CN102676085A - Yellow cleaning glue and preparation method thereof - Google Patents
Yellow cleaning glue and preparation method thereof Download PDFInfo
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- CN102676085A CN102676085A CN2012101403886A CN201210140388A CN102676085A CN 102676085 A CN102676085 A CN 102676085A CN 2012101403886 A CN2012101403886 A CN 2012101403886A CN 201210140388 A CN201210140388 A CN 201210140388A CN 102676085 A CN102676085 A CN 102676085A
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Abstract
The invention relates to yellow cleaning glue and a preparation method thereof. The yellow cleaning glue provided by the invention is prepared from water, guar gum, carrageenan, locust bean gum, triethanolamine, sodium sorbate, 3-carboxyl-5-hydroxyl-1-(p-sulfophenyl)-4-(p- sulfophenyl azobenzene)-ortho-pyrrole trisodium salt, lutein, ethyl acetate, D-limonene, citral, glycerol, propylene glycol, didecyl dimethyl ammonium chloride, sodium sesquicarbonate and lauryl sodium sulfate. The yellow cleaning glue has the advantages of strong cleaning capability, high stability, oxidation resistance, acid and alkali resistance, heat and light resistance, and long use and storage life, wherein the storage life is one year at the temperature of 5DEG C below zero to 35DEG C, and the strong cleaning capability is represented on strong ash and powder sticking capability and also represented on the strong dirt cleaning and oil pollution removing capability. On the aspect of color, the yellow pigment of the yellow cleaning glue is stable, and the yellow cleaning glue does not change color when meeting common types of dirt.
Description
Technical field
The present invention relates to a kind of cleaning rubber and preparation method thereof.
Background technology
At present, a lot of product outer structures are complicated, and especially electric equipment products can not the water big area be cleaned during cleaning, therefore can pinch into the cleaning rubber of different shape and just be pushed to the market and widespread use.Cleaning rubber is mainly used in all kinds of article of cleaning dead angle, like the cleaning computor-keyboard, and inner chamber of car, the electrical equipment that shoes and outer structure are complicated, especially to the electric equipment products of band dense arrangement button, applicability is very strong.Though existing cleaning rubber can be pinched into different shape and have stronger sticking ash to glue the powder ability, but still many deficiencies are arranged, show that mainly existing cleaning rubber is to a little less than sticking to the knot Fouling Cleaning ability on the electrical equipment outside surface; Lack ability of cleaning greasy dirt, and unstable chemcial property, especially acid and alkali-resistance; Anti-oxidant reduction and fast light hot ability cause it under 10～25 ℃ normal temperature, and the preservation life-span is not long; Generally at 6-8 month, work-ing life was shorter.
In addition, existing one type of cleaning rubber is arranged is to be formed as tenderizer and Z 150PH combined preparation by phthalic ester and analogue, and this type cleaning rubber also has toxicity, repeatedly uses naked manual manipulation very harmful to health during cleaning; Aspect color, existing cleaning rubber mainly is divided into redness, and is yellow and blue, and wherein the effect of color on cleaning rubber is very big, mainly is to be prone to see clearly be cleaned dirt and soot particle in order to clean as the cleaning rubber background color.What existing yellow cleaning rubber was used is industrial pigment, this after yellow cleaning rubber is used repeatedly, variable color easily, and especially being prone to become black behind the clean metal surface can't use.
Summary of the invention
Goal of the invention of the present invention is the deficiency that exists to above-mentioned existing cleaning rubber, provide the sticking powder ability of a kind of sticking ash strong, and it is strong to settle accounts the dirt ability, and degreasing result is good, and stability is high and use and preserve long yellow cleaning rubber of life-span.
Another object of the present invention provides the preparation method of above-mentioned cleaning rubber.
