CN102617944A - Chlorinated polyethylene rubber for manufacturing wind energy cables and preparation method for chlorinated polyethylene rubber - Google Patents
Chlorinated polyethylene rubber for manufacturing wind energy cables and preparation method for chlorinated polyethylene rubber Download PDFInfo
- Publication number
- CN102617944A CN102617944A CN2012100901494A CN201210090149A CN102617944A CN 102617944 A CN102617944 A CN 102617944A CN 2012100901494 A CN2012100901494 A CN 2012100901494A CN 201210090149 A CN201210090149 A CN 201210090149A CN 102617944 A CN102617944 A CN 102617944A
- Authority
- CN
- China
- Prior art keywords
- parts
- chlorinated polyethylene
- polyethylene rubber
- wind energy
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
The invention discloses chlorinated polyethylene rubber for manufacturing wind energy cables and a preparation method for the chlorinated polyethylene rubber. The chlorinated polyethylene rubber comprises 100 to 110 parts of chlorinated polyethylene, 10 to 15 parts of magnesium oxide, 1 to 2.5 parts of tribasic lead sulfate, 1 to 3 parts of lead stearate, 0.5 to 1.5 parts of stearic acid, 15 to 25 parts of high abrasion resistant carbon black, 1 to 3 parts of flame retardant, 15 to 20 parts of dioctyl ester, 20 to 33 parts of chlorinated paraffin, 10 to 13 parts of light calcium carbonate, 1.5 to 3.6 parts of cross-linker, 2 to 3.6 parts of assistant cross-linker, 1 to 3 parts of antioxidant, 2 to 5 parts of paraffin oil, 2 to 3.5 parts of zinc oxide, 2 to 4 parts of plasticizer, 0.5 to 2 parts of antimony trioxide, 0.5 to 1 part of zinc borate, 3 to 6 parts of basic magnesium carbonate, 2 to 6 parts of epoxy soybean oil, 13 to 18 parts of decabromodiphenyl ether, 18 to 25 parts of antimony oxide, 2 to 5 parts of anti-ultraviolet agent, and 1 to 5 parts of organic modified bentonite. The chlorinated polyethylene rubber has the advantages of wide applicable temperature range, good performance and long service life.
Description
Technical field
The present invention relates to electric wire and manufacture the field, specifically is that a kind of manufacturing wind energy cable is with chlorinated polyethylene rubber and preparation method thereof.
Background technology
Wind energy is the energy inexhaustible and that clean very much, is containing huge energy, so the development of wind-power electricity generation in the whole world is swift and violent; China annual with the speed of being doubled flourish; Being planned to of the wind power generation of country: reach 3,000 ten thousand kw to the year two thousand twenty, but see from present tempo, the wind power generation installed capacity of China will surpass the predetermined development program of country out and away; It is like a raging fire that wind-power electricity generation develops, and expedited the emergence of the heavy demand to wind energy cable.
Wind energy cable is owing to be under the severe environment throughout the year; And China's wind scale difference is bigger, and simultaneously vast in territory, north-south climate difference is also bigger; The coastland has corrodibility again; Can accelerate the aging of cable, influence the safe operating life of cable, yet the over-all properties of the wind energy cable that prior art is manufactured can't satisfy the demands well.
Summary of the invention
Technical problem to be solved by this invention provides the prescription and the preparation method of the chlorinated polyethylene rubber mixture sheath material that a kind of brand-new manufacturing wind energy cable uses; This material can be under-70 ℃ to 120 ℃ TR conditions life-time service; And keep good flexibility, anti-twisting property, anti-cracking performance; Rub resistance and flame retardant resistance, work-ing life is more than 30 years simultaneously.
