CN102550578A - Emamectin benzoate-diflubenzuron compound pesticide - Google Patents
Emamectin benzoate-diflubenzuron compound pesticide Download PDFInfo
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- CN102550578A CN102550578A CN2010106124461A CN201010612446A CN102550578A CN 102550578 A CN102550578 A CN 102550578A CN 2010106124461 A CN2010106124461 A CN 2010106124461A CN 201010612446 A CN201010612446 A CN 201010612446A CN 102550578 A CN102550578 A CN 102550578A
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- diflubenzuron
- benzoate
- emamectin
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Abstract
The invention provides an emamectin benzoate-diflubenzuron compound pesticide which comprises the following components in percentage by weight: 0.3 to 1.5 percent of emamectin benzoate, 5 to 20 percent of diflubenzuron, 2 to 6 percent of suspension auxiliary agent, 1 to 12 percent of wetting dispersant reagent, 1 to 5 percent of antifreezing agent, 0.1 to 1 percent of thickening agent, 0.2 to 0.5 percent of defoaming agent, 0.1 to 2 percent of antiseptics, and the balance of water which is added until reaching 100 percent of weight. The pesticide is formed by compounding benzoylurea pesticide diflubenzuron and emamectin benzoate, belongs to a compound pesticide, and has the advantages of strong quick-action, low residue, high inset and egg killing activity.
Description
Technical field
The present invention relates to a kind of insecticide, be specifically related to a kind of emamectin-benzoate-diflubenzuron composite insecticide.
Background technology
Emamectin-benzoate is claimed first dimension salt again, is a kind of new and effective semisynthetic antibiotics insecticide; It has super-high-efficient, low toxicity (preparation is closely nontoxic), noresidue; The nuisanceless characteristics that wait biopesticide, with AVM at first insecticidal activity improved the 1-3 one magnitude, active high to the larva of lepidopterous insects and other many insects and mite class; The double again action of contace poison of existing stomach poison function has good effect, and in the process of pest control, beneficial insect is not injured under low-down dosage; Help integrated control, enlarged insecticidal spectrum in addition, reduced toxicity people and animals to insect.
Diflubenzuron is a urea insecticide; Belong to a kind of insect chitin synthetic inhibitor; Mainly casting off a skin through interference insect makes insect slowly dead, have high-efficiency low-toxicity, the longevity of residure long, to people and animals' higher organism safety, advantage free from environmental pollution, insects such as wheat mythimna separata, pine caterpillars, cabbage caterpillar, fall webworm, mosquitos and flies are all had excellent curative; Having got permission registration in more than 40 countries since the appearance and use, is the improved seeds of comprehensive regulation pest.
In the prior art, the medicament of emamectin-benzoate and diflubenzuron adopts organic solvent such as benzene,toluene,xylene to process liquid preparation more, and production cost is high, and contaminated environment, and medicine is inflammable is produced and used all dangerous.It is not strong that this liquid preparation sprays the back adhesion strength, short in the crop surface retention time, not deficiency such as resistance of rainwater washing against.
Summary of the invention
The objective of the invention is to solve the above-mentioned technical problem that exists in the prior art, a kind of emamectin-benzoate-diflubenzuron composite insecticide is provided.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is following:
Emamectin-benzoate of the present invention-diflubenzuron composite insecticide is characterized in that this insecticide is made up of the component of following weight percentage:
Emamectin-benzoate 0.3-1.5%
Diflubenzuron 5-20%
Suspension aids 2-6%
Wetting dispersing agent 1-12%
Antifreezing agent 1-5%
Thickener 0.1-1%
Antifoaming agent 0.2-0.5%
Preservative 0.1-2%
Water is mended to 100%.
Said suspension aids is at least a in bentonite, precipitated calcium carbonate, the white carbon.
