CN102038614A - Application of dipropylene glycol and ester compounds thereof to hair perming and dyeing products - Google Patents
Application of dipropylene glycol and ester compounds thereof to hair perming and dyeing products Download PDFInfo
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- CN102038614A CN102038614A CN2009101976763A CN200910197676A CN102038614A CN 102038614 A CN102038614 A CN 102038614A CN 2009101976763 A CN2009101976763 A CN 2009101976763A CN 200910197676 A CN200910197676 A CN 200910197676A CN 102038614 A CN102038614 A CN 102038614A
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- dipropylene glycol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to application of dipropylene glycol and ester derivatives thereof, in particular to application of the dipropylene glycol and the ester derivatives thereof to hair perming and dyeing products. The release speed of ammonia on the surfaces of the hair perming and dyeing products can be reduced by adding dipropylene glycol and the ester compounds thereof in the hair perming and dyeing products, so that the effect for perming and dying hairs can be ensured and the content of the ammonia in the air can be reduced.
Description
Technical field
The present invention relates to dipropylene glycol (CAS 110-98-5; 25265-71-8) and the purposes of ester type compound, relate in particular to application in hair-waving product and hair dyeing product
Background technology
Dipropylene glycol is by 1,2-propylene glycol and expoxy propane condensation and get.With 1,2-propylene glycol and expoxy propane carry out condensation reaction under 85% effect of sulfuric acid.Reactant liquor neutralizes with sodium hydroxide solution, after filtration, distilling under reduced pressure, rectification under normal pressure is again collected 229-233 ℃ of fraction and is promptly got dipropylene glycol, and its structural formula is;
Dipropylene glycol and ester type compound thereof are applicable to that essence and flavoring agent and cosmetics etc. generally are used for the senior solvent that perfumery is used to the relatively more responsive purposes of abnormal smells from the patient, be used for easily reacting thermal sensitivity spice, also be used for dissolving cellulos, Lac, or as plasticizer, hygroscopic agent, softening agent, the water color ink solvent, lubricant, hygroscopic agent.
Summary of the invention
The object of the present invention is to provide the new purposes of dipropylene glycol and ester type compound thereof, i.e. new application in cosmetics.
Relate to dipropylene glycol and ester type compound thereof as the application in the hair-waving product of the low ammonia flavor of preparation
Relate to dipropylene glycol and ester type compound thereof as the application in the hair dyeing product of the low ammonia flavor of preparation
In order to understand essence of the present invention better, the effect of ammonia in hair-waving product and hair dyeing product introduced, sulfhydryl compound is the primary raw material of hair-waving product, under alkali condition, sulfhydryl compound has stronger reproducibility, this is because the effect of alkali can make the hair keratin expand, and helps the infiltration of Reducing agent, can improve curling effect.Alkaline agent as the agent of curling has ammonia, ammonium bicarbonate etc.Wherein the most frequently used alkali is ammonia, its action temperature and, molecule is less, is easy to infiltration, and is volatile, easily clean by washing.Alkali condition can make hair soft and expansion, helps dyestuff intermediate and infiltrates a marrow, and can improve the oxidizing force of oxidant.Therefore oxide hair dye is alkalescence, and its pH value can reach 9-10.5.The most frequently used alkali is ammonia, and some organic amines also can adopt or part replaces ammonia.Though some organic amines can all or part of replacement ammonia, effect is poorer than ammonia.On security of products, also be that ammonia is best simultaneously.In the hair-waving product of hair caring specialized market and hair dyeing product, inevitably to use ammonia, the zest of ammonia flavor can cause client and hairdresser's discomfort, therefore, country's " cosmetology place hygienic practice " regulation: manage area in the hair caring place more than 50 square metres, should be provided with between independent hair dyeing, hair-waving; Manage area less than 50 square metres hair caring place, should be provided with boiling hot, dye workplace (district), scalding, dye workplace (district) should have the force ventilation facility." barber shop, beauty salon sanitary standard " (the GB 9666-1996) that national health department formulates stipulates that the content of ammonia in every cubic metres of air is no more than 0.5 milligram.
Improve the quality of hair-waving product and hair dyeing product, the volatility that reduces its ammonia is exactly an important aspect.Utilize in dipropylene glycol and the ester type compound thereof three hydrogen atoms on the ammonia in three oxygen atoms and hair-waving product and the hair dyeing product to generate the ammonia rate of release that hydrogen bonds reduce hair-waving product and hair dyeing product surface, can guarantee to perm and hair dyeing effect can reduce the content of ammonia in the air again.
The specific embodiment
Can further be well understood to the present invention by specific embodiments of the invention given below.But they are not limitation of the invention.