A kind of manufacturing wind energy cable of the present invention is used chlorinated polyethylene rubber, and it comprises following component and parts by weight thereof: chlorinatedpolyethylene 100-110 part; Natural manganese dioxide 10-15 part; Lead sulfate tribasic 1-2.5 part; Lead stearate 1-3 part; Triple Pressed Stearic Acid 0.5-1.5 part; High wear-resistant carbon black 15-25 part; Fire retardant 1-3 part; Dibutyl ester 15-20 part; Clorafin 20-33 part; Light calcium carbonate 10-13 part; Linking agent (DCP) 1.5-3.6 part; Additional crosslinker (TAIC) 2-3.6 part; Oxidation inhibitor 1-3 part; Yellow Protopet 2A 2-5 part; Zinc oxide 2-3.5 part; Softening agent 2-4 part; Antimony Trioxide: 99.5Min 0.5-2 part; Zinc borate 0.5-1 part; Magnesium basic carbonate 3-6 part; Epoxy soybean oil 2-6 part; Decabromodiphenyl oxide 13-18 part; Weisspiessglanz 18-25 part; Anti ultraviolet agent 2-5 part; Organic bentonite 1-5 part.
In addition, the present invention also provides the preparation method who sees above-mentioned chlorinated polyethylene rubber, the steps include: except that linking agent and additional crosslinker; All batching blending are stirred, uses Banbury mixer, add linking agent and additional crosslinker continuation banburying 1-3 minute then in temperature banburying 45-60 minute during as the 65-80 ℃ of left and right sides; Sizing material is discharged from Banbury mixer, use the mill film-making, then packing; Finished product is processed; Cure conditions when producing cable is: pressure 8-10MPa, temperature 160-170 ℃, time 15-20 minute.
The present invention is when blending is stirred and produce cable in the sulfurized process; The blend glue stuff phase is even; The over-all properties of cross-linked rubber is better, when Natural manganese dioxide, lead sulfate tribasic is shared and not only make during with Antimony Trioxide: 99.5Min, zinc borate, magnesium basic carbonate and decabromodiphenyl oxide, weisspiessglanz combination matching cable obviously improve the job stability under anticorrosion, acidproof and high temperature resistance, the mal-condition, also has good flame-retardant effect; Oxygen index can be more than 36; Its anti-environmental aging performance and the effect that increases the service life are very desirable, and softening and plasticization effect and resistance to low temperature are better when Yellow Protopet 2A and softening agent (DBP) are shared with 5/3, and the combination of anti ultraviolet agent (UV9), linking agent (DCP) and additional crosslinker (TAIC) obviously improves the mechanical property of sizing material; Improve the aging resistance and the ultraviolet aging resistance of warm air; The existing reinforcing effect preferably of high wear-resistant carbon black has good crocking resistance again, and the mixing match of epoxy soybean oil and paraffin has not only improved the tensile property of sizing material, has also improved the resistance toheat of sizing material greatly and has improved work-ing life; Organic bentonite not only cooperates the filler reinforcement effect of high wear-resistant carbon black; When it was distributed to the nm level after sizing material mixes the sulfuration of stirring proportioning when, the nano effect that its powerful specific surface area is formed can bring new particular performances and characteristic; Promptly become the nano-composite insulating sizing material; After the mixing sulfuration of above-mentioned prescription mixing match, its flame retardant properties, softness, antitorque commentaries on classics performance, anti-cracking performance, high-low temperature resistant type and ageing-resistant performance have all obtained the raising of great-leap-forward, for the safety in utilization of wind energy cable provides good guarantee with increasing the service life.
Embodiment
Below in conjunction with embodiment the present invention is described further.
Implement 1
100 parts of chlorinatedpolyethylenees (135B); 10 parts in Natural manganese dioxide; 2.5 parts of lead sulfate tribasics; 2 parts of lead stearates; 1.5 parts of Triple Pressed Stearic Acid; 25 parts of high wear-resistant carbon blacks; 2 parts of fire retardants (HZR23); 15 parts of dibutyl esters; 33 parts of clorafins; 13 parts of light calcium carbonates; 3.6 parts of linking agents (DCP); 3.6 parts of additional crosslinkers (TAIC); 1 part in oxidation inhibitor (DLTP); 5 parts of Yellow Protopet 2As; 3.5 parts in zinc oxide; 4 parts in softening agent (DBP); 2 parts of Antimony Trioxide: 99.5Mins; 1 part of zinc borate; 6 parts of magnesium basic carbonates; 5 parts of epoxy soybean oils; 15 parts of decabromodiphenyl oxides; 20 parts of weisspiessglanzs; 5 parts of anti ultraviolet agents (UV9); 5 parts of organic bentonites.