In order to realize the foregoing invention purpose, the technical scheme below the present invention has adopted:
A kind of yellow cleaning rubber, should process by following component according to weight percent meter:
Water: 70～85%;
Guar gum: 4～10%;
Carrageenin: 1～4%;
Locust bean gum: 3～8%;
Trolamine: 2～3%;
Sodium sorbate: 0.2～0.5%;
3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt: 0.05～0.08%;
Xenthophylls: 0.01～0.02%;
ETHYLE ACETATE: 0.01～0.03%;
The D-ramie is rare: 0.01～0.03%;
Itral: 0.01～0.03%;
Glycerine: 0.5～2%;
Ucar 35: 1～2%;
Timbercote 2000: 0.02～0.08%;
Sodium sesquicarbonate: 0.2～0.6%
Sodium lauryl sulphate: 1～1.8%;
Said above-mentioned each component percentage composition sum is 100%.
As preferably, should process by following component according to weight percent meter:
Water: 77.83%;
Guar gum: 6%;
Carrageenin: 2%;
Locust bean gum: 5%;
Trolamine: 4%;
Sodium sorbate: 0.5%;
3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt: 0.07%;
Xenthophylls: 0.01%;
ETHYLE ACETATE: 0.01%;
The D-ramie is rare: 0.02%;
Itral: 0.01%;
Glycerine: 2%;
Ucar 35: 1%;
Timbercote 2000: 0.05%;
Sodium sesquicarbonate: 0.5%
Sodium lauryl sulphate: 1%.
A kind of preparation method of above-mentioned yellow cleaning rubber, this preparation method may further comprise the steps: (1) is poured water, Ucar 35, glycerine, carrageenin, locust bean gum and guar gum in the container into, stirs 5-10 minute; Add 3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium, xenthophylls, sodium sesquicarbonate, sodium lauryl sulphate, sodium sorbate and Timbercote 2000 again; Stir and obtained mixed glue solution in 2-5 minute; Mixed liquor is poured in the extruding machine and heat temperature raising to 120～130 ℃; Treat temperature between 120～130 ℃, start extruding machine work, pour extruding fully of the interior mixed glue solution of extruding machine the most at last into;
(2) mixed glue solution of extruding in the step (1) is added in the stirrer; Cover the stirring cover; Add again that ETHYLE ACETATE, D-ramie are rare, itral and trolamine, remain on temperature and between 95～100 ℃, stirred 20-30 minute, cooling obtains yellow cleaning rubber finished product.
Above-mentioned yellow cleaning rubber provided by the invention, as colloidal stroma, especially guar gum, carrageenin and locust bean gum combination make that colloidal stroma stability is very good by water, guar gum, carrageenin and locust bean gum.Sodium lauryl sulphate is as tensio-active agent; Its effect is the dissolving power that increases cleaning rubber; Make it possess water-soluble and oil soluble simultaneously, tensio-active agent and above-mentioned colloidal stroma cooperate, and promptly sodium lauryl sulphate is mixed into the part of yellow cleaning rubber; Make and the yellow cleaning rubber can not only remove water-soluble dirt, and degreasing result is also very good.Timbercote 2000 is the cats product with germicidal action, promptly also is a kind of sterilant.Can also strengthen cleaning effect when Timbercote 2000 is used as tensio-active agent, and sterilizing ability being very strong when the sterilant, is to go out and clean 2 times, and it also has excellent stability in hard water, kills algae effect and mould fungus inhibition effect in addition.The Timbercote 2000 that adds among the present invention plays above-mentioned dual function in final cleaning rubber; And its stability in hard water makes the yellow cleaning rubber for preparing behind the dissolving dirt; Still do not lose sterilizing ability, this also is going out and the unexistent performance of clean sterilant of using always.Glycerine and Ucar 35 are wetting Agent for Printing Inkss, keep moisture not volatile, prolong the work-ing life of these article.Itral, the D-ramie is rare and ETHYLE ACETATE as food grade essence, its effect is to remove the micro-irritating smell that trolamine brings, simultaneously to these article increase citrus scented.Sodium sesquicarbonate still is a kind of acid-base buffer agent, can stablize potential of hydrogen.Sodium sorbate is a kind of weakly alkaline sanitas, and the ability mould fungus inhibition can also be with the sterilant sterilization, and the combination sterilization effect is good.
