CN105017671A - composite stabilizer for acrylonitrile-butadiene-styrene copolymer - Google Patents
composite stabilizer for acrylonitrile-butadiene-styrene copolymer Download PDFInfo
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- CN105017671A CN105017671A CN201410205366.2A CN201410205366A CN105017671A CN 105017671 A CN105017671 A CN 105017671A CN 201410205366 A CN201410205366 A CN 201410205366A CN 105017671 A CN105017671 A CN 105017671A
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- ester
- antioxidant
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- butyl
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- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title claims abstract description 63
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 59
- 239000006084 composite stabilizer Substances 0.000 title abstract 2
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 69
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 64
- 150000002148 esters Chemical class 0.000 claims abstract description 52
- 235000006708 antioxidants Nutrition 0.000 claims description 67
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 48
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 14
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 10
- 125000000524 functional group Chemical group 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- -1 pentaerythritol stearic acid ester Chemical class 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 239000005864 Sulphur Substances 0.000 claims description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 claims description 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 5
- 229940059574 pentaerithrityl Drugs 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 4
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 4
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 3
- HCUOEKSZWPGJIM-YBRHCDHNSA-N (e,2e)-2-hydroxyimino-6-methoxy-4-methyl-5-nitrohex-3-enamide Chemical compound COCC([N+]([O-])=O)\C(C)=C\C(=N/O)\C(N)=O HCUOEKSZWPGJIM-YBRHCDHNSA-N 0.000 claims description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 2
- GSAHAZJWNMHSNI-UHFFFAOYSA-N 2,2-bis(dodecanoyloxymethyl)butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC GSAHAZJWNMHSNI-UHFFFAOYSA-N 0.000 claims description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 2
- HHRAWPICZKGGFQ-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethylidene)cyclohex-2-en-1-ol Chemical compound C(CCCCCCC)SC=C1C(C(=CC(C1)=CSCCCCCCCC)C)O HHRAWPICZKGGFQ-UHFFFAOYSA-N 0.000 claims description 2
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 claims description 2
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 claims description 2
- CAPNUXMLPONECZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-2-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=C(O)C(C(C)(C)C)=C1 CAPNUXMLPONECZ-UHFFFAOYSA-N 0.000 claims description 2
- IHLDEDLAZNFOJB-UHFFFAOYSA-N 6-octoxy-6-oxohexanoic acid Chemical compound CCCCCCCCOC(=O)CCCCC(O)=O IHLDEDLAZNFOJB-UHFFFAOYSA-N 0.000 claims description 2
- GRQZNHCKCPQIPL-UHFFFAOYSA-N CCC(CO)(CO)CO.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O Chemical compound CCC(CO)(CO)CO.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O GRQZNHCKCPQIPL-UHFFFAOYSA-N 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 241000790917 Dioxys <bee> Species 0.000 claims description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
- 239000005639 Lauric acid Substances 0.000 claims description 2
- GQJDFTIOKVGUOF-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)C(CO)(CO)CO Chemical class OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)C(CO)(CO)CO GQJDFTIOKVGUOF-UHFFFAOYSA-N 0.000 claims description 2
- ROFWDUSQKAKGIZ-UHFFFAOYSA-N P(O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)C(CO)(CO)CO Chemical compound P(O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)C(CO)(CO)CO ROFWDUSQKAKGIZ-UHFFFAOYSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 claims description 2
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 claims description 2
- 239000001273 butane Substances 0.000 claims description 2
- VNTXONBESJNLBI-UHFFFAOYSA-N dinonyl decanedioate Chemical compound CCCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCCC VNTXONBESJNLBI-UHFFFAOYSA-N 0.000 claims description 2
- 125000005908 glyceryl ester group Chemical group 0.000 claims description 2
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- LUUFSCNUZAYHAT-UHFFFAOYSA-N octadecane-1,18-diol Chemical compound OCCCCCCCCCCCCCCCCCCO LUUFSCNUZAYHAT-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 2
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- 238000005461 lubrication Methods 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 17
- 239000000203 mixture Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 12
