CN102499476A - Composite cigarette filter tip containing harm reducing particles as well as preparation method and application method of composite cigarette filter tip - Google Patents
Composite cigarette filter tip containing harm reducing particles as well as preparation method and application method of composite cigarette filter tip Download PDFInfo
- Publication number
- CN102499476A CN102499476A CN2011103432111A CN201110343211A CN102499476A CN 102499476 A CN102499476 A CN 102499476A CN 2011103432111 A CN2011103432111 A CN 2011103432111A CN 201110343211 A CN201110343211 A CN 201110343211A CN 102499476 A CN102499476 A CN 102499476A
- Authority
- CN
- China
- Prior art keywords
- rod
- cigarette
- particle
- composite tip
- tip stick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention discloses a composite cigarette filter tip containing harm reducing particles as well as a preparation method and an application method of the composite cigarette filter tip. According to the invention, inorganic particles including amino acid-loaded active carbon, alumina, silica gel or molecular sieve and the like are added into an ordinary cigarette holder to prepare a particle rod; the particle rod and an ordinary acetate fiber filter rod can be made into a dibasic or polybasic composite filter tip on a composite filter tip molding machine; smoke detecting and testing results indicate that the contents of hydrocyanic acid (HCN) and aldehydes in the mainstream smoke of a cigarette are reduced by more than 20% respectively when the composite cigarette filter tip disclosed by the invention is adopted; and taste of the cigarette is improved to a certain extent.
Description
Technical field
The invention belongs to cigarette producing field, be specifically related to a kind of cigarette harm reduction particle composite tip stick and methods for making and using same thereof.
Background technology
Progress along with social civilization; Healthy and environmental protection becomes the focus that people pay close attention to; In the face of the pressure from government and various circles of society, tobacco business is in order to seek survival, to seek development, and the cigarette manufacturer of various countries adopts the technology of aspects such as chemistry, biology and physics in succession; The comprehensive development of carrying out low tar, low harm cigarette has obtained lot of research.
Hydrogen cyanide (HCN) and volatile carbonyl compound are to mainly contain one of harmful substances in the flue gas, also are one of important environomental pollution sources simultaneously, and it possibly make the people dead, very harmful in several minutes in severe case.Contain group compounds of aldehydes and ketones in the cigarette smoke; Proved that at present the aldoketones pollutant in the atmosphere has the strong impulse effect to people's eyes, skin and respiratory tract; Wherein formaldehyde, methacrylaldehyde have carcinogenesis to animal, and some other aldoketones also has very big harm to human body health.So these two types of nuisances in the necessary reduction flue gas, data shows has a large amount of scientific and technical personnel and mechanism to do related work.
Chinese patent CN101116540A discloses a kind of " being used for reducing the tobacco additive agent of cigarette smoke content of group compounds of aldehydes and ketones ", and it declares to reduce aldoketones material in the flue gas.CN2803014Y discloses a kind of " cigarette copper palladium base remodeling activated carbon fiber composite filter-tip ", can reduce aldehyde material in the flue gas, HCN and other harmful components.But these patented technologies relate to technology than problems such as complicacy or active component securities, are difficult to large-scale industrial production, thereby do not possess application prospect basically.
Chinese patent CN1612699 discloses a kind of " cigarette and cigarette filter "; Declare basic amino acid is injected the aldehyde matter content that cigarette filter can be used for reducing cigarette smoke with aqueous solution form; But there are a lot of problems in this mode: in filter tip, add a large amount of moisture and can make drying consuming time long, be unfavorable for large-scale industrialization production; The level that moisture still allowed far above tobacco business in the filter tip after mediation in 48 hours was dry; This can cause the generation of going mouldy in the cigarette put procedure on the one hand; Add entry on the other hand in the filter tip and be used to fall evil (comprising aldehydes) this is that tobacco business is on record, have adequate cause to think in this patent, not have drying completely moisture in reducing the flue gas aldehyde material, brought into play more important role; Simultaneously in the dry run amino acid can with the generation smell substance that reacts of triacetyl glycerine in the filter tip, this is not allowed to as cigarette additive.Thereby it does not possess using value basically.
