CN102704613A - Light heat-insulating wall body material and preparation method thereof - Google Patents

Light heat-insulating wall body material and preparation method thereof Download PDF

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CN102704613A
CN102704613A CN2012101948182A CN201210194818A CN102704613A CN 102704613 A CN102704613 A CN 102704613A CN 2012101948182 A CN2012101948182 A CN 2012101948182A CN 201210194818 A CN201210194818 A CN 201210194818A CN 102704613 A CN102704613 A CN 102704613A
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light heat
preparation
wall material
insulation wall
material according
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CN102704613B (en
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王艳冰
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Jiangsu Jianhua New Wall Material Co Ltd
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Jiangsu Jianhua New Wall Material Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • Y02A30/244Structural elements or technologies for improving thermal insulation using natural or recycled building materials, e.g. straw, wool, clay or used tires

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Abstract

The invention provides light heat-insulating wall body material, which comprises a body and holes, wherein the holes are formed in the body in an intensive manner. The invention also provides a preparation method of the light heat-insulating wall body material, which comprises the steps as follows: step 1, cement, silica sand powders, ceramsites, polystyrene granules, a water-reducing agent and water are stirred uniformly to obtain concrete; and step 2, a mesh reinforcement rack is put in a die for preparing light wall body material, the stirred concrete is uniformly arranged in the die, vibration and groove compaction are carried out and then atmospheric pressure stream curing is carried out, and then high-temperature high-pressure curing is performed after the die is removed, so as to obtain light heat-insulating wall body material. The light heat-insulating wall body material achieves good thermal insulation performance, good refractability, light mass and low cost, and is convenient to use; in addition, the preparation method adopts simple technology, the adopted polystyrene granules have rich sources, the price is low, the quality is less influenced by external factors, and the preparation method is suitable for industrialized production.