The more important thing is that effect of the present invention focuses on cooperatively interacting between above-mentioned each component, therefore most components possess selectivity and irreplaceability.Though glycerine and Ucar 35 are all as wetting Agent for Printing Inks, the another one effect is also that for the character of combination of components is more stable like the solvent of Ucar 35 as itral, glycerine is as the rare solvent of D-ramie, just finally can be that it is miscible between each component.Likewise, in cleaning course, the composition complicacy of dirt is various, and it is particularly important that the mixing ability seems, Ucar 35, glycerine, water and tensio-active agent are all made combined contributions on cleaning effect, and cleaning effect is very good.Aspect ph stability; Component of the present invention is selected neutral component mostly for use, and sodium sorbate is wherein met water solvent and is extremely weak basic salt, and it cooperates sodium sesquicarbonate can stablize potential of hydrogen; Also the external dirt that dissolves in possessed very strong antiacid alkali changing capability, the ph stability of the glue that keeps clean.Carrageenin and locust bean gum still are emulsifing thickener simultaneously; Being convenient to the component emulsification of preparation process mixes; Also increased the viscosity of cleaning rubber, cooperated guar gum and water and the low component of other percentage compositions, outside finally showing is that the sticking grey ability of sticking powder is strong in the cleaning course.
Aspect color, 3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt is that a kind of another name is a Tartrazol yellow, and the lemon yellow pigment of English by name Tartrazine is though this pigment is heat-resisting, light, salt, oxidized easy to change.The chemical name of xenthophylls is 3 ' 3-dihydroxyl-alpha-carotene, is a kind of natural pigment with resistance of oxidation.Above-mentioned 3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt and xenthophylls join in the component, especially with component in sodium sesquicarbonate combination, finally make the colour stable and the nondiscoloration of yellow cleaning rubber.
In a word; This yellow cleaning rubber cleaning capacity of the present invention is strong, shows that not only the sticking powder ability of sticking ash is strong, also settles accounts dirt and ability of cleaning greasy dirt is strong; Stability is high; Antioxidant, soda acid, heat, light, and use and to preserve the life-span long, the preservation life-span wherein is under-5～35 ℃ of temperature, can preserve more than 1 year.Aspect color, the equal nondiscoloration of the stable common all kinds of dirts of chance of the xanthein of cleaning rubber of the present invention.
Embodiment
Be the present invention to be done further to describe for example below through embodiment.
Embodiment 1:
A kind of above-mentioned yellow cleaning rubber, should should the yellow cleaning rubber process according to weight percent by following component:
Water: 77.83%;
Guar gum: 6%;
Carrageenin: 2%;
Locust bean gum: 5%;
Trolamine: 4%;
Sodium sorbate: 0.5%;
3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt: 0.07%;
Xenthophylls: 0.01%;
ETHYLE ACETATE: 0.01%;
The D-ramie is rare: 0.02%;
Itral: 0.01%;
Glycerine: 2%;
Ucar 35: 1%;
Timbercote 2000: 0.05%;
Sodium sesquicarbonate: 0.5%
Sodium lauryl sulphate: 1%.
The preparation method of this yellow cleaning rubber may further comprise the steps:
(1) water, Ucar 35, glycerine, carrageenin, locust bean gum and guar gum are poured in the container, stirred 5-10 minute; Add 3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium, xenthophylls, sodium sesquicarbonate, sodium lauryl sulphate, sodium sorbate and Timbercote 2000 again; Stir and obtained mixed glue solution in 2-5 minute; Mixed liquor is poured in the extruding machine and heat temperature raising to 120～130 ℃; Treat temperature between 120～130 ℃, start extruding machine work, pour extruding fully of the interior mixed glue solution of extruding machine the most at last into; Carrageenin wherein and locust bean gum are convenient to mix between each component as emulsifying agent, have also increased the viscosity of liquid simultaneously, become glue after feasible the mixing.