The present invention is intended to the deficiency to prior art, and a kind of mouth rod that hydrogen cyanide in the flue gas (HCN) and volatile carbonyl compound is had the additive of cigarette filter stick of removal effect that is added with is provided; This additive amino acid in the preparation process is carried on the carrier and fully reacts to prepare a kind of brand-new additive with it, does not have the problem among the CN1612699; The preparation process of this additive is simple simultaneously, is easy to industrial applications, has application prospect; This additive can also partly improve cigarette odor-absorbing in addition.Therefore, utilize the mouth rod of this additive preparation to have the function of removing hydrogen cyanide in the flue gas (HCN) and volatile aldehyde ketone compounds preferably with the compound composite tip stick that is prepared from of common acetate fiber rod again.
Summary of the invention
The objective of the invention is to deficiency to prior art; A kind of composite tip stick and the methods for making and using same thereof that can better remove hydrogen cyanide in the flue gas (HCN) and volatile aldehyde ketone compounds is provided; Solved the variety of problems that can not realize industrialized production in the prior art simultaneously; As: moisture can make dry time consumption and energy consumption; The level that still allows far above tobacco business, cause in the cigarette put procedure generations of going mouldy, simultaneously in the dry run amino acid can with the generation smell substance or the like that react of triacetyl glycerine in the filter tip.。
The present invention realizes through following manner:
A kind of cigarette harm reduction particle composite tip stick is that the particle rod is combined into binary or polynary composite tip stick with common acetate fiber rod; Described particle rod is the particle rod that load is had amino acid whose inorganic carrier uniform particles to make an addition to be prepared in the regular-size cigarette mouth rod.
Described inorganic carrier particle is meant silica gel, active carbon, aluminium oxide or molecular sieve; Described amino acid is meant glycine, alanine, valine, leucine, isoleucine, phenylalanine, proline; Tryptophan, tyrosine, serine, cysteine, methionine, asparagine, glutamine, threonine; Aspartic acid, glutamic acid, one or more in lysine, arginine, the histidine.
Described inorganic carrier granularity size is the 10-100 order, preferred 40-60 order.
It is 2.5mg/mm-6.0mg/mm that described load has the addition of amino acid whose inorganic carrier particle in regular-size cigarette mouth rod.
Described regular-size cigarette mouth rod is meant acetate fiber mouth rod or polypropylene fibre mouth rod.
Described particle rod is meant that with binary or polynary composite tip stick that common acetate fiber rod is combined into the particle rod is alternately compound with common acetate fiber rod, guarantee simultaneously, with the lip end in contact be that common acetate fiber is excellent.
The preparation method of described cigarette harm reduction particle composite tip stick soaks Freamine and inorganic carrier equal-volume 5 minutes-5 hours, and described Freamine mass concentration is 0.1%-20%; Dried 3-24 hour for 80 ℃-180 ℃, getting load has amino acid whose inorganic carrier particle, makes an addition to then in the regular-size cigarette mouth rod and is prepared into the particle rod; The particle rod is combined into binary or polynary composite tip stick with common acetate fiber rod again.
Described cigarette harm reduction particle composite tip stick is used for reducing cigarette smoke hydrogen cyanide and volatility content of group compounds of aldehydes and ketones.
The present invention compared with prior art, its maximum characteristics are that particulate additive safety non-toxic and preparation technology are simple, are fit to large-scale industrial production; Particle adding technology technology and compound bar technology of preparing are ripe, can realize suitability for industrialized production very soon; Composite tip stick provided by the invention has the function of removing hydrogen cyanide (HCN) and volatile aldehyde ketone compounds in the flue gas, and cigarette odor-absorbing had to a certain degree improves.
Description of drawings
Fig. 1 is the cigarette structural representation of the band binary composite tip stick of the present invention of amplification;
Fig. 2 is the cigarette structural representation of the band ternary composite tip stick of the present invention of amplification;
Fig. 3 is the cigarette structural representation of the band quaternary composite tip stick of the present invention of amplification;
Among the figure: 1 is common acetate fiber section, and 2 for being added with the particle rod section of the amino acid whose inorganic carrier particle of load, and 3 is the pipe tobacco section.
The specific embodiment
Following examples are intended to explain the present invention rather than the present invention are further limited.