Description

A kind of light heat-insulation wall material and preparation method thereof
Technical field
The present invention relates to a kind of preparation method of materials for wall, particularly a kind of preparation method of light heat-insulation wall material.
Background technology
Along with development of science and technology, people have higher requirement to constructional materials.Existing heat-preserving heat-insulating wall material is all undesirable on various performances; Existing light wall material mainly contains: the gel materials for wall; Adopt cementitious material, haydite, sand, water reducing agent and water etc. to be made; The sheet material surface density is big, relies on haydite to improve the heat preservation and insulation of sheet material, poor effect merely; Cement perlite glass fiber light wall material, its defective are the perlite water imbibitions, indoor seasoning, and suction back wall skin comes off; Glass fiber light wall material, its defective are that alkali resistance is poor, are Powdered after the corrosion, and pulling force and tension force reduce; Cement mortar light wall material, its defective are that the materials for wall volume is heavy, are prone to moisture absorption expansion drying and shrink the generation crack; In addition in order to reach heat insulation effect, also have and adopt the outer materials for wall that pastes self-insulation system, though can improve the heat insulating effect fire endurance and combustibility does not reach requirement.
In producing light wall material technology for building, bubble mainly adopts following two kinds of system foam method formulas in the concrete at present.The one, machinery system bubble, the gas that adopts the animal/vegetable protein blowing agent to convert water and certain pressure by a certain percentage makes foam through the gauze wire cloth of certain compactness together, adds the forced mixer stirring again and in concrete, forms pore; Yet this method system bubble receives the blowing agent performance impact bigger, and the size of air pressure and the compaction rate of gauze wire cloth also can influence foaming effect, and the bubble survival rate is lower in stirring the back concrete simultaneously, and many is harmful pores of connection.The 2nd, chemical blowing gets into 50~70 ℃ of steaming kiln maintenances after adopting raw material such as aluminium powder or hydrogen peroxide solution and flyash, gypsum to mix to be stirred into mould, generation hydrogen or oxygen in this process and in concrete, form pore; Yet this method requires more sternly should not control to curing temperature, exists harmful pore of more connection to have a strong impact on concrete compressive strength and durability in the concrete simultaneously.
Summary of the invention
Goal of the invention: existing light heat insulation material heat preservation and insulation is not good in order to solve, the defective of refractoriness difference, the invention provides a kind of light heat-insulation wall material and preparation method thereof.
Technical scheme: in order solving the problems of the technologies described above, to the invention provides a kind of light heat-insulation wall material, to comprise the hole that body and body interior are intensive.
A kind of preferred as technical scheme of the present invention, the described hole diameter is 1-2mm, evenly distributes, to obtain the durability of better heat insulating ability, refractoriness and materials for wall.
The present invention also provides a kind of preparation method of light heat-insulation wall material, may further comprise the steps:
(1) with the even concrete that gets of raw material stirring, said raw material comprises cement, silica flour, haydite, granular polystyrene, water reducing agent and water;
(2) the preparation light wall material mould in place bar frame, the concrete that stirs evenly is distributed in the mould, through the indent that vibrates after atmospheric steam curing again through the HTHP maintenance, promptly gets said light heat-insulation wall material after the form removal.
In order to obtain better heat insulating ability and refractoriness, optimized process conditions:
In the step (1), mixing time is 150-240 second; Can make stirring more even, more economical;
The diameter of said granular polystyrene is 1-2mm, and the empty size of size control materials for wall through granular polystyrene makes size more even;
Said water reducing agent is preferably one or more mixture of polycarboxylate water-reducer, naphthalene water reducer, aliphatic water reducing agent and amino water reducing agent;
Said raw material also comprises blowing agent, and said blowing agent is preferably one or more mixture of vegetable protein blowing agent, rosin 206 blowing agents, azodiisobutyronitrile and neopelex;
In the step (2), said atmospheric steam curing temperature is 60-90 ℃, and the time is 3.5-6.0h; Said high-pressure steaming and cultivating temperature is controlled at 150-180 ℃, and pressure is 0.85-1.1Mpa, and the time is 5-8h;
Said raw material is to add 0.1-0.5m in the common prescription 3Granular polystyrene, every cubic meter of concrete raw material use amount is preferably: cement 200-500Kg, 0.1-1000Kg sand, silica flour 0.1-200Kg, haydite 0.1-0.8m 3, granular polystyrene 0.1-0.5m 3, water reducing agent 0.1-10Kg, water 0.1-200Kg.
Beneficial effect: the present invention compared with prior art, its remarkable advantage is: a kind of light heat-insulation wall material thermal and insulating performance provided by the invention is good, refractoriness is good, light weight, easy to use, cost is low.
