CN102603987A - Formula of safe modified polyvinylidene fluoride - Google Patents
Formula of safe modified polyvinylidene fluoride Download PDFInfo
- Publication number
- CN102603987A CN102603987A CN2012100533115A CN201210053311A CN102603987A CN 102603987 A CN102603987 A CN 102603987A CN 2012100533115 A CN2012100533115 A CN 2012100533115A CN 201210053311 A CN201210053311 A CN 201210053311A CN 102603987 A CN102603987 A CN 102603987A
- Authority
- CN
- China
- Prior art keywords
- modified polyvinilidene
- safe
- prescription
- polyvinilidene difluoroethylene
- polyvinylidene fluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002033 PVDF binder Substances 0.000 title abstract description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 title abstract description 7
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical group CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 12
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims abstract description 10
- SLETZFVTVXVPLS-UHFFFAOYSA-N [Zn].[Cd].[Ba] Chemical group [Zn].[Cd].[Ba] SLETZFVTVXVPLS-UHFFFAOYSA-N 0.000 claims abstract description 10
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical group COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims abstract description 10
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims abstract description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- WFLOTYSKFUPZQB-UHFFFAOYSA-N 1,2-difluoroethene Chemical group FC=CF WFLOTYSKFUPZQB-UHFFFAOYSA-N 0.000 claims description 29
- 239000011521 glass Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 239000004902 Softening Agent Substances 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 230000003078 antioxidant effect Effects 0.000 abstract 2
- 235000006708 antioxidants Nutrition 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- 239000003365 glass fiber Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a formula of safe modified polyvinylidene fluoride. The formula comprises modified polyvinylidene fluoride, a stabilizing agent, an auxiliary agent, a plasticizing agent, a high-toughness material, and an anti-oxidant. The stabilizing agent is barium-cadmium-zinc, the auxiliary agent is maleic anhydride, the plasticizing agent is diethyl phthalate, the high-toughness material is glass fiber, and the anti-oxidant is butylated hydroxyanisole. With the formula, the prepared safe modified polyvinylidene fluoride is advantaged in high-toughness, wear resistance, good stability, good plasticity, good safety, and the like.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of safe modified polyvinilidene difluoroethylene.
Background technology
PVDF is a kind of fluorocarbon resin of novelty, has very high physical strength and wear resistance, and weathering resistance and thermostability have outstanding erosion resistance in addition, so the raw material that must use in chemical industry, any metal all can't substitute.PVDF again in Fluroplast-4 physical strength the highest.Along with the depth development of various industries, PVDF is extensively adopted, and has good piezoelectricity, radiation hardness, and thermostability is also fine, so extensively adopted by electron trade, X-former manufacturing.Also be used in fields such as aerospace, military field, sea water desaltination, metallurgy, electric wire, electric elements, machinofacture.
But, reach in the requirement of component of machinofacture of some special dimension, or some is insufficient.As everyone knows, steel is the necessary material of manufacturing machine, but the strong acid, alkali, salt, the polar solvent aspect that are used in chemical industry are obsolete., perplexing for a long time that the material of this respect is a kind of well not to be developed, some material can be used but processing difficulties, and can not use repeatedly, so in the deep-etching chemical industry, every year is all costly.All do not reach requirement in effectiveness, performance, work-ing life.The task of top priority must solve the exotic materials of research and development this respect, makes chemical industry obtain stablizing long-range development.
Summary of the invention
The object of the present invention is to provide the prescription of the modified polyvinilidene difluoroethylene that a kind of toughness is high, wear-resistant, stable, plasticity is good, safe.
Technical scheme of the present invention is; A kind of prescription of safe modified polyvinilidene difluoroethylene comprises modified polyvinilidene difluoroethylene, stablizer, auxiliary agent, softening agent, anti-toughness material and inhibitor, and described stablizer is a barium cadmium zinc; Described auxiliary agent is a MALEIC ANHYDRIDE; Described softening agent is a diethyl phthalate, and described anti-toughness material is a spun glass, and described inhibitor is a butylated hydroxy anisole.
In preferred embodiment of the present invention; Each composition weight proportion of prescription of said safe modified polyvinilidene difluoroethylene accounts for 60%-70% for the modified polyvinilidene difluoroethylene; Barium cadmium zinc 4%-6%, MALEIC ANHYDRIDE 5%-7%, diethyl phthalate 8%-10%; Spun glass 6%-8%, butylated hydroxy anisole 7%-9%.
In preferred embodiment of the present invention; Each composition weight proportion of prescription of said safe modified polyvinilidene difluoroethylene accounts for 65%-80% for the modified polyvinilidene difluoroethylene; Barium cadmium zinc 3%-6%, MALEIC ANHYDRIDE 4%-8%, diethyl phthalate 5%-9%; Spun glass 3%-5%, butylated hydroxy anisole 5%-7%.
Each composition weight proportion of prescription of said safe modified polyvinilidene difluoroethylene accounts for 55%-65% for the modified polyvinilidene difluoroethylene, and silica flour accounts for 10%-13%, and dicumyl peroxide accounts for 18%-20%, and silicone lubricant accounts for 7%-12%.
According to the invention is a kind of prescription of safe modified polyvinilidene difluoroethylene, makes the modified polyvinilidene difluoroethylene of the safety that makes have toughness height, wear-resistant, stable, effect such as plasticity is good, safe.
Embodiment
Set forth in detail in the face of preferred embodiment of the present invention down, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
According to the invention is a kind of prescription of safe modified polyvinilidene difluoroethylene; Comprise modified polyvinilidene difluoroethylene, stablizer, auxiliary agent, softening agent, anti-toughness material and inhibitor; Stablizer is a barium cadmium zinc, and auxiliary agent is a MALEIC ANHYDRIDE, and softening agent is a diethyl phthalate; Anti-toughness material is a spun glass, and inhibitor is a butylated hydroxy anisole.
Further, each composition weight proportion of the prescription of the modified polyvinilidene difluoroethylene that this is safe accounts for 60%-70% for the modified polyvinilidene difluoroethylene, barium cadmium zinc 4%-6%; MALEIC ANHYDRIDE 5%-7%; Diethyl phthalate 8%-10%, spun glass 6%-8%, butylated hydroxy anisole 7%-9%.
Further, each composition weight proportion of the prescription of the modified polyvinilidene difluoroethylene that this is safe accounts for 65%-80% for the modified polyvinilidene difluoroethylene, barium cadmium zinc 3%-6%; MALEIC ANHYDRIDE 4%-8%; Diethyl phthalate 5%-9%, spun glass 3%-5%, butylated hydroxy anisole 5%-7%.
Can debug according to different ratios according to different demands, thereby reach different results of use.
According to the invention is a kind of prescription of safe modified polyvinilidene difluoroethylene, makes the modified polyvinilidene difluoroethylene of the safety that makes have toughness height, wear-resistant, stable, effect such as plasticity is good, safe.
The above is merely embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed; Variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the prescription of the modified polyvinilidene difluoroethylene of a safety; It is characterized in that: comprise modified polyvinilidene difluoroethylene, stablizer, auxiliary agent, softening agent, anti-toughness material and inhibitor; Described stablizer is a barium cadmium zinc, and described auxiliary agent is a MALEIC ANHYDRIDE, and described softening agent is a diethyl phthalate; Described anti-toughness material is a spun glass, and described inhibitor is a butylated hydroxy anisole.
2. the prescription of safe modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of prescription of said safe modified polyvinilidene difluoroethylene accounts for 60%-70% for the modified polyvinilidene difluoroethylene; Barium cadmium zinc 4%-6%, MALEIC ANHYDRIDE 5%-7%, diethyl phthalate 8%-10%; Spun glass 6%-8%, butylated hydroxy anisole 7%-9%.