By weight percentage, serine 6%, cysteine 8%, distilled water 86% are mixed with and fall harmful auxiliary agent; With the back oven dry of 30-70 molecules of interest sieve dipping, cooling is prepared into the harm reduction particle naturally; In 700 milligrams every mouth rod diacetate fiber, add 300 milligrams harm reduction particle, roll into 120 millimeters proboscis rods of band particle again through the mouth rod forming machine; Compound on mouth rod compounding machine with the fine mouth rod of common vinegar, it is long to prepare the particle rod: the compound bar of the fine rod long=15: 10 of pure vinegar, with behind the white sand of this harm reduction composite filter tip cigarette Changsha Cigarette Factory (red with) cigarette (Fig. 1); Through detecting, the content of hydrogen cyanide contrasts cigarette reduction by 26.2% in the main flume, and formaldehyde reduces by 47.3%; Acetaldehyde reduces by 35.0%; Crotonaldehyde reduces by 25.2%, and cigarette is smoked panel test through the expert, and cigarette odor-absorbing is softer.
Table one composite filter tip of the present invention is to the removing effect of cigarette smoke hydrogen cyanide and volatile aldehyde ketone compounds
By weight percentage, lysine 12%, distilled water 88% are mixed with and fall harmful auxiliary agent; With the back oven dry of 40-60 purpose silica gel dipping, cooling is prepared into the harm reduction particle naturally; In 700 milligrams every mouth rod diacetate fiber, add 450 milligrams harm reduction particle, roll into 120 millimeters proboscis rods of band particle again through the mouth rod forming machine; Compound on mouth rod compounding machine with the fine mouth rod of common vinegar, it is long to prepare the fine rod of pure vinegar: the particle rod is long: the fine rod long=10 of pure vinegar: 10: 5 compound bar, with behind white sand (two generations of the elaboration) cigarette of this harm reduction composite filter tip cigarette Changsha Cigarette Factory (Fig. 2); Through detecting, the content of hydrogen cyanide contrasts cigarette reduction by 28.3% in the main flume, and formaldehyde reduces by 39.5%; Acetaldehyde reduces by 38.7%, and crotonaldehyde reduces by 28.2%, and cigarette is smoked panel test through the expert; Cigarette flavor is fuller, and the flue gas conglobation property is better.
Table two composite filter tip of the present invention is to the removing effect of cigarette smoke hydrogen cyanide and volatile aldehyde ketone compounds
By weight percentage, arginine 15%, distilled water 85% are mixed with and fall harmful auxiliary agent; With the back oven dry of 40-60 purpose silica gel dipping, cooling is prepared into the harm reduction particle naturally; In 700 milligrams every mouth rod diacetate fiber, add 250 milligrams harm reduction particle, roll into 120 millimeters proboscis rods of band particle again through the mouth rod forming machine; Compound on mouth rod compounding machine with the fine mouth rod of common vinegar, it is long to prepare the fine rod of pure vinegar: the particle rod is long: the fine rod of pure vinegar is long: particle rod long=10: 5: 5: 10 compound bar, with behind white sand (Shang Pinbai) cigarette of this harm reduction composite filter tip cigarette Changsha Cigarette Factory (Fig. 3); Through detecting, the content of hydrogen cyanide contrasts cigarette reduction by 35% in the main flume, and formaldehyde reduces by 52%; Acetaldehyde reduces by 38%, and crotonaldehyde reduces by 28%, and cigarette is smoked panel test through the expert; Cigarette flavor is fuller, and the flue gas conglobation property is better.
Table three composite filter tip of the present invention is to the removing effect of cigarette smoke hydrogen cyanide and volatile aldehyde ketone compounds
Claims (8)
1. a cigarette harm reduction particle composite tip stick is characterized in that, is that the particle rod is combined into binary or polynary composite tip stick with common acetate fiber rod; Described particle rod is the particle rod that load is had amino acid whose inorganic carrier uniform particles to make an addition to be prepared in the regular-size cigarette mouth rod.
2. cigarette harm reduction particle composite tip stick according to claim 1 is characterized in that described inorganic carrier particle is meant silica gel, active carbon, aluminium oxide or molecular sieve; Described amino acid is meant glycine, alanine, valine, leucine, isoleucine, phenylalanine, proline; Tryptophan, tyrosine, serine, cysteine, methionine, asparagine, glutamine, threonine; Aspartic acid, glutamic acid, one or more in lysine, arginine, the histidine.
3. cigarette harm reduction particle composite tip stick according to claim 2 is characterized in that, described inorganic carrier granularity size is the 10-100 order.
4. cigarette harm reduction particle composite tip stick according to claim 1 is characterized in that it is 2.5mg/mm-6.0mg/mm that described load has the addition of amino acid whose inorganic carrier particle in regular-size cigarette mouth rod.