Embodiment 1
The preparation that dark Semen Castaneae color dyes cream 3.4
Respectively oil phase 16, octadecanol 120 grams, No. 26 white oil 30 grams, the different monooctyl esters 10 of Semen Myristicae acid are restrained, water dipropylene glycol 20 gram, eicosyl trimethyl ammonium chloride 10 grams, hexadecyltrimethylammonium chloride 10 grams, sodium sulfite 5 grams, 2,5-diaminotoluene sulphate 7.5 grams, resorcinol 7 grams, m-aminophenol 4 grams, 2-amino-6-chloro-4 nitrophenols 1.3 grams, disodiumedetate 2 grams, deionized water 500 gram heating in water bath to 80 ℃～85 ℃.20 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 87 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams, continue to stir 10 minutes, finish.
The preparation of dioxygen breast
Water deionized water 600 grams, sodium lauryl sulphate 30 grams, disodiumedetate 1 gram, 10 gram fatty alcohol-polyoxyethylene ether 20 are heated to 85 ℃, oil phase 16, octadecanol 50 grams are poured into and are heated to 95 ℃ in the reaction pot, water is poured in the oil phase reaction pot again, start and stirred 5 minutes, lower the temperature 40 ℃.With 2.5 gram sodium hydrogen phosphates, 172 gram hydrogen peroxide (35%), be added in the 100 gram water and dissolve, be added in the reaction pot, add deionized water to mastic and weigh 1000 grams, continue to stir 5 minutes, finish.
Embodiment 2
In brown preparation of dying cream 4.77
Respectively oil phase 16, octadecanol 120 grams, No. 26 white oil 30 grams, the different monooctyl esters 10 of Semen Myristicae acid are restrained, water dipropylene glycol 20 gram, eicosyl trimethyl ammonium chloride 10 grams, hexadecyltrimethylammonium chloride 10 grams, sodium sulfite 5 grams, 2,5-diaminotoluene sulphate 11 grams, resorcinol 4.3 grams, m-aminophenol 0.3 gram, 2-amino-6-chloro-4 nitrophenols 1.3 grams, 2-methyl-resorcinol 1.5 grams, to adjacent phenyl methylcarbamate 0.6 gram of amino, disodiumedetate 2 grams, deionized water 500 gram heating in water bath to 80 ℃～85 ℃.20 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 87 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams, continue to stir 10 minutes, finish.
The preparation of dioxygen breast
Dioxygen breast with embodiment 1
Embodiment 3
Light brown is dyed the preparation of cream 5.77
Respectively oil phase 16, octadecanol 120 grams, No. 26 white oil 30 grams, the different monooctyl esters 10 of Semen Myristicae acid are restrained, water dipropylene glycol 20 gram, eicosyl trimethyl ammonium chloride 10 grams, hexadecyltrimethylammonium chloride 10 grams, sodium sulfite 5 grams, 2,5-diaminotoluene sulphate 11 grams, resorcinol 4.3 grams, m-aminophenol 0.3 gram, 2-amino-6-chloro-4 nitrophenols 1.3 grams, 2-methyl-resorcinol 1.5 grams, to adjacent phenyl methylcarbamate 0.6 gram of amino, disodiumedetate 2 grams, deionized water 500 gram heating in water bath to 80 ℃～85 ℃.20 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 87 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams, continue to stir 10 minutes, finish.
The preparation of dioxygen breast
Dioxygen breast with embodiment 1
Comparing embodiment 1
The preparation that dark Semen Castaneae color dyes cream 3.4
Respectively with oil phase 16, octadecanol 170 grams, stearic acid monoglycerides 30 grams, water sodium lauryl sulphate 40 gram, sodium sulfite 5 grams, 7.5 grams 2,5-diaminotoluene sulphate, 7 gram resorcinol, 4 gram m-aminophenols, 1.3 gram 2-amino-6-chloro-4 nitrophenols, disodiumedetate 2 grams, deionized water 500 gram heating in water bath to 80 ℃～85 ℃.20 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 87 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams.Continue to stir 10 minutes, finish.
The preparation of dioxygen breast
Dioxygen breast with embodiment 1
Comparing embodiment 2
In brown preparation of dying cream 4.77
Respectively with oil phase 16, octadecanol 170 grams, stearic acid monoglycerides 30 grams, water sodium lauryl sulphate 40 gram, sodium sulfite 5 grams, 2,5-diaminotoluene sulphate 11 grams, resorcinol 4.3 grams, m-aminophenol 0.3 gram, 2-amino-6-chloro-4 nitrophenols 1.3 grams, 2-methyl-resorcinol 1.5 grams, to adjacent phenyl methylcarbamate 0.6 gram of amino, disodiumedetate 2 grams, deionized water 500 gram heating in water bath to 80 ℃～85 ℃.20 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 87 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams.Continue to stir 10 minutes, finish.
