CN102725032A - Ammonia-containing permanent agent and application of dipropylene glycol and ester compounds thereof as permanent product - Google Patents
Ammonia-containing permanent agent and application of dipropylene glycol and ester compounds thereof as permanent product Download PDFInfo
- Publication number
- CN102725032A CN102725032A CN2010800147631A CN201080014763A CN102725032A CN 102725032 A CN102725032 A CN 102725032A CN 2010800147631 A CN2010800147631 A CN 2010800147631A CN 201080014763 A CN201080014763 A CN 201080014763A CN 102725032 A CN102725032 A CN 102725032A
- Authority
- CN
- China
- Prior art keywords
- hair
- waving
- agent
- dipropylene glycol
- dose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
Abstract
An ammonia-containing permanent agent and the application of dipropylene glycol and its ester compounds in the preparation of a permanent agent having low ammonia odor are provided. Said ammonia-containing permanent agent consists of a perming agent I and a perming agent II, wherein said perming agent I contains ammonia water and a release inhibitor, and said release inhibitor is one of dipropylene glycol and its ester compounds or their blends. Said permanent agent is mild with obviously lower ammonia odor, no pungent smells after permanent and low damage to hair.
Description
Agent for permanent hair waving and dipropylene glycol and its ester type compound containing ammonia
Applied technical field in hair perming products
The present invention relates to a kind of application of agent for permanent hair waving containing ammonia and dipropylene glycol and its ester type compound in hair perming products.Background technology
Hair-waving is a kind of hairdressing method, is divided into physics hair-waving and chemistry hair-waving, and now most are chemical hair-wavings.The purpose of hair-waving has two in fact：Make hair more rich, the effect with curling；Change shape, the trend of hair, it is not very big effect to produce volume degree.
The basic process of chemistry hair-waving is divided into two steps, and the first step is, using first dose of hair-waving, to be broken the sulphide bond and hydrogen bond in hair by chemically reacting, i.e., divide the cystine of hair using the effect reproducibility of reducing agent（Disulphide）Key；Second step is that, using second dose of hair-waving, hair cored structure is recombinated and made it stable, that is, uses in oxidant and/or shape, so as to reply cystine（Disulphide）Key.
Conventional agent for permanent hair waving is constituted by first dose of hair-waving with second dose of the hair-waving comprising oxidant at present.And it is common, sulfhydryl compound is the primary raw material of hair perming products, in the basic conditions, sulfhydryl compound has stronger reproducibility, this is due to that the effect of alkali can expand hair keratin, is conducive to the infiltration of reducing agent, can improve rolled efficiency.Alkaline agent as curling agent has ammoniacal liquor, ammonium hydrogen carbonate etc..The alkali of most common of which is ammoniacal liquor, its action temperature and, molecule is smaller, it is easy to permeate, volatile, is easily washed with water net.Alkalescence condition can make hair soft and expansion, be conducive to dyestuff intermediate to penetrate into hair marrow, and can improve the oxidizing force of oxidant.Therefore oxide hair dye is in alkalescence, and its pH value is up to 9-10.5.The most frequently used alkali is ammoniacal liquor, and some organic amines can also be used or part replaces ammoniacal liquor.Although some organic amines can completely or partially replace ammoniacal liquor, difference of the effect than ammoniacal liquor.It is also that ammoniacal liquor is best simultaneously from the security of product.
Therefore, ammoniacal liquor is inevitably used in the hair perming products and hair dyeing product of hairdressing specialized market, the excitant of ammonia taste can cause the discomfort of customer and hairdresser.Country《Cosmetology place hygienic practice》Regulation：Hairdressing place of the area more than 50 square metres is managed, should be provided between single hair dyeing, hair-waving；The hairdressing place that area is less than 50 square metres is managed, should be provided with boiling hot, dye workplace（Area）, scald, contaminate workplace（Area）There should be force ventilation facility.What national health department formulated《Barber shop, beauty salon sanitary standard》The content of ammonia is no more than 0.5 milligram in GB 9666-1996, the every cubic metres of air of regulation.
Therefore, how to improve the hair-waving quality of the agent for permanent hair waving containing ammonia, and reduce simultaneously the volatility of ammonia in the agent for permanent hair waving containing ammonia just become one it is very in the urgent need to address the problem of.
However, not having a kind of method at present to efficiently solve above-mentioned technical barrier.The content of the invention
Therefore, one of technical problems to be solved by the invention are to provide the agent for permanent hair waving containing ammonia.
