CN102534443A - Production process for improving strength of aluminum profile - Google Patents

Production process for improving strength of aluminum profile Download PDF

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Publication number
CN102534443A
CN102534443A CN2010105867664A CN201010586766A CN102534443A CN 102534443 A CN102534443 A CN 102534443A CN 2010105867664 A CN2010105867664 A CN 2010105867664A CN 201010586766 A CN201010586766 A CN 201010586766A CN 102534443 A CN102534443 A CN 102534443A
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China
Prior art keywords
section bar
aluminium section
electrophoresis
degreasing
aluminum profile
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CN2010105867664A
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CN102534443B (en
Inventor
黄爱华
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Nantong Huayang Aluminum Products Co ltd
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Zhangjiagang Huayang Metal Products Co ltd
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Abstract

The invention provides a production process for improving the strength of an aluminum profile, which comprises the steps of carrying out extrusion after ingot casting homogenization annealing, wherein the extrusion temperature is 300-390 ℃, and obtaining the aluminum profile; after the extruded aluminum profile is subjected to solid solution at the speed of 350-400 ℃/1h, naturally standing for 80-90 h; then pre-degreasing, degreasing and washing; then carrying out electrophoresis in a solution tank with the temperature ranging from 20 ℃ to 25 ℃ and the solid content ranging from 15% to 17%, and then carrying out electrophoresis in the voltage range of 100V to 160V under the condition that the pH value is 6.0 to 6.3; the electrophoresis time is 3-4 min, and the gel is washed by clean water at normal temperature; drying and collecting materials; and packaging. The invention improves the strength and plasticity of the material, simultaneously ensures that the thickness of the electrophoresis layer is uniform, can completely cover the hidden part, has strong adhesive capacity, is not easy to fall off, has strong corrosion resistance, is flat and smooth, and better meets the requirement of environmental protection.