Described wetting dispersing agent is at least a in sodium lignin sulfonate, naphthalene sulfonate, alkyl formaldehyde condensation products sulfonate, APES formaldehyde synthesis sulphate rope primary, alkylphenol-polyethenoxy phosphate, phenethyl phenol polyethenoxy sodium sulphate, calcium dodecyl benzene sulfonate, AEO, sorbitol polyoxyethylene base ether, vinyl Nonyl pheno base ether, the alkylphenol-polyethenoxy base ether etc.
Described antifreezing agent is at least a in ethylene glycol, propane diols, the glycerine etc.
Described thickener is at least a in xanthan gum, carboxymethyl cellulose, carboxyethyl cellulose, Sodium Polyacrylate, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, the gum Arabic etc.
Said antifoaming agent is methyl-silicone oil, C
8-10At least a in fatty alcohol, the isopropyl alcohol etc.
Said preservative is at least a in paraformaldehyde, Sodium Benzoate, potassium sorbate, the sodium salicylate etc.
Formulation of the present invention is a suspending agent, and the method for optimizing of using said preparation is a foliage-spray.
Above-mentioned emamectin-benzoate-diflubenzuron processing method of compound insecticide; Comprise the steps: above-mentioned former medicine and suspending agent auxiliary material (like wetting dispersing agent, usual auxiliaries, thickener, antifreezing agent, antifoaming agent, preservative and water) dropped into to grind in ball mill, the sand mill to be the suspending agent semi-finished product; Put into the homogenizer mixing then; The requirement that reaches technical standard order is analyzed in quality testing, can be packaged as finished product, the technical indicator of suspension medicine of the present invention such as following table:
Emamectin-benzoate of the present invention-diflubenzuron composite insecticide belongs to composite insecticide, has high activity, tagging property, biological, the characteristic that the desinsection scope is wide.The very strong power of tagging is arranged, and the horizontal infiltration effect is strong, kills the ovum desinsection.The characteristic that has possessed two kinds of biopesticides simultaneously, and synergistic effect is obvious, complementary effect is obvious.First dimension diflubenzuron suspension is the water baseization formulations of pesticide, replaces hazardous solvent with water, does not adopt organic solvents such as benzene,toluene,xylene, and production cost reduces; Free from environmental pollution, nonflammable, production and use are all very safe, and particularly suspending agent has stronger adhesion strength; Long in the crop surface retention time, resistance of rainwater washing against, therefore; This formulation also is the novel form of wideling popularize in the world in recent years, and economic and social benefits are good, once is called as the novel form of " epoch-making ".
Compared with prior art, the present invention has following effect: emamectin-benzoate of the present invention-the diflubenzuron composite insecticide belongs to composite suspending agent, but desinsection kills ovum; Do not adopt human and environment harmful organic solvent; Nonflammable, dispersiveness and plate-out ability are good, and adhesion is strong; Anti-rainwater is washed away, lasting medicine.Good surface activity, permeability is strong, and suspension is excellent.
Embodiment
The present invention describes with the following example, but does not limit the present invention.
Embodiment 1
The medicine of 5.0% emamectin-benzoate-diflubenzuron suspension is formed as follows:
Emamectin-benzoate 0.3%
Diflubenzuron 4.7%
AEO 5%
White carbon 6%
Calcium lignosulfonate 2%
Ethylene glycol 2.5%
Aluminium-magnesium silicate 1.0%
Paraformaldehyde 0.2%
Methyl-silicone oil 0.3%
Water complements to 100%.
The emamectin-benzoate of proportional quantity, diflubenzuron, auxiliary agent, dispersant, antifreezing agent, preservative, water etc. are dropped into to grind in ball mill, the sand mill be the suspending agent semi-finished product; Put into the homogenizer mixing then; The requirement that reaches technical standard order is analyzed in quality testing, can be packaged as finished product.
Embodiment 2
The medicine of 10.5% emamectin-benzoate-diflubenzuron suspension is formed as follows:
Emamectin-benzoate 0.5%
Diflubenzuron 10%
Alkylphenol-polyethenoxy base ether 5%
White carbon 4%
Calcium lignosulfonate 2%
Ethylene glycol 2.0%
Polyvinyl alcohol 1.0%
Paraformaldehyde 0.2%
Isopropyl alcohol 0.2%
Water complements to 100%.