The granular polystyrene of employing 1-2mm replaces traditional sand as fine aggregate, can obviously alleviate the surface density of lightweight body of wall, makes the materials for wall quality lighter, convenient transportation and use.And materials for wall is behind the HTHP steam press maintenance, and granular polystyrene has not existed itself in the sheet material concrete structure, thereby can not influence its fire endurance because of the existence of granular polystyrene, has improved the fire resistance of sheet material greatly; And the space that granular polystyrene is left over after disappearing because of cement slurry is wrapped to form a large amount of disconnected pores, and in this pore the coefficient of thermal conductivity of secluding air well below haydite concrete, thereby improve its thermal and insulating performance greatly; And granular polystyrene is wrapped evenly distribution in concrete by cement slurry after stirring, and after pressing steaming, all becomes self-existent pore, and each pore does not link to each other mutually, and concrete durability is not had influence.
Simultaneously, this preparation method's technology is simple, and the granular polystyrene source of employing is abundant, and cheap, quality receives external factor affecting little, is suitable for suitability for industrialized production.0
Description of drawings
Fig. 1 is the light heat-insulation wall material sectional drawing.
The specific embodiment
Embodiment 1
Light heat-insulation wall material is seen Fig. 1, comprises the hole that body and body interior are intensive, and the diameter of described hole is 1-2mm, evenly distributes.Its preparation may further comprise the steps:
(1) to adopt particle diameter be the granular polystyrene of 1-2mm with cement, sand, silica flour, haydite, granular polystyrene, water reducing agent, blowing agent and the water of common prescription join stir in the forced stirrer concrete; Mixing time is 150s from beginning to be dosed into to stir to finish; Wherein, the consumption of every cubic metre of composite soil preparation need granular polystyrene is 0.1m 3
(2) in the lightweight body of wall mould of cleaning out for building, place bar frame, the concrete material that stirs is being distributed in the mould uniformly, through passing through atmospheric steam curing again behind the indent that vibrates, the atmospheric steam curing temperature is 90 ℃, and the time is 3.5h.Torn open and got into autoclave behind the mould and promptly obtain light wall material after through the HTHP maintenance.The high-pressure steaming and cultivating temperature is controlled at 150 ℃, and the time is 8h, and pressure is 1.1Mpa.
Water reducing agent is selected from one or more mixture of polycarboxylate water-reducer, naphthalene water reducer, aliphatic water reducing agent and amino water reducing agent.
Blowing agent is selected from one or more mixture of vegetable protein blowing agent, rosin 206 blowing agents, azodiisobutyronitrile and neopelex.
Embodiment 2
Light heat-insulation wall material comprises the hole that body and body interior are intensive, and the diameter of described hole is 1-2mm, evenly distributes.Its preparation may further comprise the steps:
(1) to adopt particle diameter be the granular polystyrene of 1-2mm with cement, sand, silica flour, haydite, granular polystyrene, water reducing agent and the water of common prescription join stir in the forced stirrer concrete, stirring finishes is 240s to mixing time from beginning to be dosed into; Wherein, the consumption of every cubic metre of composite soil preparation need granular polystyrene is 0.5m 3
(2) in the lightweight body of wall mould of cleaning out for building, place bar frame, the concrete material that stirs is being distributed in the mould uniformly, through passing through atmospheric steam curing again behind the indent that vibrates, the atmospheric steam curing temperature is 60 ℃, and the time is 6.0h.Torn open and got into autoclave behind the mould and promptly obtain light wall material after through the HTHP maintenance.The high-pressure steaming and cultivating temperature is controlled at 180 ℃, and the time is 5h, and pressure is 0.85Mpa.
Water reducing agent is selected from one or more mixture of polycarboxylate water-reducer, naphthalene water reducer, aliphatic water reducing agent and amino water reducing agent.
Embodiment 3
The preparation of light heat-insulation wall material may further comprise the steps:
Produce long 3000mm, thickness of slab is 100mm, and the core bore dia is the Light trabs for building of 50mm.Adopt the granular polystyrene equal-volume of diameter 1-2mm to substitute 0.2-0.4m in the common prescription 3Yellow ground; Put in the forced stirrer with cement, haydite, sand, silica flour, water reducing agent, blowing agent and water and to stir 200 seconds; Again in the lightweight body of wall mould for building cleaned out of feeding through vibrating, indent is loosed core, maintenance 5 hours in 80 ℃ steam again; Back maintenance 7 hours in 170 ℃ of high temperature, the autoclave of pressure at 0.85Mpa promptly gets.
Embodiment 4
Measure the performance of embodiment 1 to 3 said light heat-insulation wall material, the assay method of concrete coefficient of thermal conductivity, concrete density adopts conventional method:
The performance test of table 1 embodiment 1 to 3 said light heat-insulation wall material
Embodiment 5
Adopt the preparation method of embodiment 1 to prepare materials for wall, difference only is:
Every cubic meter of concrete uses raw material to be: cement 200-500Kg, sand 0.1-1000Kg, silica flour 0.1-200Kg, haydite 0.1-0.8m3, granular polystyrene 0.1-0.5m3, water reducing agent 0-10Kg, blowing agent 0-10Kg, water 0-200Kg;
Water reducing agent is one or more the mixture in polycarboxylate water-reducer, naphthalene water reducer, aliphatic water reducing agent and the amino water reducing agent.
Blowing agent is one or more the mixture in vegetable protein blowing agent, rosin 206 blowing agents, azodiisobutyronitrile and the neopelex.
The light heat-insulation wall material of table 2 different material preparation
Figure BDA00001759264500051

Claims (10)

1. a light heat-insulation wall material is characterized in that: comprise the hole that body and body interior are intensive.
2. a kind of light heat-insulation wall material according to claim 1 is characterized in that: each described hole diameter is 1-2mm.
3. a kind of light heat-insulation wall material according to claim 1, it is characterized in that: described hole evenly distributes.
4. the preparation method of a kind of light heat-insulation wall material according to claim 1 is characterized in that: may further comprise the steps:
(1) with the even concrete that gets of raw material stirring, said raw material comprises cement, sand, silica flour, haydite, granular polystyrene, water reducing agent and water;
(2) the preparation light wall material mould in place bar frame, the concrete that stirs evenly is distributed in the mould, through the indent that vibrates after atmospheric steam curing again through the HTHP maintenance, promptly gets said light heat-insulation wall material after the form removal.
5. the preparation method of a kind of light heat-insulation wall material according to claim 4, it is characterized in that: in the step (1), mixing time is 150-240 second.
6. the preparation method of a kind of light heat-insulation wall material according to claim 4, it is characterized in that: in the step (1), the diameter of said granular polystyrene is 1-2mm.
7. the preparation method of a kind of light heat-insulation wall material according to claim 4; It is characterized in that: in the step (1), said water reducing agent is one or more a mixture of polycarboxylate water-reducer, naphthalene water reducer, aliphatic water reducing agent and amino water reducing agent.
8. the preparation method of a kind of light heat-insulation wall material according to claim 4; It is characterized in that: said raw material also comprises blowing agent, and said blowing agent is one or more a mixture of vegetable protein blowing agent, rosin 206 blowing agents, azodiisobutyronitrile and neopelex.
9. the preparation method of a kind of light heat-insulation wall material according to claim 4, it is characterized in that: in the step (2), said atmospheric steam curing temperature is 60-90 ℃, and the time is 3.5-6.0h.
10. the preparation method of a kind of light heat-insulation wall material according to claim 4, it is characterized in that: in the step (2), said high-pressure steaming and cultivating temperature is controlled at 150-180 ℃, and pressure is 0.85-1.1Mpa, and the time is 5-8h.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105272011A (en) * 2015-11-03 2016-01-27 江苏建华新型墙材有限公司 Method for producing light-weight novel wall body material through detritus mixing and steam curing
CN106830809A (en) * 2017-03-09 2017-06-13 深圳市超超科技发展有限公司 A kind of light-high-strength foaming stone material materials for wall and preparation method thereof
CN108275955A (en) * 2018-04-11 2018-07-13 山东联海新型建材有限公司 A kind of light-weighted autoclaved air entrained concrete plate material of thermal-insulating type and preparation method
CN113580323A (en) * 2021-08-03 2021-11-02 重庆地下应用技术研究院有限公司 Forming processing method for building heat-insulating energy-saving cement product

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JPH0725655A (en) * 1993-07-06 1995-01-27 Shimizu Corp Hydraulic particle and production thereof
CN1931780A (en) * 2006-09-06 2007-03-21 哈尔滨工程大学 Light energy-saving heat-insulating wall material
CN102108026A (en) * 2011-01-07 2011-06-29 中山建华管桩有限公司墙体材料分公司 Novel haydite concrete light-weight building block walling material and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105272011A (en) * 2015-11-03 2016-01-27 江苏建华新型墙材有限公司 Method for producing light-weight novel wall body material through detritus mixing and steam curing
CN106830809A (en) * 2017-03-09 2017-06-13 深圳市超超科技发展有限公司 A kind of light-high-strength foaming stone material materials for wall and preparation method thereof
CN108275955A (en) * 2018-04-11 2018-07-13 山东联海新型建材有限公司 A kind of light-weighted autoclaved air entrained concrete plate material of thermal-insulating type and preparation method
CN113580323A (en) * 2021-08-03 2021-11-02 重庆地下应用技术研究院有限公司 Forming processing method for building heat-insulating energy-saving cement product

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