The two of the technical problems to be solved by the invention are to provide dipropylene glycol and its ester type compound as the application in the hair perming products for preparing low ammonia taste.
The technical problems to be solved by the invention, are achieved by following technical proposals：
A kind of agent for permanent hair waving containing ammonia, is made up of second dose of first dose of hair-waving and hair-waving, and first dose described of hair-waving releases agent containing ammoniacal liquor and suppression, and the suppression releases agent for dipropylene glycol and one kind or its mixture in dipropylene glycol ester type compound.
Further, first dose of described hair-waving ,-cetanol or stearyl alcohol 2 ~ 5% are made up of following components by mass percentage；Agent 1 ~ 10% is released in suppression；Mineral oil 2 ~ 4%；The 0.2-1.2% of stereth -30；Isopropyl myristate 1.2 ~ 2.4%；Behenyl base trimethyl ammonium chloride 0.8 ~ 1.6%；Cetrimonium chloride (30wt%) 0.2 ~ 0.8%;Hydrolyzed wheat protein 0.5 ~ 3.0%；Dithiodiglycol two ammoniums of acid (40wt%) 8 ~ 17%;TGA 6 ~ 10%；Etidronic Acid 0.1 ~ 0.5%；Ammoniacal liquor (20wt%) 10-18%；Ammonium hydrogen carbonate 2 ~ 4%；Hydroxypropyl-trimethyl ammonium chloride hydrolyzed wheat protein 0.5 ~ 1.5%；Butyl stearate 1 ~ 3%；Algae extract or sorbierite 0.2 ~ 0.8%；Polyquaternium
-22 1-5%；Pigment 0.0002 ~ 0.0008%;Essence 0.10 ~ 0.5%;Surplus is water；Agent is released in described suppression, is dipropylene glycol and one kind or its mixture in dipropylene glycol ester type compound.
It is preferred that, it is dipropylene glycol, dipropylene glycol caprylate, dipropylene glycol dibenzoate and one kind or its mixture in dipropylene glycol salicylate that agent is released in described suppression.
Optimal, agent is released in described suppression, is made up of by mass percentage following components：Dipropylene glycol 80-90%；Dipropylene glycol dibenzoate 5 ~ 10%；Dipropylene glycol salicylate 5 ~ 10%.
First dose of described hair-waving, can be prepared by following method progress-be well mixed the cetanol or stearyl alcohol of oil phase, mineral oil, isopropyl myristate and butyl stearate, heating water bath is to 80 °C ~ 85 °C;
By the part water of aqueous phase, dipropylene glycol and one kind or its mixture in dipropylene glycol ester type compound, stereth -30, behenyl base trimethyl ammonium chloride, cetrimonium chloride, hydrolyzed wheat protein, dithiodiglycol two ammoniums of acid, TGA, Etidronic Acid, ammonium hydrogen carbonate, hydroxypropyl-trimethyl ammonium chloride hydrolyzed wheat protein, algae extract or sorbierite, Merquat 280, pigment, heating water bath is to 80 °C ~ 85 °C.Partial ammonia water is added in aqueous phase, slightly stirring makes its uniform.
In the case of stirring, aqueous phase is poured into oil phase, mixed, emulsification.Side is stirred, and side cools down emulsified body to 40 °C or so.Essence and remaining ammoniacal liquor are slowly added to, lotion is added water to and weighs 1000 grams.Continue to stir 10 minutes or so, terminate.It can obtain first dose of the hair-waving of the present invention.
Second dose of described hair-waving, can also can by mass percentage constitute-hydrogen peroxide using second dose general of hair-waving of the industry by following components（35wt%) 5-7%；Lauroylamidopropyl betaine (30wt%) 2 ~ 4%；Polyquaternium -6 1 ~ 3%；Oleth -20 0.5 ~ 2%；Etidronic Acid 0.2 ~ 0.6%；Benzene second Chi copolymers 0.1 ~ 0.5%；Disodium hydrogen phosphate 0.1 ~ 0.3%；Surplus is water.
Second dose of above-mentioned hair-waving, can be prepared by following method progress-by lauroylamidopropyl betaine (30wt%：), polyquaternium -6, oleth -20, the phosphorus of hydroxyl second two
Acid, benzene second Chi/VA copolymers and water mixing, are heated to 85 ~ 95 °C, stir 10 minutes and are well mixed, be cooled to 40 °C or so, add disodium hydrogen phosphate and hydrogen peroxide, continue to stir 5 minutes, terminate.It can obtain second dose of the hair-waving of the present invention.
