CN102720075B - Machine printing binder for printing textiles and preparation method thereof - Google Patents
Machine printing binder for printing textiles and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a machine printing binder for printing textiles. The machine printing binder for printing textiles is characterized by comprising the following constituents according to part by weight: 70-100 parts of waterborne acrylic emulsion, 20-40 parts of waterborne polyurethane resin, 20 parts of glycerol, 10-20 parts of deionized water, 1 part of defoamer, 2-4 parts of abherent, 2 parts of antiblocking feel auxiliary, 6 parts of waterborne emulsion wax, 0.6 parts of multifunctional regulator, 1.6 parts of emulsifying thickener, 1.4-3.5 parts of waterborne thickener and 10 parts of ultrafine silicon dioxide. Sizes of the machine printing binder for printing textiles are printed on a screen printing machine continuously for 4-8 hours without blocking meshes; and printing products are placed for 24 hours at minus 20 DEG C, are good in feel and elasticity, and do not crack in stretching or fall off.
Description
Technical field:
The machine that the present invention relates to prints rubber cement, especially printing in textiles machine and prints rubber cement.
Background technology:
Now on market for the rubber cement product of printing in textiles roughly by aqueous acrylic emulsion and various function additive and color stuffing according to certain forming than row dispersion and emulsion.Because technical requirement threshold height is different, production technology is simplified and traditional to differ, cause the quality of a lot of printing mortars on the market uneven, product stability is not good, easily cause print works in use procedure and stamp finished product, occur below variety of issue: 1) printing mortar printing has sticky hand phenomenon after dry; 2) in plain net textile printing, fill in net; 3) pattern acute angle becomes fillet, little dot loss; 4) there is sticky random phenomenon in printed matter in transportation; 5) weatherability of Printing is poor, not water-fastness, easily come off, and fragmentation easy to crack under low temperature environment; 6) stamp product feel is bad, really up to the mark, poor flexibility.
Bonding agent printing industry can be divided into hand-printing and two kinds of modes of machinery printing by production technology at present.Because hand-printing subjectivity is excessively strong, different people, by different gimmicks, prints off product appearance and the performance come and is difficult to ensure consistent.Take a large amount of human resources and stamp inefficiency than hand-printing, print quality amount is uneven, adopts Printing Machinery stamp more convenient, quick, stable, saves a large amount of human resources, and is more suitable for large-scale production operation.At present, machine prints stamp and has been widely used in each print works and clothing factory, and respond well.
The performance of acrylic emulsion adopting due to printing mortar itself has determined most of printing mortar on the market, and under normal temperature state, serviceability is good; But temperature lower than zero degrees celsius or lower temperature conditions under, stamp product easily draw quick-fried, break, physical properties is had a greatly reduced quality.In the time that temperature is spent higher than 40, be easy to again return sticky, make the range of application of this type of slurry very limited, brought technical barrier also to numerous producers in the industry.
Add high boiling silicone oil can make slurry under low temperature environment, also can keep reluctantly stamp product physical property as antifreezing agent, the antifreeze rubber cement of major part is on the market all also to adopt in such a way to solve, but the method can not solve root problem.
Summary of the invention:
The invention provides a kind of printing in textiles machine and print rubber cement,, slurry 4-8 hour continuous printing on printing machine do not filled in net, and stamp product are deposited 24h under-20 degrees Celsius of environment, and stamp product feel elasticity is good, stretches and does not ftracture, and does not come off.
For achieving the above object, the present invention adopts following technical scheme:
Printing in textiles prints rubber cement with machine, it is characterized in that counting by weight by following component forming: aqueous acrylic emulsion 70-100 part, waterborne polyurethane resin 20-40 part, 20 parts of glycerol, deionized water 10-20 part, 1 part of defoamer, antitack agent 2-4 part, 2 parts of anti-stick feel auxiliary agents, 6 parts of water-based wax emulsions, 0.6 part of multifunctional regulator, 1.6 parts of emulsifing thickeners, water-based thickener 1.4-3.5 part, 10 parts of superfine silicon dioxides.
100 parts of aqueous acrylic emulsions described above, 40 parts of waterborne polyurethane resins, 20 parts of glycerol, 20 parts of deionized waters, 1 part of defoamer, 4 parts of antitack agents, 2 parts of anti-stick feel auxiliary agents, 6 parts of water-based wax emulsions, 0.6 part of multifunctional regulator, 1.6 parts of emulsifing thickeners, 3.5 parts of water-based thickeners, 10 parts of superfine silicon dioxides.
