CN102807723A - ABS resin and preparation method thereof - Google Patents
ABS resin and preparation method thereof Download PDFInfo
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- CN102807723A CN102807723A CN2011101440289A CN201110144028A CN102807723A CN 102807723 A CN102807723 A CN 102807723A CN 2011101440289 A CN2011101440289 A CN 2011101440289A CN 201110144028 A CN201110144028 A CN 201110144028A CN 102807723 A CN102807723 A CN 102807723A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92904—Die; Nozzle zone
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of polymer materials, and discloses an ABS resin and a preparation method thereof. The ABS resin of the present invention comprises the following components, by weight, 60-90 parts of an ABS resin, 10-35 parts of a weathering resistance polymer resin, 3-5 parts of a compatibilizer, 0.5-1 part of an anti-oxidant additive, and 0.2-0.5 part of a processing additive. The preparation method for the ABS resin in the present invention comprises the following steps: weighing 60-90 parts of an ABS resin, 10-35 parts of a weathering resistance polymer resin, 3-5 parts of a compatibilizer, 0.5-1 part of an anti-oxidant additive, and 0.2-0.5 part of a processing additive; adding the materials into a high-speed mixer to completely mix; conveying the mixed material into a twin screw extruder, wherein the mixed material is completely milled with a shearing effect of the screw; and carrying out extruding, drawing, cooling, particle cutting, packaging on the molten blend to prepare the finished product. The ABS resin preparation method of the present invention has advantages of simple and continuous process, high production efficiency, and stable product quality. The product of the present invention has high weathering resistance, and can maintain a good color for a long time under an external environment, wherein a color difference change is low.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of ABS resinoid and preparation method thereof.
Background technology
The ABS resinoid is an acrylonitrile-butadiene-styrene copolymer; It is the extremely wide thermoplastic engineering plastic of a kind of purposes; Its shock resistance, thermotolerance, lower temperature resistance, chemical proofing and excellent electrical properties; Also have characteristics such as the processing of being prone to, product size is stable, surface luster property is good; Easily application, painted can also be carried out surperficial spraymetal, plating, welding, hot pressing and secondary processing such as bonding, is widely used in industrial circles such as machinery, automobile, electronic apparatus, instrument, weaving and building.As everyone knows, the ABS resinoid is formed by three kinds of monomers (vinyl cyanide, divinyl and vinylbenzene) copolymerization, and each component of polymkeric substance has different chemical constitutions, coexist as two separate mutually in, its common capacitive is by their structure and chemical nacrostructure control.For general ABS resinoid, its external phase is the multipolymer of vinylbenzene and vinyl cyanide, and the elastomerics of being made up of divinyl then is disperse phase, and it is scattered in the external phase, and has the particular structural form.Disperse phase because of divinyl is formed all has two key unsaturated link(age) forms in monomer whose and the multipolymer form, multipolymer is in the middle of extraneous environment for use; Receive the comprehensive action of heat, oxygen, water, light, mikrobe, chemical mediator Deng environmental factors, the resinoid chemical constitution of ABS and structure, particularly divinyl rubber are met a series of variations are taken place; Physicals also can correspondingly degenerate; As material harden, become fragile, phenomenon such as variable color, changing the most intuitively is exactly the material variable color, forms xanthochromia; Influence outward appearance, limited the ABS resinoid thus in a lot of local uses.The method of traditional raising ABS weather resistance is, in the ABS resinoid, adds UV light absorber and hindered amine light stabilizers such as benzotriazole category, benzophenone, salicylate class, has high conjugated structure as the polymer of UV light absorber; UV-light had stronger sorption; Being excited the back intramolecularly can form the hydrogen bond ring, can make the molecule that is in excited electronic state become vibrational excitation ground state through the energy transformation form, with the form of heat energy deactivation effectively; Simultaneously; The absorbed UV-light energy of hydroxyl in the molecule excites, and produces reversible phenol formula-quinoid tautomerism, is very stable to a certain extent; As the hindered amine HALS family macromolecule of the steady agent of light, its effect is not to absorb ultraviolet ray, can not cancellation excited state or singlet oxygen, and mainly be the NO free radical effect, decompose the high hydroperoxide that cause, in the hope of stoping material aging.Method as traditional raising ABS weather resistance; Employed uv-absorbing agent and photostabilizer cost an arm and a leg, and for reaching a weather-proof effect of ideal, it is quite a few that it adds component; Consequent cost is high, thus big limitations the production and the application of high-quality weatherproof ABS.
