CN102532782A - High-glossiness spraying-free ABS (acrylonitrile butadiene styrene) resin and preparation method thereof - Google Patents
High-glossiness spraying-free ABS (acrylonitrile butadiene styrene) resin and preparation method thereof Download PDFInfo
- Publication number
- CN102532782A CN102532782A CN2010105786934A CN201010578693A CN102532782A CN 102532782 A CN102532782 A CN 102532782A CN 2010105786934 A CN2010105786934 A CN 2010105786934A CN 201010578693 A CN201010578693 A CN 201010578693A CN 102532782 A CN102532782 A CN 102532782A
- Authority
- CN
- China
- Prior art keywords
- abs resin
- glossiness
- exempts
- styrene
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
Abstract
The invention discloses high-glossiness spraying-free ABS (acrylonitrile butadiene styrene) resin and a preparation method thereof. The high-glossiness spraying-free ABS resin comprises the following components in parts by weight: 30 to 80 parts of ABS type resin, 10 to 50 parts of a brightening agent, 5 to 20 parts of a toughening agent, 0.5 to 1 part of an antioxidant auxiliary agent and 1 part of a processing agent. The high-glossiness spraying-free ABS resin disclosed by the invention is prepared by adopting a twin-screw extrusion process, and has the advantages of simple flow, continuity, high production efficiency and stable product quality. While the performance of the ABS resin is kept, the glossiness of the ABS resin is greatly improved, and the serviceable range of the ABS resin is enlarged, so that the ABS resin can be used on occasions with stringent requirements for surface glossiness of products, and is used for injection molding production of products of non-dermatoglyph surface molds, and the effect of high surface glossiness of the products can be achieved without a process step of spraying an oil paint; moreover, the ABS resin has a wide application prospect and apparent economic benefits.
Description
Technical field
The invention belongs to technical field of macromolecules, relate to a kind of ABS resin and preparation method thereof.
Background technology
ABS resin is the extremely wide thermoplastic engineering plastic of a kind of purposes; Its shock resistance, thermotolerance, lower temperature resistance, chemical proofing and excellent electrical properties; Also have the characteristics such as processing, product size is stable, surface luster property is good that are prone to, easy application, painted can also be carried out surperficial spraymetal, plating, welding, hot pressing and secondary processing such as bonding; Be widely used in industrial circles such as machinery, automobile, electronic apparatus, instrument, weaving and building; But general ABS resin glossiness has satisfied not some requires extra high occasion to glossiness, and like parts such as the face frame of liquid crystal TV set, Rear mirror of vehicle, traditional production process is after being injection molded into product with general ABS; Spray secondary processing; These wherein used manpower and materials and spillage of material expense are huge, for reaching the effect that an injection moulding just can reach high gloss, carry out this technological exploitation.
Summary of the invention
The object of the present invention is to provide a kind of high glossiness to exempt to spray ABS resin and preparation method thereof,, satisfy the needs of electronic enterprises development it to overcome the above-mentioned technical barrier that currently available products exists.
The object of the invention realizes through following technical proposals:
A kind of high glossiness exempts to spray the composition of ABS resin, comprises following raw material and parts by weight thereof:
30～80 parts of ABS resinoids
10～50 parts of brightening agents
5～20 parts of toughner
0.5～1 part of anti-oxidant auxiliary agent
1 part of processing aid
Described ABS resinoid comprises a kind of or its mixture in acrylonitrile-butadiene-phenylethene grafted copolymer (ABS), vinyl cyanide-ethylene, propylene elastomerics-phenylethene grafted copolymer (AES), acrylonitrile-styrene-acrylic terpolymer (ASA) or the TEB 3K-butadiene-styrene graft copolymer (MBS).Commodity are like the ABS750 (acrylonitrile-butadiene-phenylethene grafted copolymer) of: Korea S brocade lake company; The strange beautiful ASA957 (acrylonitrile-styrene-acrylic terpolymer) in Taiwan, the MBS521 (TEB 3K-butadiene-styrene graft copolymer) of middle deep pool chemistry.
Described brightening agent is the polymkeric substance of substituted phenylethylene, a kind of or its compsn of polymethylmethacrylate (CM-205).
Described substituted phenylethylene polymkeric substance is an alpha-methyl styrene, 2-methyl styrene, 2,5-dimethyl styrene, a kind of or its compsn in the 4-butylstyrene.
