CN102560190B - 一种高锌无铅黄铜合金及制备方法 - Google Patents
一种高锌无铅黄铜合金及制备方法 Download PDFInfo
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- CN102560190B CN102560190B CN 201210021140 CN201210021140A CN102560190B CN 102560190 B CN102560190 B CN 102560190B CN 201210021140 CN201210021140 CN 201210021140 CN 201210021140 A CN201210021140 A CN 201210021140A CN 102560190 B CN102560190 B CN 102560190B
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- 239000000956 alloy Substances 0.000 title claims abstract description 130
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 127
- 229910001369 Brass Inorganic materials 0.000 title claims abstract description 66
- 239000010951 brass Substances 0.000 title claims abstract description 66
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 62
- 239000011701 zinc Substances 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 57
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 49
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 34
- 239000010439 graphite Substances 0.000 claims abstract description 34
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 25
- 229910052742 iron Inorganic materials 0.000 claims abstract description 23
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052796 boron Inorganic materials 0.000 claims abstract description 21
- 238000005266 casting Methods 0.000 claims abstract description 20
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 19
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000002844 melting Methods 0.000 claims abstract description 18
- 230000008018 melting Effects 0.000 claims abstract description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 17
- 229910052802 copper Inorganic materials 0.000 claims abstract description 17
- 239000010949 copper Substances 0.000 claims abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 13
- 239000011572 manganese Substances 0.000 claims abstract description 13
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 229910001297 Zn alloy Inorganic materials 0.000 claims abstract description 9
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 claims abstract description 9
- IUYOGGFTLHZHEG-UHFFFAOYSA-N copper titanium Chemical compound [Ti].[Cu] IUYOGGFTLHZHEG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000005484 gravity Effects 0.000 claims abstract description 8
- 239000010936 titanium Substances 0.000 claims abstract description 8
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004411 aluminium Substances 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 9
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 9
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 8
- 238000003723 Smelting Methods 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 7
- 229910052746 lanthanum Inorganic materials 0.000 claims description 7
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 7
- 229910052684 Cerium Inorganic materials 0.000 claims description 6
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229910052779 Neodymium Inorganic materials 0.000 claims description 4
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 18
- 230000007797 corrosion Effects 0.000 abstract description 18
- 239000013078 crystal Substances 0.000 abstract description 7
- 238000012545 processing Methods 0.000 abstract description 7
- 229910052797 bismuth Inorganic materials 0.000 abstract description 5
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract description 5
- 239000007769 metal material Substances 0.000 abstract description 2
- 239000002893 slag Substances 0.000 abstract 1
- 229910001340 Leaded brass Inorganic materials 0.000 description 23
- 238000005520 cutting process Methods 0.000 description 21
- 239000000463 material Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910000838 Al alloy Inorganic materials 0.000 description 5
- 238000005275 alloying Methods 0.000 description 5
- 230000003628 erosive effect Effects 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000013535 sea water Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910000906 Bronze Inorganic materials 0.000 description 4
