CN102696676A - Strong oxidation reduction potential solid disinfectant, method for preparing same and application thereof - Google Patents
Strong oxidation reduction potential solid disinfectant, method for preparing same and application thereof Download PDFInfo
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Abstract
The invention provides a strong oxidation reduction potential solid disinfectant. The disinfectant is characterized by comprising a preparation which consists of a preparation A and a preparation B, wherein the preparation A mainly contains solid sodium chlorite or calcium hypochlorite; in order to improve the stability of the disinfectant, the preparation A contains a certain amount of light stabilizer of fatty alcohol-polyoxyethylene ether, pH value stabilizer of sodium carbonate or calcium chloride and synergist of nano silicon dioxide; the preparation B comprises solid citric acid, malic acid or maleic acid and aluminum trichloride; and the binary preparation consists of the preparation A and the preparation B, which are specially used for preparing a disinfectant solution with oxidation activity. The disinfectant solution prepared by the method contains a certain number of electrolytes, is based on raising the oxidation reduction potential (ORP) of the prepared solution to more than 800 to 1100mV and contains active oxygen and partial hypochlorous acid or chlorine dioxide, and simultaneously, the invention also provides a method for preparing the solid disinfectant and the application of the solid disinfectant.
Description
Invention field
The present invention relates to a kind of strong redox potential solid disinfection sanitizer, and the preparation method and its usage of this disinfection sanitizer.The solid disinfection sanitizer of this strong redox potential can be applied to body surface or the space that all culture fisheries, various animal-breedings field, hospital, family etc. are used to sterilize, and said body surface and space also comprise the sterilization of animal drinking water or the skin sterilization sterilization use of animal; Also comprise simultaneously the field use of field of environment protection and agricultural planting industry.
Background technology
Utilize the redox potential value of the seawater of actual measurement can judge the redox state of water body and the variation of character.
Corresponding to the oxidability (PE is about 12.5 volts) of the good normal seawater of ventilation, some valence variation elements mainly exist with its high oxidation state form in the water: C-CO
2, HCO
- 3, CO
+- 3, N-NO
- 3NO
- 2S-SO
+- 4Fe-FeOOH; Mn-Mn
2O
3Deng.Therefore the high oxidation state of some element of marine organisms growth needs, contains the seawater of the oxidisability of these element high price compositions, is suitable for halobiontic growth, breeding.When PE value (redox potential value) drops to pact-4.2 left and right sides, mean that just dissolved oxygen is exhausted in the seawater, H appears simultaneously
2The reducing substances that S etc. are poisonous to marine organisms, this seawater can be referred to as the reproducibility seawater.(hiding 1986 the 10th the 1st phases of volume of redox potential " Marine Sciences " of dimension tinkling of pieces of jade seawater)
Describe the power of certain system redox ability, generally can adopt redox potential or PE value.
Electrolyzed oxidizing water, its sterilization mechanism are through actings in conjunction such as oxidation and high redox potential, hydroxyl, free radical, hydroxide, disturb the DNA of pathogene and RNA to synthesize; Make the microprotein sex change, the enzyme system inactivation influences its metabolism; Increase the permeability of its cell membrane; Cause the outflow of desmoenzyme and nutriment, the pathogene dissolving is broken, and is the effect of the combination of physics and chemical disinfection sterilization principle.
Electrolyzed oxidizing water is a kind of sterilization waters of the 1980's in Japan's appearance, obtains the extensive approval of medical circle afterwards gradually.The physico chemical property of test electrolyzed oxidizing water, have following special index: pH value is below 2.7, and redox potential is more than 1000mv, and concentration of residual chlorine is in 20-80PPm.Japan related organization is to the clinical trial certificate of electrolyzed oxidizing water, and the bactericidal effect of electrolyzed oxidizing water not only is higher than common disinfectant, alcohol and potassium permanganate etc., and skin is not had bad stimulation.