3. the prescription of safe modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of prescription of said safe modified polyvinilidene difluoroethylene accounts for 65%-80% for the modified polyvinilidene difluoroethylene; Barium cadmium zinc 3%-6%, MALEIC ANHYDRIDE 4%-8%, diethyl phthalate 5%-9%; Spun glass 3%-5%, butylated hydroxy anisole 5%-7%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210053311 CN102603987B (en) | 2012-03-03 | 2012-03-03 | Formula of safe modified polyvinylidene fluoride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210053311 CN102603987B (en) | 2012-03-03 | 2012-03-03 | Formula of safe modified polyvinylidene fluoride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102603987A true CN102603987A (en) | 2012-07-25 |
| CN102603987B CN102603987B (en) | 2013-11-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210053311 Active CN102603987B (en) | 2012-03-03 | 2012-03-03 | Formula of safe modified polyvinylidene fluoride |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102603987B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105111638A (en) * | 2015-09-28 | 2015-12-02 | 无锡贺邦金属制品有限公司 | High-toughness plastic product |
| CN106009438A (en) * | 2016-07-29 | 2016-10-12 | 苏州新区特氟龙塑料制品厂 | Modified hard teflon engineering plastic |
| CN110117401A (en) * | 2019-05-16 | 2019-08-13 | 浙江名江南家居有限公司 | A kind of preparation method of anti-aging and wear-resisting seat |
| CN115028945A (en) * | 2022-07-26 | 2022-09-09 | 碧菲分离膜（大连）有限公司 | Synthetic method of polyvinylidene fluoride |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875751A (en) * | 2009-04-29 | 2010-11-03 | 成都水膜方科技有限责任公司 | Modified polyvinylidene fluoride material as well as preparation method and application thereof in hollow fiber membrane material |
| CN101954248A (en) * | 2010-06-22 | 2011-01-26 | 赵岳轩 | Polyvinylidene fluoride hollow fiber membrane and preparation method thereof |
-
2012
- 2012-03-03 CN CN 201210053311 patent/CN102603987B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875751A (en) * | 2009-04-29 | 2010-11-03 | 成都水膜方科技有限责任公司 | Modified polyvinylidene fluoride material as well as preparation method and application thereof in hollow fiber membrane material |
| CN101954248A (en) * | 2010-06-22 | 2011-01-26 | 赵岳轩 | Polyvinylidene fluoride hollow fiber membrane and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105111638A (en) * | 2015-09-28 | 2015-12-02 | 无锡贺邦金属制品有限公司 | High-toughness plastic product |
| CN106009438A (en) * | 2016-07-29 | 2016-10-12 | 苏州新区特氟龙塑料制品厂 | Modified hard teflon engineering plastic |
| CN110117401A (en) * | 2019-05-16 | 2019-08-13 | 浙江名江南家居有限公司 | A kind of preparation method of anti-aging and wear-resisting seat |
| CN115028945A (en) * | 2022-07-26 | 2022-09-09 | 碧菲分离膜（大连）有限公司 | Synthetic method of polyvinylidene fluoride |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102603987B (en) | 2013-11-06 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: NANTONG HUIYUNA PLASTICS CO., LTD. Free format text: FORMER OWNER: SUZHOU NEW DISTRICT TEFLON PLASTIC PRODUCTS FACTORY Effective date: 20150623 |
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Effective date of registration: 20150623 Address after: 226000 Jiangsu city of Nantong province Gangzha Industrial Zone happiness (Wen Jun Cun group four) Patentee after: NANTONG HUIYUAN PLASTIC Co.,Ltd. Address before: 215000 Songshan Road, Suzhou New District, Jiangsu, No. Patentee before: Suzhou New District Teflon Plastic Products Factory |
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Denomination of invention: Formula of safe modified polyvinylidene fluoride Effective date of registration: 20200302 Granted publication date: 20131106 Pledgee: Bank of China Limited by Share Ltd. Nantong branch Pledgor: NANTONG HUIYUAN PLASTIC Co.,Ltd. Registration number: Y2020980000404 |
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Date of cancellation: 20210304 Granted publication date: 20131106 Pledgee: Bank of China Limited by Share Ltd. Nantong branch Pledgor: NANTONG HUIYUAN PLASTIC Co.,Ltd. Registration number: Y2020980000404 |
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Denomination of invention: A safe formula of modified polyvinylidene fluoride Effective date of registration: 20210305 Granted publication date: 20131106 Pledgee: Bank of China Limited by Share Ltd. Nantong branch Pledgor: NANTONG HUIYUAN PLASTIC Co.,Ltd. Registration number: Y2021980001485 |
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Date of cancellation: 20220310 Granted publication date: 20131106 Pledgee: Bank of China Limited by Share Ltd. Nantong branch Pledgor: NANTONG HUIYUAN PLASTIC Co.,Ltd. Registration number: Y2021980001485 |
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Denomination of invention: A safe formula of modified polyvinylidene fluoride Effective date of registration: 20220317 Granted publication date: 20131106 Pledgee: Bank of China Limited by Share Ltd. Nantong branch Pledgor: NANTONG HUIYUAN PLASTIC Co.,Ltd. Registration number: Y2022980002710 |
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Date of cancellation: 20230303 Granted publication date: 20131106 Pledgee: Bank of China Limited by Share Ltd. Nantong branch Pledgor: NANTONG HUIYUAN PLASTIC Co.,Ltd. Registration number: Y2022980002710 |