CN102733538A - Thermoplastic non-metal composite material curtain wall board for architectural decoration and preparation method thereof - Google Patents
Thermoplastic non-metal composite material curtain wall board for architectural decoration and preparation method thereof Download PDFInfo
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- CN102733538A CN102733538A CN2012102448564A CN201210244856A CN102733538A CN 102733538 A CN102733538 A CN 102733538A CN 2012102448564 A CN2012102448564 A CN 2012102448564A CN 201210244856 A CN201210244856 A CN 201210244856A CN 102733538 A CN102733538 A CN 102733538A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/10—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/26—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
- E04C2/284—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
- E04C2/296—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and non-metallic or unspecified sheet-material
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0801—Separate fastening elements
- E04F13/0803—Separate fastening elements with load-supporting elongated furring elements between wall and covering elements
- E04F13/081—Separate fastening elements with load-supporting elongated furring elements between wall and covering elements with additional fastening elements between furring elements and covering elements
- E04F13/083—Hooking means on the back side of the covering elements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/18—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of organic plastics with or without reinforcements or filling materials or with an outer layer of organic plastics with or without reinforcements or filling materials; plastic tiles
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a thermoplastic non-metal composite material curtain wall board for architectural decoration and a preparation method of the thermoplastic non-metal composite material curtain wall board. The curtain wall board comprises a shell made from a thermoplastic non-metal composite material through injection molding and integral formation and a flame retardant foam material main body pressure injected in the shell. The composite material comprises the following raw materials in percentage by weight: 53-73% of reinforcing agent, 15-35% of polypropylene, 1-5% of flowing modifying agent, 2-4% of titanium pigment and 1-3% of antioxidant. The reinforcing agent is silicon dioxide or inorganic microfiber or a mixture of the two ingredients. The outline of the curtain wall board provided by the invention can be prepared to be level and smooth or to have such decoration effects with three-dimensional sense organ as simulative natural stone material, wood grain and metal board, and the like, the curtain wall board has high strength, high hardness, small weight, corrosion resistance and aging resistance, and the curtain wall board has the properties of heat preservation and flame retardant and is simple and convenient in installation, so that the curtain wall board has an obvious energy saving effect if being applied on outer walls of building materials.
Description
Technical field
The present invention relates to building material technical field, particularly, relate to a kind of architectural decoration thermoplastic non-metal composite material curtain wall panel and preparation method thereof.
Background technology
The waterproof that solves building masonry wall is the direction of people's long-term endeavour with insulation.Traditional building material, for example: concrete, brick, asphalt felt, polymer sheet etc., its water resistance and heat-insulating property are single, are difficult to take into account water proofing property and heat insulating ability, and the coefficient of thermal conductivity of these materials is all bigger, the utmost point is unfavorable for the energy-conservation of building.In addition, traditional constructional materials is all heavier, is unfavorable for reducing the weight of body of wall, and the body of wall that particularly cuts off body of wall and filling more need reduce weight.Developed multiple combined wall in recent years, still, level is too much, the also more complicated of constructing.
Summary of the invention
The invention provides a kind of architectural decoration curtain wall panel with fire-retardant, insulation, water resistance, its light weight, hardness and intensity are high, and construction is simple.
For achieving the above object; The invention provides a kind of thermoplastic non-metal composite material curtain wall panel; This curtain wall panel comprises the injection moulding of employing thermoplastic non-metal composite material, integrated housing, and, press and annotate the anti-flammability foamed material main body that gets into housing; The insulating foam material fuses with housing after injecting housing, and is more firm.Without glue, avoid glue to throw off after use a period of time.This composite material comprises following raw materials in percentage by weight:
Reinforcing agent 53% ~ 73%;
Polypropylene 15% ~ 35%;
Flow ability modifying agent 1% ~ 5%;
Titanium white powder 2% ~ 4%;
Antioxidant 1% ~ 3%;
Described reinforcing agent is silica or inorganic fento or the mixture of the two.