The quality of hair perming products is improved, the volatility for reducing its ammonia is exactly an important aspect.Inventor after many experiments by having found, a certain amount of suppression is added in first dose of the hair-waving in the agent for permanent hair waving containing ammonia and releases agent, that is dipropylene glycol and one kind or its mixture in dipropylene glycol ester type compound, the ammonia rate of release on hair perming products surface is reduced with three hydrogen atoms generation hydrogen bond on the ammonia in hair perming products and hair dyeing product using three oxygen atoms in dipropylene glycol and its ester type compound, can improve hair-waving effect can reduce the content of ammonia in air again.
Dipropylene glycol is condensed by 1,2- propane diols and expoxy propane and obtained.1,2- propane diols and the protective embankment of epoxy third are subjected to condensation reaction under 85% effect of sulfuric acid.Reaction solution is neutralized with sodium hydroxide solution, through filtering, vacuum distillation, then rectifying at ambient pressure, is collected 229-233 cuts and is produced dipropylene glycol.
Dipropylene glycol and its ester type compound are applied to essence and flavoring agent and cosmetics etc. to the more sensitive purposes of smell ratio, it is generally used for the senior solvent of blending, for easily reacting thermal sensitivity spices, it is also used for dissolving cellulose, shellac, or it is used as plasticizer, hygroscopic agent, softening agent, water-based ink solvent, lubricant, hygroscopic agent.
In first dose of hair-waving, agent is released in described suppression, is preferably：Dipropylene glycol, dipropylene glycol caprylate, dipropylene glycol dibenzoate and one kind or its mixture in dipropylene glycol salicylate.
Unexpectedly, inventor is had surprisingly found that, in first dose of hair-waving, agent is released in described suppression, only for following components by mass percentage：Dipropylene glycol 80 ~ 90%；Dipropylene glycol dibenzoate 5-10%；When dipropylene glycol salicylate 5 ~ 10% is constituted, ammonia volatilization best results are reduced.
The present invention also provides the new application of dipropylene glycol and its ester type compound, i.e., the new opplication in cosmetics, and in particular to dipropylene glycol and its ester type compound are used as the application in the hair perming products for preparing low ammonia taste.
The present invention improves relative to prior art with significant, be embodied as-
(1) agent for permanent hair waving of the invention, ammonia taste declines obvious, substantially non-stimulated smell after hair-waving.
(2) agent for permanent hair waving property of the invention is gentle, and under identical hair-waving times condition, hair cupric ion adsorption is low, low to the degree of injury of hair.Embodiment
With reference to specific implementation example, the present invention is further elaborated, but does not limit the present invention.
The present invention can be further well understood by the specific embodiment of invention now given below.But they are not limitation of the invention.
Embodiment 1
The preparation of straight hair cream（First dose of hair-waving）
Respectively by 32 grams, No. 26 24 grams of white oils of oil phase 16 or octadecyl alcolol, 8 grams of stearic acid monoglycerides, 16 grams of isopropyl myristate, 16 grams of the different monooctyl ester of arachidic acid, 600 grams of aqueous phase deionized water, 20 grams of dipropylene glycol, 20 12 grams of protective embankment base trimethyl ammonium chlorides, 16 4 grams of protective embankment base trimethyl ammonium chlorides, 108 grams of TGA, 30 grams of heating water baths of ammonium hydrogen carbonate are to 80 °C ~ 85 °C.By 73 grams of ammoniacal liquor（21%) it is added in aqueous phase, slightly stirring makes its uniform.In the case of stirring, aqueous phase is poured into oil phase, mixed, emulsification.Side is stirred, and side cools down emulsified body to 40 °C.5 grams of essence and 87 grams of ammoniacal liquor (21%) are slowly added to, plus deionized water to lotion weighs 1000 grams.Continue to stir 10 minutes, terminate.
The preparation of setting agent（Second dose of hair-waving）
600 grams, 1.5 grams polyquaterniums -37 of aqueous phase deionized water, 1 gram, 10 grams AEOs -20 of disodium ethylene diamine tetraacetate are heated to 85 °C, 22 grams, 6 grams stereths -20 of oil phase 16 or octadecyl alcolol, which are poured into reaction pot, is heated to 95 °C, aqueous phase is poured into oil phase reaction pot again, stirring 5 minutes is started, is cooled 40 °C.By 2.5 grams of disodium hydrogen phosphates, 57 grams of hydrogen peroxide（35%), it is added in 100 grams of water and dissolves, is added in reaction pot, plus deionized water to lotion weighs 1000 grams, continues to stir 5 minutes, terminates.
