CN102757602B - Composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications - Google Patents
Composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications Download PDFInfo
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- CN102757602B CN102757602B CN201210285865.8A CN201210285865A CN102757602B CN 102757602 B CN102757602 B CN 102757602B CN 201210285865 A CN201210285865 A CN 201210285865A CN 102757602 B CN102757602 B CN 102757602B
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Abstract
The invention discloses a composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications. The composite material comprises, by weight, 10 to 30 parts of polypropylene, 40 to 60 parts of silicon oxide series inorganic fiber, 8 to 15 parts of polyamide series organic fiber, 8 to 15 parts of polyphosphazene oligomer, 1 to 5 parts of antioxidant and 1 to 5 parts of flow modifier. The materials are manufactured through melt blending, extruding and granulation. The composite material has good impact resistance, and no heavy metal or radioactivity; the composite material is bending resistant, deformation resistant, fire proof and corrosion resistant; high sintering is not needed, the production technology is advanced, and the automation degree is high; the composite material is low-carbon and environment friendly, can be recycled, and is firmly bonded to walls and grounds, convenient to construct, and mainly used in building material decoration of interior walls, grounds, ceiling, trim strips, doors, windows, cabinets and the like.
Description
Technical field
The present invention relates to a kind of building decoration material, particularly, relate to a kind of thermoplastic composite for products such as inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door and window, cabinets and purposes.
Background technology
At present, composite inner wall, ground lines mainly contain two kinds: a kind of is full wafer marble, and its resource is increasingly exhausted; Another kind is the ceramic tile fired with potter's clay.Existing marble composite board base material is grouan or ceramic tile, and its shortcoming is its high energy consumption, maximum discharge, high pollution, has radioactivity and contains harmful heavy metal, and cannot recycle.In addition, because ceramic tile is high-temperature firing product, yielding thus cause surface irregularity in sintering procedure, easily to ftracture, broken.The marble composite board be attached on metope also easily ftractures, broken situation, and crushed product more causes secondary pollution source.In addition, marble line need be processed with the stone of marble of monoblock, grinds required concavo-convex lines, except wasting a large amount of raw material stone materials, also needs the manpower of at substantial, simultaneously again can to environment.
China's natural marble scarcity of resources, need a large amount of from external import, price is high; Containing heavy metal, have radiation to human body, product can not recycle.And use polymer composite to do base material; without the need to high temperature sintering; without condemnation factor; can recycle; and carry out special surface protection again after application 3D ink-jet technology treat surface; its pattern and color more plentiful and true to nature, be the novel equivalent material of the products such as desirable interior wall, ground, furred ceiling, ornamental strip, door and window, cabinet.
Summary of the invention
The object of this invention is to provide a kind of polymer composite and do base material, it has good shock resistance, "dead", indeformable containing heavy metal, anti-crimping, fire prevention, corrosion-resistant; Without the need to high temperature sintering, production technique is advanced, and level of automation is high, low-carbon environment-friendly and pollution-free, can be recycled, bonds firmly, easy construction with wall, ground.
In order to achieve the above object, the invention provides a kind of for pushing up, wall, ground, lines, door and window, cabinet matrix material, this matrix material comprises the following raw material counted by weight:
Polypropylene 10-30 part;
Silicon oxide series inorganic fibre 40-60 part;
Polyamide-based organic fibre 8-15 part;
Poly phosphazene oligopolymer 8-15 part;
Oxidation inhibitor 1-5 part;
Flow ability modifying agent 1-5 part.
Above-mentioned for pushing up, wall, ground, lines, door and window, cabinet matrix material, wherein, described compound material comprises the colorant counting 1-3 part by weight.
Above-mentioned for pushing up, wall, ground, lines, door and window, cabinet matrix material, wherein, the length-to-diameter ratio of described silicon oxide series inorganic fibre is 15-20:1.
Above-mentioned for pushing up, wall, ground, lines, door and window, cabinet matrix material, wherein, described polyamide-based organic fibre length is 2-5mm.
Above-mentioned for pushing up, wall, ground, lines, door and window, cabinet matrix material, wherein, described matrix material is made by melt blending, granulation by described raw material.
Present invention also offers a kind of according to above-mentioned for pushing up, wall, ground, lines, door and window, cabinet the preparation method of matrix material, described preparation method comprises: joined in proportion in forcing machine by raw material, and heating, melt blending, extrudes, granulation.
Present invention also offers a kind of purposes of above-mentioned matrix material, this matrix material is for the preparation of building decoration parts such as top, wall, ground, lines, door and window, cabinets, and described top, wall, ground refer between kitchen or ceiling material, inner wall finishing, the ground decoration plate of toilet; Described lines refer to ornamental strip.Preferably, this matrix material prepares the building decoration parts such as inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window and cabinet by injection moulding, extrusion molding or pressing process.
Because matrix material of the present invention is thermoplasticity, lines can an extrusion moulding, according to design and can need the lines making any concaveconvex shape, and greatly save starting material and manpower.And this ornamental strip is the same with wall ground, can not ftracture.