Summary of the invention
The purpose of this invention is to provide a kind of ABS resinoid,, satisfy the needs of electronic enterprises development it to overcome the above-mentioned technical barrier that currently available products exists.
Another object of the present invention provides the resinoid preparation method of a kind of above-mentioned ABS.
The object of the invention technical scheme is following:
The invention provides a kind of ABS resinoid, this resinoid comprises following component and weight part:
60～90 parts of ABS resinoids,
10～35 parts of weathering resistance macromolecule resins,
3～5 parts of compatilizers,
0.5～1 part of anti-oxidant auxiliary agent,
0.2～0.5 part of processing aid.
Described ABS resinoid is selected from one or more the mixture in acrylonitrile-butadiene-phenylethene grafted copolymer, vinyl cyanide-ethylene, propylene elastomerics-phenylethene grafted copolymer (ABS), acrylonitrile-styrene-acrylic terpolymer (ASA) or the TEB 3K-butadiene-styrene graft copolymer (MBS).
Described weathering resistance macromolecule resin is a polymethylmethacrylate.
Described compatilizer is selected from one or more in maleic anhydride graft acrylonitrile-butadiene-phenylethene grafted copolymer, maleic anhydride and cinnamic multipolymer, styrene-butadiene-styrene block copolymer, propenoate-butadienecopolymer or the vinylformic acid-BS.
Described anti-oxidant auxiliary agent is selected from four (β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester (antioxidant 1010), β-(4-hydroxy phenyl-3,5-di-t-butyl) positive octadecanol ester of propionic acid (antioxidant 1076), N; N '-1; 6-hexylidene-two [3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid amide, 2,2 '-methylene-bis (4-methyl-6-tert butyl phenol), Tri Ethyleneglycol two [β-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester], tricresyl phosphites (2; The 4-di-tert-butyl-phenyl) ester (oxidation inhibitor 168); Two (2, the 4-di-tert-butyl-phenyl) pentaerythritol diphosphites, 4,4 '-[1; 1 '-xenyl] in subunit di 2 ethylhexyl phosphonic acid-four [2,4-two trimethylphenylmethane bases] ester, phosphorous acid diphenyl ester, triphenyl phosphite or the hydroxybenzotriazole one or more.
Said processing aid is selected from one or more in lubricant, coupling agent or the processing and lubrication auxiliary agent.
Described lubricant is selected from one or more in soap or the fatty acid amide.
Described coupling agent is selected from one or more in γ-An Bingjisanyiyangjiguiwan, γ-glycidoxypropyltrime,hoxysilane, γ-mercapto propyl group dimethoxy silane, γ thiopropyl triethoxyl silane, titanic acid ester isopropyl triisostearoyl titanate or the isopropyl tri (dioctylpyrophosphato)titanate.
Described processing and lubrication auxiliary agent is selected from solid paraffin, whiteruss, low molecular weight polyethylene, calcium stearate, Zinic stearas, stearic amide, pentaerythritol stearate, ethylene bis stearic acid amide or N, one or more in the N-ethylene bis stearic acid amide.
The present invention also provides a kind of above-mentioned ABS resinoid preparation method, and this method may further comprise the steps:
Take by weighing 0.2～0.5 part of 60～90 parts of ABS resinoids, 10～35 parts of weathering resistance macromolecule resins, 3～5 parts of compatilizers, 0.5～1 part of anti-oxidant auxiliary agent and processing aid, put into the high-speed mixer thorough mixing, mixed material is sent in the twin screw extruder; Through the shearing action of screw rod, sufficient mixing, the fused blend is through extruding; Tie rod; Cooling, pelletizing, packing prepares finished product.
Described high-speed mixer rotating speed is 100～150 rev/mins, and it is 1～3 minute that height is done time.
The length-to-diameter ratio of described twin screw extruder 40: 1～44: 1, screw speed is at 150～600 rev/mins.
180～200 ℃ of the blanking section temperature of described twin screw extruder; 200～220 ℃ of melting mixing section temperature, 220～230 ℃ of extruder head section temperature.