Above-mentioned architectural decoration thermoplastic non-metal composite material curtain wall panel, wherein, described composite material also comprises the maleic anhydride modified polypropylene of percentage meter 4-6% by weight.Described maleic anhydride modified polypropylene is to be made through Grafted with Maleic Anhydride by Reactive Extrusion by polypropylene; Owing to introduced the side group of strong polarity on the nonpolar molecular backbone, maleic anhydride inoculated polypropylene can become the bridge of promoting polar material and non-polar material cementability and compatibility.When producing filled polypropylene, add maleic anhydride modified polypropylene, can greatly improve the dispersiveness of filler and polyacrylic compatibility and filler.So the dispersion of reinforcer in polypropylene effectively, thereby the stretching and the impact strength of raising filled polypropylene.
Above-mentioned architectural decoration thermoplastic non-metal composite material curtain wall panel, wherein, described polypropylene is the hard polypropylene of preferred high-strength height, its technical indicator is: bending modulus is greater than 2100, and heat distortion temperature is greater than 135 ℃, and molten finger is about 20 polypropylene.The hard polypropylene of this high-strength height can improve the intensity and the hardness of curtain wall panel greatly.
Above-mentioned architectural decoration thermoplastic non-metal composite material curtain wall panel; Wherein, Described composite material also comprises the molten polypropylene that refers to of height of percentage meter 4-6% by weight; This height is molten to refer to that polypropylene is meant that melt index is not less than 100 polypropylene, and its role is to make composite material have high finish surface, and can improve the flowability of composite material.
Above-mentioned architectural decoration thermoplastic non-metal composite material curtain wall panel, wherein, described inorganic fento is meant that draw ratio is the wollastonite of 6 ~ 12:1.The adding of wollastonite helps improving the surface property of material, like fineness, anti-pollution, corrosion-resistant etc.; Reasonably height is filled with and is beneficial to the temperature tolerance that to a certain degree improves material.
Above-mentioned architectural decoration thermoplastic non-metal composite material curtain wall panel, wherein, described curtain wall panel housing comprises decorative cover and joint face.Wherein, joint face is rattan shape or band shape, and decorative cover is a smooth plates, can carry out air brushing, spray, inlays, carves decorative Treatment such as decorations.This structure ability conservation, the weight of reduction curtain wall panel cuts down the consumption of energy.
Above-mentioned architectural decoration thermoplastic non-metal composite material curtain wall panel, wherein, described anti-flammability foamed material is meant phenolic resins, ability normal temperature cure, and light weight.
Preferably, described flow ability modifying agent is a modification ethylene bis-fatty acid acid imide.
Because the tertiary carbon atom in the polypropylene macromolecular chain is very responsive to the erosion of oxygen, easy ageing under light, heat and airborne oxygen effect so composite material of the present invention also adds antioxidant with the inhibition ageing process, and can uvioresistant be shone anti-sunshine.Preferably, described antioxidant is antioxidant 1010.
The present invention also provides the preparation method of above-mentioned architectural decoration thermoplastic non-metal composite material curtain wall panel, and this method comprises following concrete steps:
Step 1 stirs reinforcing agent, polypropylene, flow ability modifying agent, titanium white powder and antioxidant according to formula ratio in stirrer for mixing;
Step 2 joins above-mentioned mixed material in the hopper of double screw extruder hot briquetting;
Step 3 is extruded the strip composite material after the hot briquetting by extruder, and makes the composite material cooling;
Step 4 is put into granulator to the strip composite material after the cooling, is processed into granular composite material particle;
Step 5 is put into the baking oven heating, drying to described composite material particle;
Step 6 joins the composite material particle of drying in the barrel of injection machine, and heating makes the composite material pellet melting, and the composite material with fusion in the barrel is expelled in the metal die then;
Step 7 is injected into cooling water in the cold runner of metal die, makes the product cooling and shaping;
Step 8 is opened mould, takes out the curtain wall panel housing of moulding;
Step 9 is pressed fluid injection body foamed material in above-mentioned housing, after normal temperature cure 3-8 minute, moulding obtains outer curtain wall panel.