Embodiment 2
The preparation of straight hair cream（First dose of hair-waving）
Respectively by 32 grams, No. 26 24 grams of white oils of oil phase 16 or octadecyl alcolol, 8 grams of stearic acid monoglycerides, 16 grams of isopropyl myristate, 16 grams of the different monooctyl ester of arachidic acid, 600 grams of aqueous phase deionized water, 20 grams of dipropylene glycol, 20 12 grams of protective embankment base trimethyl ammonium chlorides, 4 grams of hexadecyltrimethylammonium chloride, 80 grams of heating water baths of TGA are to 80 °C ~ 85 °C.By 73 grams of ammoniacal liquor（21%) it is added in aqueous phase, slightly stirring makes its uniform.In the case of stirring, aqueous phase is poured into oil phase, mixed, emulsification.Side is stirred, and side cools down emulsified body to 40 °C.It is slowly added to 5 grams of essence and 100 grams of ammoniacal liquor（, plus deionized water to lotion weighs 1000 grams 21%).Continue to stir 10 minutes, terminate.
The preparation of setting agent（Second dose of hair-waving）
The setting agent of be the same as Example 1
Comparative example 1
The preparation of straight hair cream（First dose of hair-waving）
Respectively by 32 grams, No. 26 24 grams of white oils of oil phase 16 or octadecyl alcolol, 8 grams of stearic acid monoglycerides, 16 grams of isopropyl myristate, 16 grams of the different monooctyl ester of arachidic acid, 12 grams of the protective embankment base trimethyl ammonium chloride of aqueous phase 20,4 grams of hexadecyltrimethylammonium chloride, 108 grams of TGA, 30 grams of heating water baths of ammonium hydrogen carbonate are to 80 °C ~ 85 °C.By 73 grams of ammoniacal liquor（21%) it is added in aqueous phase, slightly stirring makes it hook.In the case of stirring, aqueous phase is poured into oil phase, mixed, emulsification.Side stir, side cool down emulsified body to 40 ° (.It is slowly added to 5 grams of essence and 87 grams of ammoniacal liquor（, plus deionized water to lotion weighs 1000 grams 21%).Continue to stir 10 minutes, terminate.
The preparation of setting agent（Second dose of hair-waving）
The setting agent of be the same as Example 1
Comparative example 2
The preparation of straight hair cream（First dose of hair-waving）
Respectively by 32 grams, No. 26 24 grams of white oils of oil phase 16 or octadecyl alcolol, 8 grams of stearic acid monoglycerides, 16 grams of isopropyl myristate, 16 grams of the different monooctyl ester of arachidic acid, aqueous phase eicosyl trimethyl ammonium chloride 12
Gram, 16 4 grams of protective embankment base trimethyl ammonium chlorides, 80 grams of heating water baths of TGA are to 80 °C ~ 85 °C.By 73 grams of ammoniacal liquor（21%) it is added in aqueous phase, slightly stirring makes it hook.In the case of stirring, aqueous phase is poured into oil phase, mixed, emulsification.Side is stirred, and side cools down emulsified body to 40 °C.It is slowly added to 5 grams of essence and 100 grams of ammoniacal liquor（, plus deionized water to lotion weighs 1000 grams 21%).Continue to stir 10 minutes, terminate.
The preparation of setting agent（Second dose of hair-waving）
The setting agent of be the same as Example 1
Table 1 below gives the results of sensory evaluation of embodiment 1,2 and hair perming products made from comparative example 1,2
The embodiment of the present invention is made into the hair perming products containing ammonia applied to customer's hair-waving than the hair perming products ammonia taste of comparative example to decline substantially, hair-waving effect is essentially identical.
Table 1:Get angry taste test table hair-waving back
* subjective appreciation is 5 people group evaluation results.
Embodiment 3
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to embodiment 3 in table 2.
