord, travelling belt etc.In recent years, along with domestic economy maintains sustained and rapid growth and the improving constantly of domestic consumption of resident ability, the demand of domestic regional polyester staple fiber also constantly increases.China's terylene series product production capacity is increasing with surprising rapidity, and increasing rapidly of polyster fibre production capacity makes China develop into the important processing base of world's terylene series products just gradually.
Polyster fibre is the maximum chemical fibre kind of processing total amount in all textile fibress, develops differential kind, improves added value of product, improves the business economic benefit, and is most important to the influence of whole chemical fibre industry; Product differentiation is the developing direction of terylene, and the polyster fibre manufacturing enterprise of China also develops along this direction just.Therefore the terylene industry also has very big potentiality to be exploited.
The present inventor is devoted to characteristics with the specific functionality aspect of ore and induces one in polyster fibre master batch synthetic.
Summary of the invention
The objective of the invention is in order to satisfy people more and more paying attention to the needs of the functional aspect of textile materials; Continually develop functional trevira; We screen through the ore that in the natural resources some is had function well property; Finally confirmed the raw material of multicolored ore, and traditional trevira has been carried out modification as nano material of the present invention.
To achieve these goals, the invention provides following technical scheme:
First aspect of the present invention provides a kind of nanometer quantum energy master batch, and said nanometer quantum energy master batch component is:
Nanometer quantum energy ore powder 10～16wt%
PET 80～85.5wt％
Auxiliary agent 1～4.5wt%
Said auxiliary agent does
Coupling agent 7.5～17.5wt%
Dispersion agent 2.5～12.5wt%
Oxidation inhibitor 0.01～0.1wt%;
Above auxiliary agent content is the mass percent that accounts for nanometer quantum energy ore powder.
Above-mentioned nanometer quantum energy ore powder particle diameter is 50nm-80nm.
Above-mentioned coupling agent is a 3-aminopropyl triethoxysilane coupling agent; Above-mentioned dispersion agent is a how sodium sulfonate of methylene-bis; Above-mentioned oxidation inhibitor is three (2,4 one di-tert-butyl-phenyl) phosphorous acid ester.
Second aspect of the present invention provides the preparation method of above-mentioned nanometer quantum energy master batch, it is characterized in that said preparation method comprises the steps:
(a) multicolored ore is calcined 2-3 time under 1000 ℃ of-1200 ℃ of high temperature repeatedly, be crushed to 50-80nm, obtain ore powder;
(b) in ore powder, add entry and ferment, fermented 60 days, again with the ore powder of fermentation through nano-pulverization, obtain nanometer quantum energy ore powder;
(c) the nanometer quantum energy ore powder that step (b) is obtained carried out vacuum-drying 1-1.5 hour;
(d) will obtain nanometer quantum energy master batch through nanometer quantum energy ore powder, PET, the proportionally consolute granulation of auxiliary agent of step (c) processing.
Pulverize in the above-mentioned steps (a) and divided for two steps carried out, tentatively pulverize multicolored ore with kibbler earlier; Carrying out secondary with NNM6 efficient nano sand mill again pulverizes.
In the above-mentioned steps (b), during fermentation, ore powder is 75wt%, and ferment is 5wt%, and water is 20%; Leavening temperature is 25 ℃, and humidity is 60%.
In the above-mentioned steps (c), under 120 ℃ temperature, nanometer quantum energy ore powder is carried out vacuum-drying.
In the above-mentioned steps (d), during the consolute granulation,, again it is dropped into twin screw extruder fusion co-extrusion with all material mixed at high speed dischargings after 15-20 minute, water-cooled, pelletizing, drying obtains nanometer quantum energy master batch.
In the above-mentioned steps (d), twin screw extruder 1-8 respectively distinguishes in the district temperature and is controlled to be 200 ℃ respectively, and 215 ℃, 235 ℃, 255 ℃, 260 ℃, 270 ℃, 270 ℃, 255 ℃; Screw pressure: 0.12Mpa; Screw speed: 1100r/min; Feeding rotating speed: 750r/min; Dicing machine rotating speed: 1200r/min; Bath temperature: 20 ℃-30 ℃; 80 ℃-100 ℃ of drying temperatures.
In the above-mentioned steps (d), during the consolute granulation,, again it is dropped into twin screw extruder fusion co-extrusion with all material mixed at high speed dischargings after 15-20 minute, water-cooled, pelletizing, drying obtains nanometer quantum energy master batch.
