CN102816534A - Structure adhesive for metal adhesion, and preparation method thereof - Google Patents
Structure adhesive for metal adhesion, and preparation method thereof Download PDFInfo
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- CN102816534A CN102816534A CN2012102870838A CN201210287083A CN102816534A CN 102816534 A CN102816534 A CN 102816534A CN 2012102870838 A CN2012102870838 A CN 2012102870838A CN 201210287083 A CN201210287083 A CN 201210287083A CN 102816534 A CN102816534 A CN 102816534A
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Abstract
The present invention relates to a two-component acrylate structure adhesive and a preparation method thereof. The adhesive is prepared by matching a component A and a component B according to a mass part ratio of 1:1, wherein the component A comprises, by mass, 40-80 parts of an acrylate monomer, 10-40 parts of a toughening resin, 0.2-10 parts of an initiator, 0.01-1 part of a stabilizer, 0.2-5 parts of a coupling agent, and 0.2-10 parts of a thixotropic agent, and the component B comprises, by mass, 40-80 parts of an acrylate monomer, 10-40 parts of a toughening resin, 0.2-10 parts of an accelerator, 0.01-1 part of a stabilizer, 0.2-5 parts of a coupling agent, and 0.2-10 parts of a thixotropic agent. The adhesive of the present invention is rapidly cured at a room temperature, provides good adhesion effects for zinc, nickel, chromium and other metals, and has characteristics of room temperature storage, stable performance, and long storage period.
Description
Technical field
The present invention relates to a kind of two-component acrylicester structural adhesive, be specifically related to two-component acrylicester structural adhesive of metal stickings such as a kind of metal that is applicable to, particularly zinc, nickel, chromium and preparation method thereof.。
Background technology
Adopt sizing agent to metallic substance carry out bondingly being superior to traditional welding in some aspects, technology such as rivet, be spirally connected, especially the defect mending to metalwork has more unique effect with maintenance.Bondingly can not look like welding and change, can not look like riveted joint yet, be spirally connected and cause stress concentration and intensity reduction because of the boring hitch because of heat causes structural distortion and metallographic structure.Will obtain satisfied metal sticking effect as long as the choosing gummed is fitted, joint is reasonable, technology is proper.
Represent s-generation acrylate adhesive to have plurality of advantages such as quick solidifying, intensity height, good toughness, flexibility be strong as the typical case of esters of acrylic acid sizing agent.But be applicable to metal sticking on the market, the two-component acrylicester structural adhesive that is specially adapted to metal stickings such as zinc, nickel, chromium is of less types.For this reason, develop this series products and show necessary especially.
Summary of the invention
The object of the present invention is to provide a kind of metal sticking that is used for, be specially adapted to two-component acrylicester structural adhesive of metal stickings such as zinc, nickel, chromium and preparation method thereof.
For realizing above-mentioned technical purpose, concrete technical scheme of the present invention is:
Propose a kind of two-component acrylicester structure glue sizing agent, said two-component acrylicester structure glue sizing agent carries out proportioning by A component and B component by mass fraction 1:1;
Described A components in mass portion number is made up of following raw material:
40 parts ~ 80 parts of acrylic ester monomers,
10 parts ~ 40 parts of toughened resins,
0.2 part ~ 10 parts of initiators,
0.01 part ~ 1 part of stablizer,
0.2 ~ 5 part of coupling agent,
0.2 ~ 10 part of thixotropic agent;
Described B components in mass portion number is made up of following raw material:
40 parts ~ 80 parts of acrylic ester monomers,
10 parts ~ 40 parts of toughened resins,
0.2 part ~ 10 parts of promotor,
0.01 part ~ 1 part of stablizer,
0.2 ~ 5 part of coupling agent,
0.2 ~ 10 part of thixotropic agent.
Said acrylic ester monomer is a TEB 3K, (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, (methyl) vinylformic acid tetrahydrofuran ester; 2-benzene oxygen ethyl-methyl propenoate, (methyl) IBOA, (methyl) n-butyl acrylate, (methyl) lauryl acrylate; (methyl) tetradecyl acrylate, (methyl) Process Conditions of Cetane Acrylate, (methyl) octadecyl acrylate, (methyl) vinylformic acid; Phenylformic acid, methylene-succinic acid, Sorbic Acid, m-phthalic acid; TGM 1, ethoxyquin double A diacrylate, one or more in the 1,4 butanediol diacrylate.
Said toughened resin is an X 050, paracril, styrene-butadiene rubber(SBR), MBS resin, ABS resin, urethane resin, propenoate quasi-oligomer, one or more in the epoxy modified acrylic resin.
Said initiator is a Lucidol, isopropyl benzene hydroperoxide, tertbutyl peroxide, one or more in the cyclohexanone peroxide.
Said promotor is triethylamine, N, accelerine, N, N-dimethyl-p-toluidine, vinyl thiocarbamide, tetramethyl thiourea, cobalt naphthenate, cobalt iso-octoate, cobalt octoate, vanadium acetylacetonate, ferric acetyl acetonade, one or more in butyraldehyde-n-aniline condensation thing.