Abroad; Electrolyzed oxidizing water not only is used for sterilization; Part medical personnel finds that also various skin diseases such as seat sore dermatitis, eczema, ringworm of the body, telephium are had result of treatment; Some medical personnel passes through the washing test to burn, wound site, but proves the healing of electrolyzed oxidizing water accelerated in wounds.Also have some medical personnels with all kinds of cankers in the electrolyzed oxidizing water treatment body, equally also received obvious effects,, can cure about 20 days generally speaking such as treatment is washed at stomach, duodenal ulcer position.
In Japan and other national effects that confirmed electrolyzed oxidizing water, about its sterilization mechanism, the most representative at present have two kinds of physics and chemical theories.
Analyze from the physics theory, think the tolerant oxidizing potential standard of general cells of microorganisms film generally at 400-700mv, the oxidizing potential standard of electrolyzed oxidizing water is then up to more than the 1000mv, and in this environment, microorganism can't survive in fact.Arrive through laboratory observation, general cells of microorganisms film will break when oxidizing potential is higher than 800mv, and is dead then.
Chemical theory also is on the bases of a large amount of tests, to obtain, and thinks that the principal element of electrolyzed oxidizing water sterilization is oxygen and chlorine and (OH) base.In fact these compositions are just in time with to undertake the composition of active oxygen of neutrophil cell bactericidal action identical in the animal body.
Advantages such as electrolyzed oxidizing water is low, pollution-free with its toxicity, bactericidal effect is good receive the attention of aquaculture, environmental protection industry and medicine and hygiene fields.But; Also there are certain restraining factors in electrolyzed oxidizing water; These restraining factors cause the popularization that it can not be general: the one, and the production of electrolyzed oxidizing water must could obtain in a kind of special electrolysis installation; This electrolysis installation not only price is high, and the loss of the yin, yang electrode of equipment is big, causes the production cost of electrolyzed oxidizing water to improve; The 2nd, the electrolyzed oxidizing water that adopts special electrolysis installation to produce, the resting period is short, can only use at the field fabrication scene; The 3rd, the pH value of the electrolyzed oxidizing water of electrolysis production is on the low side, causes a lot of inconvenience for the on-the-spot scope of using.
In the production method of solid redox current potential disinfectant, on the books among the known publication number CN1559222A, this patent application has been carried out partly describing to disclosed technology at present.In this patented method, adopt unified dosage form; And in corresponding acid regulator, adopt hydrochloric acid or niter cake; Wherein unified preparation exists active ingredient to lose gradually, and storage time and condition of storage limitation are bigger, and the acidity of acid regulator hydrochloric acid or niter cake is big; And all there is hidden danger in the hydrochloric acid of one of said active ingredient in transportation, storage and circulation, be not easy to execute-in-place especially; In addition, do not have measure and means in this patented method, comprise light stability agent and related measures such as the agent of pH value stabilization, synergist for the stability that improves its patent of invention product.
Record among another known publication number CN101356925A; Also present disclosed technology has been carried out more detailed description; But known publication number CN101356925A and known publication number CN1035477A have certain relevance, and the weak point same with recording of known publication number CN1559222A.Known publication number CN1035477A is because the technical formula design is more single; Do not carry out necessary protectiveness prescription design; Such as the design of anti-light and pH value stabilization, synergy etc., so have very big loss of active ingredients in its transportation, storage and the process of circulation.
Because there is not the adding of light stability agent; Just can not slow down the photodecomposition of light to main active ingredient in the disinfectant preparation; Can not utilize its high activity surface function, reduce the surface tension of the disinfectant solution of being prepared, the penetration of raising drug effect, lack the effect of Synergistic.But in above all publication subject schemes, all do not carry out the prescription design of light stability agent.