Aqueous acrylic emulsion described above is the chemical industry H-260 of Foshan San Shui association aqueous acrylic emulsion, described waterborne polyurethane resin is Bayer Bitterfeld GmbH 1380 waterborne polyurethane resins, described defoamer is the blue sub-chemical industry 502C defoamer in Foshan, described antitack agent is Guangzhou Si Luoke 46 high-performance antitack agents, described anti-stick feel auxiliary agent is the anti-stick feel auxiliary agent of Shanghai new promise chemical industry S-15, described water-based wax emulsion is Shanghai new promise chemical industry S-21 water-based wax emulsion, described multifunctional regulator is DOW Chemical AMP-95 multifunctional regulator, described emulsifing thickener is the modest chemical CX-42 emulsifing thickener of moral, described water-based thickener is Britain association colloid chemistry PTF water-based thickener, described superfine silicon dioxide is Degussa OK500 superfine silicon dioxide.
Printing in textiles as above prints the preparation method of rubber cement with machine, it is characterized in that comprising the steps:
The first step, add aqueous acrylic emulsion in experiment in still, then add waterborne polyurethane resin, after mixing, material is placed on stirring dispersion machine and is stirred, rotating speed is 500r/min, disperses to stir 10min;
Second step, maintenance stirring dispersion machine 500r/min continue to stir, and add successively glycerol, deionized water, defoamer, antitack agent, anti-stick feel auxiliary agent, water-based wax emulsion, is increased to 1000-1200r/min by stirring dispersion machine rotating speed after all adding, and disperses to stir 5min;
The 3rd step, treat that above-mentioned material dispersion evenly after, add multifunctional regulator, stirring dispersion machine rotating speed is 1200r/min, disperses 3min;
After the 4th step, confirmation are uniformly dispersed, slowly add emulsifing thickener, after adding, stirring dispersion machine rotating speed is increased to 1500-1800r/min, disperse to stir 5min;
The 5th step, above-mentioned material dispersion evenly after, add water-based thickener, keep stirring dispersion machine rotating speed 1800r/min to disperse to stir 5min;
The 6th step, add superfine silicon dioxide, agitator disk is down to experiment still bottommost and stirs 3min with 1800r/min; Then agitator disk is slowly elevated to experiment still middle part and keeps rotating speed to stir 3min, be so extrapolated to experiment still top and stir 3min, method circulation 2 times like this, finishes to dispersion process, and slurry is to stablize fine and smooth body of paste.
Machine printthrough gelatine size viscosity prepared by this scheme is at 80-100mps, and slurry 4-8 hour continuous printing on printing machine do not filled in net, and stamp product are deposited 24h under-20 degrees Celsius of environment, and stamp product feel elasticity is good, stretches and does not ftracture, and does not come off.
72 parts of aqueous acrylic emulsions described above, 20 parts of waterborne polyurethane resins, 20 parts of glycerol, 10 parts of deionized waters, 1 part of defoamer, 2 parts of antitack agents, 2 parts of anti-stick feel auxiliary agents, 6 parts of water-based wax emulsions, 0.6 part of multifunctional regulator, 1.6 parts of emulsifing thickeners, 1.4 parts of water-based thickeners, 10 parts of superfine silicon dioxides, also comprise 2 parts of sodium salt dispersants, 50 parts of titanium dioxides.
Aqueous acrylic emulsion described above is the chemical industry H-260 of Foshan San Shui association aqueous acrylic emulsion, described waterborne polyurethane resin is Bayer Bitterfeld GmbH 1380 waterborne polyurethane resins, described defoamer is the blue sub-chemical industry 502C defoamer in Foshan, described antitack agent is Guangzhou Si Luoke 46 high-performance antitack agents, described anti-stick feel auxiliary agent is the anti-stick feel auxiliary agent of Shanghai new promise chemical industry S-15, described water-based wax emulsion is Shanghai new promise chemical industry S-21 water-based wax emulsion, described multifunctional regulator is DOW Chemical AMP-95 multifunctional regulator, described emulsifing thickener is the modest chemical CX-42 emulsifing thickener of moral, described water-based thickener is Britain association colloid chemistry PTF water-based thickener, described superfine silicon dioxide is Degussa OK500 superfine silicon dioxide, described sodium salt dispersant is Rhom and Hass's 255 sodium salt dispersants, described titanium dioxide is Anhui An Nada AV-01 titanium dioxide.