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 10
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 9
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 8
- 239000008116 calcium stearate Substances 0.000 description 8
- 235000013539 calcium stearate Nutrition 0.000 description 8
- 235000011187 glycerol Nutrition 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 239000000956 alloy Substances 0.000 description 4
- PQYUGUXEJHLOIL-UHFFFAOYSA-N diethoxysilyl triethyl silicate Chemical compound C(C)O[SiH](O[Si](OCC)(OCC)OCC)OCC PQYUGUXEJHLOIL-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229960003742 phenol Drugs 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 2
- VTFXHGBOGGGYDO-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-methylphenol Chemical compound CCCCCCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCCCCCC)=C1 VTFXHGBOGGGYDO-UHFFFAOYSA-N 0.000 description 1
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 1
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- CFXCGWWYIDZIMU-UHFFFAOYSA-N Octyl-3,5-di-tert-butyl-4-hydroxy-hydrocinnamate Chemical group CCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 CFXCGWWYIDZIMU-UHFFFAOYSA-N 0.000 description 1
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
A composite stabilizer for acrylonitrile-butadiene-styrene copolymer is composed of an antioxidant and a polyol (ester) stabilizer. The antioxidant is contained in an amount of 0.05 to 0.5 parts by weight relative to 100 parts by weight of the acrylonitrile-butadiene-styrene copolymer. The content of the polyol (ester) stabilizer is 0.01 to 2 parts by weight with respect to 100 parts by weight of the acrylonitrile-butadiene-styrene copolymer.
Description
Technical field
The present invention is about a kind of combined type stablizer, and particularly a kind of combined type stablizer for acrylonitrile-butadiene-styrene copolymer.
Background technology
Acrylonitrile-butadiene-styrene copolymer has good chemical stability, physical strength, resistance to impact shock and electrical apparatus insulation.In addition, acrylonitrile-butadiene-styrene copolymer is easy to the dimensional stabilizing of processing, finished product, and surface luster property is good, is a kind of purposes thermoplastic engineering plastic widely.Current acrylonitrile-butadiene-styrene copolymer is widely used in the industry such as automobile, machinery, instrument.
But acrylonitrile-butadiene-styrene copolymer general on the market at present, its heat resisting temperature is 80 ~ 90 DEG C, and for the technical field of some electronic apparatuss, the heat resisting temperature of acrylonitrile-butadiene-styrene copolymer is not inconsistent demand.
In Chinese patent CN103571129, be utilize polycarbonate (Polycarbonate, PC) and acrylonitrile-butadiene-styrene copolymer to form rubber alloy, improve the thermotolerance of acrylonitrile-butadiene-styrene copolymer.And the rubber alloy that polycarbonate and acrylonitrile-butadiene-styrene copolymer are formed also also improves physical strength and the flame resistivity of acrylonitrile-butadiene-styrene copolymer simultaneously.In addition, also mention in Chinese patent CN102532787 and utilize acrylonitrile-butadiene-styrene copolymer, heat-resistant agent, toughner and compatilizer to form rubber alloy material to improve the thermotolerance of general acrylonitrile-butadiene-styrene copolymer.Can find out thus, at present existing many methods general acrylonitrile-butadiene-styrene resin formation rubber alloy being improved thermotolerance.
summary of the invention
The embodiment of the present invention provides a kind of combined type stablizer for acrylonitrile-butadiene-styrene copolymer (hereinafter referred to as Acrylonitrile Butadiene—Styrene copolymer), and this combined type stablizer can promote the colour stability of Acrylonitrile Butadiene—Styrene copolymer.
The embodiment of the present invention provides a kind of combined type stablizer for Acrylonitrile Butadiene—Styrene copolymer, and combined type stablizer comprises primary antibodie oxygenant and a polyvalent alcohol (ester) stablizer.Relative to the ABS multipolymer of 100 weight parts, the content of antioxidant is 0.05 to 0.5 weight part.Relative to the Acrylonitrile Butadiene—Styrene copolymer of 100 weight parts, the content of polyvalent alcohol (ester) stablizer is 0.01 to 2 weight part.
In sum, the invention provides a kind of combined type stablizer for Acrylonitrile Butadiene—Styrene copolymer, this combined type stablizer comprises antioxidant, polyvalent alcohol (ester) stablizer and lubrication prescription.Combined type stablizer can promote thermostability and the colour stability of Acrylonitrile Butadiene—Styrene copolymer.