Described toughner is vinylformic acid-BS, methyl or ethyl propylene acid ester copolymer, ethyl or butylacrylic acid ester copolymer, maleic anhydride graft acrylonitrile-butadiene-phenylethene grafted copolymer (ABS-g); Styrene maleic anhydride copolymer (SMA218), maleic anhydride and cinnamic multipolymer, a kind of or its mixture of styrene-butadiene-styrene block copolymer.
Described oxidation inhibitor is a kind of or its mixture in silicate, sterically hindered phenol or the hydroxybenzotriazole of the single phenol of alkylation, alkylation polyphenol, phosphorous acid diphenyl ester, triphenyl phosphite, basic metal or earth alkali metal, is the product of antioxidant 1010, oxidation inhibitor 168, antioxidant 1076 like the trade mark of vapour Bagong department production.
Described processing aid is a lubricant, and lubricant can effectively improve each component dispersiveness, reduce harmful friction when processing and moulding.
Described lubricant is solid paraffin, whiteruss, low molecular weight polyethylene, calcium stearate, Zinic stearas, stearic amide, methylene bis stearic amide, ethylene bis stearamide, pentaerythritol stearate, N; N-ethylene bis stearic acid amide, N, any in the dinethylformamide or several kinds.
A kind of above-mentioned high glossiness exempts to spray the preparation method of ABS resin, comprises step:
(1) takes by weighing ABS resin, toughner, inhibitor, processing aid by above-mentioned each set of dispense ratio;
(2) ABS resin that takes by weighing in the first step, toughner, inhibitor, processing aid are put into the high-speed mixer thorough mixing, high mixer rotating speed 50～150 commentaries on classics/min, mixing time 3～5min are The Best Mixed technology;
(3) with single screw rod feeding machine metering material conveying device, mixed material of second step is sent in the twin screw extruder, sufficient mixing through the shearing action of screw rod, through extruding tie rod, cooling, pelletizing.Be packaged into finished product.
The length-to-diameter ratio 40～60 of twin screw extruder in the said step (3), screw speed is at 150～600 rev/mins, and twin screw is extruded the working temperature interval and is done; 170～190 ℃ in one district; 190～210 ℃ in two districts, 200～230 ℃ in three districts, 210～240 ℃ in four districts; 220～250 ℃ of heads stopped 1～2 minute.
Described screw slenderness ratio is preferred 40～45, and screw speed is preferably 300～500 rev/mins.
The present invention has the following advantages:
High glossiness of the present invention exempts to spray ABS resin, adopts the preparation of twin screw expressing technique, have flow process simple, continuously, the advantage of high, the constant product quality of production efficiency.When keeping the ABS performance, significantly improve the glossiness of product, enlarged the use range of product, can be used for glossiness and require more harsh occasion, have broad application prospects.
Embodiment
High glossiness of the present invention is exempted to spray ABS resin and preparation method thereof and is seen attached list 1 and 2. with physicals
Wherein
ABS resin is 750 of a Korea S brocade lake company;
The ASA resin is 957 of a Taiwan Qi Mei company;
The MBS resin is 521 of a middle deep pool chemistry;
Brightening agent is the strange beautiful CM-205 in Taiwan;
Toughner is the SMA218 of Oil of Shanghai Petrochemical Company or the ABS-G of the outstanding company of outstanding thing;
Antioxidative stabilizer is antioxidant 1010 and the oxidation inhibitor 168 of CIBA;
Processing aid is homemade EBS (ethylene bis stearamide);
Processing aid is Sa Ji PETS (pentaerythritol stearate);
A kind of high glossiness exempts to spray ABS resin and preparation method thereof:
Embodiment 1
(1) proportioning by each component in the table 2 takes by weighing ABS resin, toughner, inhibitor, brightening agent, processing aid;
(2) ABS resin that takes by weighing in the first step, toughner, inhibitor, processing aid are put into high-speed mixer, the high mixer rotating speed is 50 commentaries on classics/min thorough mixing 5min;
(3) with metering material conveying device, mixed material of second step is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing, wherein the length-to-diameter ratio of twin screw extruder is 40; Screw speed is at 300 rev/mins, and twin screw is extruded the working temperature interval and done, 180 ℃ in a district, 195 ℃ in two districts; 210 ℃ in three districts, 215 ℃ in four districts, 230 ℃ of heads stopped 1～2 minute; Through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
Embodiment 2
(1) takes by weighing ABS resin, toughner, brightening agent, inhibitor, processing aid by the proportioning in the table 2;
(2) each component in the step (1) is put into high-speed mixer, the high mixer rotating speed is 70 commentaries on classics/min thorough mixing 4min;
(3) with metering material conveying device, mixed material in the step (2) is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing, wherein the length-to-diameter ratio of twin screw extruder is 44, and screw speed is at 150～600 rev/mins, 350 rev/mins; Twin screw is extruded the working temperature interval, 180 ℃ in a district, and 195 ℃ in two districts, 210 ℃ in three districts, 215 ℃ in four districts, 230 ℃ of heads stopped 1～2 minute, through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