- 239000010974 bronze Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 238000011109 contamination Methods 0.000 description 3
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- 239000002245 particle Substances 0.000 description 3
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- ROTPTZPNGBUOLZ-UHFFFAOYSA-N arsenic boron Chemical compound [B].[As] ROTPTZPNGBUOLZ-UHFFFAOYSA-N 0.000 description 2
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- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
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- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 206010062016 Immunosuppression Diseases 0.000 description 1
- 206010027439 Metal poisoning Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- LYVWMIHLNQLWAC-UHFFFAOYSA-N [Cl].[Cu] Chemical group [Cl].[Cu] LYVWMIHLNQLWAC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- PTVDYARBVCBHSL-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu] PTVDYARBVCBHSL-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
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- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 208000008127 lead poisoning Diseases 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
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- 210000001428 peripheral nervous system Anatomy 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
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- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
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- 238000009864 tensile test Methods 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
Images
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- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
Description
合金(退火后) | 延伸率/% | 抗拉强度/MPa | 硬度HRB | 平均脱锌层厚度/μm |
实施例1 | 48.5 | 480.7 | 44.6 | 235.5 |
实施例2 | 46.1 | 479.5 | 44.5 | 221.3 |
实施例3 | 44.7 | 476.4 | 43.9 | 187.5 |
实施例4 | 43.2 | 479.8 | 44.7 | 198.4 |
H59-1 | 45 | 420 | 44 | 361.9 |
Claims (7)
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CN 201210021140 CN102560190B (zh) | 2012-01-30 | 2012-01-30 | 一种高锌无铅黄铜合金及制备方法 |
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CN102560190A CN102560190A (zh) | 2012-07-11 |
CN102560190B true CN102560190B (zh) | 2013-09-18 |
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Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102732745B (zh) * | 2012-07-12 | 2014-02-05 | 常熟市精工模具制造有限公司 | 高镍铜合金玻璃模具及其制造方法 |
CN102888528B (zh) * | 2012-09-21 | 2014-05-28 | 厦门火炬特种金属材料有限公司 | 一种含石墨的易切削锌白铜合金及其制备工艺 |
CN102925724A (zh) * | 2012-10-30 | 2013-02-13 | 海门市海菱碳业有限公司 | 一种铜锌合金的制备方法 |
CN103725919B (zh) * | 2014-01-03 | 2016-09-14 | 安新县华昌合金厂 | 一种无铅黄铜合金 |
CN103725922B (zh) * | 2014-01-16 | 2017-06-20 | 沈阳亚欧星海铜业有限公司 | 一种无铅硅黄铜合金及制备方法 |
CN106591676A (zh) * | 2016-12-09 | 2017-04-26 | 钦州市钦南区科学技术情报研究所 | 一种无铅铜合金及制备方法 |
CN107385273B (zh) * | 2017-07-07 | 2019-03-01 | 路达(厦门)工业有限公司 | 一种铸造用环保黄铜合金及其制造方法 |
CN108384985A (zh) * | 2018-01-19 | 2018-08-10 | 无锡名精密铜带有限公司 | 低合金化铜带及其制备方法 |
CN108330319A (zh) * | 2018-01-26 | 2018-07-27 | 宁波华成阀门有限公司 | 一种抗失锌低铅黄铜及其制造方法 |
CN108893647B (zh) * | 2018-07-18 | 2020-09-01 | 上海电机学院 | 一种高强耐蚀耐磨的铜基复合材料 |
CN112962002A (zh) * | 2021-02-02 | 2021-06-15 | 宁波长振铜业有限公司 | 一种耐脱锌高塑易加工的h62简单黄铜合金及其制备方法 |
CN115747561B (zh) * | 2022-11-04 | 2023-12-12 | 广州番禺职业技术学院 | 一种耐磨耐蚀的首饰黄铜合金及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1439238A1 (de) * | 2003-01-16 | 2004-07-21 | REHAU AG + Co | Korrosionsbeständige Messinglegierung für Trinkwasserformteile |
CN1557981A (zh) * | 2004-01-15 | 2004-12-29 | 宁波博威集团有限公司 | 无铅易切削锑黄铜合金 |
CN1710126A (zh) * | 2005-06-24 | 2005-12-21 | 宁波博威集团有限公司 | 生态环保新型无铅易切削低锑铋黄铜合金及其制造方法 |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1439238A1 (de) * | 2003-01-16 | 2004-07-21 | REHAU AG + Co | Korrosionsbeständige Messinglegierung für Trinkwasserformteile |
CN1557981A (zh) * | 2004-01-15 | 2004-12-29 | 宁波博威集团有限公司 | 无铅易切削锑黄铜合金 |
CN1710126A (zh) * | 2005-06-24 | 2005-12-21 | 宁波博威集团有限公司 | 生态环保新型无铅易切削低锑铋黄铜合金及其制造方法 |
Non-Patent Citations (1)
Title |
---|
杨善宏,等.无铅易切削石墨黄铜的研究.《有色金属加工》.2009,第38卷(第6期),第13页. * |
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