Summary of the invention
The invention provides flyash plastic material and tubing, production technique and system, can improve the utilization ratio of flyash.
A flyash plastic material, raw material comprises: flyash 30-80 part, fusogen 1-4.5 part, resin-oatmeal 20-70 part, stearic acid 0.5-2.5 part, paraffin 0.02-0.1 part.
Preferably, described raw material is in parts by weight: flyash 35-75 part, fusogen 1.2-4.3 part, resin-oatmeal 25-65 part, stearic acid 0.6-2.4 part, paraffin 0.03-0.09 part;
Preferably, described raw material per-cent is: raw material is in parts by weight: flyash 40-70 part, fusogen 1.3-4 part, resin-oatmeal 30-60 part, stearic acid 0.65-2.3 part, paraffin 0.04-0.08 part.
Preferably, to add up be 100 parts for described flyash and resin-oatmeal.
Preferably, described fineness of pulverized-coal ash is 80-600 order;
Preferably, when described flyash plastic material is Powdered, fineness is 80-600 order, and when described flyash plastic material is particulate state, size is 0.5-5 millimeter.
The present invention also provides the production technique of above-mentioned flyash plastic material described in any, comprising:
Flyash, resin-oatmeal, stearic acid are mixed and stir and form the first mixture;
Fusogen is heated to boiling state;
Pour the described fusogen in boiling state and paraffin into described the first mixture, stir and form the second mixture;
Described the second mixture is stirred and is cooled to room temperature.
Preferably, after described the second mixture stirring is cooled to room temperature, described production technique further comprises:
Described the second mixture is heated to 150-190 degree, makes described the second mixture softening;
Softening described the second mixture is squeezed into strip;
The second mixture described in strip is cut off and cool to room temperature.
The present invention also provides a kind of above-mentioned tubing that prepared by flyash plastic material described in any of applying, raw material comprises: flyash, fusogen, resin-oatmeal, stearic acid, paraffin, wherein, described raw material is in parts by weight: flyash 30-80 part, fusogen 1-4.5 part, resin-oatmeal 20-70 part, stearic acid 0.5-2.5 part, paraffin 0.02-0.1 part.
The present invention also provides a kind of production technique that above-mentioned any flyash plastic material is prepared tubing of applying, and comprising:
Flyash plastic material is heated to 150-190 degree, makes described flyash plastic material softening;
Softening described flyash plastic material is clamp-oned to Cheng Mo in pipe mold;
Sizing is also cooling.
Preferably, described in, be fixed in vacuum environment and shape.
Preferably, described sizing and cooling after, the production technique of described tubing further comprises:
By cooled tubing cutting;
By the tubing enlarging after cutting;
By the tubing packing after enlarging.
The present invention also provides the production system of tubing prepared by a kind of above-mentioned any powder application coal ash plastic material, comprising: forcing machine, pipe mold, cooling tank;
Described forcing machine, it is for adding heat mixture, and the compound after heating is clamp-oned to described pipe mold;
Described pipe mold, it carries out moulding and sends into cooling tank for the flyash plastic material to clamp-oning;
Described cooling tank, it is for cooling by tubing.
Preferably, described production system further comprises: stirrer, cold mixer and feeder;
Described stirrer, it forms compound for stirring raw material;
Described cold mixer, it is for stirring the compound after stirring with cooling;
Described feeder, it is for being transferred to described forcing machine by cooling flyash plastic material.
Preferably, production system further comprises: tractor, cutting machine and pipe-expanding machine;
Described tractor, it is for sending cooled tubing into cutting machine;
Described cutting machine, it shifts for cutting through tractor the tubing of coming;
Described pipe-expanding machine, its for by cutting after pipe end enlarging.
By flyash plastic material provided by the invention and tubing, production technique and system, can bring following beneficial effect:
1, realize the extensive application of flyash, improved the utilization ratio of flyash, the raw material of producing a kind of flyash plastic material of the present invention comprises: raw material comprises: flyash, fusogen, resin-oatmeal, stearic acid, paraffin, wherein, described raw material is in parts by weight: flyash 30-80 part, fusogen 1-4.5 part, resin-oatmeal 20-70 part, stearic acid 0.5-2.5 part, paraffin 0.02-0.1 part, realized the comprehensive utilization of flyash, turns waste into wealth, turns bane into boon;
2, the flyash plastic material that the present invention produces has the advantages such as acid-alkali-corrosive-resisting, anti-oxidant, production performance is good;
3, apply product good combination property prepared by flyash plastic material of the present invention, the tubing of producing, smooth surface, insulation, waterproof, anti-external and internal pressure, acid-alkali-corrosive-resisting, workability are good, and can realize the connection of enlarging socket joint, the connection of isometrical thermosol, be applicable to various execution conditions, greatly improved tubing operating efficiency;
4, apply product prepared by flyash plastic material of the present invention reusable, discarded pollution-free, use and meet drinking water standard, may be used on the fields such as Drinking Water water pipe.
Embodiment
Below with reference to accompanying drawing, the technical scheme of various embodiments of the present invention is carried out to clear, complete description, obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiment.Embodiment based on described in the present invention, those of ordinary skills are resulting all other embodiment under the prerequisite that does not need creative work, in the scope of all protecting in the present invention.
A kind of flyash plastic material of the present invention, raw material comprises: flyash, fusogen, resin-oatmeal, stearic acid, paraffin, wherein, described raw material is in parts by weight: flyash 30-80 part, fusogen 1-4.5 part, resin-oatmeal 20-70 part, stearic acid 0.5-2.5 part, paraffin 0.02-0.1 part.
In various embodiments of the present invention, preferably, described raw material is in parts by weight: flyash 35-75 part, fusogen 1.2-4.3 part, resin-oatmeal 25-65 part, stearic acid 0.6-2.4 part, paraffin 0.03-0.09 part;
In various embodiments of the present invention, preferably, described raw material per-cent is: raw material is in parts by weight: flyash 40-70 part, fusogen 1.3-4 part, resin-oatmeal 30-60 part, stearic acid 0.65-2.3 part, paraffin 0.04-0.08 part.
In various embodiments of the present invention, preferably, it is 100 parts that described flyash and resin-oatmeal are added up.
A kind of flyash plastic material of the present invention can improve the utilization ratio of flyash, and the part by weight by conversion flyash can reach more than 60%, has realized the comprehensive utilization of flyash, turns waste into wealth, turns bane into boon.
In various embodiments of the present invention, preferably, described fineness of pulverized-coal ash is 80-600 order, such as 80 orders, 90 orders, 100 orders, 110 orders, 120 orders, 130 orders, 140 orders, 150 orders, 180 orders, 200,220 orders, 250 orders, 280 orders, 300 orders, 330 orders, 350 orders, 380 orders, 400 orders, 420 orders, 450 orders, 480 orders, 500 orders, 520 orders, 550 orders, 580 orders or 600 orders, and the scope between any two values wherein.
In various embodiments of the present invention, preferably, when described flyash plastic material is Powdered, fineness is 80 order-600 orders, such as 80 orders, 90 orders, 100 orders, 110 orders, 120 orders, 130 orders, 140 orders, 150 orders, 180 orders, 200 orders, 220 orders, 250 orders, 280 orders, 300 orders, 330 orders, 350 orders, 380 orders, 400 orders, 420 orders, 450 orders, 480 orders, 500 orders, 520 orders, 550 orders, 580 orders or 600 orders, and the scope between any two values wherein.
When described flyash plastic material is particulate state, size is 0.5-5 millimeter, such as: 0.8 millimeter, 1 millimeter, 1.2 millimeters, 1.5 millimeters, 1.8 millimeters, 2 millimeters, 2.3 millimeters, 2.5 millimeters, 2.8 millimeters, 3 millimeters, 3.3 millimeters, 3.5 millimeters, 3.8 millimeters, 4 millimeters, 4.5 millimeters, 4.8 millimeters or 5 millimeters, and wherein any two value between scope.
The present invention also provides the production technique of above-mentioned flyash plastic material described in any to comprise:
Flyash, resin-oatmeal, stearic acid are mixed and stir and form the first mixture;
Fusogen is heated to boiling state;
Pour the described fusogen in boiling state and paraffin into described the first mixture, stir and form the second mixture;
Described the second mixture is stirred and is cooled to room temperature.
In various embodiments of the present invention, preferably, after described the second mixture stirring is cooled to room temperature, described production technique further comprises:
Described the second mixture is heated to 150-190 degree, makes described the second mixture softening;
Softening described the second mixture is squeezed into strip;
The second mixture described in strip is cut off to also cold cut to room temperature.
The flyash plastic material that the present invention produces has the advantages such as acid-alkali-corrosive-resisting, anti-oxidant, processability is good, can be used for producing the fitting-up products such as tubing, well lid, urban construction guardrail fence, handrail, floor, thermal-insulation baffle plate, isolation light weight wall, bumper, table top.Apply product prepared by flyash plastic material of the present invention reusable, discarded pollution-free, use and meet drinking water standard.
The present invention also provides a kind of above-mentioned tubing that prepared by flyash plastic material described in any of applying, raw material comprises: flyash, fusogen, resin-oatmeal, stearic acid, paraffin, wherein, described raw material is in parts by weight: flyash 30-80 part, fusogen 1-4.5 part, resin-oatmeal 20-70 part, stearic acid 0.5-2.5 part, paraffin 0.02-0.1 part.
The present invention also provides a kind of production technique that above-mentioned any flyash plastic material is prepared tubing of applying, and comprising:
Flyash plastic material is heated to 150-190 degree, makes described flyash plastic material softening;
Softening described flyash plastic material is clamp-oned to Cheng Mo in pipe mold;
Sizing is also cooling.
In various embodiments of the present invention, preferably, described in be fixed in vacuum environment and shape; In vacuum environment, shape, can prevent that tubing and airborne composition from reacting, and affects the performance of tubing.The tubing that becomes mould is put into vacuum shaping sleeve, and to carry out Vacuum shaping cooling, and under vacuum condition, tubing is subject to the effect of outside radial force, makes tubing sidewall round.
In various embodiments of the present invention, preferably, described sizing and cooling after, the production technique of described tubing further comprises:
By cooled tubing cutting;
By the tubing enlarging after cutting;
By the tubing packing after enlarging.
Apply tubing prepared by flyash plastic material of the present invention, have smooth surface, insulation, waterproof, anti-external and internal pressure, acid-alkali-corrosive-resisting, workability good, can enlarging socket joint connect, isometrical thermosol connects, be applicable to various execution conditions, greatly improved tubing operating efficiency, good performance index will progressively replace pvc pipe, PE pipe, cast iron pipe, cement pipe etc. in the application of part industry.Apply tubing prepared by flyash plastic material of the present invention reusable, discarded pollution-free, use and meet drinking water standard.
The present invention also provides a kind of production system that above-mentioned any flyash plastic material is prepared tubing of applying, and comprising: forcing machine, pipe mold, cooling tank;
Described forcing machine, it is for adding heat mixture, and the compound after heating is clamp-oned to described pipe mold;
Described pipe mold, it carries out moulding and sends into cooling tank for the flyash plastic material to clamp-oning;
Described cooling tank, it is for cooling by tubing.
In various embodiments of the present invention, preferably, described production system further comprises: stirrer, cold mixer and feeder;
Described stirrer, it forms compound for stirring raw material;
Described cold mixer, it is for stirring the compound after stirring with cooling;
Described feeder, it is for being transferred to described forcing machine by cooling flyash plastic material.
In various embodiments of the present invention, preferably, production system further comprises: tractor, cutting machine and pipe-expanding machine;
Described tractor, it is for sending cooled tubing into cutting machine;
Described cutting machine, it shifts for cutting through tractor the tubing of coming;
Described pipe-expanding machine, its for by cutting after pipe end enlarging.
The composition situation of flyash plastic material is described below by several specific embodiments:
Embodiment 1
A flyash plastic material, raw material is in parts by weight: 70 parts, flyash, 4 parts of fusogens, 30 parts of resin-oatmeals, 2.3 parts of stearic acid, 0.08 part, paraffin.
Embodiment 2
A flyash plastic material, raw material is in parts by weight: 75 parts, flyash, 4.3 parts of fusogens, 25 parts of resin-oatmeals, 2.4 parts of stearic acid, 0.09 part, paraffin.
Embodiment 3
A flyash plastic material, raw material is in parts by weight: 65 parts, flyash, 4 parts of fusogens, 35 parts of resin-oatmeals, 1 part of stearic acid, 0.07 part, paraffin.
Embodiment 4
A flyash plastic material, raw material is in parts by weight: 60 parts, flyash, 3.8 parts of fusogens, 40 parts of resin-oatmeals, 1.7 parts of stearic acid, 0.065 part, paraffin.
Embodiment 5
A flyash plastic material, raw material is in parts by weight: 55 parts, flyash, 3.4 parts of fusogens, 45 parts of resin-oatmeals, 1.8 parts of stearic acid, 0.07 part, paraffin.
Embodiment 6
A flyash plastic material, raw material is in parts by weight: 45 parts, flyash, 2.8 parts of fusogens, 55 parts of resin-oatmeals, 1.65 parts of stearic acid, 0.05 part, paraffin.
Embodiment 7
A flyash plastic material, raw material is in parts by weight: 40 parts, flyash, 2.7 parts of fusogens, 60 parts of resin-oatmeals, 0.7 part of stearic acid, 0.05 part, paraffin
Embodiment 8
A flyash plastic material, raw material is in parts by weight: 35 parts, flyash, 2 parts of fusogens, 65 parts of resin-oatmeals, 1.9 parts of stearic acid, 0.03 part, paraffin.
Embodiment 9
A flyash plastic material, raw material is in parts by weight: 30 parts, flyash, 1.5 parts of fusogens, 70 parts of resin-oatmeals, 0.5 part of stearic acid, 0.09 part, paraffin.
Embodiment 10
A flyash plastic material, raw material is in parts by weight: 80 parts, flyash, 4.5 parts of fusogens, 20 parts of resin-oatmeals, 1.4 parts of stearic acid, 0.1 part, paraffin.
Lower mask body is described the production technique of above-mentioned any one flyash plastic material by an embodiment.
Be illustrated in figure 1 the production technique of pulverous flyash plastic material of above-mentioned any composition:
Step 101 is mixed flyash, resin-oatmeal, stearic acid and formation the first mixture that stirs;
Step 102 is heated to boiling state by fusogen;
Step 103 is poured the described fusogen in boiling state and paraffin into described the first mixture, stirs and forms the second mixture;
Step 104 stirs described the second mixture to be cooled to room temperature, forms the flyash plastic material of pulverulence.
When flyash plastic material is Powdered, fineness is 80 order-600 orders.
Be illustrated in figure 2 the production technique of the granular flyash plastic material of above-mentioned any composition:
Step 201 is mixed flyash, resin-oatmeal, stearic acid and formation the first mixture that stirs;
Step 202 is heated to boiling state by fusogen;
Step 203 is poured the described fusogen in boiling state and paraffin into described the first mixture, stirs and forms the second mixture;
Step 204 stirs described the second mixture to be cooled to room temperature;
Step 205 is heated to 150-190 degree by described the second mixture, makes described the second mixture softening;
Step 206 is squeezed into strip by softening described the second mixture;
Step 207 is cut off the second mixture described in strip, forms granular flyash plastic material.When flyash plastic material is particulate state, size is 0.5-5 millimeter.
Step 208 is cooled to room temperature by granular flyash plastic material.
It should be noted that, above-mentioned any one flyash plastic material may be used to prepare tubing, and the material composition that this tubing adopts is identical with the composition of above-mentioned any one flyash plastic material.
Below by a specific embodiment, the production technique that above-mentioned any one flyash plastic material is produced tubing is described, as shown in Figure 3:
Step 301 is heated to 150-190 degree by flyash plastic material, makes described flyash plastic material softening;
Step 302 is clamp-oned Cheng Mo in pipe mold by softening described flyash plastic material;
Step 303 will become the tubing of mould to move into the vacuum shaping sleeve in cooling tank, by spray, make tubing quick cooling and shaping under vacuum condition;
Step 304 is cut cooled tubing;
Step 305 is by the tubing enlarging after cutting;
Step 306 is by the tubing packing after enlarging.
The production system of tubing prepared by above-mentioned any one flyash plastic material, the annexation of its system as shown in Figure 4:
Step 401 stirrer, it forms compound for stirring raw material;
Step 402 cold mixer, it is for stirring the compound after stirring with cooling fast;
Step 403 feeder, it is for being transferred to described forcing machine by cooling flyash plastic material;
Step 404 forcing machine, it,, for feeder is shifted to the mixed material heating coming and clamp-ons shaper, forms tubing;
Step 405 Vacuum shaping cooling tank, it,, for by the tubing shift-in vacuum shaping sleeve of shaper, carries out Vacuum shaping cooling;
Step 406 tractor, it is for sending the tubing after Vacuum shaping into cutting machine;
Step 407 cutting machine, it shifts for cutting through tractor the tubing of coming;
Step 408 pipe-expanding machine, its for by cutting after pipe end enlarging.
Tubing prepared by flyash plastic material of the present invention, smooth surface, insulation, waterproof, anti-external and internal pressure, acid-alkali-corrosive-resisting, workability be good, can saw, cut, dig, brill, car, mantle fiber, can weld, bond, and can realize the connection of enlarging socket joint, the connection of isometrical thermosol, be applicable to various execution conditions, greatly improved tubing operating efficiency, good performance index will progressively replace pvc pipe, PE pipe, cast iron pipe, cement pipe etc. in the application of part industry.
Adopt above method, can also production urban construction protective grating, the material such as fence, bumper, handrail, floor, thermal-insulation baffle plate, isolation light weight wall, table top, just the shaper of tubing is changed to the corresponding shaper sizing such as urban construction protective grating, fence, bumper, handrail, floor, thermal-insulation baffle plate, isolation light weight wall, table top.Adopt above method can also produce the products such as well lid, just softening described flyash plastic material is moved in well lid mould and is pressed into mould, then carry out cooling.Apply product prepared by flyash plastic material of the present invention reusable, discarded pollution-free.
Apply the materials such as production urban construction protective grating of the present invention, fence, bumper, handrail, floor, thermal-insulation baffle plate, isolation light weight wall, table top have workability good, can saw, cut, dig, brill, car, mantle fiber, can weld, the advantage such as bonding.
The performance of the tubing that the present invention is also prepared for above-mentioned flyash plastic material has been carried out following test, as shown in Table 1 and Table 2:
The results of property of tubing prepared by table 1 flyash plastic material
The results of property of tubing prepared by table 2 flyash plastic material
By table 1 and table 2, can find out, every over-all properties of tubing prepared by flyash plastic material of the present invention is better.
Tubing prepared by table 3 flyash plastic material soaks composition synopsis front and the rear water of immersion
Check point |
Before immersion |
After immersion |
Colourity |
<5 |
<5 |
Opacity |
<0.5 |
<0.5 |
Smelly and taste |
Nothing |
Nothing |
The visible nothing of naked eyes |
Have no |
Have no |
PH |
8.7 |
8.2 |
Iron |
0.009 |
0.016 |
Manganese |
0.009 |
0.01 |
Copper |
<0.001 |
<0.001 |
Zinc |
0.003 |
0.005 |
Volatile phenol (in phenol) |
0.002 |
0.002 |
Arsenic |
<0.0002 |
<0.0002 |
[0160]
Mercury |
0.001 |
0.004 |
Chromium (sexavalence) |
<0.001 |
<0.001 |
Plumbous |
<0.001 |
<0.001 |
Silver |
<0.001 |
<0.001 |
Fluorochemical |
<0.10 |
<0.0002 |
Nitrate (in nitrogen) |
<0.2 |
0.22 |
Chloroform |
<6 |
<6 |
Tetracol phenixin |
<0.3 |
<0.3 |
Aldehydes |
<0.02 |
<0.02 |
Potassium permanganate consumption (with oxymeter) |
0.88 |
1.28 |
The tubing that uses after testing flyash plastic material of the present invention to prepare meets drinking water standard,
Can be for tap water transmission & distribution equipment and protective material.
Various embodiment provided by the invention combination mutually in any way as required, by this combination
The technical scheme obtaining, also within the scope of the invention.
Obviously, those skilled in the art can carry out various changes and modification and not depart from the spirit and scope of the present invention the present invention.Like this, if of the present invention these are revised and within modification belongs to the scope of the claims in the present invention and equivalent technologies thereof, the present invention also comprises these changes and modification interior.