Printing in textiles as above prints the preparation method of rubber cement with machine, it is characterized in that comprising the steps:
The first step, add aqueous acrylic emulsion in experiment in still, then add waterborne polyurethane resin, after mixing, material is placed on stirring dispersion machine and carries out middle stirring at low speed, rotating speed, at 500r/min, disperses to stir 10min;
Second step, maintenance stirring dispersion machine rotating speed 500r/min continue to stir, and add successively glycerol, deionized water, defoamer, antitack agent, anti-stick feel auxiliary agent, water-based wax emulsion, is increased to 1000-1200r/min by stirring dispersion machine rotating speed after all adding, and disperses to stir 5min;
The 3rd step, treat that above-mentioned material dispersion evenly after, add multifunctional regulator, sodium salt dispersant, stirring dispersion machine rotating speed disperses 3min at 1200r/min;
After the 4th step, confirmation are uniformly dispersed, slowly add emulsifing thickener, after adding, stirring dispersion machine rotating speed is increased to 1500-1800r/min, disperse to stir 5min;
The 5th step, above-mentioned material dispersion evenly after, add water-based thickener, keep stirring dispersion machine rotating speed to disperse to stir 5min in 1800r/min high speed, after completing, system should be stable emulsified body, without graininess material and exquisiteness;
The 6th step, maintenance rotating speed, add superfine silicon dioxide, and titanium dioxide is down to experiment still bottommost by agitator disk and is stirred 3min with 1800r/min; Then agitator disk is slowly elevated to experiment still middle part and keeps rotating speed to stir 3min, be so extrapolated to experiment still top and stir 3min, method circulation 2 times like this, whole system has been disperseed;
The 7th step, cross machine with three roller grinding agents and grind once.
Machine prepared by this scheme prints PVA glue viscosity at 80-100mps, and slurry 4-8 hour continuous printing on printing machine do not filled in net, and stamp product are deposited 24h under-20 degrees Celsius of environment, and stamp product feel elasticity is good, stretches and does not ftracture, and does not come off.
Advantage of the present invention:
1. slurry continuous printing for long time on printing machine is not filled in net, adds glycerol in system, adjusts the dry speed of whole system.
2. the polyurethane resin that the film of employing own is softer and good springiness wash water fastness is good, as the link stuff of rubber cement, coordinates other auxiliary agents, fundamentally solves antifreeze problem, and stamp product are deposited 24h under-20 degrees Celsius of environment;
3. in system, add superfine silicon dioxide to coordinate suitable to wax emulsion and the silicone oil of row, can make slurry reach dry and comfortable tack-free performance requirement.
4. the good stretching of stamp product feel elasticity is not ftractureed, and does not come off; Stamp product surface dry is tack-free.
Specific implementation method:
Below in conjunction with embodiment, the invention will be further described.In following enforcement, H-260 aqueous acrylic emulsion is to be provided by Foshan San Shui association chemical industry; 1380 waterborne polyurethane resins are to be provided by Bayer Bitterfeld GmbH science and technology, and glycerol solvent is to be provided by Jiangsu Shun Tiandong sky chemical industry; 502C defoamer is provided by the blue sub-chemical industry in Foshan, and 46 high-performance antitack agents are to be provided by Guangzhou Si Luoke, and S-21 water-based wax emulsion is to be provided by the new promise chemical industry in Shanghai, and the anti-stick feel auxiliary agent of S-15 is to be provided by the new promise chemical industry in Shanghai; AMP-95 multifunctional regulator is to be provided by DOW Chemical, and 255 sodium salt dispersants are to be provided by Rhom and Hass; CX-42 emulsifing thickener is provided by the modest chemistry of moral (Shanghai Co., Ltd); PTF water-based thickener is to be provided by Britain's association colloid chemistry; OK500 superfine silicon dioxide is to be provided by Degussa; AV-01 titanium dioxide is to be provided by Anhui An Nada company.
