CN102757602A - Composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications - Google Patents

Composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications Download PDF

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Publication number
CN102757602A
CN102757602A CN2012102858658A CN201210285865A CN102757602A CN 102757602 A CN102757602 A CN 102757602A CN 2012102858658 A CN2012102858658 A CN 2012102858658A CN 201210285865 A CN201210285865 A CN 201210285865A CN 102757602 A CN102757602 A CN 102757602A
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China
Prior art keywords
matrix material
ground
parts
wall
lines
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CN2012102858658A
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Chinese (zh)
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CN102757602B (en
Inventor
池立群
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SHANGHAI XIWANG HI-TECH MATERIAL Co Ltd
SHANGHAI HUDA INVESTMENT DEVELOPMENT Co Ltd
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SHANGHAI XIWANG HI-TECH MATERIAL Co Ltd
SHANGHAI HUDA INVESTMENT DEVELOPMENT Co Ltd
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Application filed by SHANGHAI XIWANG HI-TECH MATERIAL Co Ltd, SHANGHAI HUDA INVESTMENT DEVELOPMENT Co Ltd filed Critical SHANGHAI XIWANG HI-TECH MATERIAL Co Ltd
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Publication of CN102757602A publication Critical patent/CN102757602A/en
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  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses a composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications. The composite material comprises, by weight, 10 to 30 parts of polypropylene, 40 to 60 parts of silicon oxide series inorganic fiber, 8 to 15 parts of polyamide series organic fiber, 8 to 15 parts of polyphosphazene oligomer, 1 to 5 parts of antioxidant and 1 to 5 parts of flow modifier. The materials are manufactured through melt blending, extruding and granulation. The composite material has good impact resistance, and no heavy metal or radioactivity; the composite material is bending resistant, deformation resistant, fire proof and corrosion resistant; high sintering is not needed, the production technology is advanced, and the automation degree is high; the composite material is low-carbon and environment friendly, can be recycled, and is firmly bonded to walls and grounds, convenient to construct, and mainly used in building material decoration of interior walls, grounds, ceiling, trim strips, doors, windows, cabinets and the like.