Further understand feature of the present invention and technology contents for enable, refer to following detailed description for the present invention, but these explanations are only used for the present invention is described, but not any restriction is done to interest field of the present invention.
Embodiment
The embodiment of the present invention provides a kind of combined type stablizer for Acrylonitrile Butadiene—Styrene copolymer, and this combined type stablizer comprises antioxidant, polyvalent alcohol (ester) stablizer and lubrication prescription.Specifically, relative to the Acrylonitrile Butadiene—Styrene copolymer of 100 weight parts, the content of antioxidant is 0.05 to 0.5 weight part.And antioxidant is selected from by least one in the group that hindered phenol anti-oxidants, phosphorous antioxidant and sulphur system antioxidant form.
For example, hindered phenol anti-oxidants is selected from by four (β-(3, 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester (hereinafter referred to as antioxidant 1010), triethylene glycol ether-two (3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester (hereinafter referred to as antioxidant 245), 1, 3, 5-trimethylammonium-2, 4, 6-tri-(3, 5-di-tert-butyl-4-hydroxyl benzyl) benzene (hereinafter referred to as antioxidant 1330), 1, 3, 5-tri-(3, 5-di-tert-butyl-4-hydroxyl benzyl) tricarbimide (hereinafter referred to as antioxidant 3114), three (butyl cresyl) butane (hereinafter referred to as antioxidant AO-30), 4, 4'-butylidene two (the 6-tertiary butyl-3-methylphenol) (hereinafter referred to as antioxidant AO-40), 4, 4'-butylidene-bis-(6-tert-butyl-m-cresol) (hereinafter referred to as antioxidant AO-30), N, two [the 3-(3 of N'-, 5-di-tert-butyl-hydroxy phenyl) propionyl] hydrazine (hereinafter referred to as antioxidant 1024), N, N'-pair-(3-(3, 5-di-tert-butyl-hydroxy phenyl) propionyl) hexanediamine (hereinafter referred to as antioxidant 1098), 2, 2'-methylene-bis-(4-methyl-6-tert-butylphenol) (hereinafter referred to as antioxidant 246), and 3, at least one in the group that the different monooctyl ester of 5-di-t-butyl-4-hydroxy phenylpropionic acid (hereinafter referred to as antioxidant 1135) forms.
Phosphorous antioxidant be selected from by: 3, 9-bis-(2, 4-dicumyl phenoxy group)-2, 4, 8, 10-tetra-oxa--3, 9-bis-phospha spiral shell [5.5] undecane (hereinafter referred to as antioxidant 9228), three (2, 4-di-t-butyl) phenyl-phosphite (hereinafter referred to as antioxidant 168), two octadecyl pentaerythritol phosphite (hereinafter referred to as antioxidant P800), two (2, 4-di-tert-butyl-phenyl) pentaerythritol diphosphites (hereinafter referred to as antioxidant 626), and 2, 4, 8, 10-tetra-(1, 1-dimethylethyl)-6-[(2-second hexyl) oxygen]-12H-phenylbenzene [d, g] [1, 3, 2] at least one in the group that forms of dioxy phospha eight ring (hereinafter referred to as antioxidant HP-10).
Sulphur system antioxidant is then be selected from by the two octadecyl (hereinafter referred to as antioxidant DSTDP) of: thio-2 acid, the two dodecane ester (hereinafter referred to as antioxidant DLTDP) of thio-2 acid, tetramethylolmethane four (3-lauryl thiopropionate) (hereinafter referred to as antioxidant S4P), dipentaerythritol six (3-lauryl thiopropionate), 2, 4-bis-(n-octylthiomethylene)-6-methylphenol (hereinafter referred to as antioxidant S6P), 2, 4-bis-(dodecyl sulphur methylene radical)-6-methylphenol (hereinafter referred to as antioxidant 1726), 2, 4-bis-(octane base sulphur methylene radical)-6-methylphenol (hereinafter referred to as antioxidant 152), 4-[(4, the pungent sulfenyl-1 of 6-bis-, 3, 5-triazine-2-base) amino]-2, 6-DI-tert-butylphenol compounds (hereinafter referred to as antioxidant 565), and the two [3-(3 of sulfo-diethylene, 5-di-tert-butyl-hydroxy phenyl) propionic ester] at least one in (hereinafter referred to as antioxidant S35) group of forming.