The preparation method is with embodiment 1.
Embodiment 3
The medicine of 15% emamectin-benzoate-diflubenzuron suspension is formed as follows:
Emamectin-benzoate 0.5%
Diflubenzuron 14.5%
Precipitated calcium carbonate 6%
Vinyl Nonyl pheno base ether 5%
Carboxymethyl cellulose 0.3%
Ethylene glycol 2.5%
Sodium Benzoate 0.2%
C8-C10 fatty alcohol 0.2%
Water complements to 100%
Embodiment 4
The medicine of 20% emamectin-benzoate-diflubenzuron suspension is formed as follows:
Emamectin-benzoate 1.0%
Diflubenzuron 19.0%
Bentonite 4%
Sorbitol polyoxyethylene base ether 6%
Xanthan gum 0.2%
Sodium salicylate 0.3%
Propane diols 2.5%
Methyl-silicone oil 0.2%
Water complements to 100%.
The present invention is composited by benzoyl urea insecticide diflubenzuron and emamectin-benzoate, belongs to composite insecticide, and quick-acting is strong, and is residual low, has very high desinsection, ovicidal activity.Pollute and angle easy to use from Environmental security, minimizing, compound pesticide preparation can be given full play to the drug effect of existing pesticide species, reduces or avoid the harmful effect of agricultural chemicals, thereby reaches the effect in the service life that prolongs agricultural chemicals.The suspending agent that is composited by benzoyl urea insecticide diflubenzuron and emamectin-benzoate; Insect on the crops such as cotton, paddy rice, fruit tree, vegetables had relatively more outstanding effect; And residual low, pollute for a short time, control efficiency arrives more than 90%.
Through Hubei Province, two places, Hunan Province field control effectiveness test; Result of the test shows that suspending agent of the present invention has favorable effect to poplar caterpillar, and every mu of consumption is merely the 20-30 gram, and 5 days preventive effects to poplar caterpillar all reach more than 90% after the dispenser; It has the quick-acting of emamectin-benzoate; The lasting effect that has diflubenzuron again, and to the insect natural enemies security, be the desirable medicament of control poplar caterpillar.
The field control effectiveness test report of the emamectin-benzoate-diflubenzuron suspension of following additional copy invention (being called for short first dimension diflubenzuron suspension)
15% first dimension diflubenzuron suspension control poplar caterpillar field control effectiveness test report (one)
1 test objective
The test of registration property is understood the field control effect and the safety of 15% first dimension diflubenzuron suspension control poplar caterpillar, for applying of this product provides theoretical foundation.
2 experimental conditions
2.1 subjects, crop and breed selection
(1) poplar caterpillar (
Clostera anachoreta)
(2) willow (
Populus SP.)
2.2 environment or facility cultivation condition
This test in the Gongan County, Hubei Province Tawau dike town poplar forest carry out, this experimental field belongs to the Plain, Poplar Plantation is that woods use in basic farmland protection, poplar caterpillar generation over the years is heavier, this is willow growing way basically identical experimental field, is the living woods of children, about about 3 meters of the height of tree.
3 experimental scheme and arrangement
3.1 medicament
3.1.1 test medicine
15% first dimension diflubenzuron suspension, peace woods biochemical industry Co., Ltd provides
3.1.2 contrast medicament
20% diflubenzuron suspension, peace woods biochemical industry Co., Ltd produces
But 5% emamectin-benzoate dispersible granule, peace woods biochemical industry Co., Ltd provides
3.1.3 dosing and numbering
Table 1 supplies reagent agent experimental scheme
3.2 arrange the sub-district
3.2.1 arrange the sub-district
The experimental plot randomized arrangement.
3.2.2 sub-district area and repetition
The natural situation in this experimental evidence forest land selects the relatively more consistent woodland of standing forest condition to make an experiment, and all is provided with guard row between each test region.Every strain treelet is 1 processing, and the insect density investigation is carried out in 4 repetitions before the dispenser.