In above all publication subject schemes; The light of control active ingredient stable with pH value stabilization property and transportation, the convenience problem that stores and use, be their a common major obstacle, in fact; Even there is wherein obstacle; The capital is related to the stability of target product, such as for prevent product store and transportation in slow sour separation factors, the agent of pH value stabilization should be absolutely necessary.
In above all publication subject schemes; Its technical goal product is owing to lack the prescription design of above-mentioned key component; Therefore there are many obstacles in its technical goal product in the safe ready property of circulation, storage and use, to such an extent as to above-mentioned all publications are can stood big limitation in the application in some field.
Summary of the invention
Design according to subject schemes of the present invention; Mainly be to the technological deficiency that exists in the above-mentioned disclosed technology; Be mainly reflected in order to improve a kind of strong redox potential solid sterilizing stability of formulation ability of the present invention, contain a certain amount of light stability agent AEO, pH value stabilization agent sodium carbonate or calcium chloride and synergist nano silicon in the said A agent.Design according to subject schemes of the present invention; Prescription design such as light stability agent; Can slow down the photodecomposition of light to main active ingredient; Utilize its high active surfactant simultaneously, reduce the surface tension of the disinfectant solution of being prepared, the penetration of raising drug effect, have the effect of Synergistic.
According to the design of subject schemes of the present invention, the adding of said synergist nano silicon mainly is in order to address the problem: the one, through adding nano silicon, be used to improve the storage stability and the durability of disinfectant of the present invention; The 2nd, nano silicon fixedly chlorine dioxide or hypochlorite ion is stable at and is difficult for free volatilization in the disinfectant solution of being prepared, and what is called delays offending smell dissociates out in solution, thereby has synergistic effect.
Technical scheme realizes
According to the design of subject schemes of the present invention, mainly be to realize through following technical scheme:
Is the solid sterilizing preparation that medium can produce strong redox potential based on a kind of of two doses of A, B through water; Wherein, The sodium chlorite or the calcium hypochlorite that contain q.s in the said A agent; Wherein also contain a certain amount of light stability agent AEO, pH value stabilization agent sodium carbonate or calcium chloride, synergist nano silicon, be used for the stability of transportation, storage security and the use of this disinfectant preparation.Contain the mixture that comprises solid alchlor, citric acid, malic acid or maleic acid or wherein a kind of in the said B agent.
Each said characteristic in the A agent is made up of the material of following weight mark: sodium chlorite 20-80%, sodium carbonate 9-25%; Calcium chloride 8-35%, nano silicon 3-18%, AEO 0.1-2%; The material of above-mentioned weight fraction also can be by sodium chlorite 40-80%; Wherein pH value stabilization agent sodium carbonate or calcium chloride can be that wherein a kind of or both mixtures are formed, and its ratio is 8-35%; Other are synergist nano silicon 3-18%, light stability agent AEO 0.1-2%.
Each said characteristic in the said A agent also can be made up of the material of following weight mark: calcium hypochlorite 20-80%, sodium bicarbonate 9-25%; Calcium chloride 8-35%, nano silicon 3-18%, AEO 0.1-2%; The material of above-mentioned weight fraction also can be by calcium hypochlorite 40-80%; Wherein pH value stabilization agent sodium carbonate or calcium chloride can be that wherein a kind of or both mixtures are formed, and its ratio is 8-35%; Other are synergist nano silicon 3-18%, light stability agent AEO 0.1-2%.
The material that in the said B agent is the following weight mark is formed: in alchlor 20-80%, citric acid or malic acid and the maleic acid any one; Its ratio is the 20-80% that accounts for B agent toatl proportion, also can be that wherein any two or one is compatible with alchlor.
The described solid sterilizing preparation that can produce strong redox potential through aqueous medium; Wherein, The said A agent and the B agent that can produce the solid sterilizing preparation of strong redox potential through aqueous medium is dissolved in respectively in a certain amount of water, the redox potential of said sterilizing preparation be between 800mV one 1100mV or more than.