5. cigarette harm reduction particle composite tip stick according to claim 1 is characterized in that, described regular-size cigarette mouth rod is meant acetate fiber mouth rod or polypropylene fibre mouth rod.
6. cigarette harm reduction particle composite tip stick according to claim 1; It is characterized in that; Described particle rod is meant that with binary or polynary composite tip stick that common acetate fiber rod is combined into the particle rod is alternately compound with common acetate fiber rod, simultaneously, with the lip end in contact be that common acetate fiber is excellent.
7. the preparation method of any described cigarette harm reduction particle composite tip stick of claim 1-6 is characterized in that, Freamine and inorganic carrier equal-volume were soaked 5 minutes-5 hours, and described Freamine mass concentration is 0.1%-20%; Dried 3-24 hour for 80 ℃-180 ℃, getting load has amino acid whose inorganic carrier particle, makes an addition to then in the regular-size cigarette mouth rod and is prepared into the particle rod; The particle rod is combined into binary or polynary composite tip stick with common acetate fiber rod again.
8. the application process of any described cigarette harm reduction particle composite tip stick of claim 1-6 is characterized in that this composite tip stick is used for reducing cigarette smoke hydrogen cyanide and volatility content of group compounds of aldehydes and ketones.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103432111A CN102499476A (en) | 2011-11-03 | 2011-11-03 | Composite cigarette filter tip containing harm reducing particles as well as preparation method and application method of composite cigarette filter tip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103432111A CN102499476A (en) | 2011-11-03 | 2011-11-03 | Composite cigarette filter tip containing harm reducing particles as well as preparation method and application method of composite cigarette filter tip |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102499476A true CN102499476A (en) | 2012-06-20 |
Family
ID=46211658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103432111A Pending CN102499476A (en) | 2011-11-03 | 2011-11-03 | Composite cigarette filter tip containing harm reducing particles as well as preparation method and application method of composite cigarette filter tip |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102499476A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102920020A (en) * | 2012-11-16 | 2013-02-13 | 湖南中烟工业有限责任公司 | Glucosamine loaded cigarette filter stick additive, as well as preparation and application methods thereof |
| CN102920019A (en) * | 2012-11-16 | 2013-02-13 | 湖南中烟工业有限责任公司 | Cigarette filter stick additive capable of reducing harm, as well as preparation and application methods of same |
| CN105996123A (en) * | 2016-05-27 | 2016-10-12 | 阜阳卷烟材料厂 | Cigarette filter stick for reducing release quantity of crotonaldehyde in smoke gas |
| CN110833211A (en) * | 2019-11-21 | 2020-02-25 | 四川中烟工业有限责任公司 | Binary composite filter stick for reducing heavy metal release amount of main stream smoke of cigarette |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1612699A (en) * | 2002-01-08 | 2005-05-04 | 日本烟草产业株式会社 | Cigarette and cigarette filter |
| CN101116540A (en) * | 2007-08-21 | 2008-02-06 | 中国烟草总公司郑州烟草研究院 | Tobacco additive agent for reducing the content of group compounds of aldehydes and ketones in the cigarette smoke and method for preparing the same and application thereof |
| CN101194755A (en) * | 2007-12-21 | 2008-06-11 | 湖南中烟工业有限责任公司 | Additive agent selectively reducing aldehydes matter in cigarette flue gas, production method and application thereof |
| CN102029146A (en) * | 2010-11-14 | 2011-04-27 | 中国烟草总公司郑州烟草研究院 | Water retaining material, preparation method thereof and application of water retaining material in filter rod |
| CN102038286A (en) * | 2010-12-02 | 2011-05-04 | 湖南中烟工业有限责任公司 | Toxin-reducing cigarette additive and preparation method and use thereof |
-
2011
- 2011-11-03 CN CN2011103432111A patent/CN102499476A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1612699A (en) * | 2002-01-08 | 2005-05-04 | 日本烟草产业株式会社 | Cigarette and cigarette filter |
| CN101116540A (en) * | 2007-08-21 | 2008-02-06 | 中国烟草总公司郑州烟草研究院 | Tobacco additive agent for reducing the content of group compounds of aldehydes and ketones in the cigarette smoke and method for preparing the same and application thereof |