Further, in the described step 6, injection machine adopts the piston type machine barrel to be injected in the metal die of product through the composite material of high pressure with fusion.
Cooling water temperature in the described step 7 is 5 ℃ ~ 10 ℃.
Curtain wall panel of the present invention is to be that primary raw material is processed the composite material particle through extruder and granulator with inorganic strengthening agent and polypropylene, and heating and melting, adopts injection machine to be expelled to the composite material particle of fusion in the mould through high pressure, makes after the cooling.Preparation method's raw material provided by the invention is easy to get, and the preparation process need not high energy consumption and fires for a long time, and energy consumption significantly reduces; The mechanical automation degree is high, and labour intensity also alleviates, and compares with traditional handicraft; Production technology is advanced, adopts the injection machine injection, and yield rate is high; Product is fit to industrialization, large-scale production, no substandard products fully; And the curtain wall panel that adopts composite material of the present invention and preparation method to make, appearance can be processed smooth bright and clean or make the decorative effect that natural-like stone, wood grain, metal sheet etc. have three-dimensional sense organ as required; Do not stain waterproof, high strength; High rigidity, light weight, anticorrosive, ageing-resistant; And the characteristic with heat-insulating and fire-proof, simple installation, it is obvious to be used for constructional materials external wall energy-saving effect.And curtain wall panel material of the present invention can be recycled, energy-conservation and environmental friendliness.
Description of drawings
Fig. 1 is the assembling sketch map of a kind of architectural decoration thermoplastic non-metal composite material curtain wall panel of the present invention.
The specific embodiment
Below in conjunction with accompanying drawing and embodiment technical scheme of the present invention is done explanation further.
Adopt the preparation method of architectural decoration thermoplastic non-metal composite material curtain wall panel of the present invention mainly to comprise following step:
Step 1 stirs reinforcing agent, polypropylene, flow ability modifying agent, titanium white powder and antioxidant according to formula ratio in stirrer for mixing;
Step 2 joins above-mentioned mixed material in the hopper of double screw extruder hot briquetting;
Step 3 is extruded the strip composite material after the hot briquetting by extruder, and makes the composite material cooling;
Step 4 is put into granulator to the strip composite material after the cooling and is processed into granular composite material particle;
Step 5 is put into the baking oven heating, drying to described composite material particle;
Step 6; The composite material particle of oven dry is joined in the barrel of injection machine; The fusion of heating, according in the computer program of material usage input injection machine of the single product that will produce, start injection machine injection control program; Adopt injection screw to advance composite material is expelled in the metal die of curtain wall panel, described injection machine adopts the piston type machine barrel to be injected in the metal die of curtain wall panel through high pressure;
Step 7 is injected into 5 ℃ ~ 10 ℃ cooling waters in the cold runner of metal die, makes the product cooling and shaping;
Step 8 is opened mould, takes out the curtain wall panel housing of moulding;
Step 9 is pressed fluid injection body foamed material (like phenolic resin foam) in above-mentioned housing, after normal temperature cure 3-8 minute, moulding obtains curtain wall panel.
Curtain wall panel of the present invention comprises the injection moulding of employing thermoplastic non-metal composite material, integrated housing, and, press and annotate the anti-flammability foamed material main body that gets into housing, wherein, the foamed material of insulation fuses with housing after injecting housing, and is more firm.Without glue, avoid glue to throw off after use a period of time.The housing of curtain wall panel of the present invention is by decorative cover 33 (being exposed to outer), and joint face 34 (not being exposed to outer) constitutes, and as shown in Figure 1, wherein, this joint face 34 is meant the joint face that is connected and/or is connected with other curtain wall panel sides with body of wall.
