CN102675815A - Formula of reinforced ABS (acrylonitrile-butadiene-styrene) - Google Patents
Formula of reinforced ABS (acrylonitrile-butadiene-styrene) Download PDFInfo
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- CN102675815A CN102675815A CN2012101590261A CN201210159026A CN102675815A CN 102675815 A CN102675815 A CN 102675815A CN 2012101590261 A CN2012101590261 A CN 2012101590261A CN 201210159026 A CN201210159026 A CN 201210159026A CN 102675815 A CN102675815 A CN 102675815A
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- polyurethane
- vinyl acetate
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Abstract
The invention discloses a formula of reinforced ABS (acrylonitrile-butadiene-styrene), which comprises ABS 121H, 960A, a plasticizer, a preservative and an assistant, wherein the plasticizer is polyaminoethyl formate, the preservative is vinyl acetate, and the assistant is polyurethane. The reinforced ABS is prepared from the following components in percentage by weight: 76-81% of ABS 121H, 3-4% of 960A, 14-16% of polyaminoethyl formate, 1-2% of vinyl acetate and 1-2% of polyurethane. The reinforced ABS has the advantages of favorable low temperature property, low density, favorable aging resistance, strong alkali resistance, strong acid resistance and favorable softness.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of reinforced ABS.
Background technology
ABS is the general thermoplastic engineering plastic that grows up 1940's; It is the very outstanding plastics variety of a comprehensive mechanical property; Not only have favorable rigidity, hardness and processing fluidity, and have the H.T. characteristics, can injection moulding, extrude or thermoforming.All with injection molding forming method processing, the advantage of ABS resin is impact-resistance, sound insulation property, scratch-resistant to most of trolley part, and thermotolerance is better, and is more attractive in appearance than PP, especially at horizontal impact-resistance and the comparatively strict parts of use temperature.ABS resin is to use in the automobile to be only second to Polyurethane and polyacrylic the third-largest resin.ABS resin can be used for Che Nei and car outer enclosure, widgets such as bearing circle, oil guide pipe and handle and button, radiator grill and lampshade etc. before the car outside comprises.ABS resin is processed easily; Finish size stability and surface luster are good; Easily application, painted can also be carried out metallize, plating, welding and suitability for secondary processing such as bonding, can be widely used in field of electronics; Comprise various offices and consumer electronics/electrical equipment, office electrical equipment comprises electronic data processing machine, office equipment.In electronic apparatus market, ABS resin will keep its status in requiring fire-retardant and high heat-stable electronics/electrical equipment market in recent years, fire-retardant and high heat-proof ABS resin with the competition of engineering plastic alloys such as ABS/PC in have remarkable advantages.ABS resin has in the daily necessities field widely to be used, and such as building materials tubing, sheet material or sheet material, has been replaced a part by the more cheap polyvinyl chloride resin of price in recent years.ABS resin is used for and the relevant field of building, and wherein extrusion sheet is used for sanitary apparatus such as bath box, swimming pool lining etc., the tubing of injection moulding and pipe fitting in addition, the produced in small quantities extrusion moulding
Telephone cablePipeline.The AIE Asia-Pacific is international immediately following material market trend; Be devoted to the exploitation and the popularization of ABS material; Release a series of ABS automotive materials with excellent over-all properties and technology performance; The many new A BS matrix materials of exploitation place are like impact, flame retardant resistance, outward appearance, painted etc., for final user's use provides omnidistance support and helps and constantly provide new solution.
Summary of the invention
The object of the present invention is to provide that to have low-temperature performance good, density is little, and ageing-resistant performance is good, the prescription of a kind of reinforced ABS that the strong acid of anti-highly basic and flexibility are good.
Technical scheme of the present invention is: a kind of prescription of reinforced ABS, comprise ABS121H, 960A, softening agent, sanitas and auxiliary agent, and softening agent is a polyurethane; Sanitas is a vinyl acetate between to for plastic, and auxiliary agent is a urethane, and each composition weight proportion is that ABS121H accounts for 76%-81%; 960A accounts for 3%-4%; Polyurethane accounts for 14%-16%, and vinyl acetate between to for plastic accounts for 1%-2%, and urethane accounts for 1%-2%.
In preferred embodiment of the present invention, said urethane comprises organic diisocyanate or many
Isocyanic esterWith dihydroxyl or many
Oxy-compound
In preferred embodiment of the present invention, each composition weight proportion of the prescription of said reinforced ABS is that ABS121H accounts for 78.2%, and 960A accounts for 3.8%, and polyurethane accounts for 15%, and vinyl acetate between to for plastic accounts for 2%, and urethane accounts for 1%.
The prescription of a kind of reinforced ABS of the present invention, it is good to have low-temperature performance, and density is little, and ageing-resistant performance is good, strong acid of anti-highly basic and the good effect of flexibility.