The present invention compares with prior art, has following advantage and beneficial effect:
Excellent weather resistance ABS resin of the present invention adopts the preparation of twin screw expressing technique, have flow process simple, continuously, the advantage of high, the constant product quality of production efficiency; Product has higher weathering resistance, can under long-time outside atmosphere, keep color and luster preferably, and aberration changes less.
Embodiment
Below in conjunction with embodiment the present invention is further described.
Used material in following examples:
The ABS resinoid is the acrylonitrile-butadiene-phenylethene grafted copolymer 8391 of Shanghai Gaoqiao petrochemical industry.The high-weatherability resin is the strange beautiful polymethylmethacrylate CM-205 in Taiwan.
Compatilizer is the maleic anhydride and the cinnamic multipolymer SMA218 of Oil of Shanghai Petrochemical Company.
Anti-oxidant auxiliary agent is the primary antioxidant 1010,1076 and the auxiliary antioxidant 168 of CIBA (vapour Bagong department).
Processing aid is homemade ethylene bis stearic acid amide EBS and pentaerythritol stearate PETS.
Embodiment 1
Take by weighing 0.5 part of 85 parts of ABS resinoids (the ABS resinoid is the acrylonitrile-butadiene-phenylethene grafted copolymer 8391 of Shanghai Gaoqiao petrochemical industry), 11 parts of polymethylmethacrylates, compatilizer 3 parts (compatilizer is the maleic anhydride and the cinnamic multipolymer SMA218 of Oil of Shanghai Petrochemical Company), processing aid EBS, it is 0.3 part with auxiliary antioxidant 168 that main anti-oxidant auxiliary agent 1010 is 02 part; It is 100 rev/mins high-speed mixer thorough mixing 3 minutes that above-mentioned raw materials is together put into rotating speed; With delicate metering material conveying device, mixed material is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing; Wherein the length-to-diameter ratio of twin screw extruder is 40: 1, and screw speed is at 300 rev/mins, and twin screw is extruded the working temperature interval and is: 180 ℃ of blanking section temperature; 210 ℃ of melting mixing section temperature, 225 ℃ of extruder head section temperature, the fused blend is through extruding; Tie rod, cooling, is packaged into finished product at pelletizing.
The mixture that obtains is prepared into the 10cm*10cm*3mm on-gauge plate, and the test weathering resistance is the ultraviolet accelerated deterioration, and test condition is seen table 1.
Embodiment 2
Take by weighing 0.5 part of 80 parts of ABS resinoids (the ABS resinoid is the acrylonitrile-butadiene-phenylethene grafted copolymer 8391 of Shanghai Gaoqiao petrochemical industry), 15 parts of polymethylmethacrylates, compatilizer 4 parts (compatilizer is the maleic anhydride and the cinnamic multipolymer SMA218 of Oil of Shanghai Petrochemical Company), processing aid PETS, it is 0.3 part with auxiliary antioxidant 168 that main anti-oxidant auxiliary agent 1010 is 0.2 part; It is 120 rev/mins high-speed mixer thorough mixing 2 minutes that above-mentioned raw materials is together put into rotating speed; With delicate metering material conveying device, mixed material is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing; Wherein the length-to-diameter ratio of twin screw extruder is 42: 1, and screw speed is at 350 rev/mins, and twin screw is extruded the working temperature interval and is: 180 ℃ of blanking section temperature; 215 ℃ of melting mixing section temperature, 230 ℃ of extruder head section temperature, the fused blend is through extruding; Tie rod, cooling, is packaged into finished product at pelletizing.
The mixture that obtains is prepared into the 10cm*10cm*3mm on-gauge plate, and the test weathering resistance is the ultraviolet accelerated deterioration, and test condition is seen table 1.