Traditional urethane limits its Application Areas due to shortcomings such as its heat-resisting cold tolerance, flame retardant properties and hydrophobic performance are not enough.The present invention is under the prerequisite of mechanical property of unduly sacrificing urethane, utilize phosphine nitrile oligopolymer high-performance to improve the heat-resisting cold tolerance of urethane, flame retardant properties and hydrophobic performance, prepare a kind of novel architectural decoration matrix material, there is good shock resistance, without radiation, indeformable containing heavy metal, anti-crimping, fire prevention, waterproof, corrosion-resistant; And boning firmly with wall, ground, easy construction, mainly for the preparation of building decoration parts such as inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window and cabinets.
Accompanying drawing explanation
Fig. 1 is the sheet for architectural decoration such as top, wall, ground, lines, door and window, cabinet prepared by matrix material of the present invention, through UV color painting, and, the structural representation of UV top coat conservation treatment.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is described further.
Embodiment 1
Count by weight,
Polypropylene 30 parts;
Length-to-diameter ratio is the silicon oxide series inorganic fibre 45 parts of 15:1;
Polyamide-based organic fibre 10 parts;
Poly phosphazene oligopolymer 12 parts;
2 parts, oxidation inhibitor;
Flow ability modifying agent 1 part.
Described polypropylene particles is M700 polypropylene particles; Polyamide-based organic fibre length is 5 millimeters, the preferred antioxidant 1010 of oxidation inhibitor, and described flow ability modifying agent is modification ethylene bis-fatty acid imide.
Step 1, prepares composite particles: according to formula ratio by above-mentioned raw materials abundant mixing and stirring in stirrer, quantitatively joined in the hopper of twin screw extruder by mixed raw material, hot briquetting by charging opening and bypass charging opening; Then extruded by forcing machine die orifice, obtain strip matrix material, then this strip matrix material is placed in tank is down to room temperature.Strip matrix material after cooling is put into nodulizer and is processed into granular composite particles; This composite particles is put into the baking oven heating, drying of 100 DEG C ~ 120 DEG C, removing moisture.
Step 2, injection molding: the composite particles of oven dry is joined in the barrel of injection moulding machine, heat and make composite particles melting, in computer program according to the material usage input injection moulding machine of the single product that will produce, start injection moulding machine injection sequence of control, adopting injection screw to advance is expelled in metal die by the matrix material in barrel, the water coolant of 5 DEG C ~ 10 DEG C is injected in the cold runner of metal die, make product cooling and shaping, open mould, take out shaping goods with taking mechanical hand.
Embodiment 2
Count by weight,
Polypropylene 20 parts;
Length-to-diameter ratio is the silicon oxide series inorganic fibre 40 parts of 15:1;
Length-to-diameter ratio is the silicon oxide series inorganic fibre 20 parts of 20:1;
Polyamide-based organic fibre 8 parts;
Poly phosphazene oligopolymer 8 parts;
1 part, oxidation inhibitor;
Flow ability modifying agent 2 parts;
Toner 1 part.
Described polypropylene particles is that M2600 polypropylene particles mixes by 1:1 with M700 polypropylene particles; The polyamide-based organic fibre that polyamide-based organic fibre to be length be polyamide-based organic fibre and the length of 2 millimeters is 5 millimeters mixes by 1:1, and the preferred antioxidant 1010 of oxidation inhibitor, described flow ability modifying agent selects modification ethylene bis-fatty acid imide.
The architectural decoration products such as required inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window (espespecially window frame), cabinet are prepared by the method for embodiment 1.
Embodiment 3
Count by weight,
Polypropylene 10 parts;
Length-to-diameter ratio is the silicon oxide series inorganic fibre 40 parts of 15:1;
Length-to-diameter ratio is the silicon oxide series inorganic fibre 15 parts of 20:1;
Polyamide-based organic fibre 8 parts;
Poly phosphazene oligopolymer 15 parts;
4 parts, oxidation inhibitor;
Flow ability modifying agent 5 parts;
Titanium dioxide 3 parts.
Described polypropylene particles is M2600 polypropylene particles; Polyamide-based organic fibre length is 2 millimeters, the preferred antioxidant 1010 of oxidation inhibitor, and described flow ability modifying agent selects modification ethylene bis-fatty acid imide.
The architectural decoration products such as required inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window (espespecially window frame), cabinet are prepared by the method for embodiment 1.
Embodiment 4
Count by weight,
Polypropylene 26 parts;
Length-to-diameter ratio is the silicon oxide series inorganic fibre 40 parts of 20:1;
Polyamide-based organic fibre 15 parts;
Poly phosphazene oligopolymer 10 parts;
3 parts, oxidation inhibitor;
Flow ability modifying agent 4 parts;
Toner 2 parts.
Described polypropylene particles is that M2600 polypropylene particles mixes by 1:1 with M700 polypropylene particles; The polyamide-based organic fibre that polyamide-based organic fibre to be length be polyamide-based organic fibre and the length of 2 millimeters is 5 millimeters mixes by 2:1, and the preferred antioxidant 1010 of oxidation inhibitor, described flow ability modifying agent selects modification ethylene bis-fatty acid imide.