Said stablizer is a Resorcinol, quinhydrone(s), 2,6 di tert butyl 4 methyl phenol, one or more among the Na2EDTA.
Said coupling agent is γ-An Bingjisanyiyangjiguiwan (KH 550), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH 560), one or more in γ-methacryloxypropyl trimethoxy silane (KH570).
Said thixotropic agent is an organobentonite, aerosil, THIXCIN, one or more in the polyethylene wax.
The present invention also proposes a kind of preparation method of described two-component acrylicester structure glue sizing agent, and said preparation method comprises:
The preparation of A component: acrylic ester monomer is mixed, add stablizer and coupling agent successively, the toughened resin adding is stirred, the initiator adding is stirred again, add thixotropic agent at last and stir, the froth in vacuum discharging gets the A component;
The preparation of B component: acrylic ester monomer is mixed, add stablizer and coupling agent successively, the toughened resin adding is stirred, stirred promotor adding again, add thixotropic agent at last and stir, the froth in vacuum discharging gets the B component.
Beneficial effect of the present invention:
1. the normal temperature fast setting is good for the adhesive effect of metals such as zinc, nickel, chromium.
2. normal temperature storage, stable performance, storage period is long.
Embodiment
For making the object of the invention, technical scheme and advantage clearer, below in conjunction with specific embodiment, to further explain of the present invention.
Embodiment 1
| The component title | The A component | The B component |
| The methylacrylic acid tetrahydrofuran ester | 32 | 28 |
| 2-benzene oxygen ethyl-methyl propenoate | 12 | 14 |
| Methylacrylic acid | 4 | 4 |
| Toxilic acid | 4 | 4 |
| Isooctyl methacrylate | 8 | 10 |
| Paracril | 20 | 18 |
| The MBS resin | 15 | 17 |
| KH570 | 1 | 1 |
| Resorcinol | 0.05 | 0.05 |
| 2,6 di tert butyl 4 methyl phenol | 0.05 | 0.05 |
| N, accelerine | 0.8 | |
| Cobalt iso-octoate | 0.2 | |
| Isopropyl benzene hydroperoxide | 2.2 | |
| Aerosil | 2 | 2 |
Preparation technology:
A component preparation: accurately take by weighing methylacrylic acid tetrahydrofuran ester, 2-phenoxy ethyl-methyl propenoate, methylacrylic acid, toxilic acid and Isooctyl methacrylate, mix; Adding KH570, Resorcinol and 2,6 di tert butyl 4 methyl phenol mixes; Then paracril and MBS resin are added successively, it is dissolved fully; Add isopropyl benzene hydroperoxide and aerosil again, and stir; Last froth in vacuum, discharging promptly gets the A component.
B component preparation: accurately take by weighing after methylacrylic acid tetrahydrofuran ester, 2-benzene oxygen ethyl-methyl propenoate, methylacrylic acid, toxilic acid and Isooctyl methacrylate mix; Add KH570, Resorcinol and 2,6 di tert butyl 4 methyl phenol and mix, then paracril and MBS resin are added successively; It is dissolved fully; With N, accelerine and cobalt iso-octoate and aerosil add, and stir again.Last froth in vacuum, discharging promptly gets the B component.
Embodiment 2
| The component title | The A component | The B component |
| TEB 3K | 27 | 25 |
| Rocryl 400 | 15 | 17 |
| Methylacrylic acid | 6 | 6 |
| TGM 1 | 4 | 4 |
| N-BMA | 8 | 7 |
| Paracril | 19 | 18 |
| ABS resin | 14 | 16 |
| KH570 | 1 | 1 |
| Para benzoquinone | 0.05 | 0.05 |
| 2,6 di tert butyl 4 methyl phenol | 0.05 | 0.05 |
| Tetramethyl thiourea | 1.5 | |
| Cobalt naphthenate | 0.6 | |
| The Lucidol tert-butyl ester | 1.9 | |
| Aerosil | 3.5 | 3.5 |
Preparation technology:
A component preparation: accurately take by weighing TEB 3K, Rocryl 400, methylacrylic acid, TGM 1, n-BMA and mix; Add KH570, para benzoquinone and 2,6 di tert butyl 4 methyl phenol are mixed; Then paracril and ABS resin are added successively, it is dissolved fully; Add tertbutyl peroxide and aerosil again, and stir; Last froth in vacuum, discharging promptly gets the A component.
B component preparation: accurately take by weighing TEB 3K, Rocryl 400, methylacrylic acid, TGM 1, n-BMA and mix; Add KH570, para benzoquinone and 2,6 di tert butyl 4 methyl phenol are mixed; Then paracril and ABS resin are added successively, it is dissolved fully; Add cobalt naphthenate, tetramethyl thiourea and aerosil again, and stir; Last froth in vacuum, discharging promptly gets the B component.
According to GB/T 7124-2008 test shearing resistance,, see table 1 according to GB/T 7122-1996 test stripping strength.