Embodiment 2
110 parts of chlorinatedpolyethylenees (135B); 8 parts in Natural manganese dioxide; 2.2 parts of lead sulfate tribasics; 1.5 parts of lead stearates; 1.0 parts of Triple Pressed Stearic Acid; 22 parts of high wear-resistant carbon blacks; 3 parts of fire retardants (HZR23); 15 parts of dibutyl esters; 30 parts of clorafins; 10 parts of light calcium carbonates; 3 parts of linking agents (DCP); 3 parts of additional crosslinkers (TAIC); 2 parts in oxidation inhibitor (DLTP); 4 parts of Yellow Protopet 2As; 2 parts in zinc oxide; 3 parts in softening agent (DBP); 1.5 parts of Antimony Trioxide: 99.5Mins; 0.8 part of zinc borate; 5 parts of magnesium basic carbonates; 4 parts of epoxy soybean oils; 16 parts of decabromodiphenyl oxides; 22 parts of weisspiessglanzs; 4 parts of anti ultraviolet agents (UV9); 4 parts of organic bentonites.
Embodiment 3
105 parts of chlorinatedpolyethylenees (135B); 9 parts in Natural manganese dioxide; 2 parts of lead sulfate tribasics; 1.5 parts of lead stearates; 2 parts of Triple Pressed Stearic Acid; 23 parts of high wear-resistant carbon blacks; 2.5 parts of fire retardants (HZR23); 18 parts of dibutyl esters; 31 parts of clorafins; 11 parts of light calcium carbonates; 2.5 parts of linking agents (DCP); 2.5 parts of additional crosslinkers (TAIC); 2.5 parts in oxidation inhibitor (DLTP); 4 parts of Yellow Protopet 2As; 3 parts in zinc oxide; 2 parts in softening agent (DBP); 1.5 parts of Antimony Trioxide: 99.5Mins; 1 part of zinc borate; 5 parts of magnesium basic carbonates; 4 parts of epoxy soybean oils; 18 parts of decabromodiphenyl oxides; 25 parts of weisspiessglanzs; 2 parts of anti ultraviolet agents (UV9); 4 parts of organic bentonites.
The preparation method:
Earlier all the batching blending except that linking agent (DCP) and additional crosslinker (TAIC) are stirred, uses Banbury mixer, add linking agent (DCP) and additional crosslinker (TAIC) continuation banburying 1-3 minute then in temperature banburying 45-60 minute during as the 65-80 ℃ of left and right sides; Sizing material is discharged from Banbury mixer, use the mill film-making, then packing; Finished product is processed; Cure conditions when producing cable is: pressure 8-10MPa, temperature 160-170 ℃, time 15-20 minute.
The invention provides a kind of prescription that is used to make the chlorinatedpolyethylene glue mixture that wind energy cable uses and preparation method thereof; Concrete application approach is a lot, and the above only is one of embodiment of the present invention, should be understood that; Technician for the present technique field; Under the prerequisite that does not break away from the principle of the invention, just make the adjustment of simple proportioning change and consumption, these improvement all are protection scope of the present invention.
Claims (2)
1. a manufacturing wind energy cable is used chlorinated polyethylene rubber, it is characterized in that comprising following component and parts by weight thereof: chlorinatedpolyethylene 100-110 part; Natural manganese dioxide 10-15 part; Lead sulfate tribasic 1-2.5 part; Lead stearate 1-3 part; Triple Pressed Stearic Acid 0.5-1.5 part; High wear-resistant carbon black 15-25 part; Fire retardant 1-3 part; Dibutyl ester 15-20 part; Clorafin 20-33 part; Light calcium carbonate 10-13 part; Linking agent 1.5-3.6 part; Additional crosslinker 2-3.6 part; Oxidation inhibitor 1-3 part; Yellow Protopet 2A 2-5 part; Zinc oxide 2-3.5 part; Softening agent 2-4 part; Antimony Trioxide: 99.5Min 0.5-2 part; Zinc borate 0.5-1 part; Magnesium basic carbonate 3-6 part; Epoxy soybean oil 2-6 part; Decabromodiphenyl oxide 13-18 part; Weisspiessglanz 18-25 part; Anti ultraviolet agent 2-5 part; Organic bentonite 1-5 part.
