CN102500089A - Composition for removing benzene homologues, benzene homologue removing agent and preparation method - Google Patents
Composition for removing benzene homologues, benzene homologue removing agent and preparation method Download PDFInfo
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- CN102500089A CN102500089A CN2011103112664A CN201110311266A CN102500089A CN 102500089 A CN102500089 A CN 102500089A CN 2011103112664 A CN2011103112664 A CN 2011103112664A CN 201110311266 A CN201110311266 A CN 201110311266A CN 102500089 A CN102500089 A CN 102500089A
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Abstract
The invention discloses a composition for removing benzene homologues, a benzene homologue removing agent and a preparation method. Both the composition for removing the benzene homologues and the benzene homologue removing agent comprise nano titanium dioxide, an anion material and a plant extract solution at a mass ratio of (10-22.5): (80-180): (100-300). The preparation method of the composition for removing the benzene homologues and the benzene homologue removing agent comprises the steps of: squeezing the plants with a squeezer to obtain a squeezed material, adding ethanol to the squeezed material at a ratio of the squeezed material to ethanol being 1kg: (10-12kg), stirring and filtering to obtain a filtrate namely the plant extract solution; and adding nano titanium dioxide and the anion material to the plant extract solution and stirring. By using the composition for removing benzene homologues and the benzene homologue removing agent, the benzene homologues generated during decoration can be quickly removed, and the people health is guaranteed.
Description
Technical field
The present invention relates to be used to remove the material of fitting up the benzene series thing that produces, particularly a kind of composition, benzene series thing scavenger and preparation method who is used for the removing of benzene series thing.
Background technology
The additive of the synthetic fibers that use in the fitment process, paint and various paints and diluent, all kinds of solvents shape jelly, waterproof material can produce benzene series thing (benzene, toluene and xylenes etc.) behind finishing.The benzene series thing belongs to carcinogen (benzene was confirmed as carcinogenic substance in 1993 by the World Health Organization), and long-term contact can cause various cancers, especially leukaemia.That the calomel poisoning meeting causes is drowsiness, headache, dizzy, feel sick, chest tightly restraints sense etc., and slight MMi symptom can be arranged.Blurred vision appears in the severe intoxication meeting, it is shallow and fast to breathe, heart murmur, tic or stupor.Especially benzene is very big to human harm: as to suck benzene for a long time and can cause alpastic anemia; The women of child-bearing age suck benzene for a long time can cause menoxenia, and when the pregnant woman contacted toluene, xylenes and benzene series mixture, the incidence of disease of complications of pregnancy such as pregnancy-hypertension syndrome, the vomiting of pregnancy and anemia during pregnancy significantly increased, even can cause miscarriage; Benzene also can cause the fetal congenital defective; Also can cause damage to the skin and the upper respiratory tract.
Summary of the invention
To the deficiency that exists in the prior art; The object of the present invention is to provide a kind of benzene series thing scavenger that is used for composition, benzene series thing scavenger and the preparation method of the removing of benzene series thing; The benzene series thing that makes finishing produce can promptly be eliminated, and the protection people are healthy.
Technical scheme of the present invention is achieved in that and is used for the composition that the benzene series thing is removed; Comprise nano titanium oxide, anion material and plant extraction liquid, the mass ratio between nano titanium oxide, anion material and the plant extraction liquid three is (10~22.5): (80~180): (100~300).
The above-mentioned composition that is used for the removing of benzene series thing, the particle diameter of said nano titanium oxide is 10~30 nanometers.
The above-mentioned composition that is used for the removing of benzene series thing, the particle diameter of said anion material is 200~300 nanometers.
Be used for the preparation of compositions method that the benzene series thing is removed, obtain expressate after with squeezer plant being squeezed, in expressate, add ethanol, per 1 does the gram expressate adds 10~12 kilograms of ethanol, stirs, and filters, and filtrating is plant extraction liquid; In plant extraction liquid, add nano titanium oxide and anion material; Mass ratio between nano titanium oxide, anion material and the plant extraction liquid three is (10~22.5): (80~180): (100~300); Stir, promptly get the composition that is used for the removing of benzene series thing.
Benzene series thing scavenger comprises benzene series thing scavenger stoste and water, and the mass ratio of benzene series thing scavenger stoste and water is 2: 3; Benzene series thing scavenger stoste is that 5% nano titanium oxide suspension, mass percentage concentration are that 40% anion material suspension and plant extraction liquid are formed by mass percentage concentration, and the weight ratio between nano titanium oxide suspension, anion material suspension and the plant extraction liquid three is (2~4.5): (2~4.5): (1~3).