3.3 application method
3.3.1 method for using
Convert water spray.
3.3.2 spraying equipment
Knapsack sprayer, model: SWS-17.
3.3.3 spraying time and number of times
Spraying time is on June 5th, 2010, dispenser once, be the poplar caterpillar second generation larva this moment, worm age is 2-3 age.
3.3.4 use capacity
According to 40 liters of every mu of water consumptions, according to the scheme of experimental scheme, concentration is from low to high sprayed.
4 investigation, record and measuring method
4.1 meteorology and soil information
4.1.1 meteorological data
Dispenser weather on the same day is fine, 35 ℃ of the maximum air temperatures, 23 ℃ of the minimum air temperatures, relative moisture 60-80%, gentle breeze.Duration of test weather sees table 4, table 5 for details.
4.1.2 soil information
Originally experimental field be selected in the basic farmland shelter forest and carry out, soil is paddy soil, and the soil comprehensive fertility is better.
4.2 investigation method, time and number of times
4.2.1 control time and number of times
The whole strain investigation of this test, before the dispenser, after the dispenser 3 days, investigated the survival of poplar caterpillar in 5 days.
4.2.2 investigation method
Adopt whole strain investigation, investigation insect density before the dispenser, behind the medicine 3 days, investigated the survival of poplar caterpillar in 5 days, detailed recorded data also calculates control efficiency.
4.2.3 drug effect computational methods
According to formula: calculate different investigation insect population in period go down rate and control efficiency;
In the formula: PT-chemicals treatment district insect population rate CK-blank district insect population rate that goes down that goes down
4.3 to other biotic influence
4.3.1 influence to other damage by disease and insect
Do not have.
4.3.2 influence to other non-target organism
Do not have.
5 results and analysis
Annotate: the preventive effect (%) that goes up in the table repeats mean value for each.
Above The data DPS duncan's new multiple range method carries out statistical analysis.
Evaluating drug:
(1) 15% first dimension diflubenzuron suspension has the better prevention effect to poplar caterpillar.1333 times, 1600 times, 2000 times processing, 3 days preventive effects are respectively 87.0%, 86.0%, 74.0% behind the medicine; 5 days preventive effects are respectively 100%, 97.0%, 94.0% behind the medicine.Through variance analysis, 15% first dimension diflubenzuron suspension is remarkable with contrast medicament otherness, sees table 2, and from result of the test, 15% first dimension diflubenzuron suspension had both had the quick-acting of emamectin-benzoate, had the lasting effect of the young urea that goes out again.
(2) do not find that test medicine produces harmful effect to willow in the test.Do not observe this confession reagent agent to having problems on the natural enemies security property.
Conclusion:
15% first dimension diflubenzuron suspension control poplar caterpillar has effect preferably, the suggestion large scale application.Dispenser should be grasped the age at poplar caterpillar larva 2-3, and recommending consumption is 1333-2000 doubly (active ingredient 112.5-75 mg/kg), spraying.This medicine is to willow and natural enemies security.
Table 3 15% first dimension diflubenzuron suspension control poplar caterpillar result of the test application form (2010)
Table 4 dispenser same day is weather conditions table (2010) experimental field
The dispenser date | Weather conditions | Wind direction and wind-force | Temperature (℃) | Relative moisture (%) | The rainfall situation | Other climatic factor |
June 5 | Fine | Gentle breeze | 23-35 | 6.-80 | ? | ? |
Table 5 duration of test meteorological data table
15% first dimension diflubenzuron suspension control poplar caterpillar field control effectiveness test report (two)
1 test objective
The field control effect and the safety of 15% first dimension diflubenzuron suspension control poplar caterpillar are understood in the test of registration property, for the registration and the large scale application of this product provides theoretical foundation.
2 experimental conditions
2.1 subjects, crop and breed selection
Subjects: poplar caterpillar (
Clostera anachoreta)
Trial crops: willow (
Populus SP.)