Description

Be used to push up, the matrix material and the purposes of wall, ground, lines, door and window, cabinet
Technical field
The present invention relates to a kind of building decoration material, particularly, relate to a kind of thermoplastic composite and purposes that is used for products such as inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door and window, cabinet.
Background technology
At present, composite inner wall, ground lines mainly contain two kinds: a kind of is the full wafer marble, and its resource is exhausted day by day; Another kind is the ceramic tile of firing with potter's clay.Existing marble composite board base material is grouan or ceramic tile, and its shortcoming is its high energy consumption, maximum discharge, high pollution, radioactivity is arranged and contain harmful heavy metal, and can't recycle.In addition, because ceramic tile is the high-temperature firing article, thereby the yielding surface irregularity that causes in the sintering procedure easyly ftractures, fragmentation.Be attached to that marble composite board on the metope also ftractures easily, broken situation, crushed product more causes the secondary pollution source.In addition, the marble lines need be used the marble processing of stone of monoblock, grind required concavo-convex lines, except wasting a large amount of raw material stone materials, also need the manpower of labor, can pollute environment again simultaneously.
China's natural marble scarcity of resources needs in a large number from external import, and price is high; Contain heavy metal, human body is had radiation, product can not recycle.And use polymer composite to do base material; Need not high temperature sintering; No condemnation factor can recycle, and carries out the special surface protection again after using 3D ink-jet technology treat surface; Its pattern and color are more plentiful and true to nature, are the novel equivalent material of products such as ideal interior wall, ground, furred ceiling, ornamental strip, door and window, cabinet.
Summary of the invention
The purpose of this invention is to provide a kind of polymer composite and do base material, its have good shock resistance, "dead", do not contain heavy metal, anti-folding is pressed indeformable, fire prevention, corrosion-resistant; Need not high temperature sintering, production technique is advanced, and level of automation is high, and low-carbon environment-friendly and pollution-free can be recycled, and bonds firmly easy construction with wall, ground.
In order to achieve the above object, the invention provides a kind ofly be used to push up, the matrix material of wall, ground, lines, door and window, cabinet, this matrix material comprises the following raw material of meter by weight:
Vestolen PP 7052 10-30 part;
Silicon oxide is inorganic fibre 40-60 part;
Polyamide-based organic fibre 8-15 part;
Poly phosphazene oligopolymer 8-15 part;
Oxidation inhibitor 1-5 part;
Flow ability modifying agent 1-5 part.
Above-mentioned be used to push up, the matrix material of wall, ground, lines, door and window, cabinet, wherein, described compound material comprises the colorant of counting 1-3 part by weight.
Above-mentioned be used to push up, the matrix material of wall, ground, lines, door and window, cabinet, wherein, described silicon oxide is that the length-to-diameter ratio of inorganic fibre is 15-20:1.
Above-mentioned be used to push up, the matrix material of wall, ground, lines, door and window, cabinet, wherein, described polyamide-based organic fibre length is 2-5mm.
Above-mentioned be used to push up, the matrix material of wall, ground, lines, door and window, cabinet, wherein, described matrix material is that said raw material is processed through melt blending, granulation.
The present invention also provide a kind of according to above-mentioned being used to push up, the preparation method of the matrix material of wall, ground, lines, door and window, cabinet, described preparation method comprises: raw material is joined in the forcing machine in proportion, heating, melt blending is extruded, granulation.
The present invention also provides a kind of purposes of above-mentioned matrix material; This matrix material is used to prepare building decoration parts such as top, wall, ground, lines, door and window, cabinet, and described top, wall, ground are meant between the kitchen or ceiling material, inner wall finishing, the ground decoration plate of toilet; Described lines are meant ornamental strip.Preferably, this matrix material prepares building decoration parts such as inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window and cabinet through injection moulding, extrusion molding or pressing process.
Because matrix material of the present invention is thermoplasticity, lines can an extrusion moulding, can process the lines of any concaveconvex shape according to design and needs, and practice thrift starting material and manpower greatly.And this ornamental strip is the same with wall ground, can not ftracture.
Traditional urethane since drawbacks limit such as its heat-resisting cold tolerance, flame retardant properties and hydrophobic performance deficiency its Application Areas.The present invention is under the prerequisite of the mechanical property of excessively not sacrificing urethane; Utilize phosphine nitrile oligopolymer high-performance to improve heat-resisting cold tolerance, flame retardant properties and the hydrophobic performance of urethane; Prepare a kind of novel architectural decoration matrix material, have good shock resistance, do not have radiation, do not contain heavy metal, anti-folding is pressed indeformable, fire prevention, waterproof, corrosion-resistant; And bond firmly with wall, ground, easy construction is mainly used in building decoration parts such as preparation inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window and cabinet.
Description of drawings
Fig. 1 is sheet for architectural decoration such as the top, wall, ground, lines, door and window, cabinet of Composite Preparation of the present invention, through the UV color painting, and, the structural representation that the protection of UV top coat is handled.
Embodiment
Below in conjunction with embodiment technical scheme of the present invention is done explanation further.
Embodiment 1
Count by weight,
30 parts of Vestolen PP 7052;
