CN106189886A - A kind of high tenacity transparent two-component acrylicester adhesive and preparation method thereof - Google Patents
A kind of high tenacity transparent two-component acrylicester adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106189886A CN106189886A CN201610655896.6A CN201610655896A CN106189886A CN 106189886 A CN106189886 A CN 106189886A CN 201610655896 A CN201610655896 A CN 201610655896A CN 106189886 A CN106189886 A CN 106189886A
- Authority
- CN
- China
- Prior art keywords
- component
- transparent
- high tenacity
- resin
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of high tenacity transparent two-component acrylicester adhesive and preparation method thereof, including two components of A, B；Component A includes being polymerized monomer 60.0～80.0%, toughening rubber 0～10.0%, strengthens resin 0～15.0%, transparent agent 10.0～35.0%, reduction accelerator 2.0～5.0% and stabilizer 0～0.01%；B component include being polymerized monomer 60.0～80.0%, strengthen resin 0～20.0%, transparent agent 5.0～35.0%, firming agent 2.0～5.5% and stabilizer 0～0.1%.Prepared by component A: will be polymerized monomer and stabilizer stirring, and add reduction accelerator, toughening rubber, enhancing resin and transparent agent；Prepared by B component: will be polymerized monomer and stabilizer stirring, and add firming agent, strengthen resin and transparent agent.Shock resistance of the present invention is good, high tenacity, the high grade of transparency, cold curing speed is fast, adhesive strength is high.
Description
Technical field
The present invention relates to a kind of high tenacity transparent two-component acrylicester adhesive and preparation method thereof, belong to adhesive neck
Territory.
Background technology
Fast curable type acrylate adhesive, easy and simple to handle owing to having, under room temperature can fast setting, the spy that adhesion strength is high
Point, is widely used in the fields such as building, machinery, electronics, Aeronautics and Astronautics, automobile, medical treatment.At adhesive area, formed
One complete independent industrial class, the research and development of its new product, the design of formula for a product and the improvement etc. of technique, also become mesh
The problem that front production, research and development adhesive receive much concern.
Last century, the eighties rose, and the demand of individual decoration is got more and more, to disclosure satisfy that household supplies, work by people
The research of the bonding acrylate adhesive of the objects such as the skill fine arts, high-grade ornament becomes focus.Third in the market
Olefin(e) acid ester adhesive exists that impact resistance is poor, toughness is low and glue-line mostly is the shortcoming such as translucent or opaque, it is impossible to meets and uses
Demand.Therefore a kind of shock resistance of exploitation is good, high tenacity, the high grade of transparency, cold curing speed is fast, adhesive strength is high and makes
It is very important with convenient acrylate adhesive.
Summary of the invention
It is contemplated that in place of overcoming the deficiencies in the prior art, it is provided that a kind of shock resistance is good, high tenacity, high transparency
Degree, acrylate adhesive that cold curing speed is fast, adhesive strength is high and easy to use and preparation method thereof.
For solving above-mentioned technical problem, the present invention is realized in.
A kind of high tenacity transparent two-component acrylicester adhesive, with weight, including component A and B component.
Component A includes:
Polymerization monomer 60.0～80.0%；
Toughening rubber 0～10.0%；
Strengthen resin 0～15.0%；
Transparent agent 10.0～35.0%；
Reduction accelerator 2.0～5.0%；
Stabilizer 0～0.01%.
B component includes:
Polymerization monomer 60.0～80.0%；
Strengthen resin 0～20.0%；
Transparent agent 5.0～35.0%；
Firming agent 2.0～5.5%；
Stabilizer 0～0.1%.
As a kind of preferred version, polymerization monomer of the present invention is methyl methacrylate, hydroxyethyl methacrylate second
One or both and the mixture of above monomer in ester, methacrylic acid, acrylic acid.
Further, one or two during toughening rubber of the present invention is chlorosulfonated polyethylene (CSM) and nitrile rubber
The mixture planted.