Should be noted that, in the present embodiment, hindered phenol anti-oxidants is preferably antioxidant 1010, and phosphorous antioxidant is preferably antioxidant 168, and sulphur system antioxidant is then preferably antioxidant S4P.
In addition, relative to the Acrylonitrile Butadiene—Styrene copolymer of 100 weight parts, the content of polyvalent alcohol (ester) stablizer is 0.01 to 2 weight part.And polyvalent alcohol (ester) stablizer is selected from by least one in the group that dibasic alcohol (ester) molecule, trivalent alcohol (ester) molecule, tetravalent alcohol (ester) molecule and hexavalent alcohol (ester) molecule form.Specifically, dibasic alcohol (ester) molecule has following structural:
R
1O(CH
2)
nOR
1
In the structural formula of above-mentioned dibasic alcohol (ester) molecule, n is selected from 2-18, R
1be selected from hydrogen atom and functional group (C=O) C
mh
2m+1, and m is selected from 8-19.For example, dibasic alcohol (ester) molecule is selected from by 1,9-nonanediol, 1,18-octadecandiol, Octyl adipate, dinonyl sebacate(DNS), and at least one in the group that forms of glyceryl monostearate (Glyceryl Monostearate, hereinafter referred to as GMS).In the present embodiment, dibasic alcohol (ester) molecule is preferably 1,9-nonanediol and GMS.In addition, trivalent alcohol (ester) molecule is selected from the group be made up of following groups:
and
In the structural formula of above-mentioned trivalent alcohol (ester) molecule, R
2be selected from hydrogen atom and functional group (C=O) C
nh
2n+ 1, n is selected from 8-19.For example, dibasic alcohol (ester) molecule is selected from by glycerol (hereinafter referred to as glycerine), lauric acid two glyceryl ester, TriMethylolPropane(TMP), trimethylolpropane trilaurate, and at least one in the group that forms of trimethylolpropane tris stearate.And in the present embodiment, trivalent alcohol (ester) molecule is preferably glycerine.In addition, tetravalent alcohol (ester) molecule has following structural:
In the structural formula of above-mentioned tetravalent alcohol (ester) molecule, R
3be selected from hydrogen atom and functional group (C=O) C
nh
2n+ 1, n is selected from 8-19.Specifically, tetravalent alcohol (ester) molecule is selected from by tetramethylolmethane (hereinafter referred to as PETP), pentaerythritol tetrastearate (Pentaerythritol Stearate, hereinafter referred to as PETS), and at least one in the group that forms of pentaerythritol stearic acid ester 2 (hereinafter referred to as PEDS).In the present embodiment, PETP, PETS and PEDS are all satisfactory stability agent.
In addition, hexavalent alcohol (ester) molecule has following structural:
In the structural formula of above-mentioned hexavalent alcohol (ester) molecule, R
4be selected from hydrogen atom and functional group (C=O) C
nh
2n+1, n is selected from 8-19.Specifically, in the present embodiment, hexavalent alcohol (ester) molecule can be hexamethylolmelamine (hereinafter referred to as HMM).
In addition, relative to the Acrylonitrile Butadiene—Styrene copolymer of 100 weight parts, the content of lubrication prescription is 0.3 to 3.0 weight part.Lubrication prescription is selected from least one in the group that is made up of amides lubrication prescription and soap class lubrication prescription.Specifically, amides lubrication prescription is selected from least one in the group that is made up of N, N'-ethylenebisstearamide (Ethylene Bis Stearamide, hereinafter referred to as EBS), amine hydroxybenzene and erucicamide.And soap class lubrication prescription is selected from least one in the group that is made up of Zinic stearas and calcium stearate.In the present embodiment, amides lubrication prescription is preferably EBS, and soap class lubrication prescription is preferably calcium stearate.