The preparation of dioxygen breast
Dioxygen breast with embodiment 1
Comparing embodiment 3
Light brown is dyed the preparation of cream 5.77
Respectively with oil phase 16, octadecanol 170 grams, stearic acid monoglycerides 30 grams, water sodium lauryl sulphate 40 gram, sodium sulfite 5 grams, 2,5-diaminotoluene sulphate 11 grams, resorcinol 4.3 grams, m-aminophenol 0.3 gram, 2-amino-6-chloro-4 nitrophenols 1.3 grams, 2-methyl-resorcinol 1.5 grams, to adjacent phenyl methylcarbamate 0.6 gram of amino, disodiumedetate 2 grams, deionized water 500 gram heating in water bath to 80 ℃～85 ℃.20 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 87 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams.Continue to stir 10 minutes, finish.
The preparation of dioxygen breast
Dioxygen breast with embodiment 1
Following table 1 has provided the subjective appreciation result of the hair dyeing product that embodiment 1-3 and comparing embodiment 1-3 make
The embodiment of the invention and comparing embodiment are made ammoniated hair dyeing product be applied to client's hair dyeing, the hair dyeing product ammonia flavor of embodiment descends obviously, and hair color is consistent with Standard colour board
Table 1
* subjective appreciation is 5 clients or hairdresser's evaluation result, with reference colour version goodness of fit be the average result (full marks are 5 minutes) of 5 hairdresser groups evaluation
Embodiment 4
The preparation of straight hair cream
Respectively with oil phase 16, octadecanol 32 grams, No. 26 white oil 24 grams, stearic acid monoglycerides 8 grams, isopropyl myristate 16 grams, different monooctyl esters 16 grams of arachidic acid, water deionized water 600 grams, dipropylene glycol 20 grams, eicosyl trimethyl ammonium chloride 12 grams, hexadecyltrimethylammonium chloride 4 grams, TGA 108 grams, ammonium bicarbonate 30 gram heating in water bath to 80 ℃～85 ℃.73 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 87 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams.Continue to stir 10 minutes, finish.
The preparation of setting agent
Water deionized water 600 grams, 1.5 gram polyquaternary ammonium salt-37, disodiumedetate 1 gram, 10 gram fatty alcohol-polyoxyethylene ether-20 are heated to 85 ℃, oil phase 16, octadecanol 22 grams, 6 gram stearyl alcohol polyethers-20 are poured into and are heated to 95 ℃ in the reaction pot, water is poured in the oil phase reaction pot again, start and stirred 5 minutes, lower the temperature 40 ℃.With 2.5 gram sodium hydrogen phosphates, 57 gram hydrogen peroxide (35%), be added in the 100 gram water and dissolve, be added in the reaction pot, add deionized water to mastic and weigh 1000 grams, continue to stir 5 minutes, finish.
Embodiment 5
The preparation of straight hair cream
Respectively with oil phase 16, octadecanol 32 grams, No. 26 white oil 24 grams, stearic acid monoglycerides 8 grams, isopropyl myristate 16 grams, different monooctyl esters 16 grams of arachidic acid, water deionized water 600 grams, dipropylene glycol 20 grams, eicosyl trimethyl ammonium chloride 12 grams, hexadecyltrimethylammonium chloride 4 grams, TGA 80 gram heating in water bath to 80 ℃～85 ℃.73 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 100 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams.Continue to stir 10 minutes, finish.
The preparation of setting agent
Setting agent with embodiment 4
Comparing embodiment 4
The preparation of straight hair cream
Respectively with oil phase 16, octadecanol 32 grams, No. 26 white oil 24 grams, stearic acid monoglycerides 8 grams, isopropyl myristate 16 grams, different monooctyl esters 16 grams of arachidic acid, water eicosyl trimethyl ammonium chloride 12 grams, hexadecyltrimethylammonium chloride 4 grams, TGA 108 grams, ammonium bicarbonate 30 gram heating in water bath to 80 ℃～85 ℃.73 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 87 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams.Continue to stir 10 minutes, finish.
The preparation of setting agent
Setting agent with embodiment 4
Comparing embodiment 5
The preparation of straight hair cream
Respectively with oil phase 16, octadecanol 32 grams, No. 26 white oil 24 grams, stearic acid monoglycerides 8 grams, isopropyl myristate 16 grams, different monooctyl esters 16 grams of arachidic acid, water eicosyl trimethyl ammonium chloride 12 grams, hexadecyltrimethylammonium chloride 4 grams, TGA 80 gram heating in water bath to 80 ℃～85 ℃.73 gram ammonia (21%) are added to aqueous phase, and stirring makes it even slightly.Under condition of stirring, water is poured in the oil phase, mix emulsifying.Stir on the limit, limit cooling emulsified body to 40 ℃.Slowly add 5 gram essence and 100 gram ammonia (21%), add deionized water to mastic and weigh 1000 grams.Continue to stir 10 minutes, finish.