2. the preparation method of a chlorinated polyethylene rubber is characterized in that step is: except that linking agent and additional crosslinker, all batching blending are stirred; Use Banbury mixer in temperature banburying 45-60 minute during, add linking agent and additional crosslinker then and continue banburying 1-3 minute, sizing material is discharged from Banbury mixer as the 65-80 ℃ of left and right sides; Use the mill film-making, pack then, finished product is processed; Cure conditions when producing cable is: pressure 8-10MPa, temperature 160-170 ℃, time 15-20 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100901494A CN102617944A (en) | 2012-03-30 | 2012-03-30 | Chlorinated polyethylene rubber for manufacturing wind energy cables and preparation method for chlorinated polyethylene rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100901494A CN102617944A (en) | 2012-03-30 | 2012-03-30 | Chlorinated polyethylene rubber for manufacturing wind energy cables and preparation method for chlorinated polyethylene rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102617944A true CN102617944A (en) | 2012-08-01 |
Family
ID=46558180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012100901494A Pending CN102617944A (en) | 2012-03-30 | 2012-03-30 | Chlorinated polyethylene rubber for manufacturing wind energy cables and preparation method for chlorinated polyethylene rubber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102617944A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838811A (en) * | 2012-09-27 | 2012-12-26 | 四川明星电缆股份有限公司 | Rubber sheath material for cable |
| CN103627098A (en) * | 2013-11-29 | 2014-03-12 | 沈阳化工大学 | Light-colored CM/CPE (chlorinated polyethylene rubber/chlorinated polyethylene) elastic material and preparation method thereof |
| CN103937050A (en) * | 2014-05-04 | 2014-07-23 | 无锡宝通带业股份有限公司 | Cold-resistant anti-icing covering rubber for conveyor belt and preparation method thereof |
| CN105542329A (en) * | 2016-01-27 | 2016-05-04 | 安徽凯博尔特种电缆集团有限公司 | Low-smoke zero-halogen flame-retardant polyolefin cable material |
| CN106188913A (en) * | 2016-09-07 | 2016-12-07 | 马鞍山纽盟知识产权管理服务有限公司 | A kind of high temperature-resistant cable insulant |
| CN106280041A (en) * | 2015-05-15 | 2017-01-04 | 特变电工股份有限公司 | A kind of cable for wind power generation rubber material and cable cover(ing) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101221836A (en) * | 2007-12-21 | 2008-07-16 | 江苏中煤电缆集团有限公司 | Low temperature resistant anti-crack rubber sleeve flexible cable used for wind power generation |
| JP2009275190A (en) * | 2008-05-16 | 2009-11-26 | Fujikura Ltd | Flame retardant resin composition, insulated wire and wire harness |
| CN101643563A (en) * | 2009-08-27 | 2010-02-10 | 江苏久立电缆有限公司 | Chlorinated polyethylene used for preparation of low temperature wind energy cable and preparation method thereof |
| US20110166279A1 (en) * | 2010-01-07 | 2011-07-07 | Ahmed Ali Basfar | Clean flame retardant insulation composition to enhance mechanical properties and flame retardancy for wire and cable |
-
2012
- 2012-03-30 CN CN2012100901494A patent/CN102617944A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101221836A (en) * | 2007-12-21 | 2008-07-16 | 江苏中煤电缆集团有限公司 | Low temperature resistant anti-crack rubber sleeve flexible cable used for wind power generation |
| JP2009275190A (en) * | 2008-05-16 | 2009-11-26 | Fujikura Ltd | Flame retardant resin composition, insulated wire and wire harness |
| CN101643563A (en) * | 2009-08-27 | 2010-02-10 | 江苏久立电缆有限公司 | Chlorinated polyethylene used for preparation of low temperature wind energy cable and preparation method thereof |
| US20110166279A1 (en) * | 2010-01-07 | 2011-07-07 | Ahmed Ali Basfar | Clean flame retardant insulation composition to enhance mechanical properties and flame retardancy for wire and cable |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838811A (en) * | 2012-09-27 | 2012-12-26 | 四川明星电缆股份有限公司 | Rubber sheath material for cable |
| CN103627098A (en) * | 2013-11-29 | 2014-03-12 | 沈阳化工大学 | Light-colored CM/CPE (chlorinated polyethylene rubber/chlorinated polyethylene) elastic material and preparation method thereof |