The cetanol or stearyl alcohol of oil phase, mineral oil, isopropyl myristate and butyl stearate are well mixed, heating water bath is to 80 °C ~ 85 °C, wherein described mineral oil is No. 26 white oils；
By the part water of aqueous phase（Account for total Water 30%), dipropylene glycol and one kind or its mixture in dipropylene glycol ester type compound, stereth -30, behenyl base trimethyl ammonium chloride, cetrimonium chloride, hydrolyzed wheat protein, dithiodiglycol two ammoniums of acid, TGA, Etidronic Acid, ammonium hydrogen carbonate, hydroxypropyl-trimethyl ammonium chloride hydrolyzed wheat protein, algae extract or sorbierite, Merquat 280, face
Material, heating water bath is to 80 °C ~ 85 °C.By partial ammonia water（50%) being added in aqueous phase for ammonia vol is accounted for, slightly stirring makes its uniform.
In the case of stirring, aqueous phase is poured into oil phase, mixed, emulsification.Side is stirred, and side cools down emulsified body to 40 °C or so.Essence and remaining ammoniacal liquor are slowly added to, remaining water is added.Continue to stir 10 minutes or so, terminate.It can obtain first dose of the hair-waving of the present invention.
The preparation of second dose of hair-waving
By 30 grams of lauroylamidopropyl betaine (30wt%：), 20 grams of polyquaterniums -6,10 grams of oleths -20,4 grams of Etidronic Acids, 3 grams of dilute copolymers of benzene second and the mixing of 200 grams of water, it is heated to 85 ~ 95 °C, stirring is well mixed for 10 minutes, it is cooled to 40 °C or so, add 2 grams of disodium hydrogen phosphates and 60 grams of hydrogen peroxide, total amount is added water to for 1000 grams, continues to stir 5 minutes, terminates.It can obtain second dose of the hair-waving of the present invention.
Embodiment 4
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to embodiment 4 in table 2.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Embodiment 5
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to embodiment 5 in table 2.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Embodiment 6
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to embodiment 6 in table 2.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Embodiment 7
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to embodiment 7 in table 2.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Embodiment 8
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to embodiment 8 in table 2.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.Table 2:Perm the first agent prescription table（The unit of embodiment 3 ~ 8)：Mass percent
The ammoniacal liquor of Etidronic Acid 0.3 0.1 0.5 0.2 0.2 0.2（20wt%) the sorbierite 0.2 0.8 of 11.7 18.0 10.0 14.0 16.0 16.0 ammonium hydrogen carbonate, 2.5 2.0 4.0 3.0 3.0 3.0 hydroxypropyl-trimethyl ammonium chloride hydrolyzed wheat protein, 1.0 0.5 1.5 1.0 1.2 1.2 butyl stearate, 2.0 3.0 1.0 2.0 2.0 2.0 algae extract 0.5 0.8 0.2 0.2
The dipropylene glycol dibenzoate 1.0 0.5 of 3.0 1.0 5.0 3.0 3.0 3.0 dipropylene glycol of Merquat 280 10.0 1.0 3.0 8.0 9.0 10.0
Dipropylene glycol salicylate 1.0 0.5
The water surplus balance balance balance balance surplus comparative example 3 of 0.0006 0.0002 0.0008 0.0004 0.0004 0.0004 essence of pigment 0.3 0.5 0.1 0.4 0.4 0.4
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to comparative example 3 in table 3.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Comparative example 4
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to comparative example 4 in table 3.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Comparative example 5
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to comparative example 5 in table 3.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Comparative example 6
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to comparative example 6 in table 3.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Comparative example 7
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to comparative example 7 in table 3.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Comparative example 8
The preparation of first dose of hair-waving
Carry out weighing each raw material according to the concrete component corresponding to comparative example 8 in table 3.First dose of the hair-waving of the present embodiment is prepared according to the method described in embodiment 3.
Second dose of hair-waving is using second dose of hair-waving prepared by embodiment 3.
Table 3:Perm the first agent prescription table（The unit of comparative example 3 ~ 8)：Mass percent
Test case 1
The Hair grooming shampoo washes of process object, then fully clean and are slightly dried with towel.Using hair-waving, first dose carries out hair-waving processing to hair.
Specifically, being applied to perming first dose on hair, hair is wrapped on sizing rod.A small amount of the first reagent of hair-waving that applies is so that hair is equably moistened by the reagent again.The head of process object takes hair net, and applies heat so that the temperature in hair net is about 40 °C with heater.Hair is heated at such a temperature 15 minutes.
Olfactometry is carried out to the hair after above-mentioned scald by the personnel that test and assess, from far near, the hair after scalding records distance when just snuffing excitatory smell.