The preparation of setting agent
Setting agent with embodiment 4
Following table 2 has provided the subjective appreciation result of the hair-waving product that embodiment 4-5 and comparing embodiment 4-5 make
The embodiment of the invention is made ammoniated hair-waving product be applied to client hair-waving and frequently descend obviously than the hair-waving product ammonia flavor of embodiment, the hair-waving effect is basic identical.
Table 2
* subjective appreciation is 5 people group evaluation results
Claims (2)
1. relate to dipropylene glycol and ester type compound thereof as the application in the hair-waving product of the low ammonia flavor of preparation.
2. relate to dipropylene glycol and ester type compound thereof as the application in the hair dyeing product of the low ammonia flavor of preparation.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101976763A CN102038614A (en) | 2009-10-26 | 2009-10-26 | Application of dipropylene glycol and ester compounds thereof to hair perming and dyeing products |
| CN201080014763.1A CN102725032B (en) | 2009-10-26 | 2010-01-20 | Ammonia-containing permanent agent |
| PCT/CN2010/000087 WO2011050556A1 (en) | 2009-10-26 | 2010-01-20 | Ammonia-containing permanent agent and application of dipropylene glycol and ester compounds thereof as permanent product |
| ZA2012/03852A ZA201203852B (en) | 2009-10-26 | 2012-05-25 | Ammonia-containing permanent agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101976763A CN102038614A (en) | 2009-10-26 | 2009-10-26 | Application of dipropylene glycol and ester compounds thereof to hair perming and dyeing products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102038614A true CN102038614A (en) | 2011-05-04 |
Family
ID=43905387
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101976763A Pending CN102038614A (en) | 2009-10-26 | 2009-10-26 | Application of dipropylene glycol and ester compounds thereof to hair perming and dyeing products |
| CN201080014763.1A Active CN102725032B (en) | 2009-10-26 | 2010-01-20 | Ammonia-containing permanent agent |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080014763.1A Active CN102725032B (en) | 2009-10-26 | 2010-01-20 | Ammonia-containing permanent agent |
Country Status (3)
| Country | Link |
|---|---|
| CN (2) | CN102038614A (en) |
| WO (1) | WO2011050556A1 (en) |
| ZA (1) | ZA201203852B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103735429A (en) * | 2013-12-31 | 2014-04-23 | 广州市白云区大荣精细化工有限公司 | Perm preparation and preparation method thereof |
| CN107375115A (en) * | 2017-08-22 | 2017-11-24 | 刘家明 | The boiling hot formula of hydrogen hydro-thermal and technique |
| EP3662885A1 (en) * | 2018-12-06 | 2020-06-10 | Kao Germany GmbH | Process for reshaping keratin fibers |
| CN114796026A (en) * | 2022-05-13 | 2022-07-29 | 广州千羽化妆品有限公司 | Permanent wave agent with damaged hair repairing effect |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003040741A (en) * | 2001-05-21 | 2003-02-13 | Hoyu Co Ltd | Hair-deforming agent, agent for permanent wave, frizzy hair-correcting agent, article for permanent wave, and article for correcting the frizzy hair |
| JP4133017B2 (en) * | 2002-06-20 | 2008-08-13 | 株式会社資生堂 | Hair treatment composition |
| JP2006143616A (en) * | 2004-11-17 | 2006-06-08 | Sanei Kagaku Kk | Hair treatment composition |
| DE102004056801A1 (en) * | 2004-11-24 | 2006-06-08 | Wella Ag | Permanent hair shaping agent useful for carrying out reductive treatment in permanent hair shaping based on hair keratin-reducing compound, comprises cationic cellulose derivative |
-
2009
- 2009-10-26 CN CN2009101976763A patent/CN102038614A/en active Pending
-
2010
- 2010-01-20 WO PCT/CN2010/000087 patent/WO2011050556A1/en active Application Filing
- 2010-01-20 CN CN201080014763.1A patent/CN102725032B/en active Active
-
2012
- 2012-05-25 ZA ZA2012/03852A patent/ZA201203852B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011050556A1 (en) | 2011-05-05 |
| CN102725032B (en) | 2013-10-23 |
| ZA201203852B (en) | 2013-08-28 |
| CN102725032A (en) | 2012-10-10 |
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Application publication date: 20110504 |