Above-mentioned benzene series thing scavenger, the weight ratio between nano titanium oxide suspension, anion material suspension and the plant extraction liquid three is 3: 3: 1.5.
Above-mentioned benzene series thing scavenger comprises that also weight percentage is 2~5 ‰ a surfactant of water and benzene series thing scavenger stoste gross mass.
Above-mentioned benzene series thing scavenger, said surfactant is a dodecyl sodium sulfate.
The preparation method of benzene series thing scavenger obtains expressate after with squeezer plant being squeezed, and in expressate, adds ethanol, and per 1 kilogram of expressate adds 10~12 kilograms of ethanol, stirs, and filters, and filtrating is plant extraction liquid; In plant extraction liquid, add mass percentage concentration and be 5% nano titanium oxide suspension and mass percentage concentration and be 40% anion material suspension; Weight ratio between nano titanium oxide suspension, anion material suspension and the plant extraction liquid three is (2~4.5): (2~4.5): (1~3) promptly gets benzene series thing scavenger stoste after the stirring; By the weight ratio of benzene series thing scavenger stoste and water is to add water at 2: 3; Adding weight percentage at last is 2~5 ‰ surfactants of water and benzene series thing scavenger stoste gross mass.
Above-mentioned preparation method, plant extraction liquid is the mixed liquor of extract solution from aloe or fig extract or extract solution from aloe and fig extract.
The invention has the beneficial effects as follows: can remove the benzene series thing (benzene, toluene and xylenes) that the finishing back produces fast, make the content National standard of benzene series thing (benzene, toluene and xylenes), guarantee that people are healthy.
The specific embodiment
Embodiment 1
Obtain the aloe expressate after with squeezer aloe being squeezed, in the aloe expressate, add ethanol, per 1 kilogram of aloe expressate adds 10 kilograms of ethanol, stirs, and filters, and filtrating is extract solution from aloe; In extract solution from aloe, add mass percentage concentration and be 5% nano titanium oxide suspension and mass percentage concentration and be 40% anion material suspension; Weight ratio between nano titanium oxide suspension, anion material suspension and the extract solution from aloe three is 4.5: 4.5: 1, promptly gets benzene series thing scavenger stoste after the stirring; By the weight ratio of benzene series thing scavenger stoste and water is to add water at 2: 3, and promptly per 2 kilograms of benzene series thing scavenger stostes add 3 kg water; Adding weight percentage at last is 2 ‰ surfactants of water and benzene series thing scavenger stoste gross mass; Be to add 2 kilograms surfactant in the mixture of per 1000 kg water and benzene series thing scavenger stoste, surfactant described in the present embodiment is a dodecyl sodium sulfate.The particle diameter of said nano titanium oxide is 10~30 nanometers, and the particle diameter of said anion material is 200~300 nanometers.
The problem that exists the benzene series thing to exceed standard behind the finishing of A sub-district, the field sampling test result is as shown in table 1.Use the benzene series thing scavenger of present embodiment preparation indoor benzene series thing is removed, be applied in the body surface that produces the benzene series thing according to every square metre 25 gram, test benzene series thing content is as shown in table 1 after 2 days.
Table 1
The benzene series thing | Unit | Standard value | Before the removing | After the removing | Remarks |
Benzene | mg/m 3 | 0.11 | 0.40 | 0.10 | 1 little hourly value |
Toluene | mg/m 3 | 0.20 | 0.30 | 0.15 | 1 little hourly value |
Xylenes | mg/m 3 | 0.20 | 0.35 | 0.18 | 1 little hourly value |
Embodiment 2
Obtain the aloe expressate after with squeezer aloe being squeezed, in the aloe expressate, add ethanol, per 1 kilogram of aloe expressate adds 12 kilograms of ethanol, stirs, and filters, and filtrating is extract solution from aloe; In extract solution from aloe, add mass percentage concentration and be 5% nano titanium oxide suspension and mass percentage concentration and be 40% anion material suspension; Weight ratio between nano titanium oxide suspension, anion material suspension and the extract solution from aloe three is 3: 3: 1.5, promptly gets benzene series thing scavenger stoste after the stirring; By the weight ratio of benzene series thing scavenger stoste and water is to add water at 2: 3, and promptly per 2 kilograms of benzene series thing scavenger stostes add 3 kg water; Adding weight percentage at last is 5 ‰ surfactants of water and benzene series thing scavenger stoste gross mass; Be to add 5 kilograms surfactant in the mixture of per 1000 kg water and benzene series thing scavenger stoste, surfactant described in the present embodiment is a dodecyl sodium sulfate.The particle diameter of said nano titanium oxide is 10~30 nanometers, and the particle diameter of said anion material is 200~300 nanometers.