Further, enhancing resin of the present invention is modified hydroxy propylene acid resin, ABS resin, styrene-butadiene transparent anti-impact
One or both and above mixture in resin.
Further, transparent agent of the present invention is polymethyl methacrylate (PMMA), epoxy resin, unsaturated polyester
One or both and above mixture in ester.
Further, reduction accelerator of the present invention is triethylamine, vinylthiourea, tetramethyl thiourea, isooctyl acid
One or both and above mixture in cobalt.
Further, firming agent of the present invention is isopropyl benzene hydroperoxide, benzoyl peroxide, tert-butyl hydroperoxide
One or both and above mixture in hydrogen.
Further, stabilizer of the present invention be hydroquinone, 2,6-di-tert-butyl-4-methy phenol, 1,4-benzoquinone
In one or both and above mixture.
The preparation of a kind of high tenacity of the present invention transparent two-component acrylicester adhesive, can be real as follows
Execute.
(1) prepared by component A.
Polymerization monomer and stabilizer are put in Scattered Kettle, start stirring, be sequentially added into reduction accelerator, toughening rubber,
Strengthening resin and transparent agent, 10min is to being uniformly dispersed in stirring, is warming up to 43～47 C, continues stirring 2h, is cooled to room temperature i.e.
Can.
(2) prepared by B component.
Polymerization monomer and stabilizer are put in Scattered Kettle, starts stirring, be sequentially added into firming agent, strengthen resin and anti-reflection
Agent, 10min is to being uniformly dispersed in stirring, is warming up to 43～47 C, continues stirring 2h, is cooled to room temperature.
The present invention compared with prior art, has following features.
Cold curing speed is fast, it is not necessary to strict measurement, easy to use, and adhesives kind is many, applied widely；Have
Stronger adhesive strength and good electric property；There is good resistance to medium and ageing resistance；Glue-line have high transparent,
High tenacity, good impact resistance, it is adaptable to household supplies, industrial art, high-grade ornament bonding.
Detailed description of the invention
Below in conjunction with specific embodiment to a kind of high tenacity transparent two-component acrylicester adhesive of the present invention
And preparation method thereof be described further, particular make-up is listed in table 1.Be necessary it is pointed out here that be that the present embodiment is only used for example
Card, protection scope of the present invention does not limit to illustration category.
Embodiment 1.
A kind of composition and ratio of high tenacity transparent two-component acrylicester adhesive.
| Component A | B component | |
| Methyl methacrylate | 50g | 60g |
| Hydroxyethyl methylacrylate | 5g | 1.2g |
| Methacrylic acid | 6.4g | 1.7g |
| Nitrile rubber (N230S) | 2g | — |
| Polymethyl methacrylate (PMMA) | 32g | 32g |
| Isopropyl benzene hydroperoxide | — | 5g |
| Tetramethyl thiourea | 2.5g | — |
| Triethylamine | 2.1g | — |
| Hydroquinone | 0.01g | 0.1g |
Preparation method is as follows.
Component A-methyl methacrylate, hydroxyethyl methylacrylate, methacrylic acid and hydroquinone are put into dispersion
In still, start stirring, be sequentially added into tetramethyl thiourea, triethylamine, nitrile rubber (N230S) and polymethyl methacrylate
(PMMA), 10min is to being uniformly dispersed in stirring, is warming up to 45 C, continues stirring 2h, is cooled to room temperature, can make with B component collocation
With.
B component-methyl methacrylate, hydroxyethyl methylacrylate, methacrylic acid and hydroquinone are put into dispersion
In still, starting stirring, be sequentially added into isopropyl benzene hydroperoxide and polymethyl methacrylate (PMMA), stirring 10min is to dispersion
Uniformly, it is warming up to 45 C, continues stirring 2h, be cooled to room temperature, can use with component A collocation.
Embodiment 2.