Above-mentioned multicolored ore is available from Korea S QUANTUM ENERGY company; Specification: SiO
260%, K
2O 2%, Fe
2O
38%, Al
2O
325%, other 5%, diameter is between 0.1-5cm.
The technical scheme of the preparing method's of a kind of nanometer quantum energy differential fiber that the present invention solved technical problem is:
The batching proportioning is: nanometer quantum energy master batch 1-2wt%
Terylene chips 98-99wt%.
Above-mentioned differential fiber has spiral curling three-dimensional structure.
Above-mentioned differential fiber xsect is a hexahedron.Technical process: batching-mixing-drying-spinning-coiling-network bucket-boundling-stretching-heat setting type-cut-out-packing.
With the material for preparing uniform mixing in mixing machine, add wire drawing in the spinning machinery again.
Above-mentioned spinning and aftertreatment technology parameter are: spinning speed 1000m/min, 280 ℃ of melt temperatures, FR-1 rotating speed 1500r/min; FR-2 rotating speed 1500r/min, SR rotating speed 1800r/min, DF-3 vapor pressure 1.3MPa; HF vapor pressure 1.25MPa, total draft multiple 4.05.
In the above-mentioned spinning step, the orifice of the spray silk equipment of employing is hexagonal special crosssection.
In the above-mentioned spinning step, increase three-dimensional calibrator during precipitation bath.
Compared with prior art, the invention has the beneficial effects as follows: select novel ore materials, handle, ferment through nanometer, the characteristics that make its ore are applicable to the development functionality fiber; And, make nano particle be dispersed in the carrier through dispersion treatment, through high-speed stirring, mix; Fusion is extruded, and can obtain nanometer quantum energy master batch; And melt-spinning, technology is pollution-free, economic environmental protection.The ore that the present invention selects for use is after fermentation, and function is more, has enlarged the scope of application of quantum energy differential fiber.This nanometer quantum energy differential fiber technology is simple, be applicable to suitability for industrialized production, and cost is lower, cleanliness without any pollution, compliance with environmental protection requirements.
Nanometer quantum energy master batch of the present invention has the following advantages:
1. this master batch is the good carrier of functions such as temperature regulation, far infrared release, antibacterial and deodouring and hydroscopic fast-drying, because contain the effective constituent with above-mentioned functions in the master batch.
2. through master batch of the present invention, can the functionality active component of ore be evenly spread in the spinning solution.
Description of drawings
Fig. 1 is an orifice special crosssection synoptic diagram.
Fig. 2 is spiral curling three-dimensional structure fiber synoptic diagram.
Embodiment
The preparation technology of embodiment 1 nanometer quantum energy master batch:
(1) preparation of nanometer quantum energy ore powder.With a kind of multicolored ore (Korea S QUANTUM ENERGY company; Specification: SiO
260%, K
2O 2%, Fe
2O
38%, Al
2O
325%; Other 5%, diameter is between the 0.1-5cm) under 1200 ℃ of high temperature, calcine 2-3 time each 2 hours repeatedly; Remove the invalid components in the ore; Through the preliminary powder ore of common kibbler, carry out secondary with dry ground equipment-NNM6 efficient nano sand mill again and pulverize, make nanometer five colors ore powder particle diameter at 50-80nm.The nanometer for preparing five colors ore powder is carried out fermentative processing after 60 days with fermentation with ferment sneaking into water under the fixed temperature and humidity condition, and dry back nano-pulverization made nanometer quantum energy ore powder in 30 minutes.Its zymotechnique is following:
(2) vacuum-drying under 120 ℃ temperature, was carried out vacuum-drying 1.5 hours to nanometer quantum energy ore powder;
(3) consolute granulation with the discharging after 20 minutes of following material mixed at high speed, drops into twin screw extruder fusion co-extrusion with it again, water-cooled, and pelletizing, drying obtains nanometer quantum energy master batch; The melting granulating technology parameter is: twin screw extruder 1-8 respectively distinguishes in the district temperature and is controlled to be 200 ℃ respectively, and 215 ℃, 235 ℃, 255 ℃, 260 ℃, 270 ℃, 270 ℃, 255 ℃; Screw pressure: 0.12Mpa; Screw speed: 1100r/min; Feeding rotating speed: 750r/min; Dicing machine rotating speed: 1200r/min; Bath temperature: 20 ℃; 100 ℃ of drying temperatures.
The prescription of the nanometer quantum energy master batch that this programme adopted is: comprise following several kinds of compositions according to weight percent:
Nanometer quantum energy ore powder 10-16wt%
PET 80-85.5wt％
Auxiliary agent 1-4.5wt%
Described nanometer quantum energy ore powder is the nano powder that multicolored ore is made through special process, and median size is at 50nm-80nm; Described auxiliary agent comprises the following ingredients that accounts for nanometer quantum energy ore powder mass percent:
Said auxiliary agent does
Coupling agent 7.5～17.5wt%
Dispersion agent 2.5～12.5wt%
Oxidation inhibitor 0.01～0.1wt%;
Said coupling agent is a 3-aminopropyl triethoxysilane coupling agent; Said dispersion agent is a sodium methylene bis-naphthalene sulfonate; Said oxidation inhibitor is three (2,4 one di-tert-butyl-phenyl) phosphorous acid ester.
The preparation technology of embodiment 2 nanometer quantum energy differential fibers
The batching proportioning is: the nanometer quantum energy master batch 1-2wt% of embodiment 1
Terylene chips 98-99wt%
The contriver draws aforementioned proportion through lot of experiments; Increase product cost if the ratio of nanometer quantum energy master batch is crossed conference, and to spinning equipment result in blockage, disadvantageous effect such as wearing and tearing, lower efficiency and product quality; And ratio is crossed the low functional reduction that can make product or is not reached its functional attributes of design.
Technical process: batching-mixing-drying-spinning-coiling-network bucket-boundling-stretching-heat setting type-cut-out-packing.
With the material for preparing uniform mixing in mixing machine, add wire drawing in the spinning machinery again.
Main spinning and aftertreatment technology parameter: spinning speed 1000m/min; 280 ℃ of melt temperatures, FR-1 (first draw roll) rotating speed 1500r/min, FR-2 (second draw roll) rotating speed 1500r/min; SR (wind up roll) rotating speed 1800r/min; DF-3 (the 3rd drawing machine) vapor pressure 1.3MPa, HF (setting roll) vapor pressure 1.25MPa, total draft multiple 4.05.
In the spinning step, following preferred version is arranged:
(1) in spray silk equipment, makes orifice into special crosssection (as shown in Figure 1), thereby make the fiber that obtains also be special crosssection, finally improved the glossiness and the specific surface area of fiber.
(2) can also in traditional spinning coagulation bath, add three-dimensional calibrator, be not the unidirectional elongated common long filament of two dimension thereby make the fiber that obtains, but have spiral curling three-dimensional structure (as shown in Figure 2).
The above description of this invention is not limited to scope of the present invention.For the person of ordinary skill of the art, can make various corresponding changes according to technical scheme provided by the invention, these changes all should belong to protection scope of the present invention.
Claims (14)
1. a nanometer quantum energy master batch is characterized in that, said nanometer quantum energy master batch component is:
Nanometer quantum energy ore powder 10～16wt%
PET 80～85.5wt％
Auxiliary agent 1～4.5wt%
Said auxiliary agent does
Coupling agent 7.5～17.5wt%
Dispersion agent 2.5～12.5wt%
Oxidation inhibitor 0.01～0.1wt%;
Above auxiliary agent content is the mass percent that accounts for nanometer quantum energy ore powder.
2. nanometer quantum energy master batch according to claim 1 is characterized in that said nanometer quantum energy ore powder particle diameter is 50nm-80nm.
3. nanometer quantum energy master batch according to claim 1 is characterized in that said coupling agent is a 3-aminopropyl triethoxysilane coupling agent; Said dispersion agent is a how sodium sulfonate of methylene-bis; Said oxidation inhibitor is three (2,4 one di-tert-butyl-phenyl) phosphorous acid ester.
4. like the said nanometer quantum energy of claim 2 master batch, it is characterized in that said coupling agent is a 3-aminopropyl triethoxysilane coupling agent; Said dispersion agent is a how sodium sulfonate of methylene-bis; Said oxidation inhibitor is three (2,4 one di-tert-butyl-phenyl) phosphorous acid ester.
5. like the preparation method of the said nanometer quantum energy of the arbitrary claim of claim 1-4 master batch, it is characterized in that said preparation method comprises the steps:
(a) multicolored ore is calcined 2-3 time under 1000 ℃ of-1200 ℃ of high temperature repeatedly, be crushed to 50-80nm, obtain ore powder;
(b) in ore powder, add entry and ferment, fermented 60 days, again with the ore powder of fermentation through nano-pulverization, obtain nanometer quantum energy ore powder;
(c) the nanometer quantum energy ore powder that step (b) is obtained carried out vacuum-drying 1-1.5 hour;
(d) will obtain nanometer quantum energy master batch through nanometer quantum energy ore powder, PET, the proportionally consolute granulation of auxiliary agent of step (c) processing.