(2) mixed glue solution of extruding in the step (1) is added in the stirrer; Cover the stirring cover; Add again that ETHYLE ACETATE, D-ramie are rare, itral and trolamine, remain on temperature and between 95～100 ℃, stirred 20-30 minute, cooling obtains yellow cleaning rubber finished product.The effect of trolamine is that glue is frozen into deformable and flexible colloid, so just can obtain yellow cleaning rubber finished product.
Above-mentioned each step is all carried out under normal pressure.
The preservation life-span of this yellow cleaning rubber is under-5～35 ℃ of temperature, can preserve 18 months.Aspect color, the equal nondiscoloration of the stable common all kinds of dirts of chance of the xanthein of this cleaning rubber.
In the preparation test; Change two kinds of natural pigments of above-mentioned 3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt and xenthophylls in the natural pigment Gardenia Yellow (English Crocin by name; Major ingredient carrotenoid is Crocin and trans-crocetin) or sunset yellow (call orange; English Sunset yellow by name; Formal name used at school is 1-(right-the sulfophenyl azo)-beta naphthal-6-disodium sulfonate salt) or its combination, the yellow cleaning rubber that finally obtains all can blackening when cleaning, especially clean metal surface.The cleaning rubber of blackening does not have background color when cleaning, and can't see cleaning effect, can not continue to use.
Embodiment 2
A kind of above-mentioned yellow cleaning rubber, should process by following component according to weight percent meter:
Water: 75.6%;
Guar gum: 4%;
Carrageenin: 3.8%;
Locust bean gum: 4%;
Trolamine: 7%;
Sodium sorbate: 0.4%;
3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt: 0.08%;
Xenthophylls: 0.01%;
ETHYLE ACETATE: 0.02%;
The D-ramie is rare: 0.02%;
Itral: 0.01%;
Glycerine: 1.5%;
Ucar 35: 2%;
Timbercote 2000: 0.06%;
Sodium sesquicarbonate: 0.4%
Sodium lauryl sulphate: 1.1%.
Its preparation method is identical with embodiment 1.
The preservation life-span of this yellow cleaning rubber is under-5～35 ℃ of temperature, can preserve 16 months.
Embodiment 3
A kind of above-mentioned yellow cleaning rubber, should process by following component according to weight percent meter:
Water: 79.2%;
Guar gum: 8%;
Carrageenin: 1.2%;
Locust bean gum: 3.4% wears
Trolamine: 3.2%;
Sodium sorbate: 0.3%;
3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt: 0.06%;
Xenthophylls: 0.01%;
ETHYLE ACETATE: 0.01%;
The D-ramie is rare: 0.03%;
Itral: 0.01%;
Glycerine: 1.2%;
Ucar 35: 1.3%;
Timbercote 2000: 0.03%;
Sodium sesquicarbonate: 0.55%
Sodium lauryl sulphate: 1.5%.
Its preparation method is identical with embodiment 1.
The preservation life-span of this yellow cleaning rubber is under-5～35 ℃ of temperature, can preserve 16 months.
Claims (3)
1. yellow cleaning rubber is characterized in that this and is processed by following component according to weight percent meter:
Water: 70～85%;
Guar gum: 4～10%;
Carrageenin: 1～4%;
Locust bean gum: 3～8%;
Trolamine: 2～8%;
Sodium sorbate: 0.2～0.5%;
3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt: 0.05～0.08%;
Xenthophylls: 0.01～0.02%;
ETHYLE ACETATE: 0.01～0.03%;
The D-ramie is rare: 0.01～0.03%;
Itral: 0.01～0.03%;
Glycerine: 0.5～2%;
Ucar 35: 1～2%;
Timbercote 2000: 0.02～0.08%;
Sodium sesquicarbonate: 0.2～0.6%
Sodium lauryl sulphate: 1～1.8%;
Said above-mentioned each component percentage composition sum is 100%.