By 5 test and appraisal composition of personnel evaluation groups, above-mentioned test is carried out respectively, its average distance is calculated
L。
Obviously, L values are bigger, illustrate that the excitant taste of the agent for permanent hair waving is heavier；L values are smaller, illustrate that the excitant taste of the agent for permanent hair waving is lighter.
Embodiment 1 ~ 8 and comparative example 1 ~ 8 are tested using the above method.Specific data, are shown in Table 4.
Table 4:Get angry taste test table hair-waving back
Compared by embodiment 1 ~ 8 with comparative example 1 ~ 4, it is known that be similarly the agent for permanent hair waving containing ammonia and be compared,
Substantially to be less than comparative example added with the excitatory taste of the agent for permanent hair waving of the invention of one kind in dipropylene glycol and dipropylene glycol ester type compound or its mixture.Particularly, it is seen that the excitant taste of embodiment 6,7 is minimum.
Compared by embodiment 1 ~ 8 with comparative example 5 ~ 8, although understanding that agent for permanent hair waving of the present invention contains ammoniacal liquor, but by adding dipropylene glycol and dipropylene glycol ester type compound so that with the agent for permanent hair waving containing MEA relatively, excitatory taste is all than relatively low for its taste.Test case 2
Published using in December, 2005《Daily chemical industry》Volume 35 the 6th is interim《Hair damage degree is evaluated with cupric ion adsorption》Disclosed method, is tested embodiment 1 ~ 8 and comparative example 1 ~ 8.
Hair can regard the hair being without damage as former state, and its impaired grade is 0, adsorbance 2.742X10_ of the hair to copper ion2C/mol-L-^g^o simulate the process of hair-waving in the lab, and hair is soaked into 15 min as former state under 30 °C with cold wave lotion stoste, nature is taken out and dries, be once to perm, then it is once secondary hair-waving to soak, the like.Perming, number of times is more, and the extent of damage is bigger, and cupric ion adsorption is bigger.Its impaired grade can artificially be divided into gently（4.800XKT2 c/mol -L"1 -g1), in（6.720 X10-2 c/mol · L"1 · g"1), again（8.366X 10-2 c/mol - L"1 · g"1) .The Hair grooming copper ion solution different to damage rank soaks respectively, measures its adsorbance to copper ion, the results are shown in Table 5.Table 5:The corresponding table unit of hair-waving number of times and hair cupric ion adsorption： c/mol - L-1 - g 1
The 4.120X10 " of embodiment 52 5.440 X10"2 6.980 X10"2The X10 " of embodiment 6 4.0402 5.820X10"2 7.280 X10"2The X10 " of embodiment 7 4.0202 5.740 X10"2 7.140X10"2The 4.140X10 " of embodiment 82 5.120X10"2 7.360 X10"2The 4.260X10 " of comparative example 12 5.580 X10"2 7.240 X10"2The 4.140X10 " of comparative example 22 5.460 X10"2The 4.320X10 " of 7.380X10-2 comparative examples 32 5.820X10"2 7.160X10"2The 4.540X10 " of comparative example 42 5.780X10"2 7.380X10"2The 5.380X10 " of comparative example 52 6.840X10"2 8.420 X10"2The 5.460X10 " of comparative example 62 6.760 X10"2 8.560 X10"2The 5.260X10 " of comparative example 72 6.780 X10"2 8.320 X10"2The 5.540X10 " of comparative example 82 6.640 X10"2 8.440 X10"2From table 5, it can clearly see, the agent for permanent hair waving containing ammonia of the embodiment of the present invention 1 ~ 8 is under identical hair-waving times condition, and hair cupric ion adsorption is significantly less than the agent for permanent hair waving containing MEA of comparative example 5 ~ 8.It can be seen that, agent for permanent hair waving of the invention, property is gentle, low to the degree of injury of hair.
The raw material being related in above-described embodiment is general chemical raw material in cosmetic industry, in ministry of Health of China in October, 2007 issue《International cosmetic raw material standard Chinese catalogue》It is on the books in 2007 editions.The material names of relevant raw materials, INCI titles and No. CAS are shown in Table 6.