Next, by utilizing above-mentioned additive mixing Acrylonitrile Butadiene—Styrene copolymer to prepare the abs polymer with combined type stablizer, to introduce the proportion of composing of the multiple embodiment of the present invention and multiple comparative example.Described proportion of composing is only used for embodiments of the invention are described, and is not used to limit the present invention.Should be noted that, Acrylonitrile Butadiene—Styrene copolymer used in embodiments of the present invention is made up of acrylonitritrile-styrene resin and acrylonitrile-butadiene-styrene (ABS) high glue powder.In the present embodiment, the content of acrylonitritrile-styrene resin is 50-80wt%, and the content of acrylonitrile-butadiene-styrene (ABS) high glue powder is 20-50wt%.But the embodiment of the present invention does not limit proportion of composing and the composing method of Acrylonitrile Butadiene—Styrene copolymer.
embodiment 1
Have in the abs polymer of combined type stablizer in embodiment 1, antioxidant selects antioxidant 168 and antioxidant S4P, and PEDS selected by polyvalent alcohol (ester) stablizer.And EBS selected by lubrication prescription.The proportion of composing of each composition is respectively: 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant 168,0.2 weight part antioxidant S4P, 1 weight part PEDS and 1 weight part EBS.
Should be noted that, the manufacture method of abs polymer is, after being mixed by mentioned component, adds that twin screw extruder carries out extruding, granulation.And the temperature of extruder is 190 DEG C to 220 DEG C.Driving screw rotating speed is 200 revs/min, and pan feeding speed is 6 revs/min.Extrudate can again through overcooling, air-dry, pelletizing, dry process to prepare the abs polymer with combined type stablizer.
embodiment 2
Have in the abs polymer of combined type stablizer in embodiment 2, antioxidant 168 selected by antioxidant, and PETS selected by polyvalent alcohol (ester) stablizer.And EBS selected by lubrication prescription.The proportion of composing of each composition is respectively: 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant 168,1 weight part PETS and 1 weight part EBS.In addition, the method preparing ABS mixture is identical with embodiment 1, does not repeat at this.
embodiment 3
Have in the abs polymer of combined type stablizer in embodiment 3, antioxidant selects antioxidant 168 and antioxidant 1010, and GMS selected by polyvalent alcohol (ester) stablizer.And calcium stearate selected by lubrication prescription.The proportion of composing of each composition is respectively: 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant 168,0.2 weight part antioxidant 1010,2 weight part GMS and 0.2 parts by weight of calcium stearate.In addition, the method preparing ABS mixture is identical with embodiment 1, does not repeat at this.
embodiment 4
Have in the abs polymer of combined type stablizer at the present embodiment, antioxidant 168 selected by antioxidant, and PETS selected by polyvalent alcohol (ester) stablizer.And calcium stearate selected by lubrication prescription.The proportion of composing of each composition respectively, 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant 168,2 weight part PETS and 0.2 parts by weight of calcium stearate.In addition, the method preparing ABS mixture is identical with embodiment 1, does not repeat at this.
embodiment 5
Have in the abs polymer of combined type stablizer at the present embodiment, antioxidant 168 selected by antioxidant, and polyvalent alcohol (ester) stablizer selects PETS and 1,9-nonanediol.And EBS selected by lubrication prescription.The proportion of composing of each composition respectively, 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant 168,1 weight part PETS, 0.1 weight part 1,9-nonanediol and 1 weight part EBS.In addition, the method preparing ABS mixture is identical with embodiment 1, does not repeat at this.
embodiment 6
Have in the abs polymer of combined type stablizer at the present embodiment, antioxidant 168 selected by antioxidant, and polyvalent alcohol (ester) stablizer selects PETS and glycerine.And EBS selected by lubrication prescription.The proportion of composing of each composition respectively, 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant 168,1 weight part PETS, 0.08 parts by weight of glycerin and 1 weight part EBS.In addition, the method preparing ABS mixture is identical with embodiment 1, does not repeat at this.
embodiment 7
Have in the abs polymer of combined type stablizer at the present embodiment, antioxidant 168 selected by antioxidant, PETS and PETP selected by polyvalent alcohol (ester) stablizer.And EBS selected by lubrication prescription.The proportion of composing of each composition respectively, 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant 168,1 weight part PETS, 0.05 weight part PETP and 1 weight part EBS.In addition, the method preparing ABS mixture is identical with embodiment 1, does not repeat at this.
embodiment 8
Have in the abs polymer of combined type stablizer at the present embodiment, antioxidant 168 selected by antioxidant, PETS and HMM selected by polyvalent alcohol (ester) stablizer.And EBS selected by lubrication prescription.The proportion of composing of each composition respectively, 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant 168,1 weight part PETS, 0.02 weight part HMM and 1 weight part EBS.In addition, the method preparing ABS mixture is identical with embodiment 1, does not repeat at this.