Length-to-diameter ratio is that the silicon oxide of 15:1 is 45 parts of inorganic fibres;
10 parts of polyamide-based organic fibres;
12 parts of poly phosphazene oligopolymers;
2 parts in oxidation inhibitor;
1 part of flow ability modifying agent.
Described polypropylene particles is the M700 polypropylene particles; Polyamide-based organic fibre length is 5 millimeters, and the preferred antioxidant 1010 of oxidation inhibitor, described flow ability modifying agent are modification ethylene bis-fatty acid imide.
Step 1, preparation matrix material particle: according to formula ratio above-mentioned raw materials thorough mixing in stirrer is stirred, mixed raw material is quantitatively joined in the hopper of twin screw extruder hot briquetting by charging opening and bypass charging opening; Extrude through the forcing machine die orifice then, obtain the strip matrix material, place tank to reduce to room temperature in this strip matrix material again.Put into nodulizer to the strip matrix material after the cooling and be processed into granular matrix material particle; Put into 100 ℃~120 ℃ baking oven heating, drying to this matrix material particle, remove moisture.
Step 2; Injection molding: the matrix material particle of oven dry is joined in the barrel of injection moulding machine, and heating makes the matrix material pellet melting, and the material usage of the single product that will produce according to institute is imported in the computer program of injection moulding machine; Start injection moulding machine injection sequence of control; Adopt injection screw to advance the matrix material in the barrel is expelled in the metal die, be injected into 5 ℃~10 ℃ water coolants in the cold runner of metal die, make the product cooling and shaping; Open mould, take out the goods of moulding with taking mechanical hand.
Embodiment 2
Count by weight,
20 parts of Vestolen PP 7052;
Length-to-diameter ratio is that the silicon oxide of 15:1 is 40 parts of inorganic fibres;
Length-to-diameter ratio is that the silicon oxide of 20:1 is 20 parts of inorganic fibres;
8 parts of polyamide-based organic fibres;
8 parts of poly phosphazene oligopolymers;
1 part in oxidation inhibitor;
2 parts of flow ability modifying agents;
1 part of toner.
Described polypropylene particles is that the M2600 polypropylene particles is mixed by 1:1 with the M700 polypropylene particles; Polyamide-based organic fibre is that length is that 2 millimeters polyamide-based organic fibre and length is that 5 millimeters polyamide-based organic fibre mixes by 1:1, and the preferred antioxidant 1010 of oxidation inhibitor, described flow ability modifying agent are selected modification ethylene bis-fatty acid imide.
Method by embodiment 1 prepares architectural decoration products such as needed inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window (referring to window frame especially), cabinet.
Embodiment 3
Count by weight,
10 parts of Vestolen PP 7052;
Length-to-diameter ratio is that the silicon oxide of 15:1 is 40 parts of inorganic fibres;
Length-to-diameter ratio is that the silicon oxide of 20:1 is 15 parts of inorganic fibres;
8 parts of polyamide-based organic fibres;
15 parts of poly phosphazene oligopolymers;
4 parts in oxidation inhibitor;
5 parts of flow ability modifying agents;
3 parts of white titanium pigments.
Described polypropylene particles is the M2600 polypropylene particles; Polyamide-based organic fibre length is 2 millimeters, and the preferred antioxidant 1010 of oxidation inhibitor, described flow ability modifying agent are selected modification ethylene bis-fatty acid imide.
Method by embodiment 1 prepares architectural decoration products such as needed inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window (referring to window frame especially), cabinet.
Embodiment 4
Count by weight,
26 parts of Vestolen PP 7052;
Length-to-diameter ratio is that the silicon oxide of 20:1 is 40 parts of inorganic fibres;
15 parts of polyamide-based organic fibres;
10 parts of poly phosphazene oligopolymers;
3 parts in oxidation inhibitor;
4 parts of flow ability modifying agents;
2 parts of toners.
Described polypropylene particles is that the M2600 polypropylene particles is mixed by 1:1 with the M700 polypropylene particles; Polyamide-based organic fibre is that length is that 2 millimeters polyamide-based organic fibre and length is that 5 millimeters polyamide-based organic fibre mixes by 2:1, and the preferred antioxidant 1010 of oxidation inhibitor, described flow ability modifying agent are selected modification ethylene bis-fatty acid imide.
Method by embodiment 1 prepares architectural decoration products such as needed inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window (referring to window frame especially), cabinet.
Through test, be inferior light on the resulting product appearance of this embodiment 1-4, but smooth surface have the high firmness surface, the ability anti-scratch; Have super hydrophobic surface, be not easy to make moist, and have H.T., fire-retardant.
Thermoplastic composite of the present invention also can adopt processes such as extrusion molding, compacting to become building decoration parts such as architectural decoration product windows such as needed inner wall finishing, ground decoration plate, ceiling material, ornamental strip, door, window (referring to window frame especially), cabinet and cabinet except adopting injection moulding.
Among some preferred embodiment, use the polymer composite of embodiment of the invention 1-4 to do base material 10, and use 3D ink-jet technology treat surface; After obtaining UV color painting layer 11; Carry out the special surface protection again, promptly set up UV top coat resist 12, as shown in Figure 1.Resulting building decoration parts among those embodiment, pattern and color are more plentiful and true to nature, are the novel equivalent material of products such as ideal interior wall, ground, furred ceiling, ornamental strip, door and window, cabinet.
Although content of the present invention has been done detailed introduction through above-mentioned preferred embodiment, will be appreciated that above-mentioned description should not be considered to limitation of the present invention.After those skilled in the art have read foregoing, for multiple modification of the present invention with to substitute all will be conspicuous.Therefore, protection scope of the present invention should be limited appended claim.