[0023] the mutual bonding test of table 1 metallic substance
Above-described specific embodiment; The object of the invention, technical scheme and beneficial effect have been carried out further detailed description, and institute it should be understood that the above is merely specific embodiment of the present invention; Be not limited to the present invention; All within spirit of the present invention and principle, any modification of being made, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (9)
1. a two-component acrylicester structure glue sizing agent is characterized in that, said two-component acrylicester structure glue sizing agent carries out proportioning by A component and B component by mass fraction 1:1;
Described A components in mass portion number is made up of following raw material:
40 parts ~ 80 parts of acrylic ester monomers,
10 parts ~ 40 parts of toughened resins,
0.2 part ~ 10 parts of initiators,
0.01 part ~ 1 part of stablizer,
0.2 ~ 5 part of coupling agent,
0.2 ~ 10 part of thixotropic agent;
Described B components in mass portion number is made up of following raw material:
40 parts ~ 80 parts of acrylic ester monomers,
10 parts ~ 40 parts of toughened resins,
0.2 part ~ 10 parts of promotor,
0.01 part ~ 1 part of stablizer,
0.2 ~ 5 part of coupling agent,
0.2 ~ 10 part of thixotropic agent.
2. two-component acrylicester structure glue sizing agent according to claim 1 is characterized in that said acrylic ester monomer is a TEB 3K, (methyl) Hydroxyethyl acrylate; (methyl) Propylene glycol monoacrylate, (methyl) vinylformic acid tetrahydrofuran ester, 2-benzene oxygen ethyl-methyl propenoate, (methyl) IBOA; (methyl) n-butyl acrylate, (methyl) lauryl acrylate, (methyl) tetradecyl acrylate, (methyl) Process Conditions of Cetane Acrylate; (methyl) octadecyl acrylate, (methyl) vinylformic acid, phenylformic acid, methylene-succinic acid; Sorbic Acid, m-phthalic acid, TGM 1; Ethoxyquin double A diacrylate, one or more in the 1,4 butanediol diacrylate.
3. two-component acrylicester structure glue sizing agent according to claim 2 is characterized in that said toughened resin is an X 050, paracril; styrene-butadiene rubber(SBR), MBS resin, ABS resin; urethane resin, propenoate quasi-oligomer, one or more in the epoxy modified acrylic resin.
4. two-component acrylicester structure glue sizing agent according to claim 3 is characterized in that said initiator is a Lucidol, isopropyl benzene hydroperoxide, tertbutyl peroxide, one or more in the cyclohexanone peroxide.
5. two-component acrylicester structure glue sizing agent according to claim 4 is characterized in that said promotor is triethylamine, N; Accelerine, N, N-dimethyl-p-toluidine, vinyl thiocarbamide; Tetramethyl thiourea, cobalt naphthenate, cobalt iso-octoate, cobalt octoate; Vanadium acetylacetonate, ferric acetyl acetonade, one or more in butyraldehyde-n-aniline condensation thing.
6. two-component acrylicester structure glue sizing agent according to claim 5 is characterized in that said stablizer is a Resorcinol, quinhydrone(s), 2,6 di tert butyl 4 methyl phenol, one or more among the Na2EDTA.
7. two-component acrylicester structure glue sizing agent according to claim 6; It is characterized in that; Said coupling agent is γ-An Bingjisanyiyangjiguiwan (KH 550); γ-glycidyl ether oxygen propyl trimethoxy silicane (KH 560), one or more in γ-methacryloxypropyl trimethoxy silane (KH570).
8. two-component acrylicester structure glue sizing agent according to claim 1 is characterized in that said thixotropic agent is an organobentonite, aerosil, THIXCIN, one or more in the polyethylene wax.
9. preparation method like the described two-component acrylicester structure glue of claim 1-8 sizing agent is characterized in that said preparation method comprises:
The preparation of A component: acrylic ester monomer is mixed, add stablizer and coupling agent successively, the toughened resin adding is stirred, the initiator adding is stirred again, add thixotropic agent at last and stir, the froth in vacuum discharging gets the A component;
The preparation of B component: acrylic ester monomer is mixed, add stablizer and coupling agent successively, the toughened resin adding is stirred, stirred promotor adding again, add thixotropic agent at last and stir, the froth in vacuum discharging gets the B component.
Priority Applications (1)
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| CN201210287083.8A CN102816534B (en) | 2012-08-14 | 2012-08-14 | Structure adhesive for metal adhesion, and preparation method thereof |
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|---|---|---|---|
| CN201210287083.8A CN102816534B (en) | 2012-08-14 | 2012-08-14 | Structure adhesive for metal adhesion, and preparation method thereof |
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| CN102816534A true CN102816534A (en) | 2012-12-12 |
| CN102816534B CN102816534B (en) | 2014-05-07 |
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| CN111662654A (en) * | 2020-07-23 | 2020-09-15 | 北京高盟新材料股份有限公司 | Long-operation-time two-component acrylate structural adhesive and preparation method thereof |
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| CN112961612B (en) * | 2021-03-12 | 2022-07-26 | 江苏大力士投资有限公司 | High-strength high-weather-resistance rock plate adhesive and preparation method thereof |
| CN113372867A (en) * | 2021-06-28 | 2021-09-10 | 鲁东大学 | High-hardness polishable acrylic acid two-component structural adhesive for repairing and preparation method thereof |
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