Embodiment:
Machine prints antifreeze interspongioplastic substance:
The first step, add 100g H-260 acrylic emulsion in experiment in still, then add 40g 1380 water polyurethane resins, after mixing, material is placed on stirring dispersion machine and carries out middle stirring at low speed, rotating speed is advisable at 500r/min.Keep this speed to disperse to stir 10min left and right;
Second step, maintenance stirring dispersion machine 500r/min continue to stir, add successively glycerol 20g, deionized water 20g, 502C defoamer 1g, 46 high-performance antitack agent 4g, the anti-stick feel auxiliary agent of S-15 2g, is increased to 1000-1200r/min by stirring dispersion machine rotating speed after S-21 water-based wax emulsion 6g. all adds, and disperses to stir 5min;
The 3rd step, treat that above-mentioned material dispersion evenly after, add AMP-95 multifunctional regulator 0.6g, stirring dispersion machine rotating speed disperses 3min at 1200r/min;
After the 4th step, above step complete, whole material system should be more uniform mixed liquor, and graininess material does not have.After confirming to be uniformly dispersed, slowly add CX-42 emulsifing thickener 1.6g.Note must slowly adding while adding this material.After adding, stirring dispersion machine rotating speed is increased to 1500-1800r/min, disperses to stir 5min;
The 5th step, above-mentioned material dispersion evenly after, add PTF water-based thickener 3.5g, keep stirring dispersion machine 1800r/min high speed to disperse to stir 5min.After completing, system should be stable emulsified body, without graininess material and exquisiteness;
The 6th step, add OK500 superfine silicon dioxide 10g, agitator disk is down to experiment still bottommost and stirs 3min with 1800r/min; Then agitator disk is slowly elevated to experiment still middle part and keeps rotating speed to stir 3min, be so extrapolated to experiment still top and stir 3min.Method circulation 2 times like this, whole system just can be disperseed uniformly.Test the dispersion process that feeds intake and finish, slurry should be stablizes fine and smooth body of paste;
The 7th step, get suitably above-mentioned scattered slurry, scrape its fineness with Hegman grind gage.Qualified fineness is below 20um.By its viscosity of Japan product TVC-5 type viscosity instrumentation, be 80-100mps.
Machine prints antifreeze PVA glue
The first step, add 72g H-260 aqueous acrylic emulsion in experiment in still, then add 20g 1380 waterborne polyurethane resins, after mixing, material is placed on stirring dispersion machine and carries out middle stirring at low speed, rotating speed is advisable at 500r/min.Keep this speed to disperse to stir 10min left and right;
Second step, maintenance stirring dispersion machine rotating speed 500r/min continue to stir, add successively glycerol 20g, deionized water 10g, 502C defoamer 1g, 46 high-performance antitack agent 2g, the anti-stick feel auxiliary agent of S-15 2g, is increased to 1000-1200r/min by stirring dispersion machine rotating speed after S-21 water-based wax emulsion 6g. all adds, and disperses to stir 5min;
The 3rd step, treat that above-mentioned material dispersion evenly after, add APM-95 multifunctional regulator 0.6g, 255 sodium salt dispersant 2g, stirring dispersion machine rotating speed disperses 3min at 1200r/min;
After the 4th step, confirmation are uniformly dispersed, slowly add CX-42 emulsifing thickener 1.6g.Note must slowly adding while adding this material.After adding, stirring dispersion machine rotating speed is increased to 1500-1800r/min, disperses to stir 5min;
The 5th step, above-mentioned material dispersion evenly after, add PTF water-based thickener 1.4g, keep stirring dispersion machine rotating speed to disperse to stir 5min in 1800r/min high speed.After completing, system should be stable emulsified body, without graininess material and exquisiteness;
The 6th step, maintenance rotating speed, add OK500 superfine silicon dioxide 10g, and AV-01 titanium dioxide 50g is down to experiment still bottommost by agitator disk and stirs 3min with 1800r/min; Then agitator disk is slowly elevated to experiment still middle part and keeps rotating speed to stir 3min, be so extrapolated to experiment still top and stir 3min.Method circulation 2 times like this, whole system has been disperseed substantially;
The 7th step, cross machine grind once with three roller grinding agents, the now whole experiment dispersion grinding process that feeds intake completes.
The 8th step, get suitably above-mentioned scattered slurry, scrape its fineness with Hegman grind gage.Fineness is below 20um.By its viscosity of Japan product TVC-5 type viscosity instrumentation, be 80-100mps.
Table 1 is the present invention's color lattice machine seal rubber cement performance comparison situation wider with current application on the market:
Table 1
As can be seen from Table 1, rubber cement of the present invention is in application process, and COLOR FASTNESS, washing fastness, elasticity are better than comparative example, and minimum antifreeze temperature reaches-20 DEG C, and storage stability is greater than 180 days.