Description

Improve the production technique of aluminium section bar intensity
Technical field
The present invention relates to a kind of production technique that improves aluminium section bar intensity.
Background technology
Duraluminum is because not high, the easy damage of intensity; For plasticity, fracture toughness property and the fatigue property that improves duraluminum; The most directly method is exactly to improve the purity of material, and the content but its material cost that reduce Fe in the duraluminum, Si increase, and possibly in metallurgical process, be difficult to realize.
Electrophoresis has another name called---electricity, swimming lacquer, galvanic deposit.Originated the sixties in 20th century, be applied to vehicle paint base at first by Ford Motor Company.Because its outstanding anticorrosion, antirust function is used widely in military industry very soon.Just be applied to the surface treatment of haberdashery and hardware in recent years.Because its good quality and height environmental protection are progressively substituting the traditional paint spraying.
Electrocoating paint is scattered in the water with ionic condition, and under the effect of DC electric field, orientation concentrates on the five metals workpiece surface, forms compact protective film.According to the difference of charged state after the resin particle ionization in the electrocoating paint, can be divided into anodic electrophoresis (become negative ion after the resin particle ionization, be called for short AED) and ability cathode electrophoresis (become positive ion after the resin particle ionization, be called for short CED).The corrosion resistance nature of electrophoretic coating layer extremely good (generally can pass through neutral salt spray test more than 400 hours), discoloration-resisting is strong; Good with the bonding force of matrix metal, can carry out various mechanical workouts; Coat is bright in luster, can be mixed with shades of colour according to user's requirement, and common have gold, large red, emerald green, royalblue, coffee color, rifle look, black etc.; Compare with painting technology; Have good workability, pollution and significantly minimizing of harm to environment are widely used in each production department; Like automobile, motorcycle, bicycle spare parts and accessories; Building materials (lockset and door handle), hardware appliance, instrument, furniture, office appliance, metal spectacle frame, slider of zipper fastener, keyring lock, lighter fan housing, spring, plated item, aluminium section bar, watchband, label, jewellery, artwork and minaudiere; Kitchen tackle (cutter), bathhouse article (plumbing), household electrical appliance, medicine equipment and toy, and other requires the occasion of color electrophoresis.
Summary of the invention
The objective of the invention is to overcome the deficiency that prior art exists; A kind of production technique that improves aluminium section bar intensity is provided; Improve the intensity and the plasticity of material through annealing and extruding; Adopt the high low potential thickness of electrophoresis layer evenly, can cover the shelter fully, and adhesive ability strong, be not easy to come off.
The object of the invention is realized through following technical scheme:
Improve the production technique of aluminium section bar intensity, it is characterized in that may further comprise the steps:
1. with after the ingot homogenization annealing, push, extrusion temperature is 300~390 ℃, obtains aluminium section bar; Aluminium section bar after the extruding was placed 5~10 days after 350~400 ℃/1h solid solution naturally;
2. the surperficial grease removal of aluminium section bar: degreasing in advance, degreasing, washing;
3. the electrophoretic process of aluminium section bar: at first in the solution tank of 20~25 ℃ of TRs, solids content is in 15~17% scopes, then under the condition of pH value 6.0~6.3, in 100~160V voltage range, carries out electrophoresis; And electrophoresis time is 3~4min, washes with the clear water under the normal temperature; Oven dry, rewinding;
4. pack.
Further, the production technique of above-mentioned raising aluminium section bar intensity, wherein, extrusion temperature is 350 ℃, obtains aluminium section bar; Aluminium section bar after the extruding was placed 10 days after 400 ℃/1h solid solution naturally.
Further, the production technique of above-mentioned raising aluminium section bar intensity, wherein, the electrophoretic process of step aluminium section bar is 3. at first carried out the electrophoresis time of 4min in solution under 25 ℃, 150V, solids content are the condition of 16% pH value 6.1; Use clear water at normal temperatures to clean then; Oven dry, rewinding again.
The substantive distinguishing features of technical scheme of the present invention is mainly reflected in progressive:
Improve the intensity and the plasticity of material through annealing and extruding, the high low potential thickness of electrophoresis layer evenly, can cover the shelter fully, and adhesive ability strong, be not easy to come off, rotproofness is strong and open and flat smooth, compliance with environmental protection requirements more.
Embodiment
The technological process of production that the present invention improves aluminium section bar intensity is: at first aluminium alloy cast ingot is carried out homogenizing annealing, be about to aluminium alloy cast ingot and be raised to 450~480 ℃, insulation 12~24h, air cooling then from room temperature with the temperature rise rate of 45~60 ℃/h; After the ingot homogenization annealing, push, extrusion temperature is 300~390 ℃, obtains aluminium section bar; Aluminium section bar after the extruding is placed 80~90h naturally after 350~400 ℃/1h solid solution; Follow preparatory degreasing, degreasing, washing; Then in the solution tank of 20~25 ℃ of TRs, solids content is in 15~17% scopes, then under the condition of pH value 6.0~6.3, in 100~160V voltage range, carries out electrophoresis; And electrophoresis time is 3~4min, washes with the clear water under the normal temperature; Oven dry, rewinding; Packing.
Reach certain thickness (paint film resistance arrives to a certain degree greatly) when filming, workpiece surface forms insulation layer, and " heteropole is inhaled mutually " stops, the electrophoretic painting end of processing.Whole aluminium section bar treatment process can be summarized following four steps:
Electrolysis: the electrolysis of water, anode in having the solution of ionic conductivity and negative electrode are connected direct current, and negatively charged ion is inhaled toward anode, and positively charged ion is inhaled toward negative electrode, and produces chemical reaction.
Electrophoresis: the process that the polymkeric substance of band point springs up to negative electrode or anode respectively, after the anode in the colloidal solution and negative electrode connect electricity, under effect of electric field band just (or bearing) electric charge colloidal particle be called electrophoresis to negative electrode (or anode) side's swimming phenomenon.
Galvanic deposit: charged polymkeric substance is respectively in the process of negative electrode or anodically deposit; The phenomenon that solid is separated out from liquid is called aggegation (cohesion, deposition), generally be to produce owing to cooling or enriching soln, and in the electrophoretic painting be by means of.Particle positively charged when cathode electro-coating condenses on negative electrode; Electronegative particle (ion) is assembled at anode; When positively charged colloidal particle (resin and pigment) arrives negative electrode (by coating) surface region (overbasic interface layer); Obtain electronics, and become water-insoluble, be deposited on the negative electrode (coated article) with the hydroxide ion reaction.
Electric osmose: sedimentary electrophoresis film contraction, slough solvent and water, form the wet film of even compact, after two ends (negative electrode and the anode) energising with the different solution of semi-permeable membranes concentration at interval, the solvent of lower concentration is called electric osmose to the capable phenomenon of high density sidesway.Electric osmose makes hydrophilic filming become hydrophobic and film, and dehydration makes the densification of filming.
Embodiment 1
After the ingot homogenization annealing, push, extrusion temperature is 390 ℃, obtains aluminium section bar; Aluminium section bar after the extruding was placed 6 days after 350 ℃/1h solid solution naturally;
The surperficial grease removal of aluminium section bar: degreasing in advance, degreasing, washing;
The electrophoretic process of aluminium section bar: at first in the solution tank of 21 ℃ of TRs, solids content is in 15% scope, then under the condition of pH value 6.0, in the 100V voltage range, carries out electrophoresis; And electrophoresis time is 4min, washes with the clear water under the normal temperature; Oven dry, rewinding;
Packing.
Embodiment 2
After the ingot homogenization annealing, push, extrusion temperature is 300 ℃, obtains aluminium section bar; Aluminium section bar after the extruding was placed 8 days after 380 ℃/1h solid solution naturally;
The surperficial grease removal of aluminium section bar: degreasing in advance, degreasing, washing;
The electrophoretic process of aluminium section bar: at first in the solution tank of 24 ℃ of TRs, solids content is in 16% scope, then under the condition of pH value 6.3, in the 160V voltage range, carries out electrophoresis; And electrophoresis time is 3min, washes with the clear water under the normal temperature; Oven dry, rewinding;
Packing.
Embodiment 3
After the ingot homogenization annealing, push, extrusion temperature is 375 ℃, obtains aluminium section bar; Aluminium section bar after the extruding was placed 7 days after 360 ℃/1h solid solution naturally;
The surperficial grease removal of aluminium section bar: degreasing in advance, degreasing, washing;
The electrophoretic process of aluminium section bar: at first in the solution tank of 20 ℃ of TRs, solids content is in 17% scope, then under the condition of pH value 6.0, in the 150V voltage range, carries out electrophoresis; And electrophoresis time is 3min20s, washes with the clear water under the normal temperature; Oven dry, rewinding;
Packing.
The present invention improves the intensity and the plasticity of material through annealing and extruding, the high low potential thickness of electrophoresis layer evenly, can cover the shelter fully, and adhesive ability strong, be not easy to come off, rotproofness is strong and open and flat smooth, compliance with environmental protection requirements more.
It is emphasized that: above only is preferred embodiment of the present invention; Be not that the present invention is done any pro forma restriction; Every foundation technical spirit of the present invention all still belongs in the scope of technical scheme of the present invention any simple modification, equivalent variations and modification that above embodiment did.

