CN102515518A - Low-sodium lead-free high-transmittance energy-saving lamp tube glass and preparation method thereof - Google Patents
Low-sodium lead-free high-transmittance energy-saving lamp tube glass and preparation method thereof Download PDFInfo
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- CN102515518A CN102515518A CN2011104079146A CN201110407914A CN102515518A CN 102515518 A CN102515518 A CN 102515518A CN 2011104079146 A CN2011104079146 A CN 2011104079146A CN 201110407914 A CN201110407914 A CN 201110407914A CN 102515518 A CN102515518 A CN 102515518A
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Abstract
The invention relates to low-sodium lead-free high-transmittance energy-saving lamp tube glass and a preparation method thereof. The glass comprises components of, by mass: 65-70% of SiO2, 3-6% of Al2O3, 0-0.8% of Na2O, 5-10% of K2O, 0-3% of Li2O, 0-3% of MgO, 0-3% of CaO, 8-15% of SrO+BaO, and 0.1-0.5% of a clarifying agent. The preparation method comprises the steps that: SiO2, Al2O3, Na2O, K2O, Li2O, MgO, CaO, SrO+BaO, and the clarifying agent are mixed, and are fused for 6-10h under a temperature of 1430-1480 DEG C; an obtained mixture is subject to tube drawing, such that the glass is obtained. The energy-saving lamp tube glass contains no lead and low sodium. A transmittance of the glass is higher than 92%. Energy-saving lamps prepared with the glass are advantaged in long service lives and high qualities. The preparation method provided by the invention is simple. The method can be applied in scaled productions.
Description
Technical field
The invention belongs to power saving fluorescent lamps glass and preparation field thereof, the unleaded high permeability power saving fluorescent lamps of particularly a kind of low sodium glass and preparation method thereof.
Background technology
Present power saving fluorescent lamps all is to be used for the Na-Ca-Si system glass; 80% of present energy-conservation lantern pane adopts common soda-lime glass (being commonly called as lime material glass); The sodium amount that contains of common soda-lime glass is 16-17%; And external several famous illumination company all develops the electricity-saving lamp glass of different size, and it contains the sodium amount and all is higher than 5wt%.
Sodium ion is the important component part in the silicate glass, and it is that the glass melting temperature and the electric property aspect that reduce glass have very remarkable advantages.But electricity-saving lamp with Glass tubing in since Glass tubing in contain the highly compressed mercuryvapour, in use with glass in sodium ion can react, reaction formula is following:
The sodium amalgam that reaction generates will be deposited on and form black solid on the Glass tubing, and often see in our life that Here it is fluorescent lamp and electricity-saving lamp are in the reason of using the later stage usually to turn black.Electricity-saving lamp factory prevents through on Glass tubing, adding one deck coating at present, but one side increases technology one, and coating is lower for the work-ing life on the long-time high temperature high-voltage at present simultaneously, and the quality of this coating indicates the life-span of electricity-saving lamp to a certain extent.In addition, though coating is transparent, its transmitance is low than glass, has also reduced the optical throughput and the quality of electricity-saving lamp.
Summary of the invention
Technical problem to be solved by this invention provides the unleaded high permeability power saving fluorescent lamps of a kind of low sodium glass and preparation method thereof, and this glass sodium content is low, the work-ing life that can improve electricity-saving lamp, and also transmitance is up to 92%, and its preparation method is simple.
The unleaded high permeability power saving fluorescent lamps of a kind of low sodium of the present invention glass, the component of this glass comprises by massfraction: SiO
265～70%, Al
2O
33～6%, Na
2O 0～0.8%, K
2O 5～10%, Li
2O 0～3%, MgO 0～3%, CaO 0～3%, SrO+BaO 8～15% and finings 0.1～0.5%.
The component of said glass by massfraction is: SiO
265%, Al
2O
34.5%, Na
2O 0.5%, K
2O 10%, Li
2O0.5%, MgO 3%, CaO 1%, SrO+BaO 15% and finings 0.5%.
The component of said glass by massfraction is: SiO
270%, Al
2O
33%, Na
2O 0.8%, K
2O 8%, Li
2O 1%, MgO 1.5%, CaO 2.5%, SrO+BaO 13% and finings 0.2%.
Described SrO+BaO 8～15% is specially SrO 0-3%, BaO 8-12%.
Described finings is CeO
2
The preparation method of the unleaded high permeability power saving fluorescent lamps of a kind of low sodium of the present invention glass comprises:
Press massfraction, with SiO
265～70%, Al
2O
33～6%, Na
2O 0～0.8%, K
2O 5～10%, Li
2After O 0～3%, MgO 0～3%, CaO 0～3%, SrO+BaO 8～15% and finings 0.1～0.5% mix, melted 6～10 hours down at 1430～1480 ℃, last trombone slide promptly gets and hangs down the unleaded high permeability power saving fluorescent lamps of sodium glass.
Described trombone slide adopts horizontal or vertical trombone slide method.
The present invention utilizes above-mentioned glass formula to substitute the legacy power save lamp glass, through reducing Na
2O content to 0～0.8% can reduce the mercury generation chemical reaction in itself and the electricity-saving lamp, improves the work-ing life of electricity-saving lamp.
The present invention is through control glass cullet content and raw material composition, and the content of effectively controlling PbO is below 400PPM.
The present invention utilizes the SrO+BaO of interpolation 8～15% and 5～10% Li
2O has realized the high permeability of glass, and the visible light transmissivity of its glass is higher than 85% conventional electricity-saving lamp glass visible light transmissivity greater than 92%.。
The present invention utilizes the Li of interpolation and 0～3%
2O, the glass melting temperature of having realized glass is 1430～1480 ℃, and its softening temperature is 650 ± 10 ℃, keeps and the close processing characteristics of conventional electricity-saving lamp glass.
Beneficial effect
(1) the present invention can significantly improve the transmitance of electricity-saving lamp glass, improves the efficient of light through fluorescent tube;
(2) contain among the present invention and be lower than 0.8 Na
2O content, therefore reduced its with electricity-saving lamp in the mercury possibility of reacting, thereby effectively improved the transmitance of energy-saving glass;
(3) the present invention effectively controls lead content by cullet and prescription composition, and present lead content is lower than 400ppm, therefore reduces the pollution risk of this product to environment;
(4) the electricity-saving lamp glassy phase ratio of the present invention and routine, its softening temperature is low, and post-treatment is simple.
Description of drawings
Fig. 1 is the transmittance curve figure of high permeability electricity-saving lamp glass.
Embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in the restriction scope of the present invention.Should be understood that in addition those skilled in the art can do various changes or modification to the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment 1
Prescription:
| Oxide compound | SiO 2 | Al 2O 3 | Na 2O | K 2O | Li 2O | CaO | MgO | SrO+BaO | CeO 2 |
| Massfraction | 65 | 4.5 | 0.5 | 10 | 0.5 | 1 | 3 | 15 | 0.5 |
According to the glass batch of above-mentioned formulated, melted 6 hours down at 1440 ℃, utilize horizontal trombone slide technology to prepare the unleaded high permeability power saving fluorescent lamps of low sodium glass.The softening point temperature of this Glass tubing is 645 ℃.
Embodiment 2
Prescription:
| Oxide compound | SiO 2 | Al 2O 3 | Na 2O | K 2O | Li 2O | CaO | MgO | SrO+BaO | CeO 2 |
| Massfraction | 70 | 3 | 0.8 | 8 | 1 | 2.5 | 1.5 | 13 | 0.2 |
According to the glass batch of above-mentioned formulated, melted 10 hours down at 1480 ℃, utilize vertical trombone slide technology to prepare the unleaded high permeability power saving fluorescent lamps of low sodium glass.The softening point temperature of this Glass tubing is 655 ℃.