A kind of composition and ratio of high tenacity transparent two-component acrylicester adhesive.
Preparation method is as follows.
Component A-methyl methacrylate, hydroxyethyl methylacrylate, methacrylic acid and 1,4-benzoquinone are put into Scattered Kettle
In, start stirring, be sequentially added into vinylthiourea, triethylamine, chlorosulfonated polyethylene (CSM2910) and polymethyl methacrylate
(PMMA), 10min is to being uniformly dispersed in stirring, is warming up to 45 C, continues stirring 2h, is cooled to room temperature, can make with B component collocation
With；
B component-methyl methacrylate, hydroxyethyl methylacrylate, methacrylic acid and 1,4-benzoquinone are put in Scattered Kettle, opens
Dynamic stirring, is sequentially added into isopropyl benzene hydroperoxide, ABS resin and polymethyl methacrylate (PMMA), and stirring 10min is to dispersion
Uniformly, it is warming up to 45 C, continues stirring 2h, be cooled to room temperature, can use with component A collocation.
Embodiment 3.
A kind of composition and ratio of high tenacity transparent two-component acrylicester adhesive.
| Component A | B component | |
| Methyl methacrylate | 50g | 55g |
| Methacrylic acid | 14.5g | 3g |
| Acrylic acid | 7g | 6.9g |
| Nitrile rubber (N230S) | 7g | — |
| Transparent butadiene-styrene impact resin (3G55) | 5g | 5g |
| Epoxy resin E51 | 13g | 25g |
| Benzoyl peroxide | — | 5g |
| Tetramethyl thiourea | 1.5g | — |
| Vinylthiourea | 2g | — |
| Hydroquinone | 0.01g | 0.1g |
Preparation method is as follows.
Component A-methyl methacrylate, methacrylic acid, acrylic acid and hydroquinone are put in Scattered Kettle, starts and stirs
Mix, be sequentially added into tetramethyl thiourea, vinylthiourea, nitrile rubber (N230S), transparent butadiene-styrene impact resin (3G55) and epoxy
Resin E51,10min is to being uniformly dispersed in stirring, is warming up to 45 C, continues stirring 2h, is cooled to room temperature, can arrange in pairs or groups with B component
Use.
B component-methyl methacrylate, methacrylic acid, acrylic acid and hydroquinone are put in Scattered Kettle, starts and stirs
Mixing, be sequentially added into benzoyl peroxide, transparent butadiene-styrene impact resin (3G55) and epoxy resin (E51), stirring 10min is to dispersion
Uniformly, it is warming up to 45 C, continues stirring 2h, be cooled to room temperature, can use with component A collocation.
The high tenacity transparent two-component acrylicester adhesive prepared by said method, by HGT 3827-2006 to its property
Can detect.Testing result row and table 1.
Table 1 embodiment testing result.
Result shows, the performance of the high tenacity transparent two-component acrylicester adhesive of gained of the present invention fully meets standard
Requirement.
It is to be understood that above with respect to the specific descriptions of the present invention, be merely to illustrate the present invention and be not limited to this
Technical scheme described by inventive embodiments, it will be understood by those within the art that, still can carry out the present invention
Amendment or equivalent, to reach identical technique effect；As long as meet use needs, all protection scope of the present invention it
In.
Claims (9)
1. a high tenacity transparent two-component acrylicester adhesive, it is characterised in that with weight, including A group
Part and B component:
Component A includes:
Polymerization monomer 60.0～80.0%；
Toughening rubber 0～10.0%；
Strengthen resin 0～15.0%；
Transparent agent 10.0～35.0%；
Reduction accelerator 2.0～5.0%；
Stabilizer 0～0.01%；
B component includes:
Polymerization monomer 60.0～80.0%；
Strengthen resin 0～20.0%；
Transparent agent 5.0～35.0%；
Firming agent 2.0～5.5%；
Stabilizer 0～0.1%.