The problem that exists the benzene series thing to exceed standard behind the B restaurant finishing, the field sampling test result is as shown in table 2.Use the benzene series thing scavenger of present embodiment preparation indoor benzene series thing is removed, be applied in the body surface that produces the benzene series thing according to every square metre 25 gram, test benzene series thing content is as shown in table 2 after 2 days.
Table 2
The benzene series thing | Unit | Standard value | Before the removing | After the removing | Remarks |
Benzene | mg/m 3 | 0.11 | 0.37 | 0.10 | 1 little hourly value |
Toluene | mg/m 3 | 0.20 | 0.30 | 0.17 | 1 little hourly value |
Xylenes | mg/m 3 | 0.20 | 0.25 | 0.19 | 1 little hourly value |
Embodiment 3
Obtain the aloe expressate after with squeezer fig being squeezed, in the fig expressate, add ethanol, per 1 kilogram of fig expressate adds 12 kilograms of ethanol, stirs, and filters, and filtrating is the fig extract; In the fig extract, add mass percentage concentration and be 5% nano titanium oxide suspension and mass percentage concentration and be 40% anion material suspension; Weight ratio between nano titanium oxide suspension, anion material suspension and the fig extract three is 3: 3: 1.5, promptly gets benzene series thing scavenger stoste after the stirring; By the weight ratio of benzene series thing scavenger stoste and water is to add water at 2: 3, and promptly per 2 kilograms of benzene series thing scavenger stostes add 3 kg water; Adding weight percentage at last is 5 ‰ surfactants of water and benzene series thing scavenger stoste gross mass; Be to add 5 kilograms surfactant in the mixture of per 1000 kg water and benzene series thing scavenger stoste, surfactant described in the present embodiment is a dodecyl sodium sulfate.The particle diameter of said nano titanium oxide is 10~30 nanometers, and the particle diameter of said anion material is 200~300 nanometers.
The problem that exists the benzene series thing to exceed standard behind the C restaurant finishing, the field sampling test result is as shown in table 3.Use the benzene series thing scavenger of present embodiment preparation indoor benzene series thing is removed, be applied in the body surface that produces the benzene series thing according to every square metre 25 gram, test benzene series thing content is as shown in table 3 after 2 days.
Table 3
The benzene series thing | Unit | Standard value | Before the removing | After the removing | Remarks |
Benzene | mg/m 3 | 0.11 | 0.29 | 0.11 | 1 little hourly value |
Toluene | mg/m 3 | 0.20 | 0.28 | 0.15 | 1 little hourly value |
Xylenes | mg/m 3 | 0.20 | 0.26 | 0.17 | 1 little hourly value |
Embodiment 4
Obtain the fig expressate after with squeezer fig being squeezed, in the fig expressate, add ethanol, per 1 kilogram of fig expressate adds 11 kilograms of ethanol, stirs, and filters, and filtrating is the fig extract; In the fig extract, add mass percentage concentration and be 5% nano titanium oxide suspension and mass percentage concentration and be 40% anion material suspension; Weight ratio between nano titanium oxide suspension, anion material suspension and the fig extract three is 3.5: 3.5: 2, promptly gets benzene series thing scavenger stoste after the stirring; By the weight ratio of benzene series thing scavenger stoste and water is to add water at 2: 3, and promptly per 2 kilograms of benzene series thing scavenger stostes add 3 kg water; Adding weight percentage at last is 3 ‰ surfactants of water and benzene series thing scavenger stoste gross mass; Be to add 3 kilograms surfactant in the mixture of per 1000 kg water and benzene series thing scavenger stoste, surfactant described in the present embodiment is a dodecyl sodium sulfate.The particle diameter of said nano titanium oxide is 10~30 nanometers, and the particle diameter of said anion material is 200~300 nanometers.
The problem that exists the benzene series thing to exceed standard behind the D hotel finishing, the field sampling test result is as shown in table 4.Use the benzene series thing scavenger of present embodiment preparation indoor benzene series thing is removed, be applied in the body surface that produces the benzene series thing according to every square metre 25 gram, test benzene series thing content is as shown in table 4 after 2 days.