Embodiment 3
(1) takes by weighing ABS resin, toughner, brightening agent, inhibitor, processing aid by the proportioning in the table 2;
(2) each component in the step (1) is put into high-speed mixer, the high mixer rotating speed is 100 commentaries on classics/min thorough mixing 4min;
(3) with metering material conveying device, mixed material in the step (2) is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing, wherein the length-to-diameter ratio of twin screw extruder is 44; Screw speed is at 400 rev/mins, and twin screw is extruded the working temperature interval and done, 180 ℃ in a district, 200 ℃ in two districts; 220 ℃ in three districts, 225 ℃ in four districts, 240 ℃ of heads stopped 1～2 minute; Through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
Embodiment 4
(1) takes by weighing ABS resin, toughner, brightening agent, inhibitor, processing aid by the proportioning in the table 2;
(2) each component in the step (1) is put into high-speed mixer, the high mixer rotating speed is 120 commentaries on classics/min thorough mixing 3min; (3) with metering material conveying device, mixed material in the step (2) is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing, wherein the length-to-diameter ratio of twin screw extruder is 40; Screw speed is at 450 rev/mins, and twin screw is extruded the working temperature interval and done, 180 ℃ in a district, 210 ℃ in two districts; 225 ℃ in three districts, 230 ℃ in four districts, 240 ℃ of heads stopped 1～2 minute; Through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
Embodiment 5
(1) takes by weighing ASA resin, toughner, brightening agent, inhibitor, processing aid by the proportioning in the table 2;
(2) each component in the step (1) is put into high-speed mixer, the high mixer rotating speed is 90 commentaries on classics/min thorough mixing 4min;
(3) with metering material conveying device, mixed material in the step (2) is sent in the twin screw extruder, through the shearing action of screw rod, abundance is mixing, wherein the length-to-diameter ratio 42 of twin screw extruder; 350 rev/mins of screw speeds, twin screw are extruded the working temperature interval and are done, 185 ℃ in a district, 210 ℃ in two districts; 230 ℃ in three districts, 240 ℃ in four districts, 245 ℃ of heads stopped 1～2 minute; Through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
Embodiment 6
(1) takes by weighing ASA resin, toughner, brightening agent, inhibitor, processing aid by the proportioning in the table 2;
(2) each component in the step (1) is put into high-speed mixer, the high mixer rotating speed is 120 commentaries on classics/min thorough mixing 3min;
(3) with metering material conveying device, mixed material in the step (2) is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing, wherein the length-to-diameter ratio of twin screw extruder is 44; Screw speed is at 400 rev/mins, and twin screw is extruded the working temperature interval and done, 180 ℃ in a district, 205 ℃ in two districts; 230 ℃ in three districts, 235 ℃ in four districts, 240 ℃ of heads stopped 1～2 minute; Through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
Embodiment 7
(1) takes by weighing ASA resin, toughner, brightening agent, inhibitor, processing aid by the proportioning in the table 2;
(2) each component in the step (1) is put into high-speed mixer, the high mixer rotating speed is 150 commentaries on classics/min thorough mixing 3min;
(3) with metering material conveying device, mixed material in the step (2) is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing, wherein the length-to-diameter ratio of twin screw extruder is 44; Screw speed is at 450 rev/mins, and twin screw is extruded the working temperature interval and done, 180 ℃ in a district, 205 ℃ in two districts; 225 ℃ in three districts, 235 ℃ in four districts, 240 ℃ of heads stopped 1～2 minute; Through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
Embodiment 8
(1) takes by weighing MBS resin, toughner, brightening agent, inhibitor, processing aid by the proportioning in the table 2;
(2) each component in the step (1) is put into high-speed mixer, the high mixer rotating speed is 12 commentaries on classics/min thorough mixing 3min;
(3) with metering material conveying device, mixed material in the step (2) is sent in the twin screw extruder, through the shearing action of screw rod, abundance is mixing, wherein the length-to-diameter ratio 44 of twin screw extruder; Screw speed is at 350 rev/mins, and twin screw is extruded the working temperature interval and done, 190 ℃ in a district, 210 ℃ in two districts; 230 ℃ in three districts, 235 ℃ in four districts, 240 ℃ of heads stopped 1～2 minute; Through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
The mixture of each embodiment preparation is injection molded into the standard batten of testing usefulness by standard size, and the physicals among each embodiment is respectively according to China's national standard test, and is as shown in table 1.