A kind of high tenacity transparent two-component acrylicester adhesive the most according to claim 1, it is characterised in that: described
Polymerization monomer be in methyl methacrylate, hydroxyethyl methylacrylate, methacrylic acid, acrylic acid one or both and more than
The mixture of monomer.
A kind of high tenacity transparent two-component acrylicester adhesive the most according to claim 2, it is characterised in that: described
Toughening rubber is one or both mixture in chlorosulfonated polyethylene and nitrile rubber.
A kind of high tenacity transparent two-component acrylicester adhesive the most according to claim 3, it is characterised in that: described
Strengthening resin is one or both and the above mixing in modified hydroxy propylene acid resin, ABS resin, transparent butadiene-styrene impact resin
Thing.
A kind of high tenacity transparent two-component acrylicester adhesive the most according to claim 4, it is characterised in that: described
Transparent agent is one or both and above mixture in polymethyl methacrylate, epoxy resin, unsaturated polyester (UP).
A kind of high tenacity transparent two-component acrylicester adhesive the most according to claim 5, it is characterised in that: described
Reduction accelerator is one or both and above mixing in triethylamine, vinylthiourea, tetramethyl thiourea, cobalt iso-octoate
Thing.
A kind of high tenacity transparent two-component acrylicester adhesive the most according to claim 6, it is characterised in that: described
Firming agent is one or both and above mixing in isopropyl benzene hydroperoxide, benzoyl peroxide, tert-butyl hydroperoxide
Thing.
A kind of high tenacity transparent two-component acrylicester adhesive the most according to claim 7, it is characterised in that: described
Stabilizer be hydroquinone, 2, one or both and the above mixture in 6-di-tert-butyl-4-methy phenol, 1,4-benzoquinone.
9. according to the preparation method of the arbitrary described high tenacity transparent two-component acrylicester adhesive of claim 1～8, its
It is characterised by, specifically comprises the following steps that
Prepared by component A:
Monomer will be polymerized and stabilizer will put in Scattered Kettle, and start stirring, be sequentially added into reduction accelerator, toughening rubber, enhancing
Resin and transparent agent, 10min is to being uniformly dispersed in stirring, is warming up to 43～47 C, continues stirring 2h, is cooled to room temperature；
Prepared by B component:
Monomer will be polymerized and stabilizer will put in Scattered Kettle, start stirring, and be sequentially added into firming agent, strengthen resin and transparent agent,
10min is to being uniformly dispersed in stirring, is warming up to 43～47 C, continues stirring 2h, is cooled to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610655896.6A CN106189886A (en) | 2016-08-12 | 2016-08-12 | A kind of high tenacity transparent two-component acrylicester adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610655896.6A CN106189886A (en) | 2016-08-12 | 2016-08-12 | A kind of high tenacity transparent two-component acrylicester adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106189886A true CN106189886A (en) | 2016-12-07 |
Family
ID=57514971
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610655896.6A Pending CN106189886A (en) | 2016-08-12 | 2016-08-12 | A kind of high tenacity transparent two-component acrylicester adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106189886A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251702A (en) * | 2018-09-06 | 2019-01-22 | 上海回天新材料有限公司 | A kind of acrylate solder joint protective glue |
| WO2020178105A1 (en) | 2019-03-01 | 2020-09-10 | Zephyros, Inc. | Acrylate structural adhesive |
| CN114634779A (en) * | 2022-03-01 | 2022-06-17 | 哥俩好新材料股份有限公司 | Hybrid acrylate AB adhesive and preparation method thereof |