Embodiment 1-12
Table one: following is the embodiment 1-12 of each different formulations
With above-mentioned raw materials abundant mixing and stirring in mixer, mixed raw material is quantitatively joined in the hopper of double screw extruder hot briquetting according to the formula ratio of table one by charge door and bypass charge door; Extrude the strip composite material after the hot briquetting through the extruder die orifice then, and place tank to reduce to room temperature in described strip composite material; Put into granulator to the strip composite material after the cooling and be processed into granular composite material particle; Put into 100 ℃～120 ℃ baking oven heating, drying to described composite material particle, remove moisture; The composite material particle of oven dry is joined in the barrel of injection machine; Heat and make the composite material pellet melting; According in the computer program of material usage input injection machine of the single product that will produce; Start injection machine injection control program, adopt injection screw to advance the composite material in the barrel is expelled in the metal die of curtain wall panel, described injection machine adopts the piston type machine barrel to be injected in the metal die of curtain wall panel through high pressure; Be injected into 5 ℃～10 ℃ cooling water in the cold runner of metal die, make the product cooling and shaping, open mould, take out the curtain wall panel housing of moulding with taking mechanical hand.Then, in above-mentioned housing, press fluid injection body foamed material (like phenolic resin foam), after normal temperature cure 3-8 minute, moulding obtains curtain wall panel.
Embodiment 1-3 is a basic components, the curtain wall panel light weight that makes, and shock resistance and compressive strength are high, and product surface is smooth, and self-cleaning is strong, and high temperature resistant, anti-sunshine, corrosion resistance are strong; And has marmorean texture; Can reach the required basic demand of curtain wall panel.
Further, the characteristic that the high-strength height of curtain wall panel that makes of embodiment 4-6 is hard is more outstanding.
Further, the curtain wall panel high surface hardness characteristic that makes of embodiment 7-9 is more outstanding.
Further, the curtain wall panel high finish surface characteristic that makes of embodiment 10-12 is more outstanding.
In some more excellent embodiment; Also adopt 3D air brushing technology on the decorative cover of curtain wall panel; Can represent texture such as wood grain, marbling, ceramic tile, granite truly, surface, uvioresistant ageing-resistant with import and the strong coating of weatherability are carried out plated film then, break the present situation that present vertical face of outer wall of building tone is single, third dimension is not strong; Can make the facade tone rich and varied; The aesthetic that represents various ornament materials realistically, and easy for installation, from heavy and light, can practice thrift the used steel of structure to greatest extent, reduce cost.In addition, on the curtain wall panel decorative cover, also can adopt fluorocarbon-sprayed and metal powder painting, reach the effect of metal curtain wallboard.
The assembling sketch map of a kind of architectural decoration thermoplastic non-metal composite material curtain wall panel of the present invention is as shown in Figure 1; At first, connector 20 is fixed on the body of wall 10, installs on this connector 20 and be provided with some stainless steel angle hitch 21 through some built-in fittings 11; This angle sign indicating number 21 is fixed on the connector through stainless steel bolt; This angle sign indicating number 21 is fixing through CARBURIZING FURNACE FOR STAINLESS FASTENER 23 with curtain wall brace 22, and curtain wall panel 30 of the present invention is provided with some holes 31, and curtain wall brace 22 31 makes curtain wall panel be connected with connector 20 to fix through the space; Junction at curtain wall panel and brace seals through fluid sealant 32, leaks avoiding.Described connector can be channel-section steel, D shaped steel or the connector processed by composite material provided by the invention.Curtain wall panel mounting method of the present invention is easy, is convenient to construction.
Composite material provided by the invention and method are not limited only to the preparation method of curtain wall panel, can also be used for the preparation of cabinets such as outdoor products, tubing, view Handicraft decorative product, outdoor electricity distribution cabinet.