Table 6:Raw material correspondence INCI titles and CAS tables
Claims (1)
- Claim1st, a kind of agent for permanent hair waving containing ammonia, is made up of second dose of first dose of hair-waving and hair-waving, it is characterised in that：First dose of described hair-waving, agent is released containing ammoniacal liquor and suppression, and the suppression releases agent for dipropylene glycol and one kind or its mixture in dipropylene glycol ester type compound.2nd, the agent for permanent hair waving as claimed in claim 1 containing ammonia, it is characterised in that：First dose of described hair-waving, is made up of by mass percentage following components：Cetanol or stearyl alcohol 2 ~ 5%；Agent 1 ~ 10% is released in suppression；Mineral oil 2 ~ 4%；The 0.2-1.2% of stereth -30；Isopropyl myristate 1.2 ~ 2.4%；Behenyl base trimethyl ammonium chloride 0.8 ~ 1.6%；Cetrimonium chloride (30wt%) 0.2 ~ 0.8%;Hydrolyzed wheat protein0.5-3.0%；Dithiodiglycol two ammoniums of acid (40wt%) 8 ~ 17%;TGA 6-10%；Etidronic Acid 01 ~ 05%;Ammoniacal liquor（20wt%) 10-18%；Ammonium hydrogen carbonate 2 ~ 4%；Hydroxypropyl-trimethyl ammonium chloride hydrolyzed wheat protein 0.5 ~ 1.5%；Butyl stearate 1 ~ 3%；Algae extract or sorbierite 0.2 ~ 0.8%；Merquat 280 1-5%；Pigment 0.0002 ~ 0.0008%；Essence 0.10 ~ 0.5%；Surplus is water；Agent is released in described suppression, is dipropylene glycol and one kind or its mixture in dipropylene glycol ester type compound.3rd, the agent for permanent hair waving as claimed in claim 1 or 2 containing ammonia, it is characterised in that：It is dipropylene glycol, dipropylene glycol caprylate, dipropylene glycol dibenzoate and one kind or its mixture in dipropylene glycol salicylate that agent is released in described suppression.4th, the agent for permanent hair waving as claimed in claim 3 containing ammonia, it is characterised in that：Described suppression is released agent and is made up of by mass percentage following components：Dipropylene glycol 80 ~ 90%；Dipropylene glycol dibenzoate 5 ~ 10%；Dipropylene glycol salicylate 5 ~ 10%.5th, the agent for permanent hair waving as claimed in claim 1 or 2 containing ammonia, it is characterised in that：Second dose of the hair-waving, is made up of by mass percentage following components：Hydrogen peroxide（35wt%) 5-7%； Lauroylamidopropyl betaine (30wt%) 2-4%；The 1-3% of polyquaternium -6；Oleth -200.5-2%；Etidronic Acid 0.2 ~ 0.6%；Styrene/VA copolymers 0.1 ~ 0.5%；Disodium hydrogen phosphate 0.1 ~ 0.3%；Surplus is water.6th, dipropylene glycol and its ester type compound are used as the application in the hair perming products for preparing low ammonia taste.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201080014763.1A CN102725032B (en) | 2009-10-26 | 2010-01-20 | Ammonia-containing permanent agent |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910197676.3 | 2009-10-26 | ||
| CN2009101976763A CN102038614A (en) | 2009-10-26 | 2009-10-26 | Application of dipropylene glycol and ester compounds thereof to hair perming and dyeing products |
| PCT/CN2010/000087 WO2011050556A1 (en) | 2009-10-26 | 2010-01-20 | Ammonia-containing permanent agent and application of dipropylene glycol and ester compounds thereof as permanent product |
| CN201080014763.1A CN102725032B (en) | 2009-10-26 | 2010-01-20 | Ammonia-containing permanent agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102725032A true CN102725032A (en) | 2012-10-10 |
| CN102725032B CN102725032B (en) | 2013-10-23 |
Family
ID=43905387
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101976763A Pending CN102038614A (en) | 2009-10-26 | 2009-10-26 | Application of dipropylene glycol and ester compounds thereof to hair perming and dyeing products |
| CN201080014763.1A Active CN102725032B (en) | 2009-10-26 | 2010-01-20 | Ammonia-containing permanent agent |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101976763A Pending CN102038614A (en) | 2009-10-26 | 2009-10-26 | Application of dipropylene glycol and ester compounds thereof to hair perming and dyeing products |
Country Status (3)
| Country | Link |
|---|---|
| CN (2) | CN102038614A (en) |
| WO (1) | WO2011050556A1 (en) |
| ZA (1) | ZA201203852B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103735429A (en) * | 2013-12-31 | 2014-04-23 | 广州市白云区大荣精细化工有限公司 | Perm preparation and preparation method thereof |