Table 1. performance test methods
Prescription is seen and is parts by weight by table 2.
The concrete prescription that table 2 embodiment is corresponding
Detected result is seen table 3.
The properties of sample that table 3 embodiment is corresponding
The above-mentioned description to embodiment is can understand and use the present invention for ease of the those of ordinary skill of this technical field.The personnel of skilled obviously can easily make various modifications to these embodiment, and needn't pass through performing creative labour being applied in the General Principle of this explanation among other embodiment.Therefore, the invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not breaking away from the improvement that category of the present invention makes and revise all should be within protection scope of the present invention.
Claims (10)
1. a high glossiness exempts to spray ABS resin, it is characterized in that: comprise following raw material and parts by weight thereof:
30～80 parts of ABS resinoids
10～50 parts of brightening agents
5～20 parts of toughner
0.5～1 part of anti-oxidant auxiliary agent
1 part of processing aid.
2. high glossiness according to claim 1 exempts to spray ABS resin, it is characterized in that: described ABS resinoid comprises a kind of or its mixture in acrylonitrile-butadiene-phenylethene grafted copolymer, vinyl cyanide-ethylene, propylene elastomerics-phenylethene grafted copolymer, acrylonitrile-styrene-acrylic terpolymer or the TEB 3K-butadiene-styrene graft copolymer.
3. high glossiness according to claim 1 exempts to spray ABS resin, it is characterized in that: described brightening agent comprises the polymkeric substance of substituted phenylethylene, a kind of or its compsn of TEB 3K.
4. high glossiness according to claim 3 exempts to spray ABS resin, it is characterized in that: described substituted phenylethylene polymkeric substance comprises alpha-methyl styrene, 2-methyl styrene, 2,5-dimethyl styrene, a kind of or its compsn in the 4-butylstyrene.
5. high glossiness according to claim 1 exempts to spray ABS resin, it is characterized in that: described toughner is a kind of or its mixture in vinylformic acid-BS, methyl or ethyl propylene acid ester copolymer, ethyl or butylacrylic acid ester copolymer, maleic anhydride graft acrylonitrile-butadiene-phenylethene grafted copolymer, styrene maleic anhydride copolymer, maleic anhydride and cinnamic multipolymer, the styrene-butadiene-styrene block copolymer.
6. high glossiness according to claim 1 exempts to spray ABS resin, it is characterized in that: described oxidation inhibitor is a kind of or its mixture in silicate, sterically hindered phenol or the hydroxybenzotriazole of the single phenol of alkylation, alkylation polyphenol, phosphorous acid diphenyl ester, triphenyl phosphite, basic metal or earth alkali metal.
7. high glossiness according to claim 1 exempts to spray ABS resin, it is characterized in that: described processing aid is a lubricant.
8. high glossiness according to claim 7 exempts to spray ABS resin; It is characterized in that: described lubricant is solid paraffin, whiteruss, low molecular weight polyethylene, calcium stearate, Zinic stearas, stearic amide, methylene bis stearic amide, ethylene bis stearamide, pentaerythritol stearate, N; N-ethylene bis stearic acid amide, N, any in the dinethylformamide or several kinds.
9. one kind prepares among the claim 1-8 arbitrary described high glossiness and exempts to spray the method for ABS resin, it is characterized in that: comprise the steps:
(1) takes by weighing ABS resin, toughner, inhibitor, processing aid in the described ratio of claim 1;
(2) ABS resin, toughner, inhibitor, the processing aid that take by weighing in the step (1) are put into the high-speed mixer thorough mixing, high mixer rotating speed 50～150 commentaries on classics/min;
(3) with single screw rod feeding machine metering material conveying device, the mixed material of step (2) is sent in the twin screw extruder, sufficient mixing through the shearing action of screw rod, through extruding tie rod, cooling, pelletizing; Be packaged into finished product.
