CN102816534B - Structure adhesive for metal adhesion, and preparation method thereof - Google Patents
Structure adhesive for metal adhesion, and preparation method thereof Download PDFInfo
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- CN102816534B CN102816534B CN201210287083.8A CN201210287083A CN102816534B CN 102816534 B CN102816534 B CN 102816534B CN 201210287083 A CN201210287083 A CN 201210287083A CN 102816534 B CN102816534 B CN 102816534B
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Abstract
The present invention relates to a two-component acrylate structure adhesive and a preparation method thereof. The adhesive is prepared by matching a component A and a component B according to a mass part ratio of 1:1, wherein the component A comprises, by mass, 40-80 parts of an acrylate monomer, 10-40 parts of a toughening resin, 0.2-10 parts of an initiator, 0.01-1 part of a stabilizer, 0.2-5 parts of a coupling agent, and 0.2-10 parts of a thixotropic agent, and the component B comprises, by mass, 40-80 parts of an acrylate monomer, 10-40 parts of a toughening resin, 0.2-10 parts of an accelerator, 0.01-1 part of a stabilizer, 0.2-5 parts of a coupling agent, and 0.2-10 parts of a thixotropic agent. The adhesive of the present invention is rapidly cured at a room temperature, provides good adhesion effects for zinc, nickel, chromium and other metals, and has characteristics of room temperature storage, stable performance, and long storage period.
Description
Technical field
The present invention relates to the glutinous agent of a kind of two-component acrylate structural adhesive, be specifically related to one and be applicable to metal, particularly glutinous agent of two-component acrylate structural adhesive of the metal sticking such as zinc, nickel, chromium and preparation method thereof.
Background technology
Adopt sizing agent to metallic substance carry out being bondingly better than in some aspects traditional welding, the technique such as rivet, be spirally connected, especially the defect mending of metalwork and maintenance are had more to unique effect.Bondingly can because not causing structural distortion and metallographic structure, heat not change as welding, and also can be as riveted joint, be spirally connected and cause stress concentration and strength decreased because of boring hitch.As long as choosing gummed is suitable, joint is reasonable, technique is proper, will obtain satisfied metal sticking effect.
As the Typical Representative s-generation acrylate adhesive of esters of acrylic acid sizing agent, there is the plurality of advantages such as quick solidifying, intensity are high, good toughness, strong adaptability.But on market, be applicable to metal sticking, the glutinous agent of two-component acrylate structural adhesive that is specially adapted to the metal stickings such as zinc, nickel, chromium is of less types.For this reason, develop the especially aobvious necessity of this series products.
Summary of the invention
The object of the present invention is to provide one for metal sticking, be specially adapted to glutinous agent of two-component acrylate structural adhesive of the metal stickings such as zinc, nickel, chromium and preparation method thereof.
For realizing above-mentioned technical purpose, concrete technical scheme of the present invention is:
Propose a kind of two-component acrylate structural adhesive sizing agent, described two-component acrylate structural adhesive sizing agent carries out proportioning by A component and B component by mass fraction 1:1;
Described A components in mass portion number is comprised of following raw material:
40 parts～80 parts of acrylic ester monomers,
10 parts～40 parts of toughened resins,
0.2 part～10 parts of initiators,
0.01 part～1 part of stablizer,
0.2～5 part of coupling agent,
0.2～10 part of thixotropic agent;
Described B components in mass portion number is comprised of following raw material:
40 parts～80 parts of acrylic ester monomers,
10 parts～40 parts of toughened resins,
0.2 part～10 parts of promotor,
0.01 part～1 part of stablizer,
0.2～5 part of coupling agent,
0.2～10 part of thixotropic agent.
Described acrylic ester monomer is methyl methacrylate, (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, (methyl) vinylformic acid tetrahydrofuran ester, 2-benzene oxygen ethyl-methyl acrylate, (methyl) isobornyl acrylate, (methyl) n-butyl acrylate, (methyl) lauryl acrylate, (methyl) tetradecyl acrylate, (methyl) Process Conditions of Cetane Acrylate, (methyl) octadecyl acrylate, (methyl) vinylformic acid, phenylformic acid, methylene-succinic acid, Sorbic Acid, m-phthalic acid, Ethylene glycol dimethacrylate, ethoxyquin double A diacrylate, 1, one or more in 4-butylene glycol diacrylate.
Described toughened resin is chloroprene rubber, paracril, styrene-butadiene rubber(SBR), MBS resin, ABS resin, urethane resin, acrylate quasi-oligomer, one or more in epoxy modified acrylic resin.
Described initiator is benzoyl peroxide, isopropyl benzene hydroperoxide, tertbutyl peroxide, one or more in cyclohexanone peroxide.
Described promotor is triethylamine, DMA, N, N-dimethyl-p-toluidine, vinyl thiocarbamide, tetramethyl thiourea, cobalt naphthenate, cobalt iso-octoate, cobalt octoate, vanadium acetylacetonate, ferric acetyl acetonade, one or more in butyraldehyde-n-aniline condensation thing.
Described stablizer is Resorcinol, quinhydrone(s), 2,6 di tert butyl 4 methyl phenol, one or more in Na2EDTA.
Described coupling agent is γ-aminopropyl triethoxysilane (KH 550), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH 560), one or more in γ-methacryloxypropyl trimethoxy silane (KH570).
Described thixotropic agent is organobentonite, aerosil, hydrogenated castor oil, one or more in polyethylene wax.
The present invention also proposes a kind of preparation method of described two-component acrylate structural adhesive sizing agent, and described preparation method comprises:
A component preparation: acrylic ester monomer is mixed, add successively stablizer and coupling agent, toughened resin is added and stirred, then initiator is added and stirred evenly, finally add thixotropic agent to stir evenly, froth in vacuum discharging obtains A component;
B component preparation: acrylic ester monomer is mixed, add successively stablizer and coupling agent, toughened resin is added and stirred, then stirred evenly promotor adding, finally add thixotropic agent to stir evenly, froth in vacuum discharging obtains B component.
Beneficial effect of the present invention:
1. normal temperature fast setting is good for the adhesive effect of the metals such as zinc, nickel, chromium.
2. normal temperature storage, stable performance, storage period is long.
Embodiment
For making the object, technical solutions and advantages of the present invention clearer, below in conjunction with specific embodiment, the present invention is described in more detail.
Embodiment 1
| Component title | A component | B component |
| THFMA | 32 | 28 |
| 2-benzene oxygen ethyl-methyl acrylate | 12 | 14 |
| Methacrylic acid | 4 | 4 |
| Toxilic acid | 4 | 4 |
| Isooctyl methacrylate | 8 | 10 |
| Paracril | 20 | 18 |
| MBS resin | 15 | 17 |
| KH570 | 1 | 1 |
| Resorcinol | 0.05 | 0.05 |
| 2,6 di tert butyl 4 methyl phenol | 0.05 | 0.05 |
| DMA | 0.8 | |
| Cobalt iso-octoate | 0.2 | |
| Isopropyl benzene hydroperoxide | 2.2 | |
| Aerosil | 2 | 2 |
Preparation technology:
A component preparation: accurately take THFMA, 2-phenoxy group ethyl-methyl acrylate, methacrylic acid, toxilic acid and Isooctyl methacrylate, mix; Add KH570, Resorcinol and 2,6 di tert butyl 4 methyl phenol to mix; Then paracril and MBS resin are added successively, it is dissolved completely; Add again isopropyl benzene hydroperoxide and aerosil, and stir; Last froth in vacuum, discharging obtains A component.
B component preparation: after accurately taking THFMA, 2-benzene oxygen ethyl-methyl acrylate, methacrylic acid, toxilic acid and Isooctyl methacrylate and mixing, add KH570, Resorcinol and 2,6-di-tert-butyl-4-methy phenol mixes, then paracril and MBS resin are added successively, it is dissolved completely, again DMA and cobalt iso-octoate and aerosil are added, and stir.Last froth in vacuum, discharging obtains B component.
Embodiment 2
| Component title | A group | B component |
| Point | ||
| Methyl methacrylate | 27 | 25 |
| Hydroxyethyl methylacrylate | 15 | 17 |
| Methacrylic acid | 6 | 6 |
| Ethylene glycol dimethacrylate | 4 | 4 |
| N-BMA | 8 | 7 |
| Paracril | 19 | 18 |
| ABS resin | 14 | 16 |
| KH570 | 1 | 1 |
| Para benzoquinone | 0.05 | 0.05 |
| 2,6 di tert butyl 4 methyl phenol | 0.05 | 0.05 |
| Tetramethyl thiourea | 1.5 | |
| Cobalt naphthenate | 0.6 | |
| The benzoyl peroxide tert-butyl ester | 1.9 | |
| Aerosil | 3.5 | 3.5 |
Preparation technology:
A component preparation: accurately take methyl methacrylate, hydroxyethyl methylacrylate, methacrylic acid, Ethylene glycol dimethacrylate, n-BMA and mix; Add KH570, para benzoquinone and 2,6 di tert butyl 4 methyl phenol are mixed; Then paracril and ABS resin are added successively, it is dissolved completely; Add again tertbutyl peroxide and aerosil, and stir; Last froth in vacuum, discharging obtains A component.
B component preparation: accurately take methyl methacrylate, hydroxyethyl methylacrylate, methacrylic acid, Ethylene glycol dimethacrylate, n-BMA and mix; Add KH570, para benzoquinone and 2,6 di tert butyl 4 methyl phenol are mixed; Then paracril and ABS resin are added successively, it is dissolved completely; Add again cobalt naphthenate, tetramethyl thiourea and aerosil, and stir; Last froth in vacuum, discharging obtains B component.
According to GB/T 7124-2008 test shearing resistance, according to GB/T 7122-1996 test stripping strength, in Table 1.
The mutual bonding test of table 1 metallic substance
Above-described specific embodiment; object of the present invention, technical scheme and beneficial effect have been carried out to further detailed description; institute is understood that; the foregoing is only specific embodiments of the invention; be not limited to the present invention; within the spirit and principles in the present invention all, any modification of making, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (1)
1. a two-component acrylate structural adhesive sizing agent, is characterized in that, described two-component acrylate structural adhesive sizing agent carries out proportioning by A component and B component by mass fraction 1:1;
Described A components in mass portion number is comprised of following raw material:
32 parts of THFMAs
12 parts of 2-benzene oxygen ethyl-methyl acrylate
4 parts of methacrylic acids
4 parts of toxilic acids
8 parts of Isooctyl methacrylates
20 parts of paracrils
15 parts of MBS resins
1 part of KH570
0.05 part of Resorcinol
0.05 part of 2,6 di tert butyl 4 methyl phenol
2.2 parts of isopropyl benzene hydroperoxides
2 parts of aerosils;
Described B components in mass portion number is comprised of following raw material:
28 parts of THFMAs
14 parts of 2-benzene oxygen ethyl-methyl acrylate
4 parts of methacrylic acids
4 parts of toxilic acids
10 parts of Isooctyl methacrylates
18 parts of paracrils
17 parts of MBS resins
1 part of KH570
0.05 part of Resorcinol
0.05 part of 2,6 di tert butyl 4 methyl phenol
0.8 part of DMA
0.2 part of cobalt iso-octoate
2 parts of aerosils
preparation technology:
A component preparation: take THFMA, 2-phenoxy group ethyl-methyl acrylate, methacrylic acid, toxilic acid and Isooctyl methacrylate, mix; Add KH570, Resorcinol and 2,6 di tert butyl 4 methyl phenol to mix; Then paracril and MBS resin are added successively, it is dissolved completely; Add again isopropyl benzene hydroperoxide and aerosil, and stir; Last froth in vacuum, discharging obtains A component;
B component preparation: after taking THFMA, 2-benzene oxygen ethyl-methyl acrylate, methacrylic acid, toxilic acid and Isooctyl methacrylate and mixing, add KH570, Resorcinol and 2,6-di-tert-butyl-4-methy phenol mixes, then paracril and MBS resin are added successively, it is dissolved completely, then by N, accelerine and cobalt iso-octoate and aerosil add, and stir, last froth in vacuum, discharging obtains B component.
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| CN201210287083.8A CN102816534B (en) | 2012-08-14 | 2012-08-14 | Structure adhesive for metal adhesion, and preparation method thereof |
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|---|---|---|---|
| CN201210287083.8A CN102816534B (en) | 2012-08-14 | 2012-08-14 | Structure adhesive for metal adhesion, and preparation method thereof |
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| CN102816534A CN102816534A (en) | 2012-12-12 |
| CN102816534B true CN102816534B (en) | 2014-05-07 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115641A (en) * | 2010-12-03 | 2011-07-06 | 烟台德邦科技有限公司 | High-toughness acrylate structural adhesive and preparation method thereof |
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2012
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115641A (en) * | 2010-12-03 | 2011-07-06 | 烟台德邦科技有限公司 | High-toughness acrylate structural adhesive and preparation method thereof |
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