| CN107375115A (en) * | 2017-08-22 | 2017-11-24 | 刘家明 | The boiling hot formula of hydrogen hydro-thermal and technique |
| CN114796026A (en) * | 2022-05-13 | 2022-07-29 | 广州千羽化妆品有限公司 | Permanent wave agent with damaged hair repairing effect |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003040741A (en) * | 2001-05-21 | 2003-02-13 | Hoyu Co Ltd | Hair-deforming agent, agent for permanent wave, frizzy hair-correcting agent, article for permanent wave, and article for correcting the frizzy hair |
| US20060013795A1 (en) * | 2002-06-20 | 2006-01-19 | Shiseido Co., Ltd. | Composition for hair treatment |
| CN101065101A (en) * | 2004-11-24 | 2007-10-31 | 宝洁公司 | Method for the permanent shaping of hair using a cationic cellulose derivative |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006143616A (en) * | 2004-11-17 | 2006-06-08 | Sanei Kagaku Kk | Hair treatment composition |
-
2009
- 2009-10-26 CN CN2009101976763A patent/CN102038614A/en active Pending
-
2010
- 2010-01-20 CN CN201080014763.1A patent/CN102725032B/en active Active
- 2010-01-20 WO PCT/CN2010/000087 patent/WO2011050556A1/en active Application Filing
-
2012
- 2012-05-25 ZA ZA2012/03852A patent/ZA201203852B/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003040741A (en) * | 2001-05-21 | 2003-02-13 | Hoyu Co Ltd | Hair-deforming agent, agent for permanent wave, frizzy hair-correcting agent, article for permanent wave, and article for correcting the frizzy hair |
| US20060013795A1 (en) * | 2002-06-20 | 2006-01-19 | Shiseido Co., Ltd. | Composition for hair treatment |
| CN101065101A (en) * | 2004-11-24 | 2007-10-31 | 宝洁公司 | Method for the permanent shaping of hair using a cationic cellulose derivative |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103735429A (en) * | 2013-12-31 | 2014-04-23 | 广州市白云区大荣精细化工有限公司 | Perm preparation and preparation method thereof |
| CN107375115A (en) * | 2017-08-22 | 2017-11-24 | 刘家明 | The boiling hot formula of hydrogen hydro-thermal and technique |
| CN114796026A (en) * | 2022-05-13 | 2022-07-29 | 广州千羽化妆品有限公司 | Permanent wave agent with damaged hair repairing effect |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102725032B (en) | 2013-10-23 |
| WO2011050556A1 (en) | 2011-05-05 |
| CN102038614A (en) | 2011-05-04 |
| ZA201203852B (en) | 2013-08-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2563126C2 (en) | Method for semi-permanent straightening of frizzy, curly or wavy hair | |
| TWI689315B (en) | Hair care compositions | |
| CN100406474C (en) | Cation-modified galactomannan polysaccharide and cosmetic composition containing the same | |
| BR112018006961B1 (en) | method and kit to strengthen hair | |
| WO2013148064A1 (en) | Hair treatment and revitalizing composition and methods | |
| RU2730516C2 (en) | Solid effervescent hair conditioning composition | |
| BR112015001728B1 (en) | CONDITIONER COMPOSITIONS | |
| US4007261A (en) | Pearlescent hair conditioner | |
| CN102725032A (en) | Ammonia-containing permanent agent and application of dipropylene glycol and ester compounds thereof as permanent product | |
| JP6795497B2 (en) | Hair treatment agent | |
| US9463147B2 (en) | Hair treatment and revitalizing composition and methods | |
| JP2019019099A (en) | Hair coloring treatment method | |
| JP2016121091A (en) | Hair cosmetic | |
| JP3932483B2 (en) | Oxidative hair dye for temporary hair color restoration and hair dyeing method | |
| JP5830285B2 (en) | Emulsion composition for hair treatment | |
| JP7309183B2 (en) | Hair treatment agent, acid/heat treatment method, and shampoo/treatment method | |
| CN108567636A (en) | A kind of draft Haircare composition of the extract containing hamamelis | |
| JP7350303B2 (en) | Hair cosmetics and hair treatment methods | |
| JPH07330552A (en) | Hair treatment composition | |
| JP5988722B2 (en) | Hair treatment composition | |
| JP7281931B2 (en) | Hair composition and hair treatment method | |
| JP6633891B2 (en) | Hair cosmetics | |
| JPS59157011A (en) | Hair cosmetic | |
| KR101683131B1 (en) | Cosmetic composition for dandruff improvement and hair styling | |
| JP2022505085A (en) | Hair treatment composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |