CN102604458B - Natural environment-friendly plant gloss oil - Google Patents
Natural environment-friendly plant gloss oil Download PDFInfo
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- CN102604458B CN102604458B CN201210056461.1A CN201210056461A CN102604458B CN 102604458 B CN102604458 B CN 102604458B CN 201210056461 A CN201210056461 A CN 201210056461A CN 102604458 B CN102604458 B CN 102604458B
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- ethoxyquin
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Abstract
The invention relates to the technical field of gloss paint, and in particular relates to natural environment-friendly plant gloss oil. The natural environment-friendly plant gloss oil is characterized by comprising the following components by weight percent: 42-50% of natural plant secreted oil, 10-12% of bisphenol A acrylate methacrylate, 5.5-16% of ethoxylated pentahydroxy methyl oligomer, 6-8% of pentaerythritol hexapropionate, 5-6.5% of ethoxylated hydroxymethyl dimethylmethane, 7-9% of pentahydroxymethyl propane dimethyl ester, 3.5-5.5 % of dioxymethyl separating agent, 5.5-7% of polyester moisture drying agent and 0.5%-1.5% of flatting agent. The natural environment-friendly plant gloss paint provided by the invention has high environment-friendly index number, is plump and soft and has good hand feeling; the gloss oil has high transparency, and natural color of wood can be restored; the gloss oil is hard and wear-resistant, and has good scratch resistance; the gloss oil is clean-smelling, healthy, environment-friendly, good in scratch resistance and wear resistance and strong in adhesive force; and the gloss oil has good hardness, is free of after-tack and resists sea water.
Description
Technical field
The present invention relates to gloss oil technical field, relate in particular to a kind of natural environmental-protective plant gloss oil.
Background technology
Gloss oil is a kind of synthetic resins, now typically refers to surface transparent varnish, by base-material and auxiliary agent etc., is made, and does not add any pigment, glossy shinny after film forming, is commonly called as and is varnish, has dividing of UV gloss oil and PU gloss oil.
Along with the progress of human society, the development of science and technology, people have obtained physical resources and the energy of a large amount of production and consumptions, have improved the mankind's life, but synthetic chemistry is brought variation to the mankind again simultaneously.And this variation has caused the extreme variation in the living space that urban centralization brings, and along with the densification in living space, cause the synthetic chemical increase of order of contact in daily life.The minimizing of place and the use of chemical substance are constantly discharged objectionable impurities in atmosphere, and the detergent power of air is reduced.The topsoil that today is serious and the decline of Air quality have directly destroyed the ozonosphere of undertaking mankind patron saint, have brought global environmental change.
Under the impact developing rapidly in international crude vegetal paint market; in the situation that particularly compatriots' environmental consciousness strengthens gradually; the living environment of pursuing high-quality life, the applicable human living of construction is no longer the special topic that the foreigner discusses; cherish life; protection of the environment, is put on agenda by compatriots.Thousands upon thousands Chinese are reluctant because of the impact of hazardous and noxious substances, to cause the generation of disease again, and how many father and mother are reluctant seeing that child is devitalized by the impact of poisonous hazardous compound by the serious illness because having helplessly again.Therefore the high-performance of crude vegetal paint is not particularly admitted by people containing hazardous and noxious substances, so the market outlook of crude vegetal paint are optimistic.Its Nonpoisonous, non-environmental-pollution, not only thoroughly solve the pollution problem of coating, and provide a pollution-free industry chain that has a extensive future, connects one or two industries, the recycling economy development direction that not only meets national chemical building material industry policy, also the consumption concept that meets people, will be subject to the support energetically of country and people's height parent and look at, market potential is huge, and prospect is very wide.
Existing environment protection oil paint is not proper containing any chemosynthesis material, just chemical substance is down to minimumly as far as possible, environment still had to certain harm, so provide a kind of natural phant environmental protection gloss oil just to become our main task.
Summary of the invention
Object of the present invention provides a kind of pure natural environment protection plant gloss oil, and employing natural phant is starting material, health environment-friendly, and scratch resistance, wear resistance is good and strong adhesion, for environment is contributed and realizes environmental protection truly.
The weight percent of the component the present invention relates to is all to take gloss oil gross weight as benchmark.
For realizing above-mentioned object, the present invention is achieved by the following technical solutions:
A kind of natural environmental-protective plant gloss oil is provided, comprise filmogen, solvent and auxiliary agent, wherein said filmogen comprises natural phant secretion oil, dihydroxyphenyl propane vinylformic acid methacrylic acid half ester and ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing, described solvent comprises tetramethylolmethane six propionic esters, ethoxyquin first hydroxymethyl-propane and pentahydroxy-methylpropane dimethyl esters, and described auxiliary agent comprises dioxy methyl separating agent, the agent of polyester moisture drying and flow agent.The weight percent of the composition of described natural environmental-protective plant gloss oil is as follows: filmogen 57～70%, solvent 18～30%, auxiliary agent 9.5～15%.
Further concrete, the weight percent of natural environmental-protective plant gloss oil is: natural phant secretion oil 42～50%, dihydroxyphenyl propane vinylformic acid methacrylic acid half ester 10～12%, ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing 5.5～16%, tetramethylolmethane six propionic esters 6～8%, ethoxyquin first hydroxymethyl-propane 5～6.5%, pentahydroxy-methylpropane dimethyl esters 7～9%, dioxy methyl separating agent 3.5～5.5%, polyester moisture drying agent 5.5～7%, flow agent 0.5～1.5%.
Natural phant secretion oil refers to the grease of producing with various non-edible plant oil plants, includes the unedible industrial plant oil plants such as tung oil, Viscotrol C, Chinese catalpa oil, wood oil, pine tar.
The weight percent of described dioxy methyl separating agent is preferably 4.6%.
The model of described flow agent is BYK-306, and the weight percent of described BYK-306 flow agent is preferably 0.8%.
The weight percent of described polyester moisture drying agent is preferably 6.3%..
Natural environmental-protective plant gloss oil, is applicable to the aspects such as senior household electrical appliances, communication, seehears, timber floor, paint film constancy.
The beneficial effect of technical scheme of the present invention is: the invention provides natural environmental-protective Plant Light oil ring guarantor index high, be better than national standard; Paint film is plentiful soft and smooth, and feel is splendid; Gloss oil transparency is high, also protolignin's true qualities; Gloss oil hard wear resistant, adhesion strength is good; ; Gloss oil smell is pure and fresh, health environment-friendly, and scratch resistance, wear resistance are good, strong adhesion; The good characteristics such as gloss oil hardness is good, do not after-tack, sea water resistance.
Embodiment
The scientific research personnel of company confirms through a large amount of experiments, at the starting material of selecting, be natural phant secretion oil (commercially available), dihydroxyphenyl propane vinylformic acid methacrylic acid half ester (commercially available), ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing (commercially available), tetramethylolmethane six propionic esters (commercially available), ethoxyquin first hydroxymethyl-propane (commercially available), pentahydroxy-methylpropane dimethyl esters (commercially available), dioxy methyl separating agent (Ji Li chemical plant, Taiwan), polyester moisture drying agent (Beijing Hua Hui company limited), during BYK-306 flow agent (commercially available), the sticking power of the natural environmental-protective plant gloss oil of producing is best, hardness is maximum, equally on experiment basis, adopt above starting material, according to the weight percent preparation effect in disclosure of the invention content, be best.
Below in conjunction with embodiment, the present invention is described in further details.
Through great many of experiments, draw the sticking power for natural environmental-protective plant gloss oil of the present invention, what hardness had the greatest impact is natural phant secretion oil, ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing, the weight percent of dioxy methyl separating agent and the agent of polyester moisture drying, because dihydroxyphenyl propane vinylformic acid methacrylic acid half ester is to natural environmental-protective plant attaching power, when making subtle change, can there is not the change in performance in hardness, therefore, following examples adopt other amounts constant, only has natural phant secretion oil, ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing, the situation that the weight percent of dioxy methyl separating agent and the agent of polyester moisture drying changes describes,
Embodiment 1
The components by weight of natural environmental-protective plant gloss oil is table 1 for example, in the situation that the components by weight percent ratio of table 1, sticking power, the hardness of testing natural environment protecting plant gloss oil.
Table 1
Under the part by weight of the natural environmental-protective Plant Light oil ingredient of table 1, the result of test sticking power, hardness is as table 2.
Table 2
As shown in table 1, table 2, at natural phant, secreting oily part by weight is 40.5%, the part by weight of ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing is 17.5%, the part by weight of dioxy methyl separating agent is 4.0%, when the part by weight of polyester moisture drying agent is 5.8%, experimental result, coating surface is depainting slightly, and hardness is H.
Embodiment 2
The components by weight of natural environmental-protective plant gloss oil is table 3 for example, in the situation that the components by weight percent ratio of table 3, sticking power, the hardness of testing natural environment protecting plant gloss oil.
Table 3
Under the part by weight of the natural environmental-protective plant gloss oil of table 3, test the result of natural environment protecting plant gloss oil sticking power, hardness as table 4;
Table 4
As shown in table 3, table 4, at natural phant, secreting oily part by weight is 47.3%, the part by weight of ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing is 9.6%, the part by weight of dioxy methyl separating agent is 4.6%, when the part by weight of polyester moisture drying agent is 6.3%, experimental result, coating surface is without depainting, hardness of paint film 2H.
Embodiment 3
The components by weight of natural environmental-protective plant gloss oil is table 5 for example, in the situation that the components by weight percent ratio of table 5, sticking power, the hardness of testing natural environment protecting plant gloss oil.
Table 5
Under the part by weight of the natural environmental-protective plant gloss oil of table 5, test the result of natural environment protecting plant gloss oil sticking power, hardness as table 6;
Table 6
As shown in table 5, table 6, at natural phant, secreting oily part by weight is 51.3%, the part by weight of ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing is 5.6%, the part by weight of dioxy methyl separating agent is 5.2%, when the part by weight of polyester moisture drying agent is 6.8%, experimental result, coating surface has slight depainting, hardness H.
Although the object that preferred embodiment of the present invention is usingd as illustration discloses, it will be appreciated by those skilled in the art that various modifications, interpolation and replacement are possible, as long as it does not depart from the spirit and scope of the present invention that describe in detail in claims.
Claims (7)
1. a natural environmental-protective plant gloss oil, is characterized in that comprising the component of following weight percent:
Natural phant secretion oil 42～50%, dihydroxyphenyl propane vinylformic acid methacrylic acid half ester 10～12%, ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing 5.5～16%, tetramethylolmethane six propionic esters 6～8%, ethoxyquin first hydroxymethyl-propane 5～6.5%, pentahydroxy-methylpropane dimethyl esters 7～9%, dioxy methyl separating agent 3.5～5.5%, polyester moisture drying agent 5.5～7%, flow agent 0.5～1.5%.
2. natural environmental-protective plant gloss oil according to claim 1, is characterized in that: described flow agent is that model is the flow agent of BYK-306.
3. natural environmental-protective plant gloss oil according to claim 1, is characterized in that: the weight percent of described dioxy methyl separating agent is 4.6%.
4. natural environmental-protective plant gloss oil according to claim 1, is characterized in that: the weight percent of described polyester moisture drying agent is 6.3%.
5. natural environmental-protective plant gloss oil according to claim 2, is characterized in that comprising the component of following weight percent:
Natural phant secretion oil 42%, dihydroxyphenyl propane vinylformic acid methacrylic acid half ester 11.2%, ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing 16%, tetramethylolmethane six propionic esters 6.8%, ethoxyquin first hydroxymethyl-propane 5.5%, pentahydroxy-methylpropane dimethyl esters 7.9%, dioxy methyl separating agent 4%, polyester moisture drying agent 5.8%, BYK-306 flow agent 0.8%.
6. natural environmental-protective plant gloss oil according to claim 2, is characterized in that comprising the component of following weight percent:
Natural phant secretion oil 47.5%, dihydroxyphenyl propane vinylformic acid methacrylic acid half ester 11.2%, ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing 9.6%, tetramethylolmethane six propionic esters 6.8%, ethoxyquin first hydroxymethyl-propane 5.5%, pentahydroxy-methylpropane dimethyl esters 7.9%, dioxy methyl separating agent 4.6%, polyester moisture drying agent 6.3%, BYK-306 flow agent 0.8%.
7. natural environmental-protective plant gloss oil according to claim 2, is characterized in that comprising the component of following weight percent:
Natural phant secretion oil 50%, dihydroxyphenyl propane vinylformic acid methacrylic acid half ester 11.2%, ethoxyquin pentahydroxy-dimethylsiloxane oligomer thing 5.8%, tetramethylolmethane six propionic esters 6.8%, ethoxyquin first hydroxymethyl-propane 5.5%, pentahydroxy-methylpropane dimethyl esters 7.9%, dioxy methyl separating agent 5.2%, polyester moisture drying agent 6.8%, BYK-306 flow agent 0.8%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210056461.1A CN102604458B (en) | 2012-03-06 | 2012-03-06 | Natural environment-friendly plant gloss oil |
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| CN201210056461.1A CN102604458B (en) | 2012-03-06 | 2012-03-06 | Natural environment-friendly plant gloss oil |
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| CN102604458A CN102604458A (en) | 2012-07-25 |
| CN102604458B true CN102604458B (en) | 2014-04-02 |
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| CN106244001B (en) * | 2016-08-02 | 2019-02-01 | 北京楚之园环保科技有限责任公司 | Gloss oil and preparation method thereof for ancient building material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735729A (en) * | 2008-11-06 | 2010-06-16 | 夏栋 | Crude vegetal paint |
| CN101974292A (en) * | 2010-10-09 | 2011-02-16 | 广东嘉宝莉化工集团有限公司 | Hard wax oil and preparation method thereof |
| CN102120910A (en) * | 2011-01-24 | 2011-07-13 | 广东嘉宝莉化工集团有限公司 | Environmentally-friendly solvent type woodware coating with formaldehyde-absorbing function and preparation method thereof |
| CN102363712A (en) * | 2011-06-29 | 2012-02-29 | 大连林桥科技有限公司 | Environment-friendly paint |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101045940B1 (en) * | 2011-01-26 | 2011-07-01 | (주)신화엔지니어링종합건축사사무소 | Paint composition improving mechanical properties and chemical resistance |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735729A (en) * | 2008-11-06 | 2010-06-16 | 夏栋 | Crude vegetal paint |
| CN101974292A (en) * | 2010-10-09 | 2011-02-16 | 广东嘉宝莉化工集团有限公司 | Hard wax oil and preparation method thereof |
| CN102120910A (en) * | 2011-01-24 | 2011-07-13 | 广东嘉宝莉化工集团有限公司 | Environmentally-friendly solvent type woodware coating with formaldehyde-absorbing function and preparation method thereof |
| CN102363712A (en) * | 2011-06-29 | 2012-02-29 | 大连林桥科技有限公司 | Environment-friendly paint |
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Effective date of registration: 20170526 Address after: 200000 Shanghai city Jinshan District Shanyang Zhen Shan Feng Road No. 188 Patentee after: Thousand wave coating (Shanghai) Co., Ltd. Address before: Longgang District of Shenzhen City, Guangdong province 518000 Pingshan street Shahu neighborhood, B A yellow village factory workshop Patentee before: Shenzhen Qianlang Chemical Co., Ltd. |