Embodiment 3
Take by weighing 0.5 part of 70 parts of ABS resinoids (the ABS resinoid is the acrylonitrile-butadiene-phenylethene grafted copolymer 8391 of Shanghai Gaoqiao petrochemical industry), 24 parts of polymethylmethacrylates, compatilizer 5 parts (compatilizer is the maleic anhydride and the cinnamic multipolymer SMA218 of Oil of Shanghai Petrochemical Company), processing aid EBS, it is 0.3 part with auxiliary antioxidant 168 that main anti-oxidant auxiliary agent 1076 is 0.2 part; It is 120 rev/mins high-speed mixer thorough mixing 2 minutes that above-mentioned raw materials is together put into rotating speed; With delicate metering material conveying device, mixed material is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing; Wherein the length-to-diameter ratio of twin screw extruder is 40: 1, and screw speed is at 300 rev/mins, and twin screw is extruded the working temperature interval and is: 190 ℃ of blanking section temperature; 220 ℃ of melting mixing section temperature, 230 ℃ of extruder head section temperature, the fused blend is through extruding; Tie rod, cooling, is packaged into finished product at pelletizing.
The mixture that obtains is prepared into the 10cm*10cm*3mm on-gauge plate, and the test weathering resistance is the ultraviolet accelerated deterioration, and test condition is seen table 1.
Embodiment 4
Take by weighing 0.5 part of 65 parts of ABS resinoids (the ABS resinoid is the acrylonitrile-butadiene-phenylethene grafted copolymer 8391 of Shanghai Gaoqiao petrochemical industry), 29 parts of polymethylmethacrylates, compatilizer 5 parts (compatilizer is the maleic anhydride and the cinnamic multipolymer SMA218 of Oil of Shanghai Petrochemical Company), processing aid PETS, it is 0.3 part with auxiliary antioxidant 168 that main anti-oxidant auxiliary agent 1076 is 02 part; It is 100 rev/mins high-speed mixer thorough mixing 3 minutes that above-mentioned raw materials is together put into rotating speed; With delicate metering material conveying device, mixed material is sent in the twin screw extruder, through the shearing action of screw rod, sufficient mixing; Wherein the length-to-diameter ratio of twin screw extruder is 44: 1, and screw speed is at 380 rev/mins, and twin screw is extruded the working temperature interval and is: 190 ℃ of blanking section temperature; 220 ℃ of melting mixing section temperature, 230 ℃ of extruder head section temperature, the fused blend is through extruding; Tie rod, cooling, is packaged into finished product at pelletizing.
The mixture that obtains is prepared into the 10cm*10cm*3mm on-gauge plate, and the test weathering resistance is the ultraviolet accelerated deterioration, and test condition is seen table 1.
Comparative Examples 1
The Acrylonitrile Butadiene 8391 of Shanghai Gaoqiao petro-chemical corporation, this material carries out the weather resistance transformation without the present invention, has stronger representativeness.
The mixture that obtains is prepared into the 10cm*10cm*3mm on-gauge plate, and the test weathering resistance is the ultraviolet accelerated deterioration, and test condition is seen table 1.
Table 1
| Testing method | ISO?4892-3cycle6 |
| Ultraviolet wavelength | 313nm |
| The uv irradiating energy | 0.48W/m 2 |
| Uv irradiating condition in the one-period | 70℃8h |
| Dark condition in the one-period | 50℃4h |
| Test period | 20 |
| Test duration (h) | 240 |
| Aberration | Color difference meter |
| Outward appearance | Visual |
Through table 1 ultraviolet ageing condition aged on-gauge plate with carry out chromatism test without the on-gauge plate of ultraviolet ageing relatively, detected result is seen table 2.
The properties of sample that table 2 embodiment is corresponding
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative Examples 1 | |
| Aberration Δ E | 1.0 | 0.8 | 0.6 | 0.3 | 2.5 |
| Outward appearance | Faint xanthochromia | Faint xanthochromia | No considerable change | No considerable change | Obvious xanthochromia |
Can find out that from last table very big through the raising of the more common ABS resinoid of the application's gained ABS resinoid weather resistance, material gets aberration and outward appearance does not have considerable change, effect is apparent in view.
The above-mentioned description to embodiment is can understand and use the present invention for ease of the those of ordinary skill of this technical field.The personnel of skilled obviously can easily make various modifications to these embodiment, and needn't pass through performing creative labour being applied in the General Principle of this explanation among other embodiment.Therefore, the invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not breaking away from the improvement that category of the present invention makes and revise all should be within protection scope of the present invention.
Claims (10)
1. ABS resinoid, it is characterized in that: this resinoid comprises following component and weight part,
60～90 parts of ABS resinoids,
10～35 parts of weathering resistance macromolecule resins,
3～5 parts of compatilizers,
0.5～1 part of anti-oxidant auxiliary agent,
0.2～0.5 part of processing aid.