6. like the preparation method of the said nanometer quantum energy of claim 5 master batch, it is characterized in that, pulverize in the said step (a) and divided for two steps carried out, tentatively pulverize multicolored ore with kibbler earlier; Carrying out secondary with NNM6 efficient nano sand mill again pulverizes.
7. like the preparation method of the said nanometer quantum energy of claim 5 master batch, it is characterized in that in the said step (b), during fermentation, ore powder is 75wt%, ferment is 5wt%, and water is 20%; Leavening temperature is 25 ℃, and humidity is 60%.
8. like the preparation method of the said nanometer quantum energy of claim 6 master batch, it is characterized in that in the said step (b), during fermentation, ore powder is 75wt%, ferment is 5wt%, and water is 20%; Leavening temperature is 25 ℃, and humidity is 60%.
9. like the preparation method of the said nanometer quantum energy of claim 5 master batch, it is characterized in that, in the said step (c), under 120 ℃ temperature, nanometer quantum energy ore powder is carried out vacuum-drying.
10. like the preparation method of claim 6,7 or 8 said nanometer quantum energy master batches, it is characterized in that, in the said step (c), under 120 ℃ temperature, nanometer quantum energy ore powder is carried out vacuum-drying.
11. the preparation method like the said nanometer quantum energy of claim 5 master batch is characterized in that, in the said step (d), during the consolute granulation; With all material mixed at high speed dischargings after 15-20 minute, again it is dropped into twin screw extruder fusion co-extrusion, water-cooled; Pelletizing, drying obtains nanometer quantum energy master batch.
12. the preparation method like the said nanometer quantum energy of the arbitrary claim of claim 6-9 master batch is characterized in that, in the said step (d); During the consolute granulation,, again it is dropped into twin screw extruder fusion co-extrusion with all material mixed at high speed dischargings after 15-20 minute; Water-cooled; Pelletizing, drying obtains nanometer quantum energy master batch.
13. the preparation method like claim 6-9 or the said nanometer quantum energy of 11 arbitrary claims master batch is characterized in that in the said step (d), twin screw extruder 1-8 respectively distinguishes in the district temperature and is controlled to be 200 ℃ respectively; 215 ℃, 235 ℃, 255 ℃, 260 ℃; 270 ℃, 270 ℃, 255 ℃; Screw pressure: 0.12Mpa; Screw speed: 1100r/min; Feeding rotating speed: 750r/min; Dicing machine rotating speed: 1200r/min; Bath temperature: 20 ℃-30 ℃; 80 ℃-100 ℃ of drying temperatures.
14. the preparation method like claim 6-9 or the said nanometer quantum energy of 11 arbitrary claims master batch is characterized in that said multicolored ore is available from Korea S QUANTUM ENERGY company; Specification: SiO
260%, K
2O2%, Fe
2O
38%, Al
2O
325%, other 5%, diameter is between 0.1-5cm.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103572391A (en) * | 2012-07-27 | 2014-02-12 | 中浪环保股份有限公司 | Spun polyester pre-oriented yarn production method using recycled polyester bottle chips |
| CN103938293A (en) * | 2014-04-26 | 2014-07-23 | 广州市中诚新型材料科技有限公司 | Far infrared polyester fiber and preparation method thereof |
| CN104277436A (en) * | 2014-09-24 | 2015-01-14 | 苏州博利迈新材料科技有限公司 | Deodorant PET (polyethylene terephthalate) master batch and preparation method thereof |
| CN105332074A (en) * | 2014-08-05 | 2016-02-17 | 李钟斗 | Multifunctional fiber manufacturing method using mineral-based somatid qelby fusion master batch chip included in natural minerals |
| CN105563683A (en) * | 2016-01-29 | 2016-05-11 | 桐乡市中辰化纤有限公司 | Method for preparing master batches through direct PET melt mixing and equipment special for method |
| CN106884221A (en) * | 2017-02-07 | 2017-06-23 | 福建百宏聚纤科技实业有限公司 | Low melt point polyester fiber FDY filament and preparation method thereof |
| CN111254537A (en) * | 2019-12-19 | 2020-06-09 | 浙江麻尚生纺织科技有限公司 | Fiber fabric and preparation method thereof |
| CN112442198A (en) * | 2020-11-25 | 2021-03-05 | 福建紫牛塑业科技有限责任公司 | High-dispersity high-concentration monochromatic master batch method and application thereof |
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