10. method according to claim 9 is characterized in that: the length-to-diameter ratio 40～60 of twin screw extruder in the described step (3), and screw speed is 150～600 rev/mins; Twin screw is extruded the working temperature interval, 170～190 ℃ in a district, and 190～210 ℃ in two districts, 200～230 ℃ in three districts, 210～240 ℃ in four districts, 220～250 ℃ of heads stopped 1～2 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105786934A CN102532782A (en) | 2010-12-08 | 2010-12-08 | High-glossiness spraying-free ABS (acrylonitrile butadiene styrene) resin and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105786934A CN102532782A (en) | 2010-12-08 | 2010-12-08 | High-glossiness spraying-free ABS (acrylonitrile butadiene styrene) resin and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102532782A true CN102532782A (en) | 2012-07-04 |
Family
ID=46340895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105786934A Pending CN102532782A (en) | 2010-12-08 | 2010-12-08 | High-glossiness spraying-free ABS (acrylonitrile butadiene styrene) resin and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102532782A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104403560A (en) * | 2014-12-15 | 2015-03-11 | 3M中国有限公司 | Coating composition, coating as well as preparation method and application thereof |
| CN104845004A (en) * | 2015-05-18 | 2015-08-19 | 东莞市能路塑胶模具有限公司 | Black highlight ABS (acrylonitrile-butadiene-styrene) composition and preparation method thereof |
| CN105733119A (en) * | 2014-12-10 | 2016-07-06 | 中国石油天然气股份有限公司 | ABS resin composition suitable for coating part |
| CN106751388A (en) * | 2016-11-30 | 2017-05-31 | 合肥美菱股份有限公司 | One kind exempts from painted plastic material and its moulding process |
| CN104448680B (en) * | 2014-11-28 | 2018-01-26 | 上海锦湖日丽塑料有限公司 | The high glaze resin combination that a kind of finger mark improves |
| CN108623981A (en) * | 2017-03-26 | 2018-10-09 | 合肥杰事杰新材料股份有限公司 | The acrylonitrile-butadiene-styrene (ABS) composition and preparation method thereof of spraying current mark is exempted from a kind of solution |
| CN109054279A (en) * | 2018-06-19 | 2018-12-21 | 青岛海尔股份有限公司 | A kind of preparation method of ABS plate, inner container of icebox and ABS plate |
| CN111892768A (en) * | 2020-07-15 | 2020-11-06 | 覃珍锋 | Formula, production process and application method of thermoplastic elastomer surface treatment-free plasticizing material |
| CN113045854A (en) * | 2021-04-28 | 2021-06-29 | 广东宇豪新材料科技有限公司 | Highlight traceless spraying-free ABS material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475727A (en) * | 2008-11-28 | 2009-07-08 | 上海锦湖日丽塑料有限公司 | ABS/PMMA composite material |
| CN101649102A (en) * | 2009-09-30 | 2010-02-17 | 四川长虹电器股份有限公司 | High-gloss composite material and preparation method thereof |
| CN101768320A (en) * | 2008-12-31 | 2010-07-07 | 深圳市科聚新材料有限公司 | Heat-resisting ABS modified material and preparation method thereof for plating |
| CN101864142A (en) * | 2010-06-30 | 2010-10-20 | 银禧工程塑料（东莞）有限公司 | Highlight high-hardness dustproof ABS (Acrylonitrile Butadiene-Styrene) alloy material for electronic and electric products and preparation method thereof |
-
2010
- 2010-12-08 CN CN2010105786934A patent/CN102532782A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475727A (en) * | 2008-11-28 | 2009-07-08 | 上海锦湖日丽塑料有限公司 | ABS/PMMA composite material |
| CN101768320A (en) * | 2008-12-31 | 2010-07-07 | 深圳市科聚新材料有限公司 | Heat-resisting ABS modified material and preparation method thereof for plating |
| CN101649102A (en) * | 2009-09-30 | 2010-02-17 | 四川长虹电器股份有限公司 | High-gloss composite material and preparation method thereof |
| CN101864142A (en) * | 2010-06-30 | 2010-10-20 | 银禧工程塑料（东莞）有限公司 | Highlight high-hardness dustproof ABS (Acrylonitrile Butadiene-Styrene) alloy material for electronic and electric products and preparation method thereof |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448680B (en) * | 2014-11-28 | 2018-01-26 | 上海锦湖日丽塑料有限公司 | The high glaze resin combination that a kind of finger mark improves |
| CN105733119A (en) * | 2014-12-10 | 2016-07-06 | 中国石油天然气股份有限公司 | ABS resin composition suitable for coating part |
| CN104403560A (en) * | 2014-12-15 | 2015-03-11 | 3M中国有限公司 | Coating composition, coating as well as preparation method and application thereof |