2. a kind of yellow cleaning rubber according to claim 1 is characterized in that this and is processed by following component according to weight percent meter:
Water: 77.83%;
Guar gum: 6%;
Carrageenin: 2%;
Locust bean gum: 5%;
Trolamine: 4%;
Sodium sorbate: 0.5%;
3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium salt: 0.07%;
Xenthophylls: 0.01%;
ETHYLE ACETATE: 0.01%;
The D-ramie is rare: 0.02%;
Itral: 0.01%;
Glycerine: 2%;
Ucar 35: 1%;
Timbercote 2000: 0.05%;
Sodium sesquicarbonate: 0.5%
Sodium lauryl sulphate: 1%.
3. preparation method of yellow cleaning rubber according to claim 1, and be characterised in that this preparation method may further comprise the steps:
(1) water, Ucar 35, glycerine, carrageenin, locust bean gum and guar gum are poured in the container, stirred 5-10 minute; Add 3-carboxyl-5-hydroxyl-1-(right-sulfophenyl)-4-(right-the sulfophenyl azo)-adjacent pyrolle trisodium, xenthophylls, sodium sesquicarbonate, sodium lauryl sulphate, sodium sorbate and Timbercote 2000 again; Stir and obtained mixed glue solution in 2-5 minute; Mixed liquor is poured in the extruding machine and heat temperature raising to 120～130 ℃; Treat temperature between 120～130 ℃, start extruding machine work, pour extruding fully of the interior mixed glue solution of extruding machine the most at last into;
(2) mixed glue solution of extruding in the step (1) is added in the stirrer, adds that ETHYLE ACETATE, D-ramie are rare, itral and trolamine again, remain on temperature and between 95～100 ℃, stirred 20-30 minute, cooling obtains yellow cleaning rubber finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210140388.6A CN102676085B (en) | 2012-05-06 | 2012-05-06 | Yellow cleaning glue and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210140388.6A CN102676085B (en) | 2012-05-06 | 2012-05-06 | Yellow cleaning glue and preparation method thereof |
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| CN102676085A true CN102676085A (en) | 2012-09-19 |
| CN102676085B CN102676085B (en) | 2014-06-04 |
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| CN201210140388.6A Expired - Fee Related CN102676085B (en) | 2012-05-06 | 2012-05-06 | Yellow cleaning glue and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679149A (en) * | 2018-11-28 | 2019-04-26 | 中国辐射防护研究院 | Decontamination daub and application thereof in radioactive graphite dust pollution removal |
| CN110862786A (en) * | 2019-11-20 | 2020-03-06 | 浙江国能科技有限公司 | Cleaning glue and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08295607A (en) * | 1995-04-26 | 1996-11-12 | Sumitomo Chem Co Ltd | Isecticidal incense stick |
| CN101168648A (en) * | 2006-10-27 | 2008-04-30 | 保能科技股份有限公司 | Composition of hygroscopic coating with surface grain and manufacturing method for the coating |
-
2012
- 2012-05-06 CN CN201210140388.6A patent/CN102676085B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08295607A (en) * | 1995-04-26 | 1996-11-12 | Sumitomo Chem Co Ltd | Isecticidal incense stick |
| CN101168648A (en) * | 2006-10-27 | 2008-04-30 | 保能科技股份有限公司 | Composition of hygroscopic coating with surface grain and manufacturing method for the coating |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679149A (en) * | 2018-11-28 | 2019-04-26 | 中国辐射防护研究院 | Decontamination daub and application thereof in radioactive graphite dust pollution removal |
| CN109679149B (en) * | 2018-11-28 | 2021-08-17 | 中国辐射防护研究院 | Decontamination daub and application thereof in radioactive graphite dust pollution removal |
| CN110862786A (en) * | 2019-11-20 | 2020-03-06 | 浙江国能科技有限公司 | Cleaning glue and preparation method thereof |
| CN110862786B (en) * | 2019-11-20 | 2020-12-29 | 浙江国能科技有限公司 | Cleaning glue and preparation method thereof |
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| Publication number | Publication date |
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| CN102676085B (en) | 2014-06-04 |
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