2. ABS resinoid according to claim 1 is characterized in that: described ABS resinoid is selected from one or more the mixture in acrylonitrile-butadiene-phenylethene grafted copolymer, vinyl cyanide-ethylene, propylene elastomerics-phenylethene grafted copolymer, acrylonitrile-styrene-acrylic terpolymer or the TEB 3K-butadiene-styrene graft copolymer.
3. ABS resinoid according to claim 1 is characterized in that: described weathering resistance macromolecule resin is a polymethylmethacrylate.
4. ABS resinoid according to claim 1 is characterized in that: described compatilizer is selected from one or more in maleic anhydride graft acrylonitrile-butadiene-phenylethene grafted copolymer, maleic anhydride and cinnamic multipolymer, styrene-butadiene-styrene block copolymer, propenoate-butadienecopolymer or the vinylformic acid-BS.
5. ABS resinoid according to claim 1 is characterized in that: described anti-oxidant auxiliary agent is selected from four (β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester, β-(4-hydroxy phenyl-3; The 5-di-t-butyl) the positive octadecanol ester of propionic acid, N, [3-(3 for N '-hexamethylene-two; The 5-di-tert-butyl-hydroxy phenyl) propionic acid amide, 2; 2 '-methylene-bis (4-methyl-6-tert butyl phenol), Tri Ethyleneglycol two [β-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester], tricresyl phosphite (2, the 4-di-tert-butyl-phenyl) esters, two (2; The 4-di-tert-butyl-phenyl) pentaerythritol diphosphites, 4; 4 '-in [1,1 '-xenyl] subunit di 2 ethylhexyl phosphonic acid-four [2,4-two trimethylphenylmethane bases] ester, phosphorous acid diphenyl ester, triphenyl phosphite or the hydroxybenzotriazole one or more.
6. ABS resinoid according to claim 1 is characterized in that: said processing aid is selected from one or more in lubricant, coupling agent or the processing and lubrication auxiliary agent.
7. ABS resinoid according to claim 6 is characterized in that: described lubricant is selected from one or more in soap or the fatty acid amide; Described coupling agent is selected from one or more in γ-An Bingjisanyiyangjiguiwan, γ-glycidoxypropyltrime,hoxysilane, γ-mercapto propyl group dimethoxy silane, γ thiopropyl triethoxyl silane, titanic acid ester isopropyl triisostearoyl titanate or the isopropyl tri (dioctylpyrophosphato)titanate; Described processing and lubrication auxiliary agent is selected from solid paraffin, whiteruss, low molecular weight polyethylene, calcium stearate, Zinic stearas, stearic amide, pentaerythritol stearate, ethylene bis stearic acid amide or N, one or more in the N-ethylene bis stearic acid amide.
8. the resinoid preparation method of the arbitrary described ABS of claim 1 to 7, it is characterized in that: this method may further comprise the steps:
Take by weighing 0.2～0.5 part of 60～90 parts of ABS resinoids, 10～35 parts of weathering resistance macromolecule resins, 3～5 parts of compatilizers, 0.5～1 part of anti-oxidant auxiliary agent and processing aid, put into the high-speed mixer thorough mixing, mixed material is sent in the twin screw extruder; Through the shearing action of screw rod, sufficient mixing, the fused blend is through extruding; Tie rod; Cooling, pelletizing, packing prepares finished product.
9. the resinoid preparation method of ABS according to claim 8 is characterized in that: described high-speed mixer rotating speed is 100～150 rev/mins, and it is 1～3 minute that height is done time.
10. the resinoid preparation method of ABS according to claim 8 is characterized in that: the length-to-diameter ratio of described twin screw extruder 40: 1～44: 1, and screw speed is at 150～600 rev/mins; 180～200 ℃ of the blanking section temperature of described twin screw extruder; 200～220 ℃ of melting mixing section temperature, 220～230 ℃ of extruder head section temperature.