2.2 environmental condition
This test is carried out in the universal love forest farm in the Hunan Province, and this experimental field belongs to the Plain, and Poplar Plantation is that woods is used in the basic farmland protection, and poplar caterpillar over the years takes place more general, and this is willow growing way basically identical experimental field, is the living woods of children, about about 3.5 meters of the height of tree.
3 experimental scheme and arrangement
3.1 medicament
3.1.1 test medicine
15% first dimension diflubenzuron suspension, peace woods biochemical industry Co., Ltd provides
3.1.2 contrast medicament
20% diflubenzuron suspension, peace woods biochemical industry Co., Ltd produces
But 5% emamectin-benzoate dispersible granule, peace woods biochemical industry Co., Ltd provides
3.1.3 dosing and processing numbering
Table 1 supplies reagent agent experimental scheme
3.2 arrange the sub-district
3.2.1 arrange the sub-district
The experimental plot randomized arrangement.
3.2.2 sub-district area and repetition
The natural situation in this experimental evidence forest land selects the relatively more consistent woodland of standing forest condition to make an experiment, and all is provided with guard row between each test region.Every strain treelet is 1 processing, and the insect density investigation is carried out in 4 repetitions before the dispenser.
3.3 application method
3.3.1 method for using
Spraying.
3.3.2 spraying equipment
Knapsack sprayer.
3.3.3 spraying time and number of times
Spraying time is on July 8th, 2010, dispenser once, be the poplar caterpillar third generation larva this moment, worm age is 2-3 age.
3.3.4 use capacity
According to test forest land size conversion water consumption, according to supplying reagent agent experimental scheme extension rate to dilute medication.
3.3.5 prevent and treat the medicament data of other damage by disease and insect
Do not have.
4 investigation, record and measuring method
4.1 meteorology and soil information
4.1.1 meteorological data
Dispenser weather on the same day is fine, 35 ℃ of the maximum air temperatures, 23 ℃ of the minimum air temperatures, relative moisture 60-80%, gentle breeze.Duration of test weather sees table 4, table 5 for details.
4.1.2 soil information
Originally experimental field be selected in the elementary path shelter forest and carry out, soil is loamy soil, and the soil comprehensive fertility is general.
4.2 investigation method, time and number of times
4.2.1 control time and number of times
The whole strain investigation of this test, behind the medicine 1 day, 3 days, 5 days, investigated the survival of poplar caterpillar in 7 days.
4.2.2 investigation method
Adopt whole strain investigation, investigation insect density before the dispenser, behind the medicine 1 day, 3 days, 5 days, investigated the survival of poplar caterpillar in 7 days, detailed recorded data also calculates control efficiency.
4.2.3 drug effect computational methods
4.3 to other biotic influence
4.3.1 influence to other damage by disease and insect
Do not have.
4.3.2 influence to other non-target organism
Do not have.
5 results and analysis
Test data adopts DPS software duncan's new multiple range method to carry out the significance difference opposite sex and analyzes.
Effect is estimated:
15% first dimension diflubenzuron suspension has the better prevention effect to poplar caterpillar.1333 times, 1600 times, 2000 times processing, 3 days preventive effects are respectively 88.6%, 87.5%, 85.8% behind the medicine; 5 days preventive effects are respectively 97.9%, 93.2%, 91.2% behind the medicine.Through variance analysis, 15% first dimension diflubenzuron suspension is remarkable with contrast medicament otherness, sees table 2, and from result of the test, 15% first dimension diflubenzuron suspension had both had the quick-acting of emamectin-benzoate, had the lasting effect of the young urea that goes out again.
Conclusion:
15% first dimension diflubenzuron suspension control poplar caterpillar has effect preferably, the suggestion large scale application.Dispenser should be grasped the age at poplar caterpillar larva 2-3, and recommending consumption is 1333-2000 doubly (active ingredient 112.5-75 mg/kg), spraying.