The proportion of composing of above-described embodiment 1-8 arranges as table 1:
Table 1
comparative example 1
In the abs polymer of comparative example 1, antioxidant P800 selected by antioxidant, and lubrication prescription selects EBS and calcium stearate.The proportion of composing of each composition respectively, 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant P800,2 weight part EBS and 0.2 parts by weight of calcium stearate.In addition, the method preparing abs polymer is identical with embodiment 1, does not repeat at this.
comparative example 2
In the abs polymer of comparative example 2, antioxidant P800 selected by antioxidant, and lubrication prescription selects EBS and Zinic stearas.The proportion of composing of each composition respectively, 100 weight part Acrylonitrile Butadiene—Styrene copolymers, 0.2 weight part antioxidant P800,2 weight part EBS and 0.2 weight part Zinic stearas.In addition, the method preparing abs polymer is identical with embodiment 1, does not repeat at this.
The proportion of composing of above-mentioned comparative example 1-2 arranges as table 1:
Table 2
In addition, the embodiment 1-8 prepared and comparative example 1-2 can through resistance to Thermal test, to illustrate that stablizer of the present invention has effect of heat-resistant quality and colour stability.Specifically, heat-resisting test mode comprises three kinds, is baking oven test, long-term baking oven test and indoor test respectively.In baking oven test, be by the ABS complex particle of above-described embodiment 1-8 and comparative example 1-2, put into constant temperature oven 3 hours, the temperature of baking oven is 150 DEG C.In long-term baking oven test, be by the ABS complex particle of above-described embodiment 1-8 and comparative example 1-2, put into constant temperature oven 2-4 week, the temperature of baking oven is 50 DEG C.And in indoor test, be then position 2-4 week ABS complex particle being placed on indoor not irradiation.
The particle tested can put into miniature ejaculator, heats after 3.5 minutes and penetrates in 50 DEG C of round flat shape moulds, to form circular colour examining sheet.And the injection rifle temperature of miniature ejaculator is 230 DEG C, pressurize is 300bar x 30s.Afterwards, the white value (White Index, WI) of circular colour examining sheet can be measured.Should be noted that, WI value can be used for representing heat-resistant quality and the colour stability of abs polymer.WI value is higher, and heat-resistant quality and the colour stability of abs polymer are higher.
The result that embodiment 1-8 tests is as shown in table 3 below, and the result that comparative example 1-2 tests is then as shown in table 4 below.
Table 3
Table 4
Embodiment 1-8 is the ratio formula according to combined type stablizer of the present invention, prepared abs polymer.And comparative example 1-4 is the ratio formula according to current existing combined type additive, prepared abs polymer.Table 3 is the heat-resisting test result of embodiment 1-8, and table 4 is the heat-resisting test result of comparative example 1-2.Refer to table 3,4 content.
From the content of table 3, the WI initial value of embodiment 1-8 is all greater than 35.In long-term baking oven test, through the resistance to Thermal test of 7 days, the WI value of embodiment 1-8 was all greater than 20, and particularly the WI value of embodiment 2,6-8 is all greater than 28.And have passed through the resistance to Thermal test of 14 days, the WI value of embodiment 2,6-8 can also maintain and be greater than in the numerical value of 25.But from the content of table 4, the WI initial value of comparative example 1-2 is all less than 33.In long-term baking oven test, through the resistance to Thermal test of 7 days, the WI value of comparative example 1-2 dropped to less than 23.And have passed through the resistance to Thermal test of 14 days, WI value is then fallen to less than 20.
In addition, in indoor test, through the resistance to Thermal test of 7 days, the WI value of embodiment 1-8 is all greater than 30, and particularly the WI value of embodiment 4,7 is all greater than 37.And have passed through the resistance to Thermal test of 14 days, the WI value of embodiment 4,7 can also maintain and be greater than in the numerical value of 35.But through the resistance to Thermal test of 7 days, the WI value of comparative example 1,2 was all less than 30.Have passed through the resistance to Thermal test of 14 days, the WI value of comparative example 1,2 is then down to less than 29.