Embodiment
Below in conjunction with preferred embodiment of the present invention is set forth in detail, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
In one embodiment, a kind of prescription of reinforced ABS comprises ABS121H, 960A, softening agent, sanitas and auxiliary agent; Softening agent is a polyurethane, and sanitas is a vinyl acetate between to for plastic, and auxiliary agent is a urethane; Each composition weight proportion is that ABS121H accounts for 76%-81%, and 960A accounts for 3%-4%, and polyurethane accounts for 14%-16%; Vinyl acetate between to for plastic accounts for 1%-2%, and urethane accounts for 1%-2%, and said urethane comprises organic diisocyanate or many
Isocyanic esterWith dihydroxyl or many
Oxy-compound
Further specify, sample test is to place 24 hours in the sample chamber, and the sample chamber temperature remains on 23 ℃, and relative humidity is under 50 ℃:
| Test event | Unit | Testing method | Measured data |
| Dissolve index | g/10min | D1238 | ? |
| Density | g/cm3 | D792 | 1.2 |
| Notched Izod impact strength | J/M | D256 | 73 |
| Bending strength | mpa | D790 | 70.11 |
| The bending amount of touching | mpa | D790 | 3225.6 |
| Tensile strength | mpa | D638 | 41.11 |
| Elongation at break | % | D638 | 11.6 |
Each composition weight proportion of the prescription of said reinforced ABS is that ABS121H accounts for 78.2%, and 960A accounts for 3.8%, and polyurethane accounts for 15%, and vinyl acetate between to for plastic accounts for 2%; Urethane accounts for 1%, can debug according to different ratios according to different demands, thereby reach different results of use, and that ABS121H has low-temperature performance is good; It is little that 960A has density, and it is good that polyurethane has ageing-resistant performance, and vinyl acetate between to for plastic has the strong acid of anti-highly basic; And urethane has the good effect of flexibility, and the present invention provides a kind of prescription of reinforced ABS, and it is good to have low-temperature performance; Density is little, and ageing-resistant performance is good, strong acid of anti-highly basic and the good effect of flexibility.
Embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed, and variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the prescription of a reinforced ABS, it is characterized in that: comprise ABS121H, 960A, softening agent, sanitas and auxiliary agent, softening agent is a polyurethane; Sanitas is a vinyl acetate between to for plastic, and auxiliary agent is a urethane, and each composition weight proportion is that ABS121H accounts for 76%-81%; 960A accounts for 3%-4%; Polyurethane accounts for 14%-16%, and vinyl acetate between to for plastic accounts for 1%-2%, and urethane accounts for 1%-2%.
2. the prescription of reinforced ABS according to claim 1, it is characterized in that: said urethane comprises organic diisocyanate or POLYMETHYLENE POLYPHENYLISOCYANATE and dihydroxyl or polyol.
3. the prescription of reinforced ABS according to claim 1, it is characterized in that: each composition weight proportion of the prescription of said reinforced ABS is that ABS121H accounts for 78.2%, and 960A accounts for 3.8%, and polyurethane accounts for 15%, and vinyl acetate between to for plastic accounts for 2%, and urethane accounts for 1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101590261A CN102675815A (en) | 2012-05-22 | 2012-05-22 | Formula of reinforced ABS (acrylonitrile-butadiene-styrene) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101590261A CN102675815A (en) | 2012-05-22 | 2012-05-22 | Formula of reinforced ABS (acrylonitrile-butadiene-styrene) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102675815A true CN102675815A (en) | 2012-09-19 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101590261A Pending CN102675815A (en) | 2012-05-22 | 2012-05-22 | Formula of reinforced ABS (acrylonitrile-butadiene-styrene) |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050299A (en) * | 2007-05-16 | 2007-10-10 | 中国中化集团公司 | Method for preparing alloy between ABS polymer and polycarbonate based on continuous substance law |
| CN101058622A (en) * | 2007-05-16 | 2007-10-24 | 中国中化集团公司 | Method of preparing extinction injection moulding level ACS polymer based on continuous noumenon method |
| CN101117427A (en) * | 2007-07-24 | 2008-02-06 | 天津玉泉工贸有限公司 | ABS resin nano reinforcing drying agent |
| CN101121806A (en) * | 2006-08-11 | 2008-02-13 | 广州市波斯塑胶颜料有限公司 | ABS color master batch with increased color stability and preparation method thereof |
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
-
2012
- 2012-05-22 CN CN2012101590261A patent/CN102675815A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101121806A (en) * | 2006-08-11 | 2008-02-13 | 广州市波斯塑胶颜料有限公司 | ABS color master batch with increased color stability and preparation method thereof |
| CN101050299A (en) * | 2007-05-16 | 2007-10-10 | 中国中化集团公司 | Method for preparing alloy between ABS polymer and polycarbonate based on continuous substance law |
| CN101058622A (en) * | 2007-05-16 | 2007-10-24 | 中国中化集团公司 | Method of preparing extinction injection moulding level ACS polymer based on continuous noumenon method |
| CN101117427A (en) * | 2007-07-24 | 2008-02-06 | 天津玉泉工贸有限公司 | ABS resin nano reinforcing drying agent |
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120919 |