Table 3 15% first dimension diflubenzuron suspension control poplar caterpillar result of the test application form (2010)
Table 4 dispenser same day is weather conditions table (2010) experimental field
The dispenser date | Weather conditions | Wind direction and wind-force | Temperature (℃) | Relative moisture (%) | The rainfall situation | Other climatic factor |
July 8 | Fine | Gentle breeze | 23-35 | 6.-80 | ? | ? |
Table 5 duration of test meteorological data table
Claims (7)
1. emamectin-benzoate-diflubenzuron composite insecticide is characterized in that this insecticide is made up of the component of following weight percentage:
Emamectin-benzoate 0.3-1.5%
Diflubenzuron 5-20%
Suspension aids 2-6%
Wetting dispersing agent 1-12%
Antifreezing agent 1-5%
Thickener 0.1-1%
Antifoaming agent 0.2-0.5%
Preservative 0.1-2%
Water is mended to 100%.
2. according to the described emamectin-benzoate of claim 1-diflubenzuron composite insecticide, it is characterized in that: said suspension aids is at least a in bentonite, precipitated calcium carbonate, the white carbon.
3. according to claim 1 or 2 described emamectin-benzoate-diflubenzuron composite insecticides, it is characterized in that: described wetting dispersing agent is at least a in sodium lignin sulfonate, naphthalene sulfonate, alkyl formaldehyde condensation products sulfonate, APES formaldehyde synthesis sulphate rope primary, alkylphenol-polyethenoxy phosphate, phenethyl phenol polyethenoxy sodium sulphate, calcium dodecyl benzene sulfonate, AEO, sorbitol polyoxyethylene base ether, vinyl Nonyl pheno base ether, the alkylphenol-polyethenoxy base ether etc.
4. according to claim 1 or 2 described emamectin-benzoate-diflubenzuron composite insecticides, it is characterized in that: described antifreezing agent is at least a in ethylene glycol, propane diols, the glycerine etc.
5. require described emamectin-benzoate-diflubenzuron composite insecticide according to right 1 or 2, it is characterized in that: described thickener is at least a in xanthan gum, carboxymethyl cellulose, carboxyethyl cellulose, Sodium Polyacrylate, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, the gum Arabic etc.
6. require described emamectin-benzoate-diflubenzuron composite insecticide according to right 1 or 2, it is characterized in that: said antifoaming agent is methyl-silicone oil, C
8-10At least a in fatty alcohol, the isopropyl alcohol etc.
7. require described emamectin-benzoate-diflubenzuron composite insecticide according to right 1 or 2, it is characterized in that: said preservative is at least a in paraformaldehyde, Sodium Benzoate, potassium sorbate, the sodium salicylate etc.
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Cited By (4)
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CN105475274A (en) * | 2016-01-20 | 2016-04-13 | 河北天发化工科技有限公司 | Diflubenzuron suspending agent and preparation method thereof |
CN108041064A (en) * | 2018-01-26 | 2018-05-18 | 山东汤普乐作物科学有限公司 | A kind of desinsection microcapsule suspension-suspendinagent agent containing bistrifluron and preparation method thereof |
CN114145311A (en) * | 2021-12-01 | 2022-03-08 | 武汉回盛生物科技股份有限公司 | Diflubenzuron particles and preparation method and application thereof |
CN114145311B (en) * | 2021-12-01 | 2024-05-03 | 武汉回盛生物科技股份有限公司 | Diflubenzuron particles, and preparation method and application thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105475274A (en) * | 2016-01-20 | 2016-04-13 | 河北天发化工科技有限公司 | Diflubenzuron suspending agent and preparation method thereof |
CN108041064A (en) * | 2018-01-26 | 2018-05-18 | 山东汤普乐作物科学有限公司 | A kind of desinsection microcapsule suspension-suspendinagent agent containing bistrifluron and preparation method thereof |
CN114145311A (en) * | 2021-12-01 | 2022-03-08 | 武汉回盛生物科技股份有限公司 | Diflubenzuron particles and preparation method and application thereof |
CN114145311B (en) * | 2021-12-01 | 2024-05-03 | 武汉回盛生物科技股份有限公司 | Diflubenzuron particles, and preparation method and application thereof |
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Application publication date: 20120711 |