| CN103627098B (en) * | 2013-11-29 | 2016-01-20 | 沈阳化工大学 | A kind of light CM/CPE resilient material and preparation method thereof |
| CN103937050A (en) * | 2014-05-04 | 2014-07-23 | 无锡宝通带业股份有限公司 | Cold-resistant anti-icing covering rubber for conveyor belt and preparation method thereof |
| CN103937050B (en) * | 2014-05-04 | 2016-02-17 | 无锡宝通带业股份有限公司 | Cold-resistant anti-icing covering rubber for conveyor belt and preparation method thereof |
| CN106280041A (en) * | 2015-05-15 | 2017-01-04 | 特变电工股份有限公司 | A kind of cable for wind power generation rubber material and cable cover(ing) |
| CN105542329A (en) * | 2016-01-27 | 2016-05-04 | 安徽凯博尔特种电缆集团有限公司 | Low-smoke zero-halogen flame-retardant polyolefin cable material |
| CN106188913A (en) * | 2016-09-07 | 2016-12-07 | 马鞍山纽盟知识产权管理服务有限公司 | A kind of high temperature-resistant cable insulant |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102617942B (en) | Ethylene-propylene-diene monomer rubber used for manufacturing wind energy cable and preparation method thereof | |
| CN102977605B (en) | A kind of silicone rubber crosslinking fire-resistant cable material and preparation method thereof | |
| CN102617944A (en) | Chlorinated polyethylene rubber for manufacturing wind energy cables and preparation method for chlorinated polyethylene rubber | |
| CN103483707B (en) | The preparation technology of rubber cable sheath material | |
| CN102924835B (en) | High-strength high-inflaming-retardant rubber sheath material of mine cable and preparation process | |
| CN103232631B (en) | A kind of Halogen-free low-smoke flame-retardant cable sheath material and preparation method thereof | |
| CN103483708B (en) | Low-temperature-resistance flame-retardant rubber cable sheath material | |
| CN104194100A (en) | High-performance rubber material for cable sheaths | |
| CN106916438B (en) | A kind of halogen-free flameproof anti-dripping melt Thermoplastic polyurethane elastomer material and preparation method thereof | |
| CN102977614B (en) | A kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof | |
| CN102977611A (en) | Zero-halogen and low-smoke flame retardant cable material for computers, and its preparation method | |
| CN102153802A (en) | Ultraviolet-light deeply cross-linked halogen-free flame-retardant polyolefin cable material and method for preparing ultraviolet-light deeply cross-linked halogen-free flame-retardant polyolefin cable insulating or sheathing layer from same | |
| CN103483673A (en) | Low-smoke halogen-free inflaming retarding polyolefin photovoltaic cable sheath polyolefin material and method for preparing same | |
| CN102977466A (en) | Flame-retardant, environmentally-friendly and safe polyolefin sheath material and its preparation method | |
| CN101643563B (en) | Chlorinated polyethylene used for preparation of low temperature wind energy cable and preparation method thereof | |
| CN104371199A (en) | Low-smoke halogen-free coal mine electric cable material and preparation method thereof | |
| CN102977609A (en) | Oil and low-temperature resistant low-smoke and halogen-free flame retardant cable material for boats, and its preparation method | |
| CN103642140A (en) | High-tear-resistant and wear-resistant mining flame-retardant chlorinated polyethylene sheath material and preparation method thereof | |
| CN102746573A (en) | Methyl vinyl silicone rubber insulating heat-resistant control cable material and preparation method thereof | |
| CN102746609B (en) | A kind of eco-type flame retardant compound and preparation method thereof | |
| CN104610668A (en) | No-coloring low-peculiar-smell flame-retardant ethylene-propylene rubber material and preparation method thereof | |
| CN104910447A (en) | Flame-retardant rubber | |
| CN105238270A (en) | Flame-retardant and smoke-inhibition type non-cured rubber asphalt waterproof coating material | |
| CN103087395B (en) | Grade-1E K2-type radiation cross-linked halogen-free flame-retardant cable material for nuclear power plant and preparation method thereof | |
| CN102746564B (en) | Corrosion resistant CABLE MATERIALS of a kind of modified, high temperature resistant and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120801 |