In baking oven test, the WI value of embodiment 1-8 is all greater than 25, and particularly the WI value of embodiment 4 even can maintain more than 30.But compared to embodiment 1-8, the result that comparative example 1-2 tests through baking oven then finds, WI is directly less than 23.In other words, no matter be that embodiment 1-8 all has higher WI value, really can show good thermostability and colour stability in the test of shot and long term or high/low temperature.
In sum, the invention provides a kind of combined type stablizer for Acrylonitrile Butadiene—Styrene copolymer, this combined type stablizer comprises antioxidant, polyvalent alcohol (ester) stablizer and lubrication prescription.Combined type stablizer can promote thermostability and the colour stability of Acrylonitrile Butadiene—Styrene copolymer.
The foregoing is only embodiments of the invention, it is also not used to limit scope of patent protection of the present invention.Anyly have the knack of alike those skilled in the art, not departing from spirit of the present invention and scope, the equivalence of the change done and retouching is replaced, and is still in scope of patent protection of the present invention.
Claims (12)
1. for a combined type stablizer for acrylonitrile-butadiene-styrene copolymer, it is characterized in that, this combined type stablizer comprises:
One antioxidant, relative to an acrylonitrile-butadiene-styrene copolymer of 100 weight parts, the content of this antioxidant is 0.05 to 0.5 weight part; And
One polyvalent alcohol (ester) stablizer, relative to this acrylonitrile-butadiene-styrene copolymer of 100 weight parts, the content of this polyvalent alcohol (ester) stablizer is 0.01 to 2 weight part.
2. combined type stablizer according to claim 1, wherein this acrylonitrile-butadiene-styrene copolymer comprises:
One acrylonitritrile-styrene resin, and the content of this acrylonitritrile-styrene resin is 50-80wt%; And
One acrylonitrile-butadiene-styrene (ABS) high glue powder, and the content of this acrylonitrile-butadiene-styrene (ABS) high glue powder is 20-50wt%.
3. combined type stablizer according to claim 1, wherein this polyvalent alcohol (ester) stablizer is selected from least one in dibasic alcohol (ester) molecule, trivalent alcohol (ester) molecule, tetravalent alcohol (ester) molecule and hexavalent alcohol (ester) molecule.
4. combined type stablizer according to claim 3, wherein this dibasic alcohol (ester) molecule has following structural:
R
1O(CH
2)
nOR
1
Wherein n is selected from 2-18, R
1be selected from hydrogen atom and functional group (C=O) C
mh
2m+1, and m is selected from 8-19;
This trivalent alcohol (ester) molecule is selected from the group be made up of following groups:
And
Wherein R
2be selected from hydrogen atom and functional group (C=O) C
nh
2n+1, n is selected from 8-19;
This tetravalent alcohol (ester) molecule has following structural:
Wherein R
3be selected from hydrogen atom and functional group (C=O) C
nh
2n+1, n is selected from 8-19;
This hexavalent alcohol (ester) molecule has following structural:
Wherein R
4be selected from hydrogen atom and functional group (C=O) C
nh
2n+1, n is selected from 8-19.
5. combined type stablizer according to claim 4, wherein this dibasic alcohol (ester) molecule is selected from least one in 1,9-nonanediol, 1,18-octadecandiol, Octyl adipate, dinonyl sebacate(DNS) and glyceryl monostearate.
6. combined type stablizer according to claim 4, wherein this trivalent alcohol (ester) molecule is selected from least one in glycerol, lauric acid two glyceryl ester, TriMethylolPropane(TMP), trimethylolpropane trilaurate and trimethylolpropane tris stearate.
7. combined type stablizer according to claim 4, wherein this tetravalent alcohol (ester) molecule is selected from by least one in penta tetrol, pentaerythritol tetrastearate and pentaerythritol stearic acid ester 2.
8. combined type stablizer according to claim 4, wherein this hexavalent alcohol (ester) molecule comprises hexamethylolmelamine.
9. combined type stablizer according to claim 1, wherein this antioxidant is selected from least one in hindered phenol anti-oxidants, phosphorous antioxidant and sulphur system antioxidant.