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| CN2011101440289A CN102807723A (en) | 2011-05-31 | 2011-05-31 | ABS resin and preparation method thereof |
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| CN2011101440289A CN102807723A (en) | 2011-05-31 | 2011-05-31 | ABS resin and preparation method thereof |
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| CN104725762A (en) * | 2015-03-27 | 2015-06-24 | 上海瀚氏模具成型有限公司 | Anti-aging ABS (acrylonitrile-butadiene-styrene) plastic and preparation method thereof |
| CN105017671A (en) * | 2014-05-02 | 2015-11-04 | 奕益实业有限公司 | composite stabilizer for acrylonitrile-butadiene-styrene copolymer |
| CN106751381A (en) * | 2016-11-26 | 2017-05-31 | 滁州市天悦塑胶制品有限公司 | A kind of high intensity ABS alloy material and preparation method thereof |
| CN107065314A (en) * | 2017-03-03 | 2017-08-18 | 京东方科技集团股份有限公司 | Spacer material and preparation method thereof, display panel |
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| CN109782386A (en) * | 2019-01-31 | 2019-05-21 | 昆山市诚泰电气股份有限公司 | A kind of light guide plate and preparation method thereof |
| CN110003606A (en) * | 2019-04-25 | 2019-07-12 | 苏州博驰新材料有限公司 | A kind of dedicated self-lubricating high molecular material of cosmetic pencil packaging |
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| CN111286799A (en) * | 2020-02-24 | 2020-06-16 | 嘉兴市富达化学纤维厂 | Process and apparatus for making coloured fibre |
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| CN104419106A (en) * | 2013-08-24 | 2015-03-18 | 黑龙江鑫达企业集团有限公司 | High-gloss paint spray-free scratch resistant alloy material and preparation method thereof |
| CN105017671A (en) * | 2014-05-02 | 2015-11-04 | 奕益实业有限公司 | composite stabilizer for acrylonitrile-butadiene-styrene copolymer |
| CN104725762A (en) * | 2015-03-27 | 2015-06-24 | 上海瀚氏模具成型有限公司 | Anti-aging ABS (acrylonitrile-butadiene-styrene) plastic and preparation method thereof |
| CN106751381A (en) * | 2016-11-26 | 2017-05-31 | 滁州市天悦塑胶制品有限公司 | A kind of high intensity ABS alloy material and preparation method thereof |
| CN107065314A (en) * | 2017-03-03 | 2017-08-18 | 京东方科技集团股份有限公司 | Spacer material and preparation method thereof, display panel |
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| CN109161151A (en) * | 2018-06-23 | 2019-01-08 | 深圳市宝聚合塑料有限公司 | Transparent ABS frosted resin and preparation method thereof |
| CN109782386A (en) * | 2019-01-31 | 2019-05-21 | 昆山市诚泰电气股份有限公司 | A kind of light guide plate and preparation method thereof |
| CN110003606A (en) * | 2019-04-25 | 2019-07-12 | 苏州博驰新材料有限公司 | A kind of dedicated self-lubricating high molecular material of cosmetic pencil packaging |
| CN110903567A (en) * | 2019-10-14 | 2020-03-24 | 中广核俊尔（上海）新材料有限公司 | Modified ASA material for vehicles and preparation method thereof |
| CN110903567B (en) * | 2019-10-14 | 2023-10-17 | 中广核俊尔（上海）新材料有限公司 | Modified ASA material for vehicle and preparation method thereof |
| CN111286799A (en) * | 2020-02-24 | 2020-06-16 | 嘉兴市富达化学纤维厂 | Process and apparatus for making coloured fibre |
| CN111286799B (en) * | 2020-02-24 | 2022-07-19 | 嘉兴市富达化学纤维厂 | Process and apparatus for manufacturing coloured fibre |
| CN112574525A (en) * | 2020-12-10 | 2021-03-30 | 上海金发科技发展有限公司 | Heat-resistant composition for thin-wall friction welding and preparation method thereof |
| CN112574525B (en) * | 2020-12-10 | 2023-04-18 | 上海金发科技发展有限公司 | Heat-resistant composition for thin-wall friction welding and preparation method thereof |
| CN113337046A (en) * | 2021-07-23 | 2021-09-03 | 浙江智英石化技术有限公司 | Preparation method of ABS resin particles |
| CN115011062A (en) * | 2022-05-24 | 2022-09-06 | 珠海格力新材料有限公司 | ABS material and preparation method thereof |
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