The described solid sterilizing preparation that can produce strong redox potential through aqueous medium; According to instructions for use, earlier the A agent is dissolved in 6-16 and rises in the quantitative pure water, or be in the qualified running water at least; Again the B agent is added mixed dissolution, as the stoste of strong redox potential disinfectant preparation.
The described purposes scope that can produce the solid sterilizing preparation of strong redox potential through aqueous medium; Can be body surface or the space that all culture fisheries, various animal-breedings field, hospital, family etc. are used to sterilize; Said body surface and space comprise that also the sterilization of animal drinking water or the skin degerming of animal use; The present invention also can be applicable to sterilizations such as tableware, fruit and other article, wherein also comprises in field of environment protection and the agricultural planting industry field using.
The present invention has the following advantages
Design according to subject schemes of the present invention; The adding of light stability agent AEO; Can slow down the photodecomposition of light to main active ingredient in a kind of solid sterilizing preparation that can produce strong redox potential through aqueous medium of the present invention; Utilize its high activity surface function simultaneously, reduce the surface tension of the disinfectant solution of being prepared, the penetration of raising drug effect, have the effect of Synergistic.
According to the design of subject schemes of the present invention,, especially prescription has been designed the agent of pH value stabilization in order to prevent the slow sour separation factors of product of the present invention in storage and transportation.
According to the design of subject schemes of the present invention, the adding of said synergist nano silicon mainly is in order to address the problem: the one, through adding nano silicon, be used to improve the storage stability and the durability of disinfectant of the present invention; The 2nd, nano silicon fixedly chlorine dioxide or hypochlorite ion is stable at and is difficult for free volatilization in the disinfectant solution of being prepared, and what is called delays offending smell dissociates out in solution, thereby has synergistic effect.
Embodiment:
Below through embodiment the present invention is done further elaboration, the umber of each component among the embodiment is percentage.
Embodiment 1:
A agent: pct %, sodium carbonate 9%, calcium chloride 4%, nano silicon 2%, AEO 0.8%, pure water 4.2%;
B agent: citric acid 30%, alchlor 40%, malic acid 20%, maleic acid 10%;
The production of A agent: at first sodium chlorite 80%, sodium carbonate 9%, calcium chloride 4%, nano silicon 2% in the A agent are successively added a rotating speed and be no more than in the ceramic lined stainless steel stirred tank of per minute 30 commentaries on classics; Then AEO 0.8% is dissolved in 4.2% the pure water; Method with compression spraying slowly sprays on the material in the ceramic lined stainless steel stirred tank that is rotating uniformly; Stir again after spraying is accomplished and stop after 10 minutes stirring; Pour out material in tray heat resistant plastice pallet, get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-10 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the A agent.
The production of B agent: add citric acid 30%, alchlor 40%, malic acid 20%, maleic acid 10% respectively in the stainless steel stirred tank and to stir; Pour in the tray heat resistant plastice pallet; Get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-12 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the B agent.
Above-mentioned A agent is dissolved in 10 liters of pure water, and the back that stirs adds the B agent, and the back that stirs can obtain the available chlorine content about 2300mg/l, the disinfectant stock solution of redox potential about 1 volt approximately.
Embodiment 2:
A agent: sodium chlorite 85%, sodium carbonate 6%, calcium chloride 2%, nano silicon 2%, AEO 0.8%, pure water 4.2%;
B agent: alchlor 40%, malic acid 40%, maleic acid 20%;
The production of A agent: at first sodium chlorite 85%, sodium carbonate 6%, calcium chloride 2%, nano silicon 2% in the A agent are successively added a rotating speed and be no more than in the ceramic lined stainless steel stirred tank of per minute 30 commentaries on classics; Then AEO 0.8% is dissolved in 4.2% the pure water; Method with compression spraying slowly sprays on the material in the ceramic lined stainless steel stirred tank that is rotating uniformly; Stir again after spraying is accomplished and stop after 10 minutes stirring; Pour out material in tray heat resistant plastice pallet, get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-10 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the A agent.