10. combined type stablizer according to claim 9, wherein this hindered phenol anti-oxidants is selected from four (β-(3, 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester, triethylene glycol ether-two (3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester, 1, 3, 5-trimethylammonium-2, 4, 6-tri-(3, 5-di-tert-butyl-4-hydroxyl benzyl) benzene, 1, 3, 5-tri-(3, 5-di-tert-butyl-4-hydroxyl benzyl) tricarbimide, three (butyl cresyl) butane, 4, 4'-butylidene two (the 6-tertiary butyl-3-methylphenol), 4, 4'-butylidene-bis-(6-tert-butyl-m-cresol), N, two [the 3-(3 of N'-, 5-di-tert-butyl-hydroxy phenyl) propionyl] hydrazine, N, N'-pair-(3-(3, 5-di-tert-butyl-hydroxy phenyl) propionyl) hexanediamine, 2, 2'-methylene-bis-(4-methyl-6-tert-butylphenol) and 3, at least one in the different monooctyl ester of 5-di-t-butyl-4-hydroxy phenylpropionic acid.
11. combined type stablizers according to claim 9, wherein this phosphorous antioxidant is selected from 3,9-bis-(2,4-dicumyl phenoxy group)-2,4,8,10-tetra-oxa--3,9-bis-phospha spiral shell [5.5] undecane, three (2,4-di-t-butyl) phenyl-phosphite, two octadecyl pentaerythritol phosphite, two (2,4-di-tert-butyl-phenyl) pentaerythritol diphosphites and 2,4,8,10-tetra-(1,1-dimethylethyl)-6-[(2-second hexyl) oxygen]-12H-phenylbenzene [d, g] [1,3,2] at least one in dioxy phospha eight ring.
12. combined type stablizers according to claim 9, wherein this sulphur system antioxidant is selected from the two octadecyl of thio-2 acid, the two dodecane ester of thio-2 acid, tetramethylolmethane four (3-lauryl thiopropionate), dipentaerythritol six (3-lauryl thiopropionate), 2, 4-bis-(n-octylthiomethylene)-6-methylphenol, 2, 4-bis-(dodecyl sulphur methylene radical)-6-methylphenol, 2, 4-bis-(octane base sulphur methylene radical)-6-methylphenol, 4-[(4, the pungent sulfenyl-1 of 6-bis-, 3, 5-triazine-2-base) amino]-2, 6-DI-tert-butylphenol compounds and the two [3-(3 of sulfo-diethylene, 5-di-tert-butyl-hydroxy phenyl) propionic ester] at least one.
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| CN108948641A (en) * | 2018-08-15 | 2018-12-07 | 马鞍山卓凡新材料科技有限公司 | A kind of heat-proof ABS engineering plastics that mannitol is sulfated |
| CN109294151A (en) * | 2017-07-24 | 2019-02-01 | 奕益实业有限公司 | Modified polymer material and the mixture for being used to prepare polymer material |
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|---|---|---|---|---|
| CN102399408A (en) * | 2010-09-08 | 2012-04-04 | 上海纳米技术及应用国家工程研究中心有限公司 | Fiberglass reinforced black acrylonitrile-butadiene-styrene modified plastic capable of heat resistance and impact resistance, and its preparation method |
| CN102807723A (en) * | 2011-05-31 | 2012-12-05 | 合肥杰事杰新材料股份有限公司 | ABS resin and preparation method thereof |
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- 2014-05-02 TW TW103115890A patent/TW201542668A/en unknown
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102399408A (en) * | 2010-09-08 | 2012-04-04 | 上海纳米技术及应用国家工程研究中心有限公司 | Fiberglass reinforced black acrylonitrile-butadiene-styrene modified plastic capable of heat resistance and impact resistance, and its preparation method |
| CN102807723A (en) * | 2011-05-31 | 2012-12-05 | 合肥杰事杰新材料股份有限公司 | ABS resin and preparation method thereof |
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| CN109294151A (en) * | 2017-07-24 | 2019-02-01 | 奕益实业有限公司 | Modified polymer material and the mixture for being used to prepare polymer material |
| CN109294151B (en) * | 2017-07-24 | 2021-03-09 | 奕益实业股份有限公司 | Modified polymeric materials and mixtures for preparing polymeric materials |
| CN108948641A (en) * | 2018-08-15 | 2018-12-07 | 马鞍山卓凡新材料科技有限公司 | A kind of heat-proof ABS engineering plastics that mannitol is sulfated |
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