Table 4
The benzene series thing | Unit | Standard value | Before the removing | After the removing | Remarks |
Benzene | mg/m 3 | 0.11 | 0.29 | 0.11 | 1 little hourly value |
Toluene | mg/m 3 | 0.20 | 0.28 | 0.15 | 1 little hourly value |
Xylenes | mg/m 3 | 0.20 | 0.26 | 0.17 | 1 little hourly value |
Embodiment 5
Obtain the fig expressate after with squeezer fig being squeezed, in the fig expressate, add ethanol, per 1 kilogram of fig expressate adds 11.5 kilograms of ethanol, stirs, and filters, and filtrating is the fig extract; In the fig extract, add mass percentage concentration and be 5% nano titanium oxide suspension and mass percentage concentration and be 40% anion material suspension; Weight ratio between nano titanium oxide suspension, anion material suspension and the fig extract three is 2.5: 2.5: 2.5, promptly gets benzene series thing scavenger stoste after the stirring; By the weight ratio of benzene series thing scavenger stoste and water is to add water at 2: 3, and promptly per 2 kilograms of benzene series thing scavenger stostes add 3 kg water; Adding weight percentage at last is 3 ‰ surfactants of water and benzene series thing scavenger stoste gross mass; Be to add 4 kilograms surfactant in the mixture of per 1000 kg water and benzene series thing scavenger stoste, surfactant described in the present embodiment is a dodecyl sodium sulfate.The particle diameter of said nano titanium oxide is 10~30 nanometers, and the particle diameter of said anion material is 200~300 nanometers.
The problem that exists the benzene series thing to exceed standard behind the finishing of E hotel, the field sampling test result is as shown in table 5.Use the benzene series thing scavenger of present embodiment preparation indoor benzene series thing is removed, be applied in the body surface that produces the benzene series thing according to every square metre 25 gram, test benzene series thing content is as shown in table 5 after 1 day.
Table 5
The benzene series thing | Unit | Standard value | Before the removing | After the removing | Remarks |
Benzene | mg/m 3 | 0.11 | 0.20 | 0.11 | 1 little hourly value |
Toluene | mg/m 3 | 0.20 | 0.24 | 0.19 | 1 little hourly value |
Xylenes | mg/m 3 | 0.20 | 0.27 | 0.20 | 1 little hourly value |
Embodiment 6
With squeezer fig and aloe are squeezed the back respectively and mix or squeeze simultaneously and obtain mixing expressate, the mass ratio of fig and aloe is 1: 1, in the mixing expressate, adds ethanol; Per 1 kilogram is mixed 12 kilograms of ethanol of expressate adding; Stir, filter, filtrating is mixed liquor; In mixed liquor, add mass percentage concentration and be 5% nano titanium oxide suspension and mass percentage concentration and be 40% anion material suspension; Weight ratio between nano titanium oxide suspension, anion material suspension and the mixed liquor three is 4.5: 4.5: 3, promptly gets benzene series thing scavenger stoste after the stirring; By the weight ratio of benzene series thing scavenger stoste and water is to add water at 2: 3, and promptly per 2 kilograms of benzene series thing scavenger stostes add 3 kg water; Adding weight percentage at last is 3.5 ‰ surfactants of water and benzene series thing scavenger stoste gross mass; Be to add 3.5 kilograms surfactant in the mixture of per 1000 kg water and benzene series thing scavenger stoste, surfactant described in the present embodiment is a dodecyl sodium sulfate.The particle diameter of said nano titanium oxide is 10~30 nanometers, and the particle diameter of said anion material is 200~300 nanometers.
The problem that exists the benzene series thing to exceed standard behind the F mansion finishing, the field sampling test result is as shown in table 6.Use the benzene series thing scavenger of present embodiment preparation indoor benzene series thing is removed, be applied in the body surface that produces the benzene series thing according to every square metre 25 gram, test benzene series thing content is as shown in table 6 after 2 days.
Table 6
The benzene series thing | Unit | Standard value | Before the removing | After the removing | Remarks |
Benzene | mg/m 3 | 0.11 | 0.38 | 0.11 | 1 little hourly value |
Toluene | mg/m 3 | 0.20 | 0.32 | 0.19 | 1 little hourly value |
Xylenes | mg/m 3 | 0.20 | 0.40 | 0.18 | 1 little hourly value |
Embodiment 7
Be used for the composition that the benzene series thing is removed, comprise nano titanium oxide, anion material and plant extraction liquid, the mass ratio between nano titanium oxide, anion material and the plant extraction liquid three is (10~22.5): (80~180): (100~300).The particle diameter of said nano titanium oxide is 10~30 nanometers, and the particle diameter of said anion material is 200~300 nanometers.