Claims (7)
1. the unleaded high permeability power saving fluorescent lamps of low sodium glass, the component of this glass comprises by massfraction: SiO
265～70%, Al
2O
33～6%, Na
2O 0～0.8%, K
2O 5～10%, Li
2O 0～3%, MgO 0～3%, CaO 0～3%, SrO+BaO8～15% and finings 0.1～0.5%.
2. the unleaded high permeability power saving fluorescent lamps of a kind of low sodium according to claim 1 glass, it is characterized in that: the component of said glass by massfraction is: SiO
265%, Al
2O
34.5%, Na
2O 0.5%, K
2O 10%, Li
2O 0.5%, MgO 3%, CaO 1%, SrO+BaO 15% and finings 0.5%.
3. the unleaded high permeability power saving fluorescent lamps of a kind of low sodium according to claim 1 glass, it is characterized in that: the component of said glass by massfraction is: SiO
270%, Al
2O
33%, Na
2O 0.8%, K
2O 8%, Li
2O 1%, MgO 1.5%, CaO 2.5%, SrO+BaO 13% and finings 0.2%.
4. the unleaded high permeability power saving fluorescent lamps of a kind of low sodium according to claim 1 glass, it is characterized in that: described SrO+BaO 8～15% is specially SrO 0-3%, BaO 8-12%.
5. the unleaded high permeability power saving fluorescent lamps of a kind of low sodium according to claim 1 glass, it is characterized in that: described finings is CeO
2
6. the preparation method of the unleaded high permeability power saving fluorescent lamps of a low sodium glass comprises:
Press massfraction, with SiO
265～70%, Al
2O
33～6%, Na
2O 0～0.8%, K
2O 5～10%, Li
2After O 0～3%, MgO 0～3%, CaO 0～3%, SrO+BaO 8～15% and finings 0.1～0.5% mix, melted 6～10 hours down at 1430～1480 ℃, last trombone slide promptly gets.
7. the preparation method of the unleaded high permeability power saving fluorescent lamps of a kind of low sodium according to claim 6 glass, it is characterized in that: described trombone slide adopts horizontal or vertical trombone slide method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104079146A CN102515518A (en) | 2011-12-09 | 2011-12-09 | Low-sodium lead-free high-transmittance energy-saving lamp tube glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104079146A CN102515518A (en) | 2011-12-09 | 2011-12-09 | Low-sodium lead-free high-transmittance energy-saving lamp tube glass and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102515518A true CN102515518A (en) | 2012-06-27 |
Family
ID=46286664
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104079146A Pending CN102515518A (en) | 2011-12-09 | 2011-12-09 | Low-sodium lead-free high-transmittance energy-saving lamp tube glass and preparation method thereof |
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|---|---|
| CN (1) | CN102515518A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104176934A (en) * | 2014-08-07 | 2014-12-03 | 宁波杰达模具机械有限公司 | Processing method for lamp glass |
| CN106565084A (en) * | 2016-08-10 | 2017-04-19 | 上海罗金光电科技股份有限公司 | Light-trap uviol glass tube and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1196713A (en) * | 1996-05-13 | 1998-10-21 | 菲利浦电子有限公司 | Glass composition suitable for use in fluorescent lamp, lamp envelope manufactured from said glass composition and lamp envelope with said glass composition |
-
2011
- 2011-12-09 CN CN2011104079146A patent/CN102515518A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1196713A (en) * | 1996-05-13 | 1998-10-21 | 菲利浦电子有限公司 | Glass composition suitable for use in fluorescent lamp, lamp envelope manufactured from said glass composition and lamp envelope with said glass composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104176934A (en) * | 2014-08-07 | 2014-12-03 | 宁波杰达模具机械有限公司 | Processing method for lamp glass |
| CN106565084A (en) * | 2016-08-10 | 2017-04-19 | 上海罗金光电科技股份有限公司 | Light-trap uviol glass tube and preparation method thereof |
| CN106565084B (en) * | 2016-08-10 | 2019-01-18 | 上海罗金光电科技股份有限公司 | A kind of lamplight insect lure type holvi glass pipe and preparation method thereof |
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Application publication date: 20120627 |