Claims (2)
1. printing in textiles prints rubber cement with machine, it is characterized in that counting by weight by following component and form: aqueous acrylic emulsion 70-100 part, waterborne polyurethane resin 20-40 part, 20 parts of glycerol, deionized water 10-20 part, 1 part of defoamer, antitack agent 2-4 part, 2 parts of anti-stick feel auxiliary agents, 6 parts of water-based wax emulsions, 0.6 part of multifunctional regulator, 1.6 parts of emulsifing thickeners, water-based thickener 1.4-3.5 part, 10 parts of superfine silicon dioxides, described aqueous acrylic emulsion is the chemical industry H-260 of Foshan San Shui association aqueous acrylic emulsion, described waterborne polyurethane resin is Bayer Bitterfeld GmbH 1380 waterborne polyurethane resins, described defoamer is the blue sub-chemical industry 502C defoamer in Foshan, described antitack agent is Guangzhou Si Luoke 46 high-performance antitack agents, described anti-stick feel auxiliary agent is the anti-stick feel auxiliary agent of Shanghai new promise chemical industry S-15, described water-based wax emulsion is Shanghai new promise chemical industry S-21 water-based wax emulsion, described multifunctional regulator is DOW Chemical AMP-95 multifunctional regulator, described emulsifing thickener is the modest chemical CX-42 emulsifing thickener of moral, described water-based thickener is Britain association colloid chemistry PTF water-based thickener, described superfine silicon dioxide is Degussa OK500 superfine silicon dioxide,
Described printing in textiles prints the preparation method of rubber cement with machine, comprise the steps:
The first step, add aqueous acrylic emulsion in experiment in still, then add waterborne polyurethane resin, after mixing, material is placed on stirring dispersion machine and is stirred, rotating speed is 500r/min, disperses to stir 10min;
Second step, maintenance stirring dispersion machine 500r/min continue to stir, and add successively glycerol, deionized water, defoamer, antitack agent, anti-stick feel auxiliary agent, water-based wax emulsion, is increased to 1000-1200r/min by stirring dispersion machine rotating speed after all adding, and disperses to stir 5min;
The 3rd step, treat that above-mentioned material dispersion evenly after, add multifunctional regulator, stirring dispersion machine rotating speed is 1200r/min, disperses 3min;
After the 4th step, confirmation are uniformly dispersed, slowly add emulsifing thickener, after adding, stirring dispersion machine rotating speed is increased to 1500-1800r/min, disperse to stir 5min;
The 5th step, above-mentioned material dispersion evenly after, add water-based thickener, keep stirring dispersion machine rotating speed 1800r/min to disperse to stir 5min;
The 6th step, add superfine silicon dioxide, agitator disk is down to experiment still bottommost and stirs 3min with 1800r/min; Then agitator disk is slowly elevated to experiment still middle part and keeps rotating speed to stir 3min, be so extrapolated to experiment still top and stir 3min, method circulation 2 times like this, finishes to dispersion process, and slurry is to stablize fine and smooth body of paste.
2. printing in textiles as claimed in claim 1 prints rubber cement with machine, it is characterized in that: also comprise 2 parts of sodium salt dispersants, 50 parts of titanium dioxides, described sodium salt dispersant is Rhom and Hass's 255 sodium salt dispersants, described titanium dioxide is Anhui An Nada AV-01 titanium dioxide, described sodium salt dispersant adds together with multifunctional regulator in the 3rd step, and described titanium dioxide adds together with superfine silicon dioxide in the 6th step.
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Family Cites Families (8)
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| GB2330586B (en) * | 1997-10-27 | 2001-03-14 | Scott Bader Co | Aqueous pigment printing paste composition |
| JP2005139340A (en) * | 2003-11-07 | 2005-06-02 | Nippon Carbide Ind Co Inc | Aqueous composition of acrylic copolymer for textile printing |
| CN100419152C (en) * | 2006-09-13 | 2008-09-17 | 合肥安大天辐新材料有限公司 | Environment-protection coating printing adhesive and its preparing method |
| CN101948555B (en) * | 2010-09-30 | 2013-08-21 | 东莞长联新材料科技股份有限公司 | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder |
| CN102093780B (en) * | 2010-12-31 | 2013-06-12 | 广东佳景科技有限公司 | Non-woven fabric environmental-protection water-based ink and preparation method thereof |
| CN102191694B (en) * | 2011-03-22 | 2012-11-14 | 广州慧谷化学有限公司 | Environmentally-friendly machine-printed rubber adhesive used for embossing on textile coating as well as preparation method and application thereof |
| CN102321984B (en) * | 2011-06-25 | 2013-04-03 | 百利合化工（中山）有限公司 | High-gloss washing resistant environmental-friendly print paste and preparation method thereof |
| CN102286888A (en) * | 2011-07-12 | 2011-12-21 | 宏大研究院有限公司 | Environment-friendly printing mortar |
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