CN102660901A - 一种无施胶熟化期半交联akd中/碱性施胶剂的制备方法 - Google Patents
一种无施胶熟化期半交联akd中/碱性施胶剂的制备方法 Download PDFInfo
- Publication number
- CN102660901A CN102660901A CN2012101362231A CN201210136223A CN102660901A CN 102660901 A CN102660901 A CN 102660901A CN 2012101362231 A CN2012101362231 A CN 2012101362231A CN 201210136223 A CN201210136223 A CN 201210136223A CN 102660901 A CN102660901 A CN 102660901A
- Authority
- CN
- China
- Prior art keywords
- gram
- akd
- mass ratio
- add
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 112
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- -1 Alkyl Ketene Dimer Chemical compound 0.000 title claims abstract description 4
- 239000003513 alkali Substances 0.000 title abstract 4
- 230000007935 neutral effect Effects 0.000 title abstract 4
- 240000003183 Manihot esculenta Species 0.000 claims abstract description 132
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims abstract description 132
- 229920002472 Starch Polymers 0.000 claims abstract description 95
- 239000008107 starch Substances 0.000 claims abstract description 95
- 235000019698 starch Nutrition 0.000 claims abstract description 95
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 87
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 87
- 235000013871 bee wax Nutrition 0.000 claims abstract description 45
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 45
- 239000000839 emulsion Substances 0.000 claims abstract description 36
- 102000004139 alpha-Amylases Human genes 0.000 claims abstract description 29
- 108090000637 alpha-Amylases Proteins 0.000 claims abstract description 29
- 229940024171 alpha-amylase Drugs 0.000 claims abstract description 29
- 230000002538 fungal effect Effects 0.000 claims abstract description 29
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 27
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 15
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 230000000593 degrading effect Effects 0.000 claims abstract description 15
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 3
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims abstract description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 112
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 103
- 150000001768 cations Chemical class 0.000 claims description 70
- 230000035800 maturation Effects 0.000 claims description 59
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 56
- 239000000243 solution Substances 0.000 claims description 56
- 239000003292 glue Substances 0.000 claims description 53
- 238000006243 chemical reaction Methods 0.000 claims description 44
- 239000007864 aqueous solution Substances 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 42
- 239000000178 monomer Substances 0.000 claims description 42
- 239000007787 solid Substances 0.000 claims description 42
- 238000010792 warming Methods 0.000 claims description 42
- 239000012166 beeswax Substances 0.000 claims description 32
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 claims description 16
- 238000013019 agitation Methods 0.000 claims description 14
- 238000007599 discharging Methods 0.000 claims description 14
- 238000001914 filtration Methods 0.000 claims description 14
- 230000004927 fusion Effects 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 14
- 230000001105 regulatory effect Effects 0.000 claims description 14
- CSPHGSFZFWKVDL-UHFFFAOYSA-M (3-chloro-2-hydroxypropyl)-trimethylazanium;chloride Chemical class [Cl-].C[N+](C)(C)CC(O)CCl CSPHGSFZFWKVDL-UHFFFAOYSA-M 0.000 claims description 12
- 125000005395 methacrylic acid group Chemical class 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 abstract description 6
- 229920001577 copolymer Polymers 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 238000007334 copolymerization reaction Methods 0.000 abstract description 3
- 238000004945 emulsification Methods 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 125000002091 cationic group Chemical group 0.000 abstract 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 63
- 235000007164 Oryza sativa Nutrition 0.000 description 63
- 235000009566 rice Nutrition 0.000 description 63
- 239000011436 cob Substances 0.000 description 28
- 239000007844 bleaching agent Substances 0.000 description 7
- 239000010791 domestic waste Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 244000085692 Cordia alliodora Species 0.000 description 1
- 235000004258 Cordia alliodora Nutrition 0.000 description 1
- 241000202567 Fatsia japonica Species 0.000 description 1
- 206010016590 Fibrin deposition on lens postoperative Diseases 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Paper (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210136223.1A CN102660901B (zh) | 2012-05-04 | 2012-05-04 | 一种无施胶熟化期半交联akd中/碱性施胶剂的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210136223.1A CN102660901B (zh) | 2012-05-04 | 2012-05-04 | 一种无施胶熟化期半交联akd中/碱性施胶剂的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102660901A true CN102660901A (zh) | 2012-09-12 |
CN102660901B CN102660901B (zh) | 2014-01-29 |
Family
ID=46770470
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210136223.1A Expired - Fee Related CN102660901B (zh) | 2012-05-04 | 2012-05-04 | 一种无施胶熟化期半交联akd中/碱性施胶剂的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102660901B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106032657A (zh) * | 2015-03-20 | 2016-10-19 | 上海东升新材料有限公司 | 一种增强型表面施胶剂及其制备方法 |
CN106471014A (zh) * | 2014-07-04 | 2017-03-01 | 巴斯夫欧洲公司 | 含淀粉的细碎聚合物分散体、其制备方法以及在造纸中作为胶料的用途 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002285493A (ja) * | 2001-03-27 | 2002-10-03 | Seiko Kagaku Kogyo Co Ltd | 製紙用表面サイズ剤及びその製造方法 |
CN101949108A (zh) * | 2010-10-29 | 2011-01-19 | 天津市奥东化工有限公司 | 聚乙烯亚胺改性akd施胶剂及其制备方法 |
CN102101918A (zh) * | 2010-12-17 | 2011-06-22 | 江南大学 | 一种促进烷基烯酮二聚体熟化的交联体及其制备方法 |
CN102127191A (zh) * | 2010-12-24 | 2011-07-20 | 江苏富淼科技股份有限公司 | 用于表面施胶的接枝共聚物的制备方法 |
-
2012
- 2012-05-04 CN CN201210136223.1A patent/CN102660901B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002285493A (ja) * | 2001-03-27 | 2002-10-03 | Seiko Kagaku Kogyo Co Ltd | 製紙用表面サイズ剤及びその製造方法 |
CN101949108A (zh) * | 2010-10-29 | 2011-01-19 | 天津市奥东化工有限公司 | 聚乙烯亚胺改性akd施胶剂及其制备方法 |
CN102101918A (zh) * | 2010-12-17 | 2011-06-22 | 江南大学 | 一种促进烷基烯酮二聚体熟化的交联体及其制备方法 |
CN102127191A (zh) * | 2010-12-24 | 2011-07-20 | 江苏富淼科技股份有限公司 | 用于表面施胶的接枝共聚物的制备方法 |
Non-Patent Citations (1)
Title |
---|
李小瑞等: "PVA接枝阳离子聚丙烯酸酯施胶剂及其增强作用研究", 《中华纸业》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106471014A (zh) * | 2014-07-04 | 2017-03-01 | 巴斯夫欧洲公司 | 含淀粉的细碎聚合物分散体、其制备方法以及在造纸中作为胶料的用途 |
CN106471014B (zh) * | 2014-07-04 | 2018-12-21 | 巴斯夫欧洲公司 | 含淀粉的细碎聚合物分散体、其制备方法以及在造纸中作为胶料的用途 |
CN106032657A (zh) * | 2015-03-20 | 2016-10-19 | 上海东升新材料有限公司 | 一种增强型表面施胶剂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN102660901B (zh) | 2014-01-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102660897B (zh) | 一种高分散阳离子akd中/碱性施胶剂的制备方法 | |
CN102635033B (zh) | 一种无施胶滞后蜂蜡/akd中/碱性施胶剂的制备方法 | |
CN102627734B (zh) | 一种无施胶滞后两性akd中/碱性施胶剂的制备方法 | |
CN102660901B (zh) | 一种无施胶熟化期半交联akd中/碱性施胶剂的制备方法 | |
CN102627735B (zh) | 一种高分散阳离子半交联akd中/碱性施胶剂的制备方法 | |
CN102627737B (zh) | 一种高分散akd中/碱性施胶剂的制备方法 | |
CN102627732A (zh) | 一种高活性半交联akd中/碱性施胶剂的制备方法 | |
CN102635030B (zh) | 一种阳离子玉米淀粉akd中/碱性施胶剂的制备方法 | |
CN102635026B (zh) | 一种无施胶熟化期akd中/碱性施胶剂的制备方法 | |
CN102635025B (zh) | 一种两性玉米淀粉akd中/碱性施胶剂的制备方法 | |
CN102660898B (zh) | 一种高分散半交联akd中/碱性施胶剂的制备方法 | |
CN102635015B (zh) | 一种阳离子高分散半交联akd中/碱性施胶剂的制备方法 | |
CN102635032B (zh) | 一种无施胶滞后半交联akd中/碱性施胶剂的制备方法 | |
CN102635034B (zh) | 一种无施胶熟化期蜂蜡/akd中/碱性施胶剂的制备方法 | |
CN102635029A (zh) | 一种阳离子红薯淀粉akd中/碱性施胶剂的制备方法 | |
CN102627738B (zh) | 一种无施胶熟化期两性akd中/碱性施胶剂的制备方法 | |
CN102627736B (zh) | 一种无施胶滞后akd中/碱性施胶剂的制备方法 | |
CN102660894A (zh) | 一种阳离子akd中/碱性施胶剂的制备方法 | |
CN102635036A (zh) | 一种两性红薯淀粉akd中/碱性施胶剂的制备方法 | |
CN102635022B (zh) | 一种高活性地蜡/akd中/碱性施胶剂的制备方法 | |
CN102635031A (zh) | 一种阳离子土豆淀粉微晶蜡/akd中/碱性施胶剂的制备方法 | |
CN102660900A (zh) | 一种两性玉米淀粉微晶蜡/akd中/碱性施胶剂的制备方法 | |
CN102635028A (zh) | 一种阳离子红薯淀粉微晶蜡/akd中/碱性施胶剂的制备方法 | |
CN102660899B (zh) | 一种阳离子土豆淀粉akd中/碱性施胶剂的制备方法 | |
CN102635035A (zh) | 一种两性土豆淀粉akd中/碱性施胶剂的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201221 Address after: 224000 Qingyang Road (within Qingdun Office), Nanyang Town, Tinghu District, Yancheng City, Jiangsu Province (8) Patentee after: Yancheng Qinglong Jinbang water Co.,Ltd. Address before: 518000 No.6 Qinglong Road, Qinglong Road, Qinghua community, Longhua street, Longhua District, Shenzhen City, Guangdong Province Patentee before: Shenzhen Pengbo Information Technology Co.,Ltd. Effective date of registration: 20201221 Address after: 518000 No.6 Qinglong Road, Qinglong Road, Qinghua community, Longhua street, Longhua District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Pengbo Information Technology Co.,Ltd. Address before: 710021 Shaanxi province Xi'an Weiyang university campus of Shaanxi University of Science and Technology Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY |
|
TR01 | Transfer of patent right | ||
CI03 | Correction of invention patent |
Correction item: Patentee|Address Correct: Yancheng Qingdun Jinbang Water Co., Ltd.|224000 Qingyang Road, Nanyang Town, Tinghu District, Yancheng City, Jiangsu Province (in Qingdun Office) (8) False: Yancheng Qingyi Jinbang Water Affairs Co., Ltd.|224000 Qingyang Road, Nanyang Town, Tinghu District, Yancheng City, Jiangsu Province (in Qingdun Office) (8) Number: 01-01 Volume: 37 |
|
CI03 | Correction of invention patent | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140129 |
|
CF01 | Termination of patent right due to non-payment of annual fee |