The architectural decoration products such as required inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window (espespecially window frame), cabinet are prepared by the method for embodiment 1.
After tested, the product appearance that this embodiment 1-4 obtains is sub-light, but smooth surface, there is high rigidity surface, energy anti-scratch; There is super hydrophobic surface, be not easy to make moist, and there is high tenacity, fire-retardant.
Thermoplastic composite of the present invention, except adopting injection moulding, also can adopt the building decoration parts such as architectural decoration product window and cabinet such as inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window (espespecially window frame), cabinet required for the processes such as extrusion molding, compacting one-tenth.
In some preferred embodiments, the polymer composite of embodiment of the present invention 1-4 is used to do base material 10, and application 3D ink-jet technology treat surface; after obtaining UV color painting layer 11; carry out special surface protection again, namely set up UV top coat protective layer 12, as shown in Figure 1.The building decoration parts obtained in those embodiments, pattern and color more plentiful and true to nature, be the novel equivalent material of the products such as desirable interior wall, ground, furred ceiling, ornamental strip, door and window, cabinet.
Although content of the present invention has done detailed introduction by above preferred embodiment, will be appreciated that above-mentioned description should not be considered to limitation of the present invention.After those skilled in the art have read foregoing, for multiple amendment of the present invention and substitute will be all apparent.Therefore, protection scope of the present invention should be limited to the appended claims.
Claims (6)
1. for pushing up, wall, ground, lines, door and window, cabinet a matrix material, it is characterized in that, described matrix material comprises the following raw material counted by weight:
Polypropylene 10-30 part;
Silicon oxide series inorganic fibre 40-60 part;
Polyamide-based organic fibre 8-15 part;
Poly phosphazene oligopolymer 8-15 part;
Oxidation inhibitor 1-5 part;
Flow ability modifying agent 1-5 part;
Described matrix material is made by melt blending, granulation by above-mentioned raw materials.
2. as claimed in claim 1 for pushing up, wall, ground, lines, door and window, cabinet matrix material, it is characterized in that, described matrix material comprises the colorant counting 1-3 part by weight.
3. as claimed in claim 1 or 2 for pushing up, wall, ground, lines, door and window, cabinet matrix material, it is characterized in that, the length-to-diameter ratio of described silicon oxide series inorganic fibre is 15-20:1.
4. as claimed in claim 3 for pushing up, wall, ground, lines, door and window, cabinet matrix material, it is characterized in that, described polyamide-based organic fibre length is 2-5mm.
5. the purposes of a matrix material according to claim 1, it is characterized in that, this matrix material is for the preparation of top, wall, ground, lines, door and window, cabinet, described top, wall, ground refer between kitchen or ceiling material, inner wall finishing, the ground decoration plate of toilet, and described lines refer to ornamental strip.
6. the purposes of matrix material as claimed in claim 5, is characterized in that, this matrix material prepares top, wall, ground, lines, door and window, cabinet by injection moulding, extrusion molding or pressing process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210285865.8A CN102757602B (en) | 2012-08-13 | 2012-08-13 | Composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210285865.8A CN102757602B (en) | 2012-08-13 | 2012-08-13 | Composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications |
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| Publication Number | Publication Date |
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| CN102757602A CN102757602A (en) | 2012-10-31 |
| CN102757602B true CN102757602B (en) | 2015-01-07 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062359A (en) * | 1990-12-14 | 1992-07-01 | 阿托化学公司 | Be used in particular for the composition based on polyphosphonitrile of mulching material |
| CN101747607A (en) * | 2009-12-25 | 2010-06-23 | 上海琥达投资发展有限公司 | Resin-based composite material sanitary ware hardware and preparation method thereof |
| CN101864108A (en) * | 2010-06-03 | 2010-10-20 | 上海琥达投资发展有限公司 | Wollastonite modified thermoplastic resin composite material and product preparation method thereof |
| CN102061032A (en) * | 2010-06-29 | 2011-05-18 | 上海琥达投资发展有限公司 | Thermoplastic resin composite material modified by nonmetallic material and method for preparing products |
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- 2012-08-13 CN CN201210285865.8A patent/CN102757602B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062359A (en) * | 1990-12-14 | 1992-07-01 | 阿托化学公司 | Be used in particular for the composition based on polyphosphonitrile of mulching material |
| CN101747607A (en) * | 2009-12-25 | 2010-06-23 | 上海琥达投资发展有限公司 | Resin-based composite material sanitary ware hardware and preparation method thereof |
| CN101864108A (en) * | 2010-06-03 | 2010-10-20 | 上海琥达投资发展有限公司 | Wollastonite modified thermoplastic resin composite material and product preparation method thereof |
| CN102061032A (en) * | 2010-06-29 | 2011-05-18 | 上海琥达投资发展有限公司 | Thermoplastic resin composite material modified by nonmetallic material and method for preparing products |
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