Be used for the preparation of compositions method that the benzene series thing is removed in the present embodiment, obtain expressate after with squeezer plant being squeezed, in expressate, add ethanol, per 1 kilogram of expressate adds 10~12 kilograms of ethanol, stirs, and filters, and filtrating is plant extraction liquid; In plant extraction liquid, add nano titanium oxide and anion material, stir, promptly get the composition that is used for the removing of benzene series thing.Plant extraction liquid can be the mixed liquor of extract solution from aloe or fig extract or extract solution from aloe and fig extract.
Being used for the composition that the benzene series thing removes and can directly being used for removing the benzene series thing that the finishing back produces of present embodiment is used to remove the benzene series thing after also can diluting, and uses after can also adding surfactant.
Claims (10)
1. be used for the composition that the benzene series thing is removed; It is characterized in that; Comprise nano titanium oxide, anion material and plant extraction liquid, the mass ratio between nano titanium oxide, anion material and the plant extraction liquid three is (10~22.5): (80~180): (100~300).
2. the composition that is used for the removing of benzene series thing according to claim 1 is characterized in that the particle diameter of said nano titanium oxide is 10~30 nanometers.
3. the composition that is used for the removing of benzene series thing according to claim 1 is characterized in that the particle diameter of said anion material is 200~300 nanometers.
4. the arbitrary said preparation of compositions method that the benzene series thing is removed that is used for of claim 1-3; It is characterized in that, obtain expressate after with squeezer plant being squeezed, in expressate, add ethanol; Per 1 kilogram of expressate adds 10~12 kilograms of ethanol; Stir, filter, filtrating is plant extraction liquid; In plant extraction liquid, add nano titanium oxide and anion material; Mass ratio between nano titanium oxide, anion material and the plant extraction liquid three is (10~22.5): (80~180): (100~300); Stir, promptly get the composition that is used for the removing of benzene series thing.
5. benzene series thing scavenger is characterized in that, comprises benzene series thing scavenger stoste and water, and the mass ratio of benzene series thing scavenger stoste and water is 2: 3; Benzene series thing scavenger stoste is that 5% nano titanium oxide suspension, mass percentage concentration are that 40% anion material suspension and plant extraction liquid are formed by mass percentage concentration, and the weight ratio between nano titanium oxide suspension, anion material suspension and the plant extraction liquid three is (2~4.5): (2~4.5): (1~3).
6. benzene series thing scavenger according to claim 5 is characterized in that the weight ratio between nano titanium oxide suspension, anion material suspension and the plant extraction liquid three is 3: 3: 1.5.
7. benzene series thing scavenger according to claim 6 is characterized in that, comprises that also weight percentage is 2~5 ‰ a surfactant of water and benzene series thing scavenger stoste gross mass.
8. benzene series thing scavenger according to claim 7 is characterized in that said surfactant is a dodecyl sodium sulfate.
9. the preparation method of the arbitrary said benzene series thing scavenger of claim 5-8 is characterized in that, obtains expressate after with squeezer plant being squeezed; In expressate, add ethanol, per 1 kilogram of expressate adds 10~12 kilograms of ethanol, stirs; Filter, filtrating is plant extraction liquid; In plant extraction liquid, add mass percentage concentration and be 5% nano titanium oxide suspension and mass percentage concentration and be 40% anion material suspension; Weight ratio between nano titanium oxide suspension, anion material suspension and the plant extraction liquid three is (2~4.5): (2~4.5): (1~3) promptly gets benzene series thing scavenger stoste after the stirring; By the weight ratio of benzene series thing scavenger stoste and water is to add water at 2: 3; Adding weight percentage at last is 2~5 ‰ surfactants of water and benzene series thing scavenger stoste gross mass.
10. preparation method according to claim 9 is characterized in that, plant extraction liquid is the mixed liquor of extract solution from aloe or fig extract or extract solution from aloe and fig extract.
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CN108938508A (en) * | 2018-10-15 | 2018-12-07 | 北京工商大学 | A kind of fig fruit extract and application thereof with sun-proof synergistic effect |
CN114053853A (en) * | 2021-11-22 | 2022-02-18 | 常州市福欧车辆配件有限公司 | Preparation process of benzene series remover for car accessories |
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CN101474419A (en) * | 2008-01-03 | 2009-07-08 | 欧阳林 | Compound catalytic material for purifying harmful gas |
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CN108938508A (en) * | 2018-10-15 | 2018-12-07 | 北京工商大学 | A kind of fig fruit extract and application thereof with sun-proof synergistic effect |
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Application publication date: 20120620 |