| CN116731615A (en) * | 2023-06-08 | 2023-09-12 | 宁波鑫智达新材料有限公司 | Double-component acrylic adhesive and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103725206A (en) * | 2014-01-06 | 2014-04-16 | 江苏东禾电声配件有限公司 | Two-component high-temperature-resisting adhesive for assembling loudspeaker and preparation method thereof |
-
2016
- 2016-08-12 CN CN201610655896.6A patent/CN106189886A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103725206A (en) * | 2014-01-06 | 2014-04-16 | 江苏东禾电声配件有限公司 | Two-component high-temperature-resisting adhesive for assembling loudspeaker and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 宋启煌等: "《高等学校教材 精细化工工艺学 （第二版）》", 31 July 2004, 化学工业出版社教材出版中心 * |
| 熊腊森: "《粘接手册》", 31 August 2008, 机械工业出版 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251702A (en) * | 2018-09-06 | 2019-01-22 | 上海回天新材料有限公司 | A kind of acrylate solder joint protective glue |
| WO2020178105A1 (en) | 2019-03-01 | 2020-09-10 | Zephyros, Inc. | Acrylate structural adhesive |
| CN113767120A (en) * | 2019-03-01 | 2021-12-07 | 泽费罗斯股份有限公司 | Acrylate structural adhesive |
| CN113767120B (en) * | 2019-03-01 | 2023-11-07 | 泽费罗斯股份有限公司 | Acrylic Structural Adhesive |
| CN114634779A (en) * | 2022-03-01 | 2022-06-17 | 哥俩好新材料股份有限公司 | Hybrid acrylate AB adhesive and preparation method thereof |
| CN116731615A (en) * | 2023-06-08 | 2023-09-12 | 宁波鑫智达新材料有限公司 | Double-component acrylic adhesive and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106189886A (en) | A kind of high tenacity transparent two-component acrylicester adhesive and preparation method thereof | |
| CN105219317B (en) | A kind of glutinous agent of the medical polyacrylate pressure-sensitive adhesive of environmental protection | |
| CN101362929B (en) | Emulsion type adhesive for paper and plastics and preparation method thereof | |
| CN102850973A (en) | Low-water-absorptivity acrylate structural adhesive and preparation method thereof | |
| CN103074000A (en) | Novel environmental-friendly double-component acrylate adhesive and preparation method thereof | |
| TW200504170A (en) | Pressure-sensitive adhesive composition and pressure-sensitive adhesive product | |
| CN100489047C (en) | Process for preparing acrylic acid emulsion adhesive for rubber | |
| CN101679709A (en) | Cyanoacrylate compositions containing dispersions of core shell rubbers in (meth)acrylates | |
| EP2090617A4 (en) | (meth)acrylic resin composition, imidized (meth)acrylic resin composition, and film obtained by molding them | |
| CN106753087A (en) | A kind of aqueous, environmental protective all-purpose adhesive and preparation method thereof | |
| CN109777308A (en) | A kind of low-odor acrylate adhesive and preparation method thereof for horizontal ruler bonding | |
| JPH06145606A (en) | Cyanoacrylate adhesive composition | |
| AR112991A1 (en) | PRESSURE SENSITIVE WATER-BASED ADHESIVE COMPOSITIONS AND METHODS OF MANUFACTURING THEM | |
| CN108084927A (en) | A kind of water soluble acrylic acid adhesive and preparation method thereof | |
| JP2011241342A (en) | Two-component curing type acrylic adhesive | |
| CN110684488A (en) | Removable adhesive formula | |
| KR102360748B1 (en) | composition | |
| CN109735236A (en) | A kind of development of low smell bicomponent structure bonding acrylic adhesive | |
| CN103421265B (en) | Transparent PMMA flexibilizer | |
| CN103773287B (en) | A kind of Water-Soluble Emulsion Adhesive and preparation method thereof | |
| KR101920242B1 (en) | High performance water-soluble acrylic adhesive compositon and the preparation method thereof | |
| BR112022003792A2 (en) | Adhesive composition and article | |
| JPH04272980A (en) | Adhesive composition | |
| CN105802420B (en) | One kind is based on the luminous styrene-acrylic emulsion preparation method and applications of carbazole | |
| CN106519998A (en) | Water-based adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |