CN102626379A - Anhydrous ultra-sticky type double-component tooth-whitening sticking film - Google Patents

Anhydrous ultra-sticky type double-component tooth-whitening sticking film Download PDF

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CN102626379A
CN102626379A CN2012101420082A CN201210142008A CN102626379A CN 102626379 A CN102626379 A CN 102626379A CN 2012101420082 A CN2012101420082 A CN 2012101420082A CN 201210142008 A CN201210142008 A CN 201210142008A CN 102626379 A CN102626379 A CN 102626379A
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CN102626379B (en
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阮仕星
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Guangzhou Onuo Clean Personal Care Products Co Ltd
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Abstract

The invention relates to an anhydrous ultra-sticky type double-component tooth-whitening sticking film formed by combining two components: a component A, namely, anhydrous ultra-sticky whitening component, and a component B, namely, active permeation-boosting component. The component A has a double-layer structure; a first layer of the component A is an ultra-sticky whitening layer while a second layer is a peeling backing layer; the component B has a three-layer structure; a first layer of the component B is a waterproof sticking layer, a second layer is an active permeation-boosting layer and a third layer is a peeling backing layer; and the ultra-sticky whitening layer of the component A and the active permeation-boosting layer of the component B are respectively provided with three preferable formulas for corresponding and matching. During a use process, firstly, the ultra-sticky whitening layer of the component A is attached to teeth, and then the waterproof sticking layer and the active permeation-boosting layer of the component B are attached to the ultra-sticky whitening layer of the component A. The anhydrous ultra-sticky type double-component tooth-whitening sticking film has the advantages of water-free formula and structure, and capabilities of greatly prolonging the retention time of products and greatly increasing the tooth-whitening effect.

Description

The two component teeth whitening pad pastings of anhydrous ultra sticking formula
Technical field
The present invention relates to the pad pasting that a kind of human teeth of being used in whitens, especially relate to a kind of pad pasting that the human teeth is brightened, belong to the oral-cavity article field.
Background technology
Improving constantly of Along with people's living standard; The modern to the love of tooth, protect, kindness knows more and more and payes attention to, the requirement that dental prosthetics is brightened grows with each passing day, and is increasingly high to methods and effect requirements that dental prosthetics brightens; Both required in the dental prosthetics whitening, not damage dentine; Require again to save time conveniently, simple and practical effect is remarkable, makes the methods of teeth whitening and product face the more problem of deep layer.
The methods of teeth whitening and product roughly are divided into two major types, one type of method that is to use machinery or ultrasound wave toothwash, and the shortcoming of these class methods is only to play the effect of cleaning teeth; Spot to tooth does not reach the effect that decolouring is brightened; Dentine there is certain infringement and will be operated by the professional in hospital or dentist's office, spended time, convenient inadequately; And the generation of tooth stain is regular and persistence; Can not through for several times or the cleaning of limited number of times reach the purpose that tooth often brightens, and mechanical whitening teeth whitens and can make the enamel attenuation, and dentine is caused damage.
Another major types is to use the method for chemical substance bleaching, promptly with the chemical bleaching agent tooth is bleached, and these class methods are through the facing administration on the clinical medicine; Make bleach keep Long contact time with facing; Discharge active ingredient, bleach commonly used is the Opalescemce depigmenting agent, and its active ingredient 10% urea peroxide (Carbamide peroxide) perhaps uses the peroxide of other high concentrations to come bleaching teeth; And the peroxide of high concentration has very strong acidity; To tooth and on every side its hetero-organization stronger stimulation is arranged, treatment time is long and price is more expensive, ordinary consumer is difficult to approval and accepts.
Current; Adopting chemical method to process that tooth film brightens tooth and whiten is a kind of product of popular day by day and commonplace use, and present teeth whitening pad pasting roughly has two kinds of dry type pad pasting and wet type pad pastings, these pad pastings mostly with the peroxide of large percentage, high concentration as main bleach; The ratio of its peroxide is about 10%; But peroxide is a kind of very unsettled material, along with the prolongation effect of time can become more and more bad, solve this way at present and mainly be the content that improves peroxide and add peroxide stabiliser and regulate stabilization of peroxide property; The content that increases peroxide can have very strong stimulation to use to tooth and tissue on every side thereof; And the gel when using overflows, and can increase the weight of to stimulate the oral cavity, and exists and be pasted not strongly; Fall down easily, cause using problems such as uncomfortable; After the peroxidating thing has added stabilizing agent in addition, through the time stable be to obtain certain control, but make peroxide reduce effectiveness equally; Destroyed release conditions and the effect of peroxide, to a great extent, influenced the effect that brightens at degrading activity oxygen; So; Present teeth whitening pad pasting uses simple, convenient and practical advantage and certain effect though have, and also has described shortcoming and defect.
Summary of the invention
The object of the invention; Be to overcome the existing above-mentioned shortcoming and defect of present teeth whitening pad pasting; Provide a kind of anhydrous ultra sticking formula two component teeth whitening pad pastings, solve brightening the moisture and technical problem that reduces teeth whitening effect of composition and solving the technical problem that general teeth whitening pad pasting is low to the dental surface adhesion strength, the adhesion time is short of general teeth whitening pad pasting.Most important is to have overcome the ageing stability that contains the peroxide whitening products, at the whitening effect that improves tooth, has also prolonged the storage time of product and can not be directed at because of the time lengthening that stores and brightened composition decomposition loss.
Technical scheme of the present invention is: combined by two kinds of components, comprise anhydrous ultra sticking component and the two kinds of components of the active short infiltration component of B component of brightening of A component.
The A component is a two-layer structure, and its ground floor is the ultra sticking layer that brightens, and its second layer is to peel off backing layer.Ground floor ultra sticking brighten layer by as the peroxide of brightener for tooth with have the macromolecule filming material that can form ultra mucosa and process, have three kinds of optimization formulas can supply enforcement, its optimization formula A1 is:
Figure BSA00000713967600021
Figure BSA00000713967600031
Perhaps optimization formula A1 is replaced as optimization formula A2:
Figure BSA00000713967600032
Perhaps optimization formula A1 is replaced as optimization formula A3:
Prescription is dissolved in the effumability solution ethanol, through 60 ℃ to 80 ℃ temperature the oven dry of effumability solution ethanol is processed then.Be one deck or multiwalled overlay structure, its shape is the shape with suitable user dental bed and tooth.
It is transparent or the plastic opaque thin film that the second layer of A component is peeled off backing layer, and preferred material is plastic sheeting, paper tinsel or the paper of PET material, and it is furnished with mould release silicon or fluorine or their mixture with the ultra sticking layer surfaces coated that contacts that brighten of ground floor.The effect of mould release is easily the ultra sticking layer that brightens of ground floor to be peeled off backing layer from the second layer and cut separation in use.
The B component is a three-decker, and its ground floor is transparent water proof adhesion layer, and its second layer is the short permeable formation of activity of being close to ground floor, and its 3rd layer is to peel off backing layer.
The material of the ground floor water proof adhesion layer of B component is transparent plastic sheeting; Adhere to ultra sticking the brightening on the layer of ground floor of A component in use; It plays a part to isolate saliva and the B component second layer can be adhered fixed in the above, and shape is the shape with suitable user dental bed and tooth.
The second layer of B component is the short permeable formation of activity of being close to ground floor; Its prescription contains the macromolecule filming material that can form ultra mucosa; Produce powerful viscosity, can fuse mutually, make peroxide can discharge active oxygen with the ultra sticking layer that brightens of A component ground floor; Oxygen-derived free radicals in the active oxygen can rapid permeability in the enamel with tooth in the color base neutralization, impel color base to decompose and reach teeth whitening effect.The ultra sticking prescription that brightens layer of the prescription of the active short permeable formation of the B component second layer and A component ground floor is corresponding supporting, can have three kinds of optimization formulas can supply enforcement, and the ultra sticking optimization formula B1 that brightens layer optimization formula A1 of its corresponding supporting A component is:
Perhaps the optimization formula B1 with the active short permeable formation of B component is replaced as the ultra sticking optimization formula B2 that brightens layer optimization formula A2 of corresponding supporting A component:
Figure BSA00000713967600042
Perhaps the optimization formula B1 with the B component second layer is replaced as the ultra sticking optimization formula B3 that brightens layer optimization formula A3 of corresponding supporting A component:
Figure BSA00000713967600051
The method for making of the active short permeable formation of the B component second layer is that its prescription is dissolved in the effumability solution ethanol equally; Through 60 ℃ to 80 ℃ temperature the oven dry of effumability solution ethanol is processed then; Its thickness is between the 0.01mm to 0.05mm; Its shape is the shape with suitable user dental bed and tooth, and its prescription can impel the peroxide of A component accelerate to discharge and make and brightens composition and be penetrated in the enamel, reaches the raising whitening effect.
The B component is peeled off backing layer for the 3rd layer and is close to the second layer, is transparent or the plastic opaque thin film, and preferred material is plastic sheeting, paper tinsel or the paper of PET material.Its surfaces coated that contacts with the second layer is furnished with mould release silicon or fluorine or their mixture, makes the second layer be easy to cut separation from the 3rd layer.
During use; Earlier ultra sticking the brightening of the ground floor of A component layer peeled off backing layer from the second layer and peeled off; Be attached on the tooth, then the ground floor water proof adhesion layer of B component and the active short permeable formation of the second layer peeled off backing layer from the 3rd layer and peel off, be attached at the ultra sticking layer that brightens of ground floor of A component.
The present invention adopts the mode of operation of two components, and this method can effectively prolong the activity of peroxide, and it is independent fully that A component of the present invention brightens component; And adding ph nertralizer makes the ph value of the second layer be rendered as alkalescence; Ph is adjusted between the 3-4, and the stabilization of peroxide property that brightens under such environment in the component will be greatly improved, and can not decompose because of the prolongation in storage time; And the active short infiltration component ph value of B component is about 8-10; It can brighten acidity in the component 6-7 that neutralizes with the A component during use, thereby makes product reduce acid stimulation to the oral cavity in use, and can accelerate the decomposition of peroxide; Discharge more free oxygen, thereby reach best teeth whitening effect.
The polymeric material that the present invention adopts comprises hydroxypropyl emthylcellulose, PVP-K90, PVP-K30 and their mixture.
PVP-K30 and PVP-K90 are the polyvinylpyrrolidone products; It is a kind of nonionic high-molecular copolymer; Certain viscosity is arranged; But with the hydroxypropyl methylcellulose mixed dissolution behind effumability solution ethanol, behind hyperthermia drying, can reach the viscosity of superelevation and can form the membranaceous material that height glues.
Peroxide is selected from one or more following materials: hydrogen peroxide, urea peroxide, perboric acid are received or their compositions.
An advantage of the invention is that the A component is complete water-free prescription and dry structure; Can better wrap up brightener for tooth; Can not cause brightening agent to produce because of the existence that moisture content is arranged and decompose and instability, the structure of dryness also lets the ageing stability of product more reliable.
The ph value that another advantage of the present invention is the A component is acidity or faintly acid; Peroxide self is to be tart; Thereby peroxide can obtain better protection and can not produce decomposition or a small amount of the decomposition under this acid condition; Thereby the holding time of product is prolonged greatly, and further improved the whitening effect of tooth.
The prior advantage of the present invention is, the B component is to adopt alkaline structure, during use in the ability with the ph value of A component; Thereby let user not have acidity and bring stimulation tooth; And environment to neutral, when alkali condition is drawn close, peroxide can produce rapidly and decompose, when the B component is attached on the A component; Thereby can be rapidly impel the peroxide on the A component to accelerate to discharge and be penetrated in the enamel ph value neutralization of A component, thereby reach more superior teeth whitening effect.
In sum, the present invention has adopted a kind of brand-new two component matching design, provides a kind of more reliable, and it is longer that active ingredient keeps, the product that result of use is more given prominence to, bring a kind of comfortable, MC new concept easily.
Description of drawings
Fig. 1 is that the master of B component of the present invention looks sketch map;
Fig. 2 is the vertical view of Fig. 1;
Fig. 3 is that the master of A component of the present invention looks sketch map;
Fig. 4 is the vertical view of Fig. 3.
Among the figure:
1, water proof adhesion layer 2, activity are urged permeable formation 3, are peeled off backing layer B
4, peel off backing layer A 5, the ultra sticking layer that brightens
The specific embodiment
To combine accompanying drawing and embodiment that the present invention is described in detail below.
The present invention is combined by two kinds of components, comprises anhydrous ultra sticking component and the two kinds of components of the active short infiltration component of B component of brightening of A component.
The A component is a two-layer structure, and its ground floor is the ultra sticking layer 5 that brightens, and its second layer is to peel off backing layer A4.Ground floor ultra sticking brighten layer 5 by as the peroxide of brightener for tooth with have the macromolecule filming material that can form ultra mucosa and process, have three kinds of optimization formulas can supply enforcement, its optimization formula A1 is:
Figure BSA00000713967600071
Perhaps optimization formula A1 is replaced as optimization formula A2:
Perhaps optimization formula A1 is replaced as optimization formula A3:
Figure BSA00000713967600073
The B component is a three-decker, and its ground floor is a water proof adhesion layer 1, and its second layer is the short permeable formation 2 of activity of being close to ground floor, and its 3rd layer is to peel off backing layer B3.
The material of B component ground floor water proof adhesion layer 1 is transparent plastic sheeting, and it plays a part to isolate saliva and the B component second layer can be adhered fixed in the above, and shape is the shape with user dental bed and tooth.
The prescription of the active short permeable formation 2 of the B component second layer contains the macromolecular material and active short infiltration composition that can form ultra mucosa; Three kinds of optimization formulas and A component ground floor are arranged, and ultra sticking to brighten layer three kinds of optimization formula of 5 corresponding supporting, and the ultra sticking optimization formula B1 that brightens layer 5 optimization formula A1 of its corresponding supporting A component is:
Figure BSA00000713967600081
Perhaps the optimization formula B1 of the active short permeable formation 2 of B component is replaced as the optimization formula B2 of corresponding supporting optimization formula A2:
Perhaps the optimization formula B1 of the active short permeable formation 2 of B component is replaced as the optimization formula B3 of corresponding supporting optimization formula A3:
The anhydrous ultra sticking ground floor that brightens component of A component is ultra, and sticking to brighten layer 5 be that its prescription is dissolved in the effumability solution; Through 60 ℃ to 80 ℃ temperature effumability solution ethanol is dried then and form; Be one deck or multiwalled overlay structure, its shape is the shape with suitable user dental bed and tooth.
It is transparent or the plastic opaque thin film that the A component second layer is peeled off backing layer A4, and preferred material is plastic sheeting, paper tinsel or the paper of PET material, and it is furnished with perhaps their mixture of mould release silicon or fluorine with ultra sticking layer 5 surfaces coated that contact that brighten of ground floor.The effect of mould release is easily the ultra sticking layer 5 that brightens of ground floor to be peeled off backing layer A4 from the second layer and cut separation in use.
The active short permeable formation 2 of the second layer of the short infiltration of B component activity component is that its prescription is dissolved in the effumability solution ethanol equally, through 60 ℃ to 80 ℃ temperature effumability solution ethanol is dried then to form.Its thickness is between the 0.01mm to 0.05mm, and its shape is the shape with suitable user dental bed and tooth; The 3rd layer is peeled off backing B3 is transparent or the plastic opaque thin film, and preferred material is plastic sheeting, paper tinsel or the paper of PET material, and it is furnished with mould release silicon or fluorine or their mixture with the surfaces coated that the active short permeable formation 2 of the second layer contacts.
During use; Earlier stickingly brighten layers 5 and peel off backing layer A4 from the second layer and peel off the ground floor of A component is ultra; Be attached on the tooth; Then the ground floor water proof adhesion layer 1 of B component is peeled off backing layer B3 with the active short permeable formation 2 of the second layer from the 3rd layer and peel off, be attached at the ultra sticking layer 5 that brightens of ground floor of A component.

Claims (3)

1. the two component teeth whitening pad pastings of anhydrous ultra sticking formula is characterized in that: combined by two kinds of components, comprise anhydrous ultra sticking component and the two kinds of components of the active short infiltration component of B component of brightening of A component; The A component is a two-layer structure, and its ground floor is the ultra sticking layer (5) that brightens, by as the peroxide of brightener for tooth with have the macromolecule filming material that can form ultra mucosa and process, the second layer is to peel off backing layer A (4); The ultra sticking layer (5) that brightens of ground floor has three kinds of optimization formulas, and its optimization formula A1 is: urea peroxide 18%, ethanol 6% (oven dry back); Hydroxypropyl emthylcellulose 14%, sorbitol 12%, PVP-K9014%; PVP-K30 35%, peroxide chelating agen 0.5%, sweeting agent 0.1%; Herba Menthae 0.1%, citric acid 0.3% (acid regulator); Perhaps optimization formula A1 is replaced as optimization formula A2: hydrogen peroxide 6%, ethanol 8% (oven dry back), hydroxypropyl emthylcellulose 14%; Glycerol 15%, PVP-K9015%, PVP-K30 41%; Peroxide chelating agen 0.5%; Sweeting agent 0.1%, Herba Menthae 0.1%, citric acid 0.3% (acid regulator); Perhaps optimization formula A1 is replaced as optimization formula A3: Dexol 10%, ethanol 5% (oven dry back), hydroxypropyl emthylcellulose 14%; Propylene glycol 16%, PVP-K9018%, PVP-K30 36%; Peroxide chelating agen 0.5%; Sweeting agent 0.1%, Herba Menthae 0.1%, citric acid 0.3% (acid regulator); The B component is a three-decker, and its ground floor is water proof adhesion layer (1), and its second layer is the short permeable formation (2) of activity of being close to ground floor, and its 3rd layer is to peel off backing layer B (3); The prescription of the active short permeable formation (2) of the second layer contains the macromolecular material and active short infiltration composition that can form ultra mucosa; Have the ultra sticking three kinds of optimization formulas that brighten layer (5) of three kinds of optimization formulas and A component ground floor corresponding supporting, the optimization formula B1 of its corresponding ultra adhesion coating of supporting A component (5) optimization formula A1 is: ethanol 5% (oven dry afterwards), hydroxypropyl emthylcellulose 15%; Sorbitol 15%; PVP-K9019.5%, PVP-K30 45%, sweeting agent 0.1%; Herba Menthae 0.1%, sodium hydroxide 0.3% (antalkali); Perhaps the optimization formula B1 of the active short permeable formation (2) of B component is replaced as the optimization formula B2 of corresponding supporting optimization formula A2: ethanol 5% (oven dry back); Hydroxypropyl emthylcellulose 12%, glycerol 15%, PVP-K902 0.5%; PVP-K30 47%; Sweeting agent 0.1%, Herba Menthae 0.1%, sodium hydroxide 0.3% (antalkali); Perhaps the optimization formula B1 of the active short permeable formation (2) of B component is replaced as the optimization formula B3 of corresponding supporting optimization formula A3: ethanol 5% (oven dry back); Hydroxypropyl emthylcellulose 17%, propylene glycol 10%, PVP-K90 19.5%; PVP-K30 48%; Sweeting agent 0.1%, Herba Menthae 0.1%, sodium hydroxide 0.3% (antalkali).
2. the two component teeth whitening pad pastings of anhydrous ultra sticking formula according to claim 1; It is characterized in that: the anhydrous ultra sticking ground floor that brightens component of A component is ultra, and sticking to brighten layer (5) be that its prescription is dissolved in the effumability solution ethanol; Through 60 ℃ to 80 ℃ temperature effumability solution ethanol is dried then and form; Be one deck or multiwalled overlay structure; Its shape is the shape with suitable user dental bed and tooth; It is transparent or the plastic opaque thin film that the A component second layer is peeled off backing layer A (4), and preferred material is plastic sheeting, paper tinsel or the paper of PET material, and it is furnished with perhaps their mixture of mould release silicon or fluorine with the ultra sticking surfaces coated that contact of layer (5) that brightens of ground floor.
3. the two component teeth whitening pad pastings of anhydrous ultra sticking formula according to claim 1; It is characterized in that: the active short permeable formation (2) of the second layer of the active short infiltration component of B component is that its prescription is dissolved in the effumability solution ethanol equally; Through 60 ℃ to 80 ℃ temperature effumability solution ethanol is dried then and form; Its thickness is between the 0.01mm to 0.05mm, and its shape is the shape with suitable user dental bed and tooth; The 3rd layer is peeled off backing layer B (3) is transparent or the plastic opaque thin film, and preferred material is plastic sheeting, paper tinsel or the paper of PET material, and it is furnished with mould release silicon or fluorine or their mixture with the surfaces coated that the active short permeable formation (2) of the second layer contacts.
CN 201210142008 2012-05-09 2012-05-09 Anhydrous ultra-sticky type double-component tooth-whitening sticking film Active CN102626379B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112957280A (en) * 2021-02-04 2021-06-15 南昌思麦科技有限公司 Dry tooth whitening adhesive film
CN113207278A (en) * 2019-12-19 2021-08-03 株式会社Lg生活健康 Adhesive sheet for attaching to teeth
CN114028242A (en) * 2021-10-12 2022-02-11 南昌思麦科技有限公司 Easy-to-peel tooth whitening dry paste and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1713882A (en) * 2002-11-21 2005-12-28 Lg生活健康株式会社 Dry type patches safe for gum
CN1813656A (en) * 2005-11-07 2006-08-09 徐良 Tooth-whitening paster and its use method
CN101019812A (en) * 2006-04-21 2007-08-22 阮仕星 Elastic gel tooth film for deep whitening

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1713882A (en) * 2002-11-21 2005-12-28 Lg生活健康株式会社 Dry type patches safe for gum
CN1813656A (en) * 2005-11-07 2006-08-09 徐良 Tooth-whitening paster and its use method
CN101019812A (en) * 2006-04-21 2007-08-22 阮仕星 Elastic gel tooth film for deep whitening

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113207278A (en) * 2019-12-19 2021-08-03 株式会社Lg生活健康 Adhesive sheet for attaching to teeth
CN113207278B (en) * 2019-12-19 2023-10-03 株式会社Lg生活健康 Patch for attaching teeth
CN112957280A (en) * 2021-02-04 2021-06-15 南昌思麦科技有限公司 Dry tooth whitening adhesive film
CN114028242A (en) * 2021-10-12 2022-02-11 南昌思麦科技有限公司 Easy-to-peel tooth whitening dry paste and preparation method thereof

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Effective date of registration: 20160126

Address after: 510000 Guangdong Province, Guangzhou Baiyun District and the town of Donghua Hua Industrial Zone No. 29.

Patentee after: Guangzhou onuo clean personal care products Co. Ltd.

Address before: 14-402 room 510410, compound 2, Lok Tong Road, Baiyun District, Guangdong, Guangzhou

Patentee before: Ruan Shixing