The production of B agent: add alchlor 40%, malic acid 40%, maleic acid 20% respectively in the stainless steel stirred tank and to stir; Pour in the tray heat resistant plastice pallet; Get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-12 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the B agent.
Above-mentioned A agent is dissolved in 10 liters of pure water, and the back that stirs adds the B agent, and the back that stirs can obtain the above available chlorine content of 2300mg/l approximately, and redox potential is at the disinfectant stock solution more than 1 volt.
Embodiment 3:
A agent: sodium chlorite 90%, sodium carbonate 3%, nano silicon 2%, AEO 0.8%, pure water 4.2%;
B agent: citric acid 30%, alchlor 50%, malic acid 20%;
The production of A agent: at first sodium chlorite 90%, sodium carbonate 3%, nano silicon 2% in the A agent are successively added a rotating speed and be no more than in the ceramic lined stainless steel stirred tank of per minute 30 commentaries on classics; Then AEO 0.8% is dissolved in 4.2% the pure water; Method with compression spraying slowly sprays on the material in the ceramic lined stainless steel stirred tank that is rotating uniformly; Stir again after spraying is accomplished and stop after 10 minutes stirring; Pour out material in tray heat resistant plastice pallet, get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-10 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the A agent.
The production of B agent: add citric acid 30%, alchlor 50%, malic acid 20% respectively in the stainless steel stirred tank and to stir; Pour in the tray heat resistant plastice pallet; Get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-12 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the B agent.
Above-mentioned A agent is dissolved in 10 liters of pure water, and the back that stirs adds the B agent, and the back that stirs can obtain the above available chlorine of 2300mg/l approximately, and redox potential is at the disinfectant stock solution more than 1.1 volts.
Embodiment 4:
A agent: calcium hypochlorite 80%, sodium carbonate 9%, calcium chloride 4%, nano silicon 2%, nano silicon 2%, AEO 0.8%, pure water 4.2%;
B agent: citric acid 30%, alchlor 40%, malic acid 20%, maleic acid 10%;
The production of A agent: at first sodium chlorite 80%, sodium carbonate 9%, calcium chloride 4%, nano silicon 2% in the A agent are successively added a rotating speed and be no more than in the ceramic lined stainless steel stirred tank of per minute 30 commentaries on classics; Then AEO 0.8% is dissolved in 4.2% the pure water; Method with compression spraying slowly sprays on the material in the ceramic lined stainless steel stirred tank that is rotating uniformly; Stir again after spraying is accomplished and stop after 10 minutes stirring; Pour out material in tray heat resistant plastice pallet, get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-10 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the A agent.
The production of B agent: citric acid 30%, alchlor 40%, malic acid 20%, maleic acid 10% add respectively in the stainless steel stirred tank and stir; Pour in the tray heat resistant plastice pallet; Get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-12 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the B agent.
Above-mentioned A agent is dissolved in 10 liters of pure water, and the back that stirs adds the B agent, and the back that stirs can obtain 2300mg/l left and right sides available chlorine content, the disinfectant stock solution of redox potential about 1 volt approximately.
Embodiment 5:
A agent: calcium hypochlorite 85%, sodium carbonate 6%, calcium chloride 2%, nano silicon 2%, AEO 0.8%, pure water 4.2%;
B agent: alchlor 40%, malic acid 40%, maleic acid 20%;
The production of A agent: at first calcium hypochlorite 85%, sodium carbonate 6%, calcium chloride 2%, nano silicon 2% in the A agent are successively added a rotating speed and be no more than in the ceramic lined stainless steel stirred tank of per minute 30 commentaries on classics; Then AEO 0.8% is dissolved in 4.2% the pure water; Method with compression spraying slowly sprays on the material in the ceramic lined stainless steel stirred tank that is rotating uniformly; Stir again after spraying is accomplished and stop after 10 minutes stirring; Pour out material in tray heat resistant plastice pallet, get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-10 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the A agent.
The production of B agent: add alchlor 40%, malic acid 40%, maleic acid 20% respectively in the stainless steel stirred tank and to stir; Pour in the tray heat resistant plastice pallet; Get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-12 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the B agent.
Above-mentioned A agent is dissolved in 10 liters of pure water, and the back that stirs adds the B agent, and the back that stirs can obtain the above available chlorine content of 2300mg/l approximately, and redox potential is at the disinfectant stock solution more than 1 volt.
Embodiment 6:
A agent: calcium hypochlorite 90%, sodium carbonate 3%, nano silicon 2%, AEO 0.8%, pure water 4.2%;
B agent: citric acid 30%, alchlor 50%, malic acid 20%;
The production of A agent: at first calcium hypochlorite 90%, sodium carbonate 3%, nano silicon 2% in the A agent are successively added a rotating speed and be no more than in the ceramic lined stainless steel stirred tank of per minute 30 commentaries on classics; Then AEO 0.8% is dissolved in 4.2% the pure water; Method with compression spraying slowly sprays on the material in the ceramic lined stainless steel stirred tank that is rotating uniformly; Stir again after spraying is accomplished and stop after 10 minutes stirring; Pour out material in tray heat resistant plastice pallet, get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-10 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the A agent.
The production of B agent: add citric acid 30%, alchlor 50%, malic acid 20% respectively in the stainless steel stirred tank and to stir; Pour in the tray heat resistant plastice pallet; Get into the low temperature drying case after (temperature is not higher than 50 degree) inner drying 8-12 hour, with 55 grams be sub-packed in the moistureproof plastic sack and the sealing back as the B agent.
Above-mentioned A agent is dissolved in 10 liters of pure water, and the back that stirs adds the B agent, and the back that stirs can obtain containing more than the 2300mg/l effective chlorinity approximately, and redox potential is at the disinfectant stock solution more than 1.1 volts.
The use liquid medium of above-described strong redox potential solid sterilizing preparation mainly is pure water or qualified running water.
The purposes scope of the strong redox potential solid of above-described this patent sterilizing preparation; Can be body surface or the space that all culture fisheries, various animal-breedings field, hospital, family etc. are used to sterilize; Said body surface and space also comprise the sterilizing of animal drinking water or the skin sterilization sterilization use of animal; The present invention also can be applicable to sterilizings such as tableware, fruit and other article, also comprises the field use of field of environment protection and agricultural planting industry.
Claims (10)
1. one kind strong redox potential solid sterilizing preparation is characterized in that:
Based on A, B is the solid sterilizing preparation that medium can produce strong redox potential through water for two doses; Wherein, The sodium chlorite or the calcium hypochlorite that contain q.s in the said A agent; Contain the mixture that comprises solid alchlor, citric acid, malic acid or maleic acid or wherein a kind of in the said B agent, wherein, sodium chlorite or calcium hypochlorite are to exist with unbodied form in the said A agent.
2. strong redox potential solid sterilizing preparation according to claim 1; Wherein, Contain a certain amount of light stability agent AEO, pH value stabilization agent sodium carbonate or calcium chloride, synergist nano silicon in the said disinfectant A agent, be used for the stability of transportation, storage security and the use of this disinfectant preparation.
3. according to each said characteristic in the A agent among the claim 1-2, form: sodium chlorite 20-80%, sodium carbonate 9-25% by the material of following weight mark; Calcium chloride 8-35%, nano silicon 3-18%, AEO 0.1-2%; The material of above-mentioned weight fraction also can be by sodium chlorite 40-80%; Wherein pH value stabilization agent sodium carbonate or calcium chloride can be that wherein a kind of or both mixtures are formed, and its ratio is 8-35%; Other are synergist nano silicon 3-18%, light stability agent AEO 0.1-2%.
4. according to the strong redox potential solid sterilizing preparation described in the claim 1-3, each said characteristic in the said A agent also can be made up of the material of following weight mark: calcium hypochlorite 20-80%; Sodium bicarbonate 9-25%, calcium chloride 8-35%, nano silicon 3-18%; AEO 0.1-2%, the material of above-mentioned weight fraction also can be by calcium hypochlorite 40-80%, wherein pH value stabilization agent sodium carbonate or calcium chloride; Can be that wherein a kind of or both mixtures are formed; Its ratio is 8-35%, and other are synergist nano silicon 3-18%, light stability agent AEO 0.1-2%.
5. according to the described strong redox potential solid sterilizing preparation of claim 1-4, the material that contains the following weight mark in the said B agent is formed: comprise solid alchlor 20-80%, citric acid 9-25%, malic acid 8-35%, maleic acid 3-20%.
6. according to the strong redox potential solid sterilizing preparation described in the claim 5; The material that also can be the following weight mark in the said B agent is formed: in alchlor 20-80%, citric acid or malic acid and the maleic acid any one; Its ratio is the 20-80% that accounts for B agent toatl proportion, also can be that wherein any two or one is compatible with alchlor.
7. according to the strong redox potential solid sterilizing preparation described in the claim 1-6, said A agent and B agent pack respectively, and before packing respectively in temperature the drying box inner drying of 30-60 degree 1-24 hour.
8. according to the strong redox potential solid sterilizing preparation described in the claim 1-7; Wherein, According to instructions for use; The A agent and the B agent of said strong redox potential solid sterilizing preparation are dissolved in respectively in a certain amount of water, and its pH value is between the 2-8 scope, the redox potential of said sterilizing preparation be between the 800mV-1100mV or more than.
9. the strong redox potential solid sterilizing preparation described in according to Claim 8; According to instructions for use, earlier the A agent is dissolved in 6-16 and rises in the quantitative pure water, or be in the qualified running water at least; Again the B agent is added mixed dissolution, as the stoste of strong redox potential disinfectant preparation.
10. according to the purposes scope of each described strong redox potential solid sterilizing preparation among the claim 1-9; Can be body surface or the space that all culture fisheries, various animal-breedings field, hospital, family etc. are used to sterilize; Said body surface and space comprise that also the sterilization of animal drinking water or the skin degerming of animal use, and also comprise the field use of field of environment protection and agricultural planting industry.
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| CN107326389A (en) * | 2017-07-05 | 2017-11-07 | 北京瑞和益生科技有限公司 | A kind of production method for stablizing the hypochlorite solution preserved |
| CN109418261A (en) * | 2017-08-25 | 2019-03-05 | 三博生化科技（上海）有限公司 | A kind of oxidation-reduction potential regulator, preparation method and its application |
| CN109418261B (en) * | 2017-08-25 | 2021-10-26 | 三博生物科技(上海)有限公司 | Oxidation-reduction potential regulator, preparation method and application thereof |
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| CN109907069A (en) * | 2019-03-25 | 2019-06-21 | 天津市郁峰化工有限公司 | A kind of hypochlorous acid thimerosal and preparation method thereof |
| CN111296477A (en) * | 2020-04-07 | 2020-06-19 | 成都民生消毒剂有限责任公司 | Composite calcium hypochlorite disinfectant |
| TWI759989B (en) * | 2020-12-02 | 2022-04-01 | 全鵬科技股份有限公司 | Disinfectant, manufacturing method of the same and use of the same |
| CN112831797A (en) * | 2020-12-31 | 2021-05-25 | 平湖爱之馨环保科技有限公司 | Composite electrolytic salt and electrolytic mother liquor prepared by using same |
| WO2024078778A1 (en) * | 2022-10-10 | 2024-04-18 | Wiab Water Innovation Ab | Compositions and methods for treatment and prevention of pathogens |
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