Although content of the present invention has been done detailed introduction through above-mentioned preferred embodiment, will be appreciated that above-mentioned description should not be considered to limitation of the present invention.After those skilled in the art have read foregoing, for multiple modification of the present invention with to substitute all will be conspicuous.Therefore, protection scope of the present invention should be limited appended claim.
Claims (8)
1. architectural decoration thermoplastic non-metal composite material curtain wall panel is characterized in that, this curtain wall panel comprises the injection moulding of employing thermoplastic non-metal composite material, integrated housing, and, press and annotate the anti-flammability foamed material main body that gets in this housing;
This composite material comprises following raw materials in percentage by weight:
Reinforcing agent 53% ~ 73%;
Polypropylene 15% ~ 35%;
Flow ability modifying agent 1% ~ 5%;
Titanium white powder 2% ~ 4%;
Antioxidant 1% ~ 3%;
Described reinforcing agent is silica or inorganic fento or the mixture of the two.
2. architectural decoration thermoplastic non-metal composite material curtain wall panel as claimed in claim 1; It is characterized in that described polypropylene is the hard polypropylene of high-strength height, its technical indicator is: bending modulus is greater than 2100; Heat distortion temperature is greater than 135 ℃, and melt index is 20 polypropylene.
3. architectural decoration thermoplastic non-metal composite material curtain wall panel as claimed in claim 1 is characterized in that described composite material also comprises the maleic anhydride modified polypropylene of percentage meter 4-6% by weight.
4. architectural decoration thermoplastic non-metal composite material curtain wall panel as claimed in claim 1; It is characterized in that; Described composite material also comprises the molten polypropylene that refers to of height of percentage meter 4-6% by weight, and this height is molten to refer to that polypropylene is meant that melt index is not less than 100 polypropylene.
5. architectural decoration thermoplastic non-metal composite material curtain wall panel as claimed in claim 1 is characterized in that described inorganic fento is meant that draw ratio is the wollastonite of 6 ~ 12:1.
6. like any one described architectural decoration thermoplastic non-metal composite material curtain wall panel among the claim 1-5; It is characterized in that; Described curtain wall panel housing comprises decorative cover (33) and joint face (34); Wherein, decorative cover (33) is a smooth plates, and joint face (34) is rattan shape or banded plane.
7. architectural decoration thermoplastic non-metal composite material curtain wall panel as claimed in claim 6 is characterized in that described anti-flammability foamed material is meant phenolic resins.
8. the preparation method of an architectural decoration thermoplastic non-metal composite material curtain wall panel as claimed in claim 1 is characterized in that this method comprises following concrete steps:
Step 1 stirs reinforcing agent, polypropylene, flow ability modifying agent, titanium white powder and antioxidant according to the described raw material consumption of claim 1 in stirrer for mixing;
Step 2 joins above-mentioned mixed material in the hopper of double screw extruder hot briquetting;
Step 3 is extruded the strip composite material after the hot briquetting by double screw extruder, and makes the composite material cooling;
Step 4 joins the strip composite material after the cooling in the granulator, is processed into granular composite material particle;
Step 5 is inserted heating, drying in the baking oven to described composite material particle;
Step 6 joins the composite material particle of above-mentioned oven dry in the barrel of injection machine, heats to make and utilize injection machine the composite material in the barrel to be expelled in the mould of curtain wall panel by the composite material pellet melting;
Step 7 is injected into cooling water in the cold runner of mould, makes the product cooling and shaping;