| CN104403560B (en) * | 2014-12-15 | 2017-06-06 | 3M中国有限公司 | Coating composition, coating and its preparation method and application |
| CN104845004A (en) * | 2015-05-18 | 2015-08-19 | 东莞市能路塑胶模具有限公司 | Black highlight ABS (acrylonitrile-butadiene-styrene) composition and preparation method thereof |
| CN106751388A (en) * | 2016-11-30 | 2017-05-31 | 合肥美菱股份有限公司 | One kind exempts from painted plastic material and its moulding process |
| CN108623981A (en) * | 2017-03-26 | 2018-10-09 | 合肥杰事杰新材料股份有限公司 | The acrylonitrile-butadiene-styrene (ABS) composition and preparation method thereof of spraying current mark is exempted from a kind of solution |
| CN108623981B (en) * | 2017-03-26 | 2022-05-10 | 合肥杰事杰新材料股份有限公司 | Acrylonitrile-butadiene-styrene composition for solving spraying-free flow mark and preparation method thereof |
| CN109054279A (en) * | 2018-06-19 | 2018-12-21 | 青岛海尔股份有限公司 | A kind of preparation method of ABS plate, inner container of icebox and ABS plate |
| CN111892768A (en) * | 2020-07-15 | 2020-11-06 | 覃珍锋 | Formula, production process and application method of thermoplastic elastomer surface treatment-free plasticizing material |
| CN111892768B (en) * | 2020-07-15 | 2023-11-21 | 覃珍锋 | Formula, production process and application method of thermoplastic elastomer surface treatment-free plasticizing material |
| CN113045854A (en) * | 2021-04-28 | 2021-06-29 | 广东宇豪新材料科技有限公司 | Highlight traceless spraying-free ABS material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102532782A (en) | High-glossiness spraying-free ABS (acrylonitrile butadiene styrene) resin and preparation method thereof | |
| CN102532787B (en) | ABS resin of a kind of high heat resistance high tenacity and preparation method thereof | |
| CN102807723A (en) | ABS resin and preparation method thereof | |
| CN102924773B (en) | Master batch for scratch-resistant polypropylene and preparation method thereof | |
| CN105175924A (en) | Antistatic master batch, PC alloy with the same and preparing method of PC alloy | |
| CN103183870A (en) | Polyolefin/styrene based resin composition and preparation method thereof | |
| CN103059391A (en) | Toughened foamed master batch, and preparation method and application thereof | |
| CN101531801A (en) | Preparation method of scratch-resistant lacquer-free ABS moulding composition with high glaze | |
| CN103342859A (en) | Low-odor and low-VOC (Volatile Organic Compounds) glass fiber reinforced polypropylene composite material and preparation method thereof | |
| CN103589073A (en) | UV-resistant polypropylene composite material and preparation method thereof | |
| CN112375324B (en) | HIPS (high impact polystyrene) composite material as well as preparation method and application thereof | |
| CN102863753B (en) | Matte PCABS (polycarbonate acrylonitrile butadiene styrene) composite material and preparation method thereof | |
| CN102337025A (en) | High notched impact PA/ASA alloy material and its preparation method | |
| CN104693595A (en) | Recycled material used for preparing vehicle bumper and preparation method of recycled material | |
| CN103951949A (en) | Glass fiber enhanced toughening balanced type PET composition and preparation method thereof | |
| CN103772880A (en) | ABS/PET material for extrusion process and preparation method of ABS/PET material | |
| CN104817810A (en) | Thermoplastic elastomer material for high-welding-strength refrigerator sealing strips and preparation method thereof | |
| CN102304250B (en) | High-melt-index halogen-free flame-retarding polypropylene and preparation method thereof | |
| CN106589584B (en) | Lightweight, scratch-resistant, high luster materials and preparation method thereof and preparing the application in automobile instrument panel | |
| CN102391626A (en) | Non-petroleum base complete degradation master batch and preparation method thereof | |
| CN104072843B (en) | A kind of multiple dimensioned composite functional agglomerate and preparation method thereof | |
| CN105218856A (en) | Precipitation-resistant efficient polypropylene weather-resistant master batch | |
| CN103113709A (en) | Special high-filling master batch for acrylonitrile butadiene styrene and preparation method thereof | |
| CN112442251B (en) | ABS composite material and preparation method and application thereof | |
| CN104744775A (en) | Composite material for polyethylene film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120704 |