Claims (7)

  1. One kind be used to push up, the matrix material of wall, ground, lines, door and window, cabinet, it is characterized in that described matrix material comprises the following raw material of meter by weight:
    Vestolen PP 7052 10-30 part;
    Silicon oxide is inorganic fibre 40-60 part;
    Polyamide-based organic fibre 8-15 part;
    Poly phosphazene oligopolymer 8-15 part;
    Oxidation inhibitor 1-5 part;
    Flow ability modifying agent 1-5 part.
  2. 2. the matrix material of top as claimed in claim 1, wall, ground, lines, door and window, cabinet is characterized in that, described compound material comprises the colorant of counting 1-3 part by weight.
  3. 3. according to claim 1 or claim 2 top, wall, ground, lines, door and window, the matrix material of cabinet is characterized in that described silicon oxide is that the length-to-diameter ratio of inorganic fibre is 15-20:1.
  4. 4. as claimed in claim 3ly be used to push up, the matrix material of wall, ground, lines, door and window, cabinet, it is characterized in that described polyamide-based organic fibre length is 2-5mm.
  5. 5. as claimed in claim 4ly be used to push up, the matrix material of wall, ground, lines, door and window, cabinet, it is characterized in that described matrix material is that said raw material is processed through melt blending, granulation.
  6. 6. purposes with the described matrix material of claim 1; It is characterized in that; This matrix material is used to prepare top, wall, ground, lines, door and window, cabinet; Described top, wall, ground are meant between the kitchen or ceiling material, inner wall finishing, the ground decoration plate of toilet, and described lines are meant ornamental strip.
  7. 7. the purposes of matrix material as claimed in claim 6 is characterized in that, this matrix material prepares top, wall, ground, lines, door and window, cabinet through injection moulding, extrusion molding or pressing process.
CN201210285865.8A 2012-08-13 2012-08-13 Composite material used on ceilings, walls, grounds, strips doors, windows and cabinets and applications Active CN102757602B (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114407320A (en) * 2021-12-30 2022-04-29 宁波盒象科技有限公司 Manufacturing method of logistics turnover box substrate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062359A (en) * 1990-12-14 1992-07-01 阿托化学公司 Be used in particular for the composition based on polyphosphonitrile of mulching material
CN101747607A (en) * 2009-12-25 2010-06-23 上海琥达投资发展有限公司 Resin-based composite material sanitary ware hardware and preparation method thereof
CN101864108A (en) * 2010-06-03 2010-10-20 上海琥达投资发展有限公司 Wollastonite modified thermoplastic resin composite material and product preparation method thereof
CN102061032A (en) * 2010-06-29 2011-05-18 上海琥达投资发展有限公司 Thermoplastic resin composite material modified by nonmetallic material and method for preparing products

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062359A (en) * 1990-12-14 1992-07-01 阿托化学公司 Be used in particular for the composition based on polyphosphonitrile of mulching material
CN101747607A (en) * 2009-12-25 2010-06-23 上海琥达投资发展有限公司 Resin-based composite material sanitary ware hardware and preparation method thereof
CN101864108A (en) * 2010-06-03 2010-10-20 上海琥达投资发展有限公司 Wollastonite modified thermoplastic resin composite material and product preparation method thereof
CN102061032A (en) * 2010-06-29 2011-05-18 上海琥达投资发展有限公司 Thermoplastic resin composite material modified by nonmetallic material and method for preparing products

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114407320A (en) * 2021-12-30 2022-04-29 宁波盒象科技有限公司 Manufacturing method of logistics turnover box substrate

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