| CN101194755A (en) * | 2007-12-21 | 2008-06-11 | 湖南中烟工业有限责任公司 | Additive agent selectively reducing aldehydes matter in cigarette flue gas, production method and application thereof |
| CN102029146A (en) * | 2010-11-14 | 2011-04-27 | 中国烟草总公司郑州烟草研究院 | Water retaining material, preparation method thereof and application of water retaining material in filter rod |
| CN102038286A (en) * | 2010-12-02 | 2011-05-04 | 湖南中烟工业有限责任公司 | Toxin-reducing cigarette additive and preparation method and use thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102920020A (en) * | 2012-11-16 | 2013-02-13 | 湖南中烟工业有限责任公司 | Glucosamine loaded cigarette filter stick additive, as well as preparation and application methods thereof |
| CN102920019A (en) * | 2012-11-16 | 2013-02-13 | 湖南中烟工业有限责任公司 | Cigarette filter stick additive capable of reducing harm, as well as preparation and application methods of same |
| CN102920019B (en) * | 2012-11-16 | 2014-04-16 | 湖南中烟工业有限责任公司 | Application methods of cigarette filter stick additive capable of reducing harm |
| CN105996123A (en) * | 2016-05-27 | 2016-10-12 | 阜阳卷烟材料厂 | Cigarette filter stick for reducing release quantity of crotonaldehyde in smoke gas |
| CN110833211A (en) * | 2019-11-21 | 2020-02-25 | 四川中烟工业有限责任公司 | Binary composite filter stick for reducing heavy metal release amount of main stream smoke of cigarette |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102177137B1 (en) | Graphene adsorbent, its manufacturing method and use, and cigarette filter tips and tobacco | |
| CN102499476A (en) | Composite cigarette filter tip containing harm reducing particles as well as preparation method and application method of composite cigarette filter tip | |
| CN102715655B (en) | Cigarette filter stick capable of reducing phenol and crotonaldehyde ingredients in cigarette smoke | |
| CN102499477B (en) | Additive with harm reducing function for cigarette filter tip as well as preparation method and application method of additive | |
| CN102793270A (en) | Cigarette filter rod capable of reducing content of volatile carbonyl compounds in cigarette smoke and preparation method of cigarette filter rod | |
| CN102038286A (en) | Toxin-reducing cigarette additive and preparation method and use thereof | |
| CN101015394B (en) | Filter tip capable of eliminating nitrite amine and phenols in cigarette fume and its making process | |
| CN102697182B (en) | Preparation method of filter nozzle additive for lowering ammonia in smoke of cigarette and application thereof | |
| CN102517981B (en) | Cellulose paper capable of reducing content of hydrocyanic acid or volatile carbonyl compound in cigarette smoke and preparation and application thereof | |
| CN102806067A (en) | Water-retaining modified active carbon material and preparation method thereof | |
| CN104116133A (en) | Application of polymers rich in amino groups in paper filter stick | |
| CN209284314U (en) | A kind of binary compound filter candle reducing CO in cigarette mainstream flue gas | |
| CN102719923A (en) | Production method of bamboo coal cellulose diacetate tow | |
| CN102771893B (en) | Tip rod adopting chitosan fiber beams as filter materials and preparation method of tip rod | |
| CN101574536A (en) | Glucoside-containing composition, preparation method thereof and use thereof | |
| CN104432507B (en) | Cigarette filter-tip additive agent of aldehyde material and its preparation method and application in a kind of removable cigarette mainstream flue gas | |
| CN102499479A (en) | Complex adsorbent capable of reducing release amount of heavy metals in mainstream smoke of cigarettes, preparation method for complex adsorbent and application of complex adsorbent | |
| CN204812019U (en) | Novel compound cigarette filter of graphite alkene | |
| CN203226264U (en) | Binary composite cigarette filter rod of different hardnesses | |
| CN103252213B (en) | Active carbon with microporous-mesoporous structure | |
| CN102697179A (en) | Cigarette filter stick additive with harm-reducing effect and preparation and application method thereof | |
| CN202456393U (en) | Ternary composite filter rod containing porous starch granules | |
| CN102524956B (en) | Application of alginate fiber in cigarette filter rod | |
| CN102524960B (en) | A kind of preparation method of harm reduction cigarette filter | |
| CN103736490B (en) | The Catalysts and its preparation method of hydrogen cyanide burst size in selectivity reducing cigarette main flume based on nickel oxide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120620 |