Step 8 is opened mould, takes out the curtain wall panel housing of moulding;
Step 9 is pressed fluid injection body foamed material in above-mentioned housing, the normal temperature cure moulding obtains curtain wall panel.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210244856.4A CN102733538B (en) | 2012-07-16 | 2012-07-16 | Architectural decoration thermoplastic non-metal composite material curtain wall and preparation method thereof |
| PCT/CN2012/001604 WO2014012199A1 (en) | 2012-07-16 | 2012-11-30 | Nonmetallic thermoplastic composite material curtain wall board for building decoration and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210244856.4A CN102733538B (en) | 2012-07-16 | 2012-07-16 | Architectural decoration thermoplastic non-metal composite material curtain wall and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102733538A true CN102733538A (en) | 2012-10-17 |
| CN102733538B CN102733538B (en) | 2015-08-19 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210244856.4A Expired - Fee Related CN102733538B (en) | 2012-07-16 | 2012-07-16 | Architectural decoration thermoplastic non-metal composite material curtain wall and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN102733538B (en) |
| WO (1) | WO2014012199A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103132621A (en) * | 2013-03-11 | 2013-06-05 | 上海琥达投资发展有限公司 | Thermoplastic nonmetallic composite material curtain wall insulation board and preparation method for architectural ornament |
| WO2014012199A1 (en) * | 2012-07-16 | 2014-01-23 | 上海琥达投资发展有限公司 | Nonmetallic thermoplastic composite material curtain wall board for building decoration and preparation method therefor |
| CN109705605A (en) * | 2018-12-11 | 2019-05-03 | 浙江钧通塑胶科技有限公司 | A kind of parian type uvioresistant pipe material and preparation method thereof |
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|---|---|---|---|---|
| CN1094653A (en) * | 1993-11-25 | 1994-11-09 | 石家庄市塑料工贸总公司聚丙烯厂 | The compound filter plate of a kind of pressure filter, filter frame |
| CN1156155A (en) * | 1996-01-29 | 1997-08-06 | 中国科学院化学研究所 | Polypropylene resin composition and its preparing method and use |
| CN2651340Y (en) * | 2003-08-29 | 2004-10-27 | 陈坤杰 | Plastics-wood composite wall body |
| JP2007231589A (en) * | 2006-02-28 | 2007-09-13 | Dainippon Printing Co Ltd | Decorative sheet |
| CN101974244A (en) * | 2010-11-13 | 2011-02-16 | 杨大可 | Polyvinyl chloride-based wood plastic composite and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102733538B (en) * | 2012-07-16 | 2015-08-19 | 上海琥达投资发展有限公司 | Architectural decoration thermoplastic non-metal composite material curtain wall and preparation method thereof |
-
2012
- 2012-07-16 CN CN201210244856.4A patent/CN102733538B/en not_active Expired - Fee Related
- 2012-11-30 WO PCT/CN2012/001604 patent/WO2014012199A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094653A (en) * | 1993-11-25 | 1994-11-09 | 石家庄市塑料工贸总公司聚丙烯厂 | The compound filter plate of a kind of pressure filter, filter frame |
| CN1156155A (en) * | 1996-01-29 | 1997-08-06 | 中国科学院化学研究所 | Polypropylene resin composition and its preparing method and use |
| CN2651340Y (en) * | 2003-08-29 | 2004-10-27 | 陈坤杰 | Plastics-wood composite wall body |
| JP2007231589A (en) * | 2006-02-28 | 2007-09-13 | Dainippon Printing Co Ltd | Decorative sheet |
| CN101974244A (en) * | 2010-11-13 | 2011-02-16 | 杨大可 | Polyvinyl chloride-based wood plastic composite and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014012199A1 (en) * | 2012-07-16 | 2014-01-23 | 上海琥达投资发展有限公司 | Nonmetallic thermoplastic composite material curtain wall board for building decoration and preparation method therefor |
| CN103132621A (en) * | 2013-03-11 | 2013-06-05 | 上海琥达投资发展有限公司 | Thermoplastic nonmetallic composite material curtain wall insulation board and preparation method for architectural ornament |
| CN109705605A (en) * | 2018-12-11 | 2019-05-03 | 浙江钧通塑胶科技有限公司 | A kind of parian type uvioresistant pipe material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102733538B (en) | 2015-08-19 |
| WO2014012199A1 (en) | 2014-01-23 |
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