Claims (3)

1. improve the production technique of aluminium section bar intensity, it is characterized in that may further comprise the steps:
1. with after the ingot homogenization annealing, push, extrusion temperature is 300~390 ℃, obtains aluminium section bar; Aluminium section bar after the extruding was placed 5~10 days after 350~400 ℃/1h solid solution naturally;
2. the surperficial grease removal of aluminium section bar: degreasing in advance, degreasing, washing;
3. the electrophoretic process of aluminium section bar: at first in the solution tank of 20~25 ℃ of TRs, solids content is in 15~17% scopes, then under the condition of pH value 6.0~6.3, in 100~160V voltage range, carries out electrophoresis; And electrophoresis time is 3~4min, washes with the clear water under the normal temperature; Oven dry, rewinding;
4. pack.
2. the production technique of raising aluminium section bar intensity according to claim 1 is characterized in that: said extrusion temperature is 350 ℃, obtains aluminium section bar; Aluminium section bar after the extruding was placed 10 days after 400 ℃/1h solid solution naturally.
3. the production technique of raising aluminium section bar intensity according to claim 1; It is characterized in that: the electrophoretic process of said step aluminium section bar 3., at first, 25 ℃, 150V, solids content in solution, carry out the electrophoresis time of 4min under being the condition of 16% pH value 6.1; Use clear water at normal temperatures to clean then; Oven dry, rewinding again.
CN201010586766.4A 2010-12-14 2010-12-14 Production process for improving strength of aluminum profile Active CN102534443B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104324973A (en) * 2014-09-04 2015-02-04 明达铝业科技(太仓)有限公司 Making method of high-strength aluminum section tubes
CN105463268B (en) * 2015-11-27 2017-11-03 如皋市华阳铝制品有限公司 Aluminum alloy section bar of lock core

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101597710A (en) * 2009-06-10 2009-12-09 苏州有色金属研究院有限公司 A kind of 2 xxx aluminium alloy for aviation and working method thereof
CN101760679A (en) * 2009-12-28 2010-06-30 东北轻合金有限责任公司 Preparation method of 7B04 aluminium alloy section

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101597710A (en) * 2009-06-10 2009-12-09 苏州有色金属研究院有限公司 A kind of 2 xxx aluminium alloy for aviation and working method thereof
CN101760679A (en) * 2009-12-28 2010-06-30 东北轻合金有限责任公司 Preparation method of 7B04 aluminium alloy section

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
唐亮: "铝型材电泳涂漆工艺的生产实践", 《轻合金加工技术》, vol. 34, no. 4, 31 December 2006 (2006-12-31), pages 36 - 39 *
柯跃虎: "电泳涂装工艺参数对铝型材涂膜质量的影响", 《现代涂料与涂装》, vol. 13, no. 7, 31 July 2010 (2010-07-31), pages 51 - 54 *
皮丕辉等: "铝型材用丙烯酸酯类阴极电泳涂料树脂的合成及应用", 《电镀与涂饰》, vol. 24, no. 6, 30 June 2005 (2005-06-30), pages 55 - 58 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104324973A (en) * 2014-09-04 2015-02-04 明达铝业科技(太仓)有限公司 Making method of high-strength aluminum section tubes
CN105463268B (en) * 2015-11-27 2017-11-03 如皋市华阳铝制品有限公司 Aluminum alloy section bar of lock core

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Address before: 215628, Jiangsu, Suzhou province Zhangjiagang Nanfeng Zhenhai Village Yang Hua metal products Co., Ltd.

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Address after: 226500 No. 28, Taoli Road, Xiayuan Town, Rugao City, Nantong City, Jiangsu Province

Patentee after: Nantong Huayang aluminum products Co.,Ltd.

Address before: 226543 No. 8, Huiren Road, Xiayuan Town, Rugao City, Jiangsu Province (in the industrial concentration zone of Xiayuan town)

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Denomination